EPOXY DAMP PROOF MEMBRANE RESIN 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION & OF THE COMPANY UNDERTAKING

Transcription

1 EPOXY DAMP PROOF MEMBRANE RESIN SDS 192 ISSUE 2 DECEMBER IDENTIFICATION OF THE SUBSTANCE/PREPARATION & OF THE COMPANY UNDERTAKING A Product Name Epoxy Damp Proof Membrane Resin B Supplier Sovereign Chemicals Limited Park Road Barrow-in-Furness Cumbria. LA14 4EQ C. Emergency Tel. No Office hours Out of hours D. Appearance Blue Liquid E. Odour Slight 2. HAZARDS IDENTIFICATION May cause sensitisation by skin contact. Irritating to eyes and skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 3. COMPOSITION/INFORMATION ON INGREDIENTS Key to proportions High %, Med 11-60%, Low 1-10%, Very Low <1% Key to identification: A = Chip Index No. B = EC No. C = CAS No. Component Classification R-Phrases Proportions Exposure Levels (8hr TWA) Identification BISPHENOL TYPE F EPOXY RESIN Xi; R36/38 N; R51/53 R43. C13/15 ALKYLGLYCIDYL ETHER Xi; R36/38 N; R51/53 R43. MED NOT ASSIGNED (C) LOW NOT ASSIGNED (C) EPOXY RESIN (No. ave. MW <= 700 ) R43 Xi; R36/38 N; R51/53 MED NOT ASSIGNED (C) OXIRANE, MONO [(C ALKYLOXY) METHYL] DERIVS R43 Xi; R38 LOW NOT ASSIGNED (C) 4. FIRST AID MEASURES SKIN: INGESTION: INHALATION: Immediately rinse with water. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. Rinse mouth thoroughly. Drink plenty of water. Do not induce vomiting. Get medical attention immediately. Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Medical Practitioners may obtain further information from the National Poisons Information Centre. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Extinguish with foam, carbon dioxide or dry powder. Do not use water jet as an extinguisher, as this will spread the fire. 1 of 4

2 EPOXY DAMP PROOF MEMBRANE RESIN SDS 192 ISSUE 2 DECEMBER 2007 SPECIFIC HAZARDS PROTECTIVE MEASURES Toxic gases/vapours/fumes of Carbon monoxide (CO). Carbon dioxide (CO2). Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Avoid contact with skin and eyes. Provide adequate ventilation. Use protective gloves, goggles and suitable protective clothing. ENVIRONMENTAL PRECAUTIONS Do not allow to enter drains, sewers or watercourses. Avoid discharge onto the ground. Contain spillages with sand, earth or any suitable absorbent material. SPILL CLEAN UP METHODS Collect spillage in containers, seal securely and deliver for disposal as hazardous waste. Spillages into waterways must be reported to the Environmental Agency Incident Report Line (Tel: Freephone ). 7. HANDLING AND STORAGE USAGE PRECAUTIONS: STORAGE PRECAUTIONS: Provide good ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Do not eat, drink or smoke when using the product. Keep separate from food, feedstuffs, fertilisers and other sensitive material. Store in closed original container at temperatures between 5 C and 25 C. Store in a cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If risk of splashing, wear safety goggles or face shield. HANDS, FACE, BODY: RESPIRATORY: Wear suitable protective clothing as protection against splashing or contamination. Protective gloves must be used if there is a risk of direct contact or splash. If ventilation is inadequate, wear respirator fitted with organic vapour filters (see HSE Guidance Booklet HS(G) 53 - Respiratory Protective Equipment - A Practical Guide to Users ). Provide adequate general or local exhaust ventilation. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: Liquid COLOUR: Blue ODOUR: Slight odour SPECIFIC GRAVITY: VOLATILITY: N/A FLASH POINT O C: N/A VISCOSITY: degc AUTO-IGNITION TEMP O C: N/A FLASH POINT METHOD: N/A 10. STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID: Stable under normal temperature conditions. Considerable exothermic reaction can occur when mixed with 2 of 4

3 EPOXY DAMP PROOF MEMBRANE RESIN SDS 192 ISSUE 2 DECEMBER 2007 MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS epoxide hardeners. Strong acids. Strong alkalis. Strong oxidising substances. During fire, toxic gases (CO, CO2) are formed. 11 TOXICOLOGICAL INFORMATION INHALATION INGESTION: SKIN: May cause irritation to the respiratory system. Liquid irritates mucous membranes and may cause abdominal pain if swallowed. Irritating to skin. May cause sensitisation by skin contact. Irritating and may cause redness and pain. 12. ECOLOGICAL INFORMATION The product contains substances which are toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment. Do not allow to reach ground water, water courses or sewage system 13. DISPOSAL CONSIDERATIONS Small quantities of product may be treated with an equivalent quantity of product hardener, allowed to cure and disposed of as low hazard waste. Larger quantities should be disposed of as hazardous waste via a licensed waste operator. Product containers must not be re-used without commercial cleaning. Dispose of as special waste in accordance with Local Authority Regulations. Use only licensed waste hauliers and disposal contractors. 14. TRANSPORT INFORMATION UK ROAD CLASS 9 PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (EPOXY RESIN (Number average MW <= 700 ), BISPHENOL TYPE F EPOXY RESIN) UN NO. ROAD 3082 UK ROAD PACK GR. III ADR CLASS NO. 9 ADR CLASS Class 9: Miscellaneous dangerous substances and articles. ADR PACK GROUP III ADR LABEL NO. 9 HAZCHEM CODE 2X CEFIC TEC(R) NO. 90GM6-III RID CLASS NO. 9 RID PACK GROUP III UN NO. SEA 3082 IMDG CLASS 9 IMDG PAGE NO. 9 IMDG PACK GR. III EMS FA - SF MFAG See Guide MARINE POLLUTANT No. ICAO CLASS 9 AIR PACK GROUP III UN NO of 4

4 EPOXY DAMP PROOF MEMBRANE RESIN SDS 192 ISSUE 2 DECEMBER REGULATORY INFORMATION IRRITANT DANGEROUS FOR THE ENVIRONMENT CONTAINS: BISPHENOL TYPE F EPOXY RESIN C13/15 ALKYLGLYCIDYL ETHEREPOXY RESIN (Number average MW <= 700 ) OXIRANE, MONO [(C ALKYLOXY)METHYL] DERIVS RISK PHRASES: R36/38 Irritating to eyes and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. SAFETY PHRASES: S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. P5 Contains epoxy constituents. See information supplied by the manufacturer. 16. OTHER INFORMATION EH40 Occupational Exposure Limits. Control Of Substances Hazardous To Health Regulations. HS(G)97 A Step by Step Guide to C.O.S.H.H. Assessment. Approved Carriage and Supply Lists. The Chemicals (Hazards, Identification, Packaging) Regulations Risk Phrases used in Section 2 R36/38 Irritating to eyes and skin. R38 Irritating to skin. R43. May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 4 of 4

5 EPOXY DAMP PROOF MEMBRANE HARDENER SDS 193 ISSUE 4 MARCH IDENTIFICATION OF THE SUBSTANCE/PREPARATION & OF THE COMPANY/UNDERTAKING A Product Name Epoxy Damp Proof Membrane Hardener B Supplier Sovereign Chemicals Limited Park Road Barrow-in-Furness Cumbria. LA14 4EQ C. Emergency Tel. No Office hours Out of hours msds@sovchem.co.uk D. Appearance Amber Liquid E. Odour Slight Ammonia 2. HAZARDS IDENTIFICATION Harmful by inhalation and if swallowed. Causes burns. May cause sensitisation by skin contact. CLASSIFICATION Xn;R20/22. C;R34. R43. ENVIRONMENT Not established. Product should not be released to ground or surface waters untreated. HUMAN HEALTH The product contains a sensitising substance which may provoke an allergic reaction among sensitive individuals. This product can cause burns, 3. COMPOSITION/INFORMATION ON INGREDIENTS Key to proportions High %, Med 11-60%, Low 1-10%, Very Low <1% Key to identification: A = Chip Index No. B = EC No. C = CAS No. Component Classification R-Phrases Proportions Exposure Levels (8hr TWA) Identification 2,4,6-TRIS(DIMETHYLAMINOMETHYL) PHENOL Xn R22 Xi R36/38 MED NOT ASSIGNED (C) 3-AMINOMETHYL-3, 5, 5 - TRIMETHYLCYCLOHEXYLAMINE 3-AMINOPROPYLDIMETHYLAMINE Xn;R21/22. C;R34. R43,R52/53 R10 C;R34 Xn;R22 R43 LOW NOT ASSIGNED (C) LOW NOT ASSIGNED (C) BENZYL ALCOHOL Xn R20/22 MED NOT ASSIGNED (C) BIS(DIMETHYLAMINOMETHYL)PHENOL C;R34 LOW NOT ASSIGNED (C) BISPHENOL A EPOXY RESIN Repr. Cat. 3; R62. Xi; R37,R41, R52 LOW NOT ASSIGNED (C) M-PHENYLENEBIS(METHYLAMINE) Xn;R20/22. C;R34. R43,R52/53. LOW NOT ASSIGNED (C) The Full Text for all R-Phrases are Displayed in Section 16 COMPOSITION COMMENTS Amine curing agent 1 of 4

6 EPOXY DAMP PROOF MEMBRANE HARDENER SDS 193 ISSUE 4 MARCH FIRST AID MEASURES Immediately rinse with water. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. SKIN: Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention if irritation persists after washing. INGESTION: Rinse mouth thoroughly. Drink plenty of water. Do not induce vomiting. Get medical attention immediately! INHALATION: Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Medical Practitioners may obtain further information from the National Poisons Information Centre. 5. FIRE FIGHTING MEASURES EXTINGUISHING MEDIA SPECIFIC HAZARDS PROTECTIVE MEASURES Extinguish with foam, carbon dioxide or dry powder. Do not use water jet as an extinguisher, as this will spread the fire. Toxic gases/vapours/fumes of Oxides of Carbon and Nitrogen Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6. ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS ENVIRONMENTAL PRECAUTIONS SPILL CLEAN UP METHODS Avoid contact with skin and eyes. Provide adequate ventilation. Use protective gloves, goggles and suitable protective clothing. Do not allow to enter drains, sewers or watercourses. Avoid discharge onto the ground. Contain spillages with sand, earth or any suitable absorbent material. Collect spillage in containers, seal securely and deliver for disposal as hazardous waste. Spillages into waterways must be reported to the Environmental Agency Incident Report Line (Tel: Freephone ). 7. HANDLING AND STORAGE USAGE PRECAUTIONS: STORAGE PRECAUTIONS: Provide good ventilation. Avoid contact with skin and eyes. Observe good industrial hygiene practices. Do not eat, drink or smoke when using the product. Keep separate from food, feedstuffs, fertilisers and other sensitive material. Store in closed original container at temperatures between 5 C and 30 C. Store in a cool and well-ventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If there is a risk of splashing, wear chemical resistant goggles or visor approved to BS EN166. HANDS, FACE, BODY: RESPIRATORY: Wear suitable protective clothing as protection against splashing or contamination. Protective gloves should be used if there is a risk of direct contact or splash. Nitrile gloves to BSEN374 are recommended. Break through times can vary depending on thickness, use and source. Change gloves regularly. If ventilation is inadequate, wear respirator fitted with organic vapour filters (see HSE Guidance Booklet HS(G) 53 - Respiratory Protective Equipment - A Practical Guide to Users ). 2 of 4

7 EPOXY DAMP PROOF MEMBRANE HARDENER SDS 193 ISSUE 4 MARCH 2012 ENGINEERING MEASURES HYGIENE MEASURES Provide adequate general and local exhaust ventilation. Promptly remove any clothing that becomes contaminated. Wash promptly with soap & water if skin becomes contaminated. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE: liquid COLOUR: amber ODOUR: Slight ammonia 10. STABILITY AND REACTIVITY STABILITY: CONDITIONS TO AVOID: MATERIALS TO AVOID HAZARDOUS DECOMPOSITION PRODUCTS Stable under normal temperature conditions. Considerable exothermic reaction can occur when mixed with epoxide hardeners. Strong acids. Strong alkalis. Strong oxidising substances. During fire, toxic gases (CO, CO 2 & NO X ) are formed. 11. TOXICOLOGICAL INFORMATION INHALATION: INGESTION: SKIN: Harmful by inhalation. Harmful if swallowed. May cause burns in the mouth, oesophagus and stomach. Causes burns, may cause sensitisation by skin contact. May cause chemical eye burns. 12. ECOLOGICAL INFORMATION Do not allow to reach ground water, water courses or sewage system 13. DISPOSAL CONSIDERATIONS Small quantities of product may be treated with an equivalent quantity of product hardener, allowed to cure and disposed of as low hazard waste. Larger quantities should be disposed of as hazardous waste via a licensed waste operator. Product containers must not be re-used without commercial cleaning. Hazardous Waste Codes: Product: * ; Contaminated empty container * Dispose of as special waste in accordance with Local Authority Regulations. Use only licensed waste hauliers and disposal contractors. 14. TRANSPORT INFORMATION UK ROAD CLASS 8 PROPER SHIPPING NAME CORROSIVE LIQUID, N.O.S. (BIS(DIMETHYLAMINOMETHYL)PHENOL, M- PHENYLENEBIS(METHYLAMINE)) UN NO. ROAD 1760 UK ROAD PACK GR. III ADR CLASS NO. 8 ADR CLASS Class 8: Corrosive substances ADR PACK GROUP III ADR LABEL NO. 8 HAZARD NO (ADR) 80 HAZCHEM CODE 2X RID CLASS NO. 8 CEFIC TEC(R) NO. 80GC9- II+III RID PACK GROUP III UN NO. SEA 1760 MARINE POLLUTANT No. 3 of 4

8 EPOXY DAMP PROOF MEMBRANE HARDENER SDS 193 ISSUE 4 MARCH 2012 IMDG PAGE NO. 8 IMDG CLASS 8 EMS FA - SB IMDG PACK GR. III MFAG See Guide ICAO CLASS 8 UN NO AIR PACK GROUP III 15. REGULATORY INFORMATION CORROSIVE HARMFUL CONTAINS: 2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL, 3-AMINOMETHYL-3, 5, 5 TRIMETHYLCYCLOHEXYLAMINE, 3-AMINOPROPYLDIMETHYLAMINE, BENZYL ALCOHOL, BIS(DIMETHYLAMINOMETHYL)PHENOL, BISPHENOL A EPOXY RESIN, M-PHENYLENEBIS(METHYLAMINE) RISK PHRASES: R20/22 Harmful by inhalation and if swallowed R34 Causes burns R43 May cause sensitisation by skin contact SAFETY PHRASES: S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S51 Use only in well-ventilated areas. S60 This material and its container must be disposed of as hazardous waste. P5 Contains epoxy constituents. See information supplied by the manufacturer. 16. OTHER INFORMATION EH40 Occupational Exposure Limits. Control Of Substances Hazardous To Health Regulations. HS(G)97 A Step by Step Guide to C.O.S.H.H. Assessment. Approved Carriage and Supply Lists. The Chemicals (Hazards, Identification, Packaging) Regulations This Document, Issue 4, replaces Issue 3 after review. Risk Phrases used in Section 2 R10 Flammable R34 Causes burns R20/22 Harmful by inhalation and if swallowed R21/22 Harmful in contact with skin and if swallowed R22 Harmful if swallowed R36/38 Irritating to eyes and skin R37 Irritating to respiratory system R41 Risk of serious damage to eyes R43 May cause sensitisation by skin contact R62 Possible risk of impaired fertility R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment R52 Harmful to aquatic organisms 4 of 4