Revision Number: Issue date: 04/17/ PRODUCT AND COMPANY IDENTIFICATION. IDH number: HAZARDS IDENTIFICATION

Transcription

1 Safety Data Sheet Revision Number: Issue date: 04/17/ PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE LIOFOL LA known as LIOFOL LA Product type: Laminating adhesive Restriction of Use: This product is for industrial use only. Region: United States Company address: Contact information: Henkel Corporation Henkel Way One Rocky Hill, Connecticut Telephone: +1 (860) MEDICAL EMERGENCY Phone: Poison Control Center (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION DANGER: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A RESPIRATORY SENSITIZATION 1 SKIN SENSITIZATION 1 SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Do not breathe vapors, mist, or spray. Wash affected area thoroughly after handling. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves, eye protection, and face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of water. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. If experiencing respiratory symptoms: Call a poison center or physician. Take off contaminated clothing. Not prescribed Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Page 1 of 7

2 Classification complies with OSHA Hazard Communication Standard (29 CFR ) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Methylenebis(phenylisocyanate) methylenebis[4-isocyanatobenzene], Hexane, 1,6-diisocyanato-, homopolymer * Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If symptoms develop and persist, get medical attention. Asthmatic-type symptoms may develop and may be immediate or delayed up to several hours. Wash affected area immediately with soap and water. Remove contaminated clothing and footwear. If symptoms develop and persist, get medical attention. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get immediate medical attention. Ingestion: Get immediate medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Symptoms: See Section 11. Notes to physician: Persons with asthmatic-type conditions, chronic bronchitis, other chronic respiratory diseases or recurrent skin eczema or sensitization should be excluded from working with isocyanates. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. During emergency conditions, overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. Uncontrolled polymerization may occur at high temperatures resulting in explosions or rupture of storage containers. Cool pressurized can containers with jet of water. Containers may explode. Page 2 of 7

3 Hazardous combustion products: Toxic and irritating vapors. Oxides of carbon. Oxides of nitrogen. Isocyanates. Hydrogen cyanide. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Prevent further leakage or spillage if safe to do so. Prevent contamination of soil and water. Evacuate the area promptly. Wear suitable protective clothing, gloves and eye/face protection. Avoid skin contact and inhalation of vapors during disposal of spills. Confine in small area; use absorbent to clean up. Place in container for disposal with accordance with federal, state and local regulations. 7. HANDLING AND STORAGE Handling: Storage: Wear suitable protective clothing, safety glasses and gloves. Avoid skin and eye contact. Wash hands before breaks and immediately after handling the product. Avoid breathing vapors or mists of this product. Protect from moisture. Keep container closed. For safe storage, store between 10 C (50 F) and 50 C (122 F) Keep the container tightly closed and in a cool, well-ventilated place. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Methylenebis(phenylisocyanate) methylenebis[4-isocyanatobenzene], None None None None ppm TWA 0.02 ppm (0.2 mg/m3) Ceiling None None None None None None Hexane, 1,6-diisocyanato-, homopolymer None None None 0.5 mg/m3 TWA 1.0 mg/m3 STEL Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Work should be done in an adequately ventilated area (i.e., ventilation sufficient to maintain concentrations below one half of the PEL and other relevant standards). Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Observe OSHA regulations for respirator use (29 CFR ). Safety goggles or safety glasses with side shields. Wear face shield as necessary when spraying. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Page 3 of 7

4 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Colorless to light yellow Odor: Slight Odor threshold: ph: Not applicable Vapor pressure: < mm hg (20 C (68 F)) Boiling point/range: Melting point/ range: Specific gravity: Vapor density: Flash point: > 163 C (> F) Cleveland open cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Not determined Flammability: Not applicable Evaporation rate: Not determined Solubility in water: Not soluble. Reacts with water to liberate carbon dioxide gas. Partition coefficient (n-octanol/water): Not applicable VOC content: Negligible Viscosity: Decomposition temperature: 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under normal conditions of storage and use. Hazardous polymerization may occur at temperatures above C (400 F). Oxides of carbon. Oxides of nitrogen. Isocyanates. Hydrogen cyanide. Reacts with alcohols and amines. Acids and bases. Reaction with oxidants. Reacts slowly with water to liberate carbon dioxide gas. Avoid moisture. Container can be pressurised by carbon dioxide due to reaction with humid air and/or water. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes Page 4 of 7

5 Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: May cause respiratory tract irritation. This compound contains a material that may cause sensitization in some individuals, resulting in allergic symptoms of the respiratory tract producing asthma-like conditions (including wheezing, shortness of breath and difficulty breathing). Over exposure to isocyanates has also been reported to cause lung damage (including decrease in lung function) which may be permanent. May cause skin irritation. May cause allergic skin reaction in susceptible individuals. May cause irritation. Pain and discomfort. May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Methylenebis(phenylisocyanate) methylenebis[4-isocyanatobenzene], None Inhalation LC50 (Rat, 4 h) = 0.38 mg/l Inhalation LC50 (Rat, 4 h) = mg/l None No Records Irritant, Respiratory, Allergen Irritant, Allergen, Respiratory Hexane, 1,6-diisocyanato-, homopolymer None Allergen, Irritant, Respiratory Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) No No No Methylenebis(phenylisocyanate) No No No methylenebis[4-isocyanatobenzene], No No No Hexane, 1,6-diisocyanato-, homopolymer No No No 12. ECOLOGICAL INFORMATION Ecological information: Do not empty into drains / surface water / ground water. Page 5 of 7

6 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Legal disposition of wastes is the responsibility of the owner/generator of the waste. Applicable federal, state and/or local regulations must be followed during treatment, storage, or disposal of waste containing this product. To the best of our knowledge, this product is not listed nor does it meet the criteria of a hazardous waste if discarded in its purchased form. However, under RCRA, it is the responsibility of the user to determine at the time of disposal whether a product meets any of the RCRA hazardous waste criteria. This is because product uses, transformations, mixtures, processes, etc., may render the resulting material hazardous, under the criteria of ignitability, corrosivity, reactivity and toxicity characteristics under the new Toxicity Characteristics Leaching Procedure (TCLP) 40 Code of Federal Regulations TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III DOT Hazardous Substance(s): Methylene diphenyl diisocyanate International Air Transportation (ICAO/IATA) Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s. Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard class or division: 9 Identification number: UN 3082 Packing group: III United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. None above reporting de minimis None above reporting de minimis. Immediate Health, Delayed Health This product contains the following toxic chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40 CFR 372). Methylenebis(phenylisocyanate) (CAS# ). Methylenebis(phenylisocyanate) (CAS# ) 5,000 lbs. (2,270 kg) No California Proposition 65 listed chemicals are known to be present. Canada Regulatory Information CEPA DSL/NDSL Status: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. Page 6 of 7

7 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: Updated composition in Section 3. Prepared by: C. Poulsen, Regulatory Affairs Issue date: 04/17/2017 DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 7 of 7