SAFETY DATA SHEET according to regulation 1907 / 2006 / EG

Transcription

1 Print date : Page : 1 / 7 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product code -- Use of the substance/preparation Manufacturer / Supplier Distributor Chemical Decalcifying Product for industry and household use FAEKA Chemie GmbH, Zug Postfach 121 CH-8423 Embrach-Embraport FAEKA Chemie GmbH, Zug Postfach 121 CH-8423 Embrach-Embraport Contact for technical information Tel (Mo Fr : 08:00 16:00) Fax info@awimac.ch Emergency telephone 2. HAZARDS IDENTIFICATION Classification : Schweiz. Notfalldienst (CH local) 145 Toxikologisches Informationszentrum Xn Harmful GHS Labeling Elements R 36/37/38 Irritating to eyes, respiratory system and skin. Warning Hazards to man and environment : Prevention : Response : 3.3/2 - Causes serious eye irritation. Specified use. IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF EYE IRRITATION PERSISTS : Get medical advice/attention. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical characterization Acid tablets. Hazardous components Components value0%-area CAS EINECS Symbol R-phrases Sulfamic acid % Xi 36/38; 52/53 Citric acid monohydrate % Xi 36 Sodium Persulfate % Xn 8;22;36/37/38;42/43 (Contd. on page 2)

2 Print date : Page : 2 / 7 4. FIRST-AID MEASURES Information : Following inhalation : After skin contact : After Eye contact : After swallowing : 5. FIRE-FIGHTING MEASURES Suitable extinguishing agents : Special exposure hazards arising from The substance or preparation itself : (Contd. of page 1) First Aider: Pay attention to self-protection! General advice: No induce of vomiting by layman. Immediately remove any clothing soiled by the product. Provide fresh air. In case of respiratory difficulties seek medical attention. Immediately rinse with water. In case of skin reactions, consult a physician. Immediately flush eyes with plenty of flowing water for 15 minutes holding eyelids apart. Subsequently consult an ophthalmologist. Rinse out mouth immediately, If the casualty is conscious. Do not induce vomiting. Seek medical advice immediately and show the container or label. Water, Dry powder, CO 2, Foam extinguisher. Use fire-extinguishing methods suitable to surrounding conditions. none Combustion products or resulting gases : Carbon dioxide (CO 2 ), Carbon monoxide (CO), Sulphuric gases (SO x ). Protective equipment : 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Avoid contact with the eyes and skin. Environmental precautions : Do not allow entering sewers/ surface or ground water. Wear self-contained respiratory protective device. Wear fully protective suit. Methods for cleaning / collecting : Pick up tablets or abrasion mechanically dry. Wash product in solution with plenty of water. (Contd. on page 3)

3 Print date : Page : 3 / 7 7. HANDLING AND STORAGE Handling : Information for safe handling : (Contd. of page 2) Use intact containers only. Prevent formation of dust, if unavoidable, absorb periodically. Keep containers, equipment and working place clean. Information about fire - and explosion protection : No special measures required. Storage : Requirements for storerooms and receptacles : Protect against humidity. Storage temperature 10 ÅC < 30ÅC. Information about clustering : Store away from foodstuffs. Further information about storage conditions : No special requirements. Stability : Specific use : 8. EXPOSURE CONTROLS / PERSONAL PROTECTION At ambient temperature and low humidity min 1 Year stable. Decalcifying tablets for Soda systems. Ingredients with limit values that require monitoring at the workplace : At intended use not required. Personal protective equipment General protective and hygienic measures : Keep away from foodstuffs, beverages and feed. Do not breathe dust. Avoid contact with the eyes and skin. Respiratory protection : At intended use (Tabs in Blister) not required. Protection of hands : Use standard domestic gloves for direct contact with the tablets according to DIN EN 420. At intended use (Tabs in Blister) not required. Eye protection : At intended use (Tabs in Blister) not required. Body protection : At intended use (Tabs in Blister) not required. (Contd. on page 4)

4 Print date : Page : 4 / 7 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Color : Odor : Melting point / area: Flash point: Point of ignite : Explosive properties: Density: -- Solubility in water: ph-value (20 ÅC, 12Å dh, 30g/l) ~2 10. STABILITY AND REACTIVITY Conditions to be avoided : Materials to be avoided : Dangerous reactions : tablet white neutral easy soluble Thermal stress Water, high humidity. (Contd. of page 3) Dangerous decomposition products : Carbon monoxide (CO), Sulphuric gases (SO x ). 11. TOXICOLOGICAL INFORMATION Acute toxicity : LD/LC50 values relevant for classification : Primary irritant effect on the skin : Primary irritant effect on Mucosa : Primary irritant effect on the eye : After inhalation : Sensitization : Additional toxicological information : Specification for 100% Sodium Persulfate Oral LD mg/kg (Rat) Slight irritations. Irritating effect. Irritating effect. Irritating effect. sensitizing effects possible. After swallowing irritations in the mouth, throat, esophagus and gastrointestinal tract. (Contd. on page 5)

5 Print date : Page : 5 / ECOLOGICAL INFORMATION (Contd. of page 4) Ecotoxical effects : Mobility : Persistence and degradability : Bioaccumulation potential : Aquatic toxicity, Fish toxicity : Other deleterious effect : Other information: Deleterious effect to aquatic organism due to the change of the ph - Value. Do not allow entering waters, wastewater, or soil! Not expected. Slightly water-dangerous. 13. ADVICE ON DISPOSAL Unused Product : Uncleaned packaging : The disposal is regionally differently regulated; therefore the kind of disposal is to be inquired at the responsible authorities. Disposal according to official regulations. 14. TRANSPORT INFORMATION UN Number 1505, Oxidizing solid, n.o.s. (Sodium Persulfate) 5.1, III Land transport ADR/RID und GGVS/GGVE (cross-border) : ADR/RID-GGVS/E class : 5.1 Maritime transport IMDG/GGVSea : IMDG/GGVSea-class : 5.1 Marine pollutant : No Air transport ICAO-TI and IATA-DGR : ICAO/IATA-class : 5.1 UN Model Regulation : - (Contd. on page 6)

6 Print date : Page : 6 / REGULATORY INFORMATION Labeling according to EU guidelines : Classification and labeling is performed according to EU directive GefStofV. (Contd. of page 5) Code letter and hazard designation of product : Risk phrases : Safety phrases : Xn Harmful National regulations, Information about limitation of use: In dealing with chemicals the national laws must be observed. R22 Harmful if swallowed. R 36/37/38 Irritating to eyes respiratory system and skin. R42/43 May cause sensitization by inhalation and skin contact. S 2 Keep out of the reach of children. S16 Keep away from sources of ignition No smoking. S17 Keep away from combustible material. S22 Do not breathe dust. S 25 Avoid contact with eyes. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 46 If swallowed, seek medical advice immediately and show this container or label. (Contd. on page 7)

7 Print date : Page : 7 / OTHER INFORMATION (Contd. of page 6) This information is based on our present knowledge, especially based on the knowledge of our suppliers. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Abbreviations and acronyms : ADR : RID : IMDG : IATA : Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RÑglement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) International Maritime Code for Dangerous Goods International Air Transport Association IATA-DGR : Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO : ICAO-TI : GHS : EINECS : CAS : GefStoffV : LC50 : LD50 : International Civil Aviation Organization Technical Instructions by the "International Civil Aviation Organization" (ICAO) Globally Harmonized System of Classification and Labeling of Chemicals European Inventory of Existing Commercial Chemical Substances Chemical Abstracts Service (division of the American Chemical Society) Gefahrstoffverordnung (Ordinance on Hazardous Substances, Germany) Lethal concentration, 50 percent Lethal dose, 50 percent Ö * Data compared to the previous version altered.