ISOPA PRODUS PROGRAM STEWART. Walk the Talk. Clorura de Metilen

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1 ISOPA PRODUS PROGRAM STEWART Walk the Talk Clorura de Metilen 1

2 Clorura de metilen - Informaţii de etichetare CLP Cuvânt de avertizare: Atenţie Fraze de pericol H315: Provoacă iritarea pielii H319: Provoacă o iritare gravă a ochilor H335: Poate provoca iritarea căilor respiratorii H336: Poate provoca somnolenţă sau ameţeală H351: Susceptibil de a provoca cancer H373: Poate provoca leziuni ale ficatului sau afecţiuni ale sângelui în caz de expunere prelungită sau repetată Fraze de precauţie Respectaţi frazele de precauţie şi indicaţiile de etichetare a produsului din (e)fds furnizată de producător. DSD Cuvânt de avertizare: Nociv Fraze de risc R40 Posibil efect cancerigen, dovezi insuficiente R36/37/38 Iritant pentru ochi, căile respiratorii şi piele R67 Inhalarea vaporilor poate cauza somnolenţă şi ameţeală Fraze de siguranţă Respectaţi frazele de siguranţă şi indicaţiile de etichetare a produsului din (e)fds furnizată de producător.

3 Clorura de Metilen: Proprietati Riscante PRINCIPALE PREOCUPARI PRACTICE: Mari concentratii de vapori vor cauza pierderi de simturi (anestezie) si inconstienta (narcosia) Iritarea pielii prin contact direct ALTE PROPRETATI DE AVERTIZRARE: -> Miros dulce la un nivel destul de ridicat: avertizare pentru expuneri riscante. ->Densitate gaz >>>aer: vaporii tind sa ramanalocalizati sau sa se disperseze incet in zona unde respira muncitorii ->Scara de inflamabilitate: 14% la 22% (in aer) : risc relaiv scazut 3

4 Masuri de protectie Expunerea la nivele ridicate de clorura de metilen este probabila daca clorura de metilen sau un produs care o contine, este folosit intr-o camera cu ventilatie necorespunzatoare. Cand e incalzit la descompunere, chiar si cu o tigara aprinsa, clorura de metilen poate genera fosgen si fluorura de carbon... SO Folositi PPE cand lucrati Verificati ca sistemul de extractie sa fie pornit Nu mancati, nu beti sau fumati la locul de munca Daca nu va simtiti bine, informati-va colegii si parasiti locul de munca Unde ati putea fi expus? 4

5 Unde ati putea fi expus? Zona de spumare Zona de debitare Zona de maturare Operatii de curatare folosind clorura de metilen ca solvent Scurgeri 5

6 ISOPA PRODUCT STEWARDSHIP PROGRAMMES Walk the Talk Pentane 6

7 Pentanul - informaţii de etichetare CLP Cuvânt de avertizare: Pericol Fraze de pericol: H224: Lichid şi vapori extrem de inflamabili. H304: Poate fi mortal în caz de înghiţire şi de pătrundere în căile respiratorii. H336: Poate provoca somnolenţă sau ameţeală. H411: Toxic pentru mediul acvatic, cu efecte pe termen lung. EUH066: Expunerea repetată poate cauza uscarea sau crăparea pielii. Fraze de precauţie Respectaţi frazele de precauţie şi indicaţiile de etichetare a produsului din (e)fds furnizată de producător. DSD Cuvânt de avertizare: Nociv Fraze de risc: R12: Extrem de inflamabil. R65: Nociv: poate provoca afecţiuni pulmonare prin înghiţire. R66: Expunerea repetată poate provoca uscarea sau crăparea pielii. R67: Inhalarea vaporilor poate provoca somnolenţă şi ameţeală. R51/53: Toxic pentru organismele acvatice, poate provoca efecte adverse pe termen lung asupra mediului acvatic. Fraze de siguranţă Respectaţi frazele de siguranţă şi indicaţiile de etichetare a produsului din (e)fds furnizată de producător. 7 Pentru informaţii suplimentare privind pericolele ciclopentanului şi ale amestecurilor acestuia, consultaţi (e)fds furnizată de producător.

8 Hazardous Properties of Pentane Flash Point: -40 C to - 20 C (the lowest temperature at which liquid releases sufficient vapour for ignition) Auto ignition temperature ca. 280 C (where the vapour-air mixture ignites on a hot surface.) Explosive vapour-air mixtures: Lower explosion limit: 1,4 Vol% = 41 g/m³ Upper explosion limit 7,8 Vol% = 240 g/m³ (Evaporation rate at 20 C - 30 C > 2,4 kg/h per m² surface) Vapour has higher density than air! Easy build-up of electric charge. Highly flammable. 8

9 Protective Measures Avoid explosive atmosphere (primary measure) No open handling, closed systems. Controlled ventilation. Generate inert atmosphere with Nitrogen. Avoid sources of ignition (secondary measures) Explosion protected machinery (encapsulation, no sparks, no hot surfaces) Avoid electrostatic sparks (earth machinary, no plastic containers) 9

10 Incident / Alarm In case of spillage or alarm from monitors Keep calm Stop pentane dosage, avoid ignition sources Increase ventilation Stop leakage Cover spillage with absorbant Self-contained breathing apparatus if ventilation is insufficient Protective clothing Extinguishing material: CO 2, Foam, Powder; no water! 10

11 Use of Pentane Pentane is highly flammable and may build up explosive mixtures with air Avoid any ignition source Ensure that static electricity cannot build-up Monitor level of pentane in air; remember that pentane is heavier than air 11

12 ISOPA PRODUCT STEWARDSHIP PROGRAMMES Walk the Talk Catalysts 12

13 Catalysts Catalysts can be corrosive, irritants, sensitisers and flammable Symptoms of exposure include chemical burn, swelling, itching, redness and hazy vision Use PPE when working with catalysts and polyol formulation components 13

14 ISOPA PRODUCT STEWARDSHIP PROGRAMMES Walk the Talk Methyl Isocyanates 14

15 Monoisocyanates and Diisocyanates Monoisocyanates are used for various applications but not for polyurethanes For example, methyl isocyanate is used for pesticides and insecticides All polyurethanes are made with diisocyanates such as MDI or TDI 15

16 Monoisocyanates and Diisocyanates Monoisocyanates are used for various applications but not for polyurethanes For example, methyl isocyanate is used for pesticides and insecticides Methyl-isocyanate is not used in making polyurethanes All polyurethanes are made with diisocyanates such as MDI or TDI 16

17 Disclaimer These product stewardship initiatives of ISOPA and its members do not exempt customers, producers and others in the supply chain of their occupational health, safety and environmental duties and regulatory obligations. With respect to this, ISOPA and its associated members disclaim any liability in connection with the use of services rendered and of the related information provided. It is the responsibility of the user to verify the accuracy of the services and the related information which can be used by the user at his own risk. 17

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