The Future of Aluminium Complex Greases Peter Baladincz a, György Pölczmann b, József Tóth a

Transcription

1 The Future of Aluminium Complex Greases Peter Baladincz a, György Pölczmann b, József Tóth a a MOL-LUB Ltd., Fő str. 21, Almásfüzitő, H-2931, Hungary b University of Pannonia, Egyetem str. 10, Veszprém, H-8200, Hungary Introduction The grease thickener components not only transform the liquid lubricant into consistent lubricant, but also alter their properties. The gelling component of greases are mostly soaps (fatty acid salt - normal or complex), but they can be different chemical structure materials too (organic and ionic-non ionic polyureas, organoclay, well-dispersed silica acid, etc.) [1]. Aluminium complex greases began to appear in the mid-1960s, and a number of patents were issued over the next several years covering various modifications. Most of the efforts were in the areas of improved water resistance, and thermal and mechanical stability. Out of the aluminium complex greases one type is currently dominant in the world, which contains aluminium stearate and benzoate (Figure 1). The importance of the aluminium complex greases shows a trend to decline in the past decades. However, there were attempts for better understanding of the soap formation and to broaden the application areas. Figure 1 Aluminium stearate and benzoate complex Main properties of the aluminium complex greases include high dropping point and thus high maximal application temperature; excellent water resistance with a slight hardening of consistency in the presence of water; good working, mechanical and shear stability; very good oxidation stability; excellent pumpability and thus easy handling and applicability in central lubrication systems and bulk storage; wide operating temperature range; chemical resistance; good compatibility with a wide range of other greases. Its reversibility or ability to retain consistency after repeated heating and cooling, is unique as well [2][3]. Moreover, high quality aluminium complex greases can be formulated relatively easily on different types of base oils, which is being a current development focus. These properties enable their application in steel mill applications. In addition, their non-toxicity also enables their applicability in the food industry (NSF category H1 grease may be produced), as well as in the formulation of biodegradable, environmentally sound -1-

2 lubricating greases or any other highly specialized areas which require the use of lubrication by greases [4]. There are different methods to produce aluminium complex greases. In case of 2 step process method is known (Figure2). This is a more complex and long process which may be difficult to handle/manage. In the first step, an aluminium containing compound which is a reaction product of aluminium and isopropyl alcohol is reacted with fatty acid thus aluminium and long carbon chain containing material is formed. In this step, the alcohol component of the feedstock is released, so ventilation of the system is essential. In the second step, the reaction product of the first step is reacted with benzoic acid to make the aluminium complex grease. Figure2 Aluminium complex grease production via 2 step method In case of the 1 step aluminium complex grease production procedure, the thickener agent feedstock is easy to handle (only slight pre-warming may be necessary), and it is a relatively short and easy to handle process as well (Figure 3) [5]. In the process the aluminium thickener is reacted with benzoic acid and aluminium complex soap is formed. Because there is only a trace or no amount of alcohol is in the precursor, there is no need for ventilation of the system, which can also mean cost reduction. Figure 3 Aluminium complex grease production via 1 step method -2-

3 Because of the increasing need for better performance, there is a growing need for high performance, specially designed and formulated lubricants based on special base fluids. This is already changing the lubrication market and thus the lubrication industry itself. If the lubricant manufacturers would like to keep up with the trends, they have to find and offer solutions for these needs for the benefit of their customers. However it lags behind a bit when it is about change, this tendency also applies for the grease industry, too. Experimental Objectives Our main objective is the continuous development and to meet the challenges of the future. Therefore we continuously explore the possibilities of lubricating greases and grease thickener formulation for special needs and applications, based on paraffinic base oils and based on biodegradable base oils. We are experimenting continuously to find the optimal maximum yield vs. maximum performance combinations in the formulation of aluminium complex lubricating greases. On the course of this, we investigated the possibilities of the formulation of excellent performance aluminium complex greases on different oil bases, from Group I. to Group V. and vegetable oils as well. Feedstocks During the experiments, we used different types of base oils, such as mineral oils with different characteristic (naphthenic, Group I. to Group III.), different synthetic bases (ester, polyalphaolefin, polyisobuthylene) and organic oil (rapeseed oil), too. As thickener component we used aluminium containing thickener agent which contained approximately 50w/w% aluminium stearate thickener dissolved in Group I. base oil. To make the aluminium complex structure, technical grade benzoic acid was used. Sample production The samples were produced in a laboratory scale open grease kettle. The whole quantity of base oil mixture was poured into the kettle. After that stirring and heating has been started. At about 60 C, powdered benzoic acid and in some cases excess fatty component was added. After the acids were dissolved, the pre warmed thickener component had been added at C. After this the mixture has been heated to 150 C at first, for saponification. Then the temperature has been increased to the maximum of about C, mainly depending on the type of base oil used. After reaching the maximum temperature, the grease has been -3-

4 Worked penetration, 0.1 mm Worked penetration, 0.1 mm Worked penetration, 0.1 mm cooled immediately. After cooling, finishing operations, such as milling and deaeration had been done. Analytical methods The analytic methods used for determining the properties of the grease samples were standardized (ISO, DIN, ASTM) methods commonly used in the grease industry. Results and discussion Formulation on different base oils In the first stage of our experiments the effect of changing the base oil types were investigated. During this our goal was to formulate greases with NLGI grade 2 consistency greases on different types of base fluids. It can be seen on Figure 4, that for the formulation of NLGI grade 2 grease in case of different base oils, different amount of soap (thickener and benzoic acid) were needed Naphthenic BO Group I. BO (X) Group I. BO (Y) Group II. BO Group III. BO Group IV. BO (PAO) Group V. BO (PIB) NLGI NLGI Amount of thickener in the formula, m/m % Amount of thickener in the formulation, m/m % a, b, Group V. BO (SynE) Vegetable oil (RO) NLGI 2 X SN base oil with medium viscosity, high paraffin content, low naphthenic aromatic content Y SN base oil with higher viscosity, higher naphthenic and aromatic content; PAO Polyalphaolefin; PIB Polyisobuthylene; SynE Synthetic ester; RO Rapeseed oil Amount of thickener in the formulation, m/m % c, Figure 4 Worked penetration of the grease samples formulated on different types of base fluids as a function of the necessary amount of thickener agent -4-

5 Table 2 Formulation of NLGI 2 lubricating grease on Group I. and Naphthenic base oils Sample name Type of base oil Naphthenic Group I. (X) Group I. (Y) Molar ratio (Al stearate:ba) 1:1 1:1 1:1 Amount of thickener, % Visual yellow-brown yellow-brown yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN over 2100 over 2100 Oil separation at 100 C over 24h, % IP X SN base oil with medium viscosity, high paraffin content, low naphthenic aromatic content; Y SN base oil with higher viscosity, higher naphthenic and aromatic content; BA Benzoic acid In case of applying naphthenic base oil only 8% of thickener component was enough to reach NLGI 2 grade. In case of Group I base oils 10% was needed. But when applying highly paraffinic (or similar structure) Group II-V. base oils to reach the required grade 13-14% of thickener had to be applied. Furthermore working with synthetic ester and vegetable oil, the thickener component had to be applied above 20%. Table 3 Formulation of NLGI 2 lubricating grease on Group II.-IV. base oils Sample name Type of base oil Group II. Group III. Group IV. (PAO) Molar ratio (Al stearate:ba) 1:1 1:1 1:1 Amount of thickener, % Visual yellow yellow light yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN over Oil separation at 100 C over 24h, % IP PAO Polyalphaolefin; BA Benzoic acid These results are shown in Table 2-4 also, with alongside further properties which had been measured. The results shown in Figure 4-5, and also in Table 2-4 show that by increasing the soap content, the desired consistency grade with acceptable properties can be made. However in -5-

6 Penetration, 0.1 mm case some of the utilized base fluids, this increase of the soap components is not too economical because of the relatively high price of the components. Table 4 Formulation of NLGI 2 lubricating grease on Group V. and vegetable oil Sample name Type of base oil Group V. (SynE) Group V. (PIB) Rapeseed oil Molar ratio (Al stearate:ba) 1:1 1:1 1:1 Amount of thickener, % Visual yellow-brown light yellow yellow-brown Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN over 2100 over 2100 Oil separation at 100 C/24h, % IP Thickener agent has approx. 50w/w% active material content PIB Polyisobuthylene; SynE Synthetic ester; BA Benzoic acid Penetration Penetration change after 10,000 strokes Worked penetration Penetration change after 100,000 strokes Figure 5 Penetration and mechanical stability Thickener agent has approx. 50w/w% active material content; X SN base oil with medium viscosity, high paraffin content, low naphthenic aromatic content; Y SN base oil with higher viscosity, higher naphthenic and aromatic content; PAO Polyalphaolefin; PIB Polyisobuthylene; SynE Synthetic ester Changing the molar ratio In the second stage of our experiments the effect of changing the molar ratio of the feedstocks were investigated. Because of the special structure (one cyclic and one paraffin -6-

7 component) of the aluminium complex grease, it can be tailored for different base oils relatively easily. Sample name Type of base oil Molar ratio (SA:Al:BA) Type of thickener Amount of thickener, % Amount of excess stearic acid, % Table5 Modification of the molar ratio of the soap components 6A PAO 6B PAO 1:1:1 1.2:1:0.8 mineral oil based mineral oil based ~1 Visual yellow yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN Oil separation at 100 C over 24h, % IP Thickener agent has approx. 50w/w% active material content PAO Polyalphaolefin; SA Stearic acid; Al - Aluminium, BA Benzoic acid Based on this idea the molar ratio of the cyclic component (benzoic acid) and the paraffin component (carbon chain of the stearic acid) has been changed to produce a more paraffin heavy grease structure. Based on the results (Table 5) it was determined that with the modification of the molar ratio with lower amount of thickener similar grease can be produced. This means that the thickener can be tailored well to the applied base oil, and not only with the use of excessive amount of thickener, but only with a small amount of excessive fatty acid, which is much cheaper. Thus this formulation method can mean economical benefit and can lead to extra profit. Utilization of different fatty acids As it was presented above, with the use of a small amount of excessive fatty acid, the desired consistency grade grease can be produced with such good performance as with increasing the soap content. In the third stage of our experiments the effect of the use of different fatty acids were investigated. The results are shown in Table 6-8 and Figure 6. It was investigated that if the different chemical formulas (ligand, unsaturation etc.) and the excess of the fatty acids had effect to grease properties. In these experiments we applied different amounts of excess fatty acids, namely distilled stearic acid (mixture of highly saturated C16 and mainly C18 carbon chains), 12 hydroxystearic acid (widely used in grease production) and oleic acid (unsaturated C18 chains). -7-

8 Table 6 Formulation with excess stearic acid Sample name 6A 6C 6D Type of base oil PAO PAO PAO Amount of thickener, % Amount of excess fatty acid, % Type of excess fatty acid - DSA DSA Visual yellow yellow yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN Oil separation at 100 C over 24h, % IP PAO Polyalphaolefin; DSA Distilled stearic acid Table 7 Formulation with excess 12 hydroxystearic acid Sample name 6A 6E 6F Type of base oil PAO PAO PAO Amount of thickener, % Amount of excess fatty acid, % Type of excess fatty acid - 12HSA 12HSA Visual yellow yellow yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN Oil separation at 100 C over 24h, % IP PAO Polyalphaolefin; 12HSA 12 hydroxystearic acid It was concluded that applying the thickener component in 10-12% with applying different types of excess fatty acids, proper NLGI 2 grade greases could be produced with relatively same, very good performance levels. This means that the performance of the grease is not necessarily depends on the price or availability of the utilized fatty component. -8-

9 Penetration, 0.1 mm Table 8 Formulation with excess oleic acid Sample name 6A 6G 6H Type of base oil PAO PAO PAO Amount of thickener, % Amount of excess fatty acid, % Type of excess fatty acid - OA OA Visual yellow yellow yellow Penetration at 25 C, 0.1 mm ISO Worked penetration at 25 C, 0.1 mm ISO Penetration change after 10,000 double strokes, 0.1 mm ISO Penetration change after 100,000 double strokes, 0.1 mm ISO Water wash out, % ASTM D Flow pressure at -30 C, mbar DIN Oil separation at 100 C over 24h, % IP PAO Polyalphaolefin; OA oleic acid Penetration Change in penetration after 10,000 strokes Worked penetration Change in penetration after 100,000 strokes % Thickener 12% Thickener, 0.7% DSA 10% Thickener, 1.4% DSA 12% Thickener, 0.7% 12HSA 10% Thickener, 1.4% 12HSA 10% Thickener, 1.4% OA 12% Thickener, 0.7% OA Conclusions Figure 6 Penetration and mechanical stability of grease as a function of the applied amount of thickener and excess fatty component ; DSA Distilled stearic acid; 12HSA 12 hydroxystearic acid; OA oleic acid It can be concluded that the aluminium complex lubricating grease have a bright future in special areas, where there is a need for high dropping point, high water resistance, wide operating temperature range and chemical resistance. Such areas are steel industry, food industry, any application which requires lubrication and a chemically active environment. During our experimental work, we determined that aluminium complex greases are easily made in a one step process with the utilization of aluminium stearate containing thickener -9-

10 compositions and moreover it is relatively easy to formulate lubricating greases, even specialities on different base oil types with excellent properties. References [1] Qvist, S.: Greases, Tekniskafdeling, February 28. [2] S. K. Sharma, P. Vasudevan, U. S. Tewari: High temperature lubricants oils and greases, Tribology International, Volume 16, Issue 4, 1983, [3] A. T. Polishuk: Physical and chemical properties of complex soap greases, Lubr. Eng., 1963, 19, [4] Lubricants and Lubrication. 2nd Ed. Edited by Th. Mang and W. Dresel, 2007, WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim, ISBN: , pp [5] MOL-LUB: KOMAD 8400, a lubricating grease thickener -10-