Dow Surfactants. A guide to products and performance for paints and coatings

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1 Dow Surfactants A guide to products and performance for paints and coatings

2 Dow Surfactants for Paints and Coatings Unmatched Selection and Performance from the World s Leading Supplier A drilling platform off the coast of Venezuela withstands the corrosive effects of seawater, thanks to a specially formulated marine coating. In the U.S., workers brighten the interior walls of a newly constructed office complex with a low VOC paint. And in Korea, workers apply durable automotive finishes to cars slated for export around the globe. No matter where you are, Dow Coating Materials can provide you with innovative paint and coating solutions for a wide range of architectural and industrial applications. We bring together two of the industry s strongest suppliers of coating solutions The Dow Chemical Company and Rohm and Haas. Together, we offer the world s leading portfolio of coatings innovations, including surfactant chemistries. And our coatings experts around the world can help you find the optimal solution for your application. The breadth of our product portfolio is driven by innovation to address formulators critical needs: Improving sustainability along with performance and cost advantages Enhancing environmental performance Reducing application, manufacturing and processing costs Enabling smart coatings We offer an innovative and diverse portfolio of coatings solutions that includes these well-known surfactant products: TRITON specialty nonionic and anionic surfactants DOWFAX specialty anionic surfactants TERGITOL specialty and general purpose nonionic surfactants The total value of Dow surfactants goes well beyond brand names. Our investments in surfactant products and innovative technology have created a capabilities package unsurpassed in the paint and coatings industry. A wide range of available chemistries enables solutions that meet almost any performance requirement. Unsurpassed experience across the full range of paint and coatings means we can help you optimize surfactant performance in your formulation. Our industry knowledge and expertise fosters innovation and collaboration, bringing new products and technologies as we work with you to meet your current and future needs. Awareness of regulations and legislation allows us to provide you with the most up-to-date information as well as valuable assistance with product stewardship. Our global sales, distribution and technical support network means we are on the ground in your local area, ready to serve your surfactant needs. World-class surfactant manufacturing facilities contribute to the operational excellence of Dow Coating Materials, for high-performance products that are consistently high-quality and cost-effective. Our broad portfolio of ingredients for paints and coatings offers you the convenience of focused supply, backed by our in-depth knowledge of other formulation components. Our Broad Range of Surfactant Chemistries Expands Your Possibilities Surfactants from Dow Coating Materials include many diverse products across several surfactant chemistries. The unique functional and economic characteristics of these materials open the door to innovative surfactant solutions for paint and coatings formulations. Dow Coating Materials currently offers almost 200 surfactant products. Read on to learn more about the major families of our surfactant products, their functional contributions and their key applications. To find out how we can help with your coatings challenges, please contact your Dow Coating Materials representative (see back cover). What can we make possible for you? 2

3 Explore Your Surfactant Possibilities Secondary Alcohol Ethoxylates TERGITOL 15-S Series Surfactants TERGITOL TMN Series Surfactants TERGITOL 15-S-Series and TERGITOL TMN Series Surfactants offer a unique combination of excellent emulsifying, dispersing, stabilizing and wetting property profiles. These secondary alcohol ethoxylate (SAE) surfactants feature narrow aqueous gel ranges, rapid dissolution even in cold water, fast foam collapse rates, wide range of solvent compatibility and solubility, and favorable handling and formulating properties, making them ideal surfactants for many paints and coatings. The SAE fast aqueous dissolution properties of the water soluble surfactants (7-40 EO) result in even the low mole ethoxylate (3-5 EO) surfactants, which are oil soluble, being readily water dispersible. This allows the use of the low mole SAE to enhance the coalescing of emulsion polymers for low VOC (volatile organic compounds) systems, while also providing pigment wetting and stabilization, and substrate wetting and rewetting. TERGITOL 15-S-Series and TERGITOL TMN Series Surfactants are widely regarded as highly effective nonionic wetting agents having low aqueous dynamic and equilibrium surface tension profiles. These SAE surfactants may provide the necessary substrate wetting and rewetting properties often provided by anionic surfactants, but with lower foam profiles and with less water sensitivity compared to anionics. Low Foam Surfactants TRITON DF-16 Surfactants TRITON CF-10 (90%) Surfactants TRITON CF-10 Surfactants TERGITOL MinFoam 1X and 2X Surfactants TERGITOL MinFoam 1X, TERGITOL MinFoam 2X, TRITON CF-10 and TRITON CF-10 (90%) feature low foam and outstanding wetting and dispersing properties. TRITON CF-10 (90%) is a lower pour point product for enhanced handling at cooler temperatures and storage. These low foam surfactants are widely used for pigment stabilization in a range of coating formulations, including architectural, industrial, maintenance and automotive paints. Seed Oil Surfactants ECOSURF SA-7 Surfactants ECOSURF SA-9 Surfactants ECOSURF SA-15 Surfactants ECOSURF SA Surfactants offer a distinct combination of dispersing and wetting properties with excellent handling performance in a product based on seed oil. ECOSURF SA Surfactants have excellent wetting properties, with low equilibrium surface tension and rapid dynamic surface tension reduction. These surfactants feature no aqueous gelling, rapid dissolution even in cold water, fast foam collapse and favorable formulating and handling properties, making them ideal for many paint, coating and ink systems. They are especially suited to pigment wetting and stabilization. Octylphenol Ethoxylate Surfactants TRITON X Series Surfactants TRITON X Series Surfactants are versatile nonionic specialty surfactants that provide excellent emulsification performance. They are recognized as the industry standard OPE for pigment wetting and stabilization in coatings and are offered in a range of HLB to match specific wetting and dispersing requirements and waterborne coating stabilization requirements. Sulfosuccinates TRITON GR Series Surfactants GR-5M, GR-7M TRITON GR Series Surfactants feature outstanding wetting, emulsifying and dispersing properties. They are available in a range of solvent compatibilities and are widely used as substrate wetting and rewetting agents for waterborne paint applications. Alkyl Diphenyl Oxide Disulfonates DOWFAX 2A1 Surfactants DOWFAX 8390 Surfactants DOWFAX Surfactants DOWFAX 2EP Surfactants DOWFAX 2A1 Surfactant is the workhorse of the family of DOWFAX Surfactants. It s used widely in emulsion polymerization, providing increased mechanical and chemical stability, lower reactor waste and low critical micelle concentration (CMC). 3

4 Sulfates and Sulfonates TRITON XN-45S Surfactants TRITON X-200 Surfactants TRITON XN-45S Surfactant is an outstanding anionic emulsifier and stabilizer that offers excellent particle size control in emulsion polymerization. TRITON X-200 Surfactant is an excellent emulsion polymerization emulsifier and stabilizer. Specialty Surfactant TRITON CA Surfactants TRITON CA Surfactant is a superb pigment stabilizer with the unique ability to correct many colorant acceptance problems resulting from unknown pigment instability issues in paint production environments. TRITON CA Surfactant is an outstanding wetting and stabilizer for pigment and colorant dispersions. It improves color acceptance in even marginal, unstable pigment systems. Its broad HLB range makes this versatile surfactant suitable for use in most paint systems. TRITON CA Surfactant is also an effective wetting agent for pigments and extenders. EO/PO Copolymers TERGITOL XD, XH, XJ Surfactants TERGITOL L Series Surfactants TERGITOL XD, TERGITOL XH, TERGITOL XJ and TERGITOL L Series Surfactants are efficient emulsifiers and stabilizers for a broad range of materials, including aromatic and chlorinated solvents. TERGITOL XD Surfactant provides excellent pigment and colorant stabilization especially for concentrated dispersions such as carbon black and other very small particle pigments. Nonylphenol Ethoxylates TERGITOL NP Series Surfactants TERGITOL NP Series Surfactants cover a wide range of ethoxylation and HLB values. They are used as emulsifiers, wetting agents and dispersants in a variety of applications, including emulsion polymerization and paints and coatings. 4

5 Match One or More Dow Surfactants to Your Performance Requirements Dow surfactants include products designed to provide a wide range of valuable functional contributions to paint and coatings formulations. Refer to the table below to identify the most likely Dow solution to meet your functional requirements. If you require... We recommend... Because... Conventional Pigment Wetting and Stabilizing (APE) Conventional Pigment Wetting and Stabilizing (Non-APE) Low-Foam Pigment Wetting and Stabilizing (APE) Low-Foam Pigment Wetting and Stabilizing (Non-APE) EO/PO Copolymer Steric Stabilizers (Non-APE) High Mole Ethoxylate Steric Stabilizers (APE Based) TERGITOL NP-9 & NP-10 TRITON N-57, X-114, X-100, X-102 & X-165 (70%) ECOSURF SA-4, SA-7, SA-9 TERGITOL 15-S-3, 15-S-5, 15-S-7 & 15-S-9 TERGITOL TMN-3, TMN-6 (90%), TMN-10 (90%), TMN-100X TRITON CF-10 (90%) & CF-10 TRITON DF-16 TERGITOL MinFoam 1X & 2X TERGITOL XJ, XD & XH TRITON X-705 (70%), X-405 (70%) & X-305 (70%) TERGITOL NP-70 (70%), NP-50 (70%), NP-40 (70%) & NP-30 (70%) NPE 5 EO readily water dispersible; NPE and OPE 7-12 EO water soluble global standard and most often used for pigment wetting and stabilization SAE 3-5 EO readily water dispersible SAE 7-9 EO water soluble pigment and colorant wetting OPE global standard low foam nonionic for pigment wetting and stabilization; Enhances freeze-thaw stability and colorant stability; CF-10 (90%) has lower pour point and enhanced handling SAA low foam nonionic 1:1 MinFoam 1X / 2X blend matches CF-10 cloud point High MW EO / PO copolymer steric stabilizers; 100% solid OPE and NPE EO steric stabilizers; Aqueous versions for enhanced customer-friendly handling; 100% actives solid available High Mole Ethoxylate Steric Stabilizers (Non-APE) TERGITOL 15-S-40 (70%), 15-S-30 & 15-S-20 (80%) SAE EO steric stabilizers; Aqueous version for enhanced customer-friendly handling; 100% actives solid available Substrate Wetting and Re-Wetting (Anionic) DOWFAX 2A1 TRITON GR-5M & GR-7M GR-DOSS standard anionic for substrate wetting and rewetting; Low equilibrium and dynamic aqueous surface tension Substrate Wetting and Re-Wetting (Nonionic) ECOSURF SA-4 & SA-7 TERGITOL TMN-3, TMN-6 (90%), TMN-10 (90%) & TMN-100X TERGITOL 15-S-3, 15-S-5 & 15-S-7 SAE 3-8 mole EO have low equilibrium and dynamic aqueous surface tension APE = Alkylphenol Ethoxylate Non-APE = Not APE Based NPE = Nonylphenol Ethoxylate OPE = Octylphenol Ethoxylate SAE = Secondary Alcohol Ethoxylate SAA = Secondary Alcohol Alkoxylate PAA = Primary Alcohol Alkoxylate 5

6 If you require... We recommend... Because... Substrate Wetting Alternative and Complementary and Compatible with Fluoro Surfactants (Nonionic) (Non-APE) Dynamic and Equilibrium Low Aqueous Surface Tension (Anionic) Equilibrium Low Aqueous Surface Tension (Nonionic) (Non-APE) Dynamic and Equilibrium Low Aqueous Surface Tension (Nonionic) (Non-APE) Biodegradeable Seed Oil Surfactants with Low Aquatic Toxicity Surfactants with Low Gel Range (Non-APE) Hydrophobic Wetting Surfactants; Oil-Soluble But Readily Water-Dispersible (Non-APE) Color Acceptance Enhancement (APE) Color Acceptance Enhancement (Non-APE) Freeze-Thaw Enhancement (APE ) ECOSURF SA-4 & SA-7 TERGITOL TMN-3 & TMN-6 (90%), TERGITOL 15-S-3, 15-S-5 & 15-S-7 DOWFAX 2A1, TRITON GR-5M & GR-7M TERGITOL TMN-6 (90%), TMN-10 (90%) & TMN-100X TERGITOL 15-S-7 ECOSURF SA-4, SA-7 & SA-9 TERGITOL TMN-3, TMN-6 (90%), TMN-10 (90%) & TMN-100X TERGITOL 15-S-3, 15-S-5 & 15-S-7 ECOSURF SA-4, SA-7 & SA-9 ECOSURF SA-7 & SA-9 TERGITOL TMN-6 (90%), TMN-10 (90%) & TMN-100X TERGITOL 15-S-7, 15-S-9 & 15-S-12 ECOSURF SA-4, SA-7 & SA-9 TERGITOL TMN-3 & TMN-5 TERGITOL 15-S-3 & 15-S-5 TRITON CA TRITON N-57 TRITON CF-10 (90%) & CF-10 ECOSURF SA-4, SA-7 & SA-9 TERGITOL 15-S-3 & 15-S-5 TERGITOL TMN-3 & TMN-5 TERGITOL MinFoam 1X & 2X TERGITOL 15-S-7 & 15-S-9 TRITON DF-16 TRITON CF-10 (90%) & CF-10 TRITON X-405 (70%) SAE 3-8 EO levels; Fast aqueous dissolution rates; Low dynamic and equilibrium aqueous surface tension; Use as blends with fluorocarbon surfactants for lower cost Disulfonate steric stabilizer DOSS wetting and rewetting; DOSS in various solvents SAE lowest equilibrium aqueous surface tension for any conventional ethoxylated nonionics SAE 7-11 EO levels give lowest dynamic aqueous surface tension for any conventional ethoxylated nonionics; 3-5 EO levels have low dynamic surface tension due to being readily water dispersible, which is difficult for low EO APE nonionics ECOSURF Surfactants are biodegradable per OECD 301 test and > 1mg / L aquatic toxicity; surfactants for pigment and substrate wetting or for color acceptance SAE 7-12 EO levels; Very low gel ranges; Unstable foam with fast foam collapse rates; Water soluble; Fast aqueous dissolution rates; SAE hydrophobic low 3-5 mole EO; Readily water dispersible; Contributes to emulsion polymer coalescing CA specialty hydrophobic low EO blend; N-57 hydrophobic 5 mole EO easily water dispersible; CF-10 low foam dual bulky hydrophobes SAE hydrophobic low EO levels; Readily water dispersible; MinFoam 1X / 2X low foam SAA; Pigment wetting and stabilization Contributes to freeze-thaw stability of water-based systems; likely mechanisms: CF-10 low foam, due to large / bulky dual hydrophobes; X-405, due to large EO levels, water hydration and steric stabilization Freeze-Thaw Enhancement (Non-APE) TERGITOL 15-S-20, 15-S-30 & 15-S-40 TERGITOL XJ, XD, XH TERGITOL TMN-10 TERGITOL 15-S-20, 15-S-30 and 15-S-40 enhance freeze-thaw stability due to large EO levels; water hydration and steric stabilization; TERGITOL X-Series enhances freeze-thaw stability due to large EO/PO levels. 6

7 Properties of Dow Surfactants Gel Range and Foam Profiles A comparison of gel ranges and foam profiles of SAE, NPE, OPE and PAE nonionic surfactant families. Secondary Alcohol Ethoxylates (SAE) TERGITOL 15-S Series O (C H 2 C H 2 O) X H TERGITOL TMN Series O (C H 2 C H 2 O) X H Aqueous Gel Range of Surfactants with HLB=13 Gel Range at 25ºC Ross-Miles Foam of Surfactants with HLB=13 at 25ºC, 0.1 wt. % aqueous surfactant 120 Initial 5 Minute SAE 100 Surfactant NPE OPE Foam Height, mm PAE Wt. % Surfactant 0 SAE NPE OPE PAE Surfactant SAE have a very narrow gel range, giving them a very favorable advantage in aqueous formulations. PAE and NPE have broader gel ranges. SAE require a much shorter dissolution time. Broader gel range is partly due to the lower hydrophobicity. All families have a very similar initial form. SAE have the advantage of a much less stable foam. PAE, being the least hydrophobic, have a slower bubble film drainage. 7

8 Properties of Dow Surfactants Equilibrium Aqueous Surface Tension A comparison of equilibrium aqueous suface tension values featuring SAE, NPE, OPE and PAE nonionic surfactant families. Equilibrium Aqueous Surface Tension Values TERGITOL and TRITON Nonionic Surfactants Aqueous Surface Tension Values at 0.1 wt% 31 dynes/cm NP-10 X-100 NP-9 15-S-9 NP-7 X S-7 TMN-10 TMN-6 Nonionics Equilibrium Aqueous Surface Tension Values Conventional Ethoxylated Nonionic Surfactants vs. Fluorocarbon Aqueous Surface Tension Values at 0.1 wt% 28 dynes/cm NP-10 Min Foam 1X / 2X 15-S-7 TMN-10 TMN-6 Fluoro 8

9 Properties of Dow Surfactants Dynamic Aqueous Surface Tension A comparison of dynamic aqueous surface tension values featuring SAE and OPE nonionic surfactants. TRITON X Series OPE Surfactants TERGITOL 15-S Series SAE Surfactants Surface Tension, dynes/cm TRITON X-305 TRITON X-105 TRITON X-45 TRITON X-100 Surface Tension, dynes/cm TERGITOL 15-S-5 TERGITOL 15-S-7 TERGITOL 15-S-9 TERGITOL 15-S-20 TERGITOL 15-S Bubble Frequency, Hz Bubble Frequency, Hz Comparison to Acetylenic Diol TERGITOL SAE Surfactants Surface Tension, dynes/cm TERGITOL TMN-3 TERGITOL 15-S-3 Acetylenic Diol TRITON X-100 TERGITOL TMN-6 Surface Tension, dynes/cm TERGITOL 15-S-9 TERGITOL TMN-10 TERGITOL TMN-6 TERGITOL TMN Bubble Frequency, Hz Bubble Frequency, Hz Emulsion Polymer Coalescing A comparison of low-mole (3-5 EO) oil-soluble but readily water dispersible secondary alcohol ethoxylate (SAE) nonionic surfactants for lowering the mimimum filming temperature profile of emulsion polymers (polymer coalescing) compared to higher-mole (7-10 EO) ethoxylate nonionic surfactants and conventional coalescing solvents. Acrylic Polymer: Minimum Filming Temperature Vinyl-Acrylic Polymer: Minimum Filming Temperature 25 TERGITOL 15-S-9 TERGITOL TMN-6 TERGITOL 15-S-3l TERGITOL TMN-3 Butyl CARBITOL Ester Alcohol 14 TERGITOL 15-S-9 TERGITOL TMN-6 TERGITOL 15-S-3l TERGITOL TMN-3 Butyl CARBITOL Ester Alcohol ºC ºC MFT 22ºC Tg 19ºC 4 2 MFT 21ºC Tg 19ºC PHR (wt%) 2, 2, 4-Trimethyl-1, 2- Pentanedid Monoisbutyrate PHR (wt%) 9

10 ECOSURF SA Surfactants Performance The ECOSURF SA Surfactants, based on seed oil hydrophobes, show no loss in performance compared to conventional nonionic surfactants used in paints and coatings. In fact, they have a positive impact on minimum film formation temperature. At the same time, they reduce costs through faster dissolution and reduced cycle times. Since they are based on seed oil alcohols and create no VOC emissions, ECOSURF SA Surfactants also give paint systems an improved overall environmental profile. ECOSURF SA Surfactants were compared to a conventional nonionic surfactant in a gloss, semigloss and a flat formulated paint. ECOSURF SA Surfactant Performance in Formulated Paints Nonionic Surfactant ECOSURF SA-7 ECOSURF SA-9 Gloss Film Gloss, 60º Gloss, 20º Flow & Leveling Tint Strength % Contrast Ratio, % / / / Semigloss Film Gloss, 60º Gloss, 20º Flow & Leveling Tint Strength % Contrast Ratio, % / / / Flat Film Gloss, 60º Gloss, 20º Flow & Leveling Tint Strength % Contrast Ratio, % / / / Gloss - ASTM D Flow & Leveling ASTM D Tint Strength Y Value / Y Rub-up Contrast Ratio ASTM D A 10

11 Dow Surfactants for Coatings Selected Product Line Product ECOSURF Specialty Ethoxylates Cloud Moles Point (1) HLB (2) EO CMC (3) / Surface Tension (4) Foam Height (5) Pour Point (6) Form (7) Features ECOSURF SA PRT(8) 17 / / 20 3 L Based on seed oil, low odor, no gel range, rapid dissolution; wetting & effective emulsifier ECOSURF SA PRT 22 / / 20 4 L Based on seed oil, low odor, no gel range, rapid dissolution; wetting & effective emulsifier ECOSURF SA-15 > PRT 153 / / S Based on seed oil, low odor, rapid dissolution; wetting & effective emulsifier TERGITOL NP Nonyl Phenyl Ethoxylates TERGITOL NP / 90 L Outstanding wetting, improves color acceptance TERGITOL NP / 115 L Outstanding wetting, improves color acceptance TERGITOL NP-40 (70%) > / 115 L Highly water-soluble emulsifier and stabilizer TRITON X Octyl Phenyl Ethoxylates TRITON X-45 Disp / / 9-24 L emulsifier with good wetting TRITON X / / L wetting; Improves color acceptance dispersant, and emulsifier for oil-in-water systems; Improves color acceptance; TRITON X / / L Freeze-thaw stabilizer TRITON X / / L dispersant; Improves color acceptance TRITON X-405 (70%) > / / 22-6 L emulsion stabilizer; Provides freeze-thaw and ionic stability TRITON Specialty Alkoxylates TRITON CA Disp PRT - / / 0-20 L Improves color acceptance and prevents agglomeration of pigments TRITON N-57 Disp / / L Emulsifier; Enhances associative thickener efficiency; Improves colorant acceptance TRITON X-207 Disp 10.7 PRT - / / L Improves color acceptance TERGITOL 15-S Secondary Alcohol Ethoxylates TERGITOL 15-S-5 Disp Disp Disp -25 L emulsifier; Enhances paint associative thickener efficiency and latex coalescence TERGITOL 15-S / / 28 1 L Superior wetting; Improves color acceptance TERGITOL 15-S / / 43 9 L Good substrate wetting; Improves color acceptance TERGITOL 15-S-20 (80%) > / / 42 6 L Emulsion stabilizer; Provides freeze-thaw and ionic stability; Good handling properties TERGITOL 15-S-40 (70%) > / / 28 5 L Emulsion stabilizer; Provides freeze-thaw and ionic stability; Good handling properties (1) Cloud point: C, 1 wt% aqueous solution (5) Ross-Miles foam height: mm at 0.1 wt% actives, 25 C, initial / 5 minute (2) HLB Range: <10 w/o emulsifier, >10 w/o emulsifier good wetting, detergents (6) Pour point: C (3) Critical micelle concentration: ppm at 25 C (7) Form at 25 C: L = Liquid, S = Solid (4) Surface tension: dynes/cm at 1%, 25 C (8) PRT = Proprietary Product Cloud Moles Point (1) HLB (2) EO CMC (3) / Surface Tension (4) Foam Height (5) Pour Point (6) Form (7) Features TERGITOL Ethylene Oxide / Propylene Oxide (EO/PO) Copolymer TERGITOL L PRT - / / 30-2 L Efficient foam control agent; Wetting agent TERGITOL XD 74 - PRT - / / S steric and freeze-thaw stabilizer; Effective pigment and carbon black dispersant TRITON and TERGITOL Low Foam Surfactants TRITON CF PRT 75 / L Pigment dispersant; Freeze-thaw stability; Colorant acceptance TRITON DF PRT 530 / 30-7 L Non APEO low foam pigment dispersant; Colorant acceptance TERGITOL MinFoam 1X PRT 20 / L Non APEO low foam pigment dispersant; Colorant acceptance TERGITOL TMN Branched Secondary Alcohol Ethoxylates TERGITOL TMN-3 Ins Ins Ins -49 L oil soluble emulsifier; Enhances paint associative thickener efficiency and latex coalescence TERGITOL TMN-6 (90%) / / 22 <-40 L Superior wetting agent; Narrow gel range TERGITOL TMN-10 (90%) / / L High HLB emulsifier; Freeze-thaw stabilizer; Narrow gel range Surface Tension (10) Foam (11) DOWFAX : Alkyldiphenyloxide Disulfonate Salts Actives Diluent Form (9) Neutral (12) Alkaline (13) Neutral (12) Alkaline (13) Features DOWFAX 2A1 45 Water L / / 145 Emulsion polymerization TRITON GR: Dioctyl Sulfosuccinates IPA (14) / TRITON GR-5M 60 Water L 26 NR (15) 190 / 180 NR wetting, emulsifying and dispersing ability TRITON GR-7M 64 Petroleum Distillate (16) L Ins (17) Ins Ins Ins emulsifying and dispersing ability; Oil soluble TRITON : Sulfates and Sulfonates TRITON X-200K 28 Water L / / 175 Emulsion polymerization Ethanol/ TRITON XN-45S 60 Water L / / 170 Emulsion polymerization (9) FORM AT 25ºC: L = Liquid, S = Solid (10) Surface Tension: dynes/cm at 1 wt% actives, 25ºC (11) Ross-Miles foam height: mm at 1 wt% actives, 25ºC, initial/ 5 minute (12) Actual ph = 7 (distilled water) (13) Actual ph = 12.5 (sodium hydroxide solution) (14) IPA = Isopropanol (15) NR = Not recommended; can hydrolyze under some alkaline conditions (16) Blend of ethanol, naphtha, propylene glycol and naphthalen (17) Ins = Insoluble 11

12 In addition to Dow Surfactants, The Dow Chemical Company also supplies a variety of other high-performance formulating ingredients for paints and coatings, including: CARBITOL, CELLOSOLVE, DOWANOL Glycol Ethers Biocides POLYOX Water-Soluble Resins Emulsion Polymers Specialty Alkanolamines Ethylenamines ETHOCEL Ethylcellulose METHOCEL Cellulose Ethers CELLOSIZE Hydroxyethyl Cellulose CYRACURE Cycloaliphatic Epoxides DAXAD Dispersants TONE Caprolactones Hydrocarbon Resins Polyvinyl Acetate Nitroparaffins Epoxidized Products Redispersible Powders Solution Vinyl Resins Acrylic Acid Acrylate Esters Amino Alcohols Contract Manufacturing (Fine Chemicals) Visit our web site: or call From the United States and Canada: Phone: Fax: In Europe: Toll-free Phone: Phone: Fax: In Latin America: Phone: Fax: In Asia Pacific: Phone: Fax: All Pacific countries except Indonesia & Vietnam: Toll-free Phone: Toll-free Fax: Toll free from Austria (00), Belgium (00), Denmark (00), Finland (990), France (00), Germany (00), Hungary (00), Ireland (00), Italy ( ), The Netherlands (00), Norway (00), Portugal (00), Spain (00), Sweden (00), Switzerland (00) and the United Kingdom (00). NOTICE: No freedom from any patent owned by Seller or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer s use and for ensuring that Customer s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Seller assumes no obligation or liability for the information in this document. Published January 2010 Printed in the United States Form No BBI NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. The DOW Diamond Logo and Human element and design are trademarks of The Dow Chemical Company 2010 Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow

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