Safety data sheet according to 1907/2006/EC, Article 31

Transcription

1 Page 1/9 * 1 Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Article number: UK Relevant identified uses of the substance or mixture and uses advised against Sector of Use SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites SU22 Professional uses: Public domain (administration, education, entertainment, services, craftsmen) Application of the substance / the preparation Degreaser 1.3 Details of the supplier of the safety data sheet Manufacturer/Supplier: ZEP UK; Forward Chemicals Limited P.O. Box 12 Tanhouse Lane Widnes Cheshire WA8 salesandservice@forwardchem.com Tel: Fax: ZEP Industries BV Vierlinghweg PN Bergen op Zoom The Netherlands Tel: (NL) (B) Fax:(NL) (B) sales@zepbenelux.com ZEP Italy s.r.l. Via Netunese Km IT Aprilia (LT) Tel: Fax: info@zepitalia.it Sito: Further information obtainable from: Customer Service NL: Tel: Fax: B: Tel: Fax: IT: Tel: Fax: UK: Tel: Fax: Emergency telephone number: Customer Service NL: Tel: Fax: B: Tel: Fax: IT: Tel: Fax: UK: Tel: Fax: * 2 Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS08 health hazard Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. (Contd. on page 2)

2 Page 2/9 (Contd. of page 1) GHS07 Eye Irrit. 2 H319 Causes serious eye irritation. Skin Sens. 1 H317 May cause an allergic skin reaction. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Sensitising R43: May cause sensitisation by skin contact. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. Hazard pictograms GHS08 GHS09 Signal word Danger Hazard-determining components of labelling: (R)-p-mentha-1,8-diene 豆油 Hazard statements H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Precautionary statements P285 In case of inadequate ventilation wear respiratory protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 2.3 Other hazards The product does not contain any organic halogen compounds (AOX), nitrates, heavy metal compounds. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 3 Composition/information on ingredients 3.2 Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. (Contd. on page 3)

3 Page 3/9 Dangerous components: CAS: EINECS: Reg.nr.: CAS: EINECS: CAS: EINECS: Reg.nr.: CAS: CAS: Polymer CAS: EINECS: (R)-p-mentha-1,8-diene Xn R65 Xi R38 Xi R43 N R50/53 R10 Flam. Liq. 3, H226 Asp. Tox. 1, H304 Aquatic Acute 1, H400; Aquatic Chronic 1, H410 Skin Irrit. 2, H315; Skin Sens. 1, H317 豆油 Xn R42 Resp. Sens. 1, H334 Coconut diethanolamide based on coconut fatty acid. Xi R38-41 Eye Dam. 1, H318 Skin Irrit. 2, H315 Alcohol ethoxylate C12 - C mol EO Xi R41 N R50 Eye Dam. 1, H318 Aquatic Acute 1, H400 Acute Tox. 4, H312 Alcohol ethoxylate C12 - C mol EO Xi R41 N R50 Eye Dam. 1, H318 Aquatic Acute 1, H400 Acute Tox. 4, H312 dodecyldimethylamine oxide Xn R22 Xi R36/38 N R50 Aquatic Acute 1, H400 Skin Irrit. 2, H315; Eye Irrit. 2, H319 (Contd. of page 2) 5-10% 1-5% 1-5% 0.1-1% 0.1-1% 0.1-1% Additional information; Ingrediënts according to detergents guideline EEC 89/542: For the wording of the listed risk phrases refer to section 16. perfumes (LIMONENE) 5-15% non-ionic surfactants, cationic surfactants, preservation agents, colouring agents < 5% * 4 First aid measures 4.1 Description of first aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. No special measures required. After skin contact: If skin irritation continues, consult a doctor. Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: If symptoms persist consult doctor. 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available. 4.3 Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures 5.1 Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. 5.2 Special hazards arising from the substance or mixture No further relevant information available. (Contd. on page 4)

4 Page 4/9 5.3 Advice for firefighters Protective equipment: No special measures required. (Contd. of page 3) * 6 Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Not required. 6.2 Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. 6.3 Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). 6.4 Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage 7.1 Precautions for safe handling No special measures required. Information about fire - and explosion protection: No special measures required. 7.2 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: None. 7.3 Specific end use(s) No further relevant information available. * 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. DNELs (R)-p-mentha-1,8-diene Oral DNEL acute-systemic 4.76 mg/kg human/day (consumer) Inhalative DNEL Acute-systemic mg/m mg/m3 (worker) Additional information: The lists valid during the making were used as basis. 8.2 Exposure controls Personal protective equipment: General protective and hygienic measures: Immediately remove all soiled and contaminated clothing Respiratory protection: Not required. Protection of hands: Generally the product does not irritate the skin. Protective gloves Material of gloves Not required. Penetration time of glove material Not required. The determined penetration times according to EN 374 part III are not performed under practical conditions. Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended. Not suitable are gloves made of the following materials: Strong material gloves Eye protection: Goggles recommended during refilling (Contd. on page 5)

5 Page 5/9 (Contd. of page 4) * 9 Physical and chemical properties 9.1 Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Characteristic Odour threshold: Not determined. ph-value at 20 C: 7.4 Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C Flash point: Not applicable. Flammability (solid, gaseous): Not applicable. Ignition temperature: 255 C Decomposition temperature: Not determined. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Explosion limits: Lower: Upper: Vapour pressure at 20 C: 23 hpa Not determined. Not determined. Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibility with water: Insoluble. Partition coefficient (n-octanol/water): Not determined. Viscosity: Dynamic: Not determined. Kinematic at 20 C: 10 s (DIN 53211/4) Solvent content: Organic solvents: 8.6 % Solids content: 7.9 % 9.2 Other information No further relevant information available. * 10 Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications Possibility of hazardous reactions No dangerous reactions known Conditions to avoid No further relevant information available Incompatible materials: No further relevant information available Hazardous decomposition products: No dangerous decomposition products known. * 11 Toxicological information 11.1 Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: (R)-p-mentha-1,8-diene Oral LD mg/kg (Rat) (Contd. on page 6)

6 Page 6/9 (Contd. of page 5) Dermal LD50 >5000 mg/kg (Rat) >2000 mg/kg (Rabbit) EC mg/ltr (Daphnia magna (water flea)) 豆油 Oral LD mg/kg (Mouse) INTRAVENOUS mg/kg (Rat) INTRAVENOUS Coconut diethanolamide based on coconut fatty acid. Oral LD mg/kg (Rat) Fatty acids, soya, Me esters Oral LD50 >2000 mg/kg (Rat) Alcohol ethoxylate C12 - C mol EO Dermal LD mg/kg (Rat) Alcohol ethoxylate C12 - C mol EO Dermal LD mg/kg (Rat) dodecyldimethylamine oxide Oral LD mg/kg (Rat) ,6-di-tert-butyl-p-cresol Oral LD mg/kg (Rat) glutaral Oral LD mg/kg (Rat) Dermal LD50 >2000 mg/kg (Rat) Inhalative LC50 / 4 h mg/ltr (Rat) EC 50 / 48 h (static) 5.75 mg/ltr (Daphnia magna (water flea)) EC 50 / 72 H 0.92 (Skeletonema costatum) mg/l 0.6 (Desmodesmus subspicatus) mg/l EC 50 / 96 h (dynamic) 0.75 mg/ltr (Crassotrea virginica) LC50 / 96 h (static) 9.4 mg/ltr (Lepomis Macrochirus) 39 mg/ltr (Cyprinodon Variegatus) 5.5 mg/ltr (Mysidopsis bahia) sodium 4-[(2-hydroxy-1-naphthyl)azo]benzenesulphonate Oral LD mg/kg (Rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant * 12 Ecological information 12.1 Toxicity Aquatic toxicity: (R)-p-mentha-1,8-diene OECD test 301 D >92 (biodegradation in % after 28 days) glutaral BOD 235 (mg O2 / g product) mg/g COD 1385 (mg O2 / g product) mg/g (Contd. on page 7)

7 Page 7/9 (Contd. of page 6) OECD test 301 A (biodegradation in % after 28 days) 12.2 Persistence and degradability No further relevant information available. Other information: The product is biodegradable Bioaccumulative potential No further relevant information available Mobility in soil No further relevant information available. Ecotoxical effects: Remark: Toxic for fish Additional ecological information: General notes: Water danger class 3 (German Regulation) (Self-assessment): extremely hazardous for water Do not allow product to reach ground water, water course or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. The material is harmful to the environment. In accordance with the requirements of the RVO in the Act on Detergents and Cleansing Agents, tensides are biodegradable up to at least 90 %. Toxic for aquatic organisms 12.5 Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable Other adverse effects No further relevant information available. 13 Disposal considerations 13.1 Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * 14 Transport information 14.1 UN-Number ADR, ADN, IMDG, IATA Void 14.2 UN proper shipping name ADR Void ADN, IMDG, IATA Void 14.3 Transport hazard class(es) ADR, ADN, IMDG, IATA Class Void 14.4 Packing group ADR, IMDG, IATA Void 14.5 Environmental hazards: Marine pollutant: No 14.6 Special precautions for user Not applicable Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. UN "Model Regulation": - * 15 Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. (Contd. on page 8)

8 Page 8/9 Hazard pictograms (Contd. of page 7) GHS08 GHS09 Signal word Danger Hazard-determining components of labelling: (R)-p-mentha-1,8-diene 豆油 Hazard statements H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H317 May cause an allergic skin reaction. H411 Toxic to aquatic life with long lasting effects. Precautionary statements P285 In case of inadequate ventilation wear respiratory protection. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P501 Dispose of contents/container in accordance with local/regional/national/international regulations. National regulations: Technical instructions (air): Class Share in % NK 5-10 Waterhazard class: Water danger class 3 (Self-assessment): extremely hazardous for water Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. R10 Flammable. R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R41 Risk of serious damage to eyes. R42 May cause sensitisation by inhalation. R43 May cause sensitisation by skin contact. R50 Very toxic to aquatic organisms. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. Department issuing MSDS: (Contd. on page 9)

9 Page 9/9 (Contd. of page 8) Customer Service NL: Tel: Fax: B: Tel: Fax: IT: Tel: Fax: UK: Tel: Fax: Contact: Customer Service NL: Tel: Fax: B: Tel: Fax: IT: Tel: Fax: UK: Tel: Fax: Abbreviations and acronyms: RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) ICAO: International Civil Aviation Organization ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals DNEL: Derived No-Effect Level (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent * Data compared to the previous version altered.