: Diesel EGR 3 (Aerosol)
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- Dina Andrews
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1 MSDS Version: E03.02 Datum izdavanja: 10/02/2015 Blend Version: 2 ODJELJAK 1: Identifikacija tvari/smjese i podaci o tvrtki/poduzeću 1.1. Identifikacija proizvoda Proizvod u obliku : Smjese Naziv proizvoda : Diesel EGR 3 (Aerosol) Sifra proizvoda : W Odgovarajuće identificirane namjene tvari ili smjese i namjene koje se ne preporučuju Upotreba proizvoda Upotreba materijala / pripravka : Maintenance product Namjene koje se ne preporučuju 1.3. Podaci o dobavljaču koji isporučuje sigurnosno-tehnički list Wynn's Belgium Industriepark-West Sint-Niklaas - Belgium T F msds@wynns.eu Broj telefona za izvanredna stanja Broj hitne pomoći : BIG: +32(0)14/ ODJELJAK 2: Identifikacija opasnosti 2.1. Razvrstavanje tvari ili smjese Razvrstavanje sukladno uredbi (EZ-a) br. 1272/2008 [CLP] Aerosol 1 Eye Irrit. 2 STOT SE 3 STOT SE 3 Aquatic Chronic 2 Cijeli tekst H-izraza: vidi odjeljak 16 H222;H229 H319 H335 H336 H411 Razvrstavanje prema Direktivi 67/548/EEZ [DSD] ili 1999/45/EZ [DPD] F+; R12 Xi; R37 N; R51/53 R66 R67 Cijeli tekst R-fraze/upozorenja vidi pod odlomkom 16 Štetni fiziokemijski rizici te rizici za ljudsko zdravlje i okoliš 2.2. Elementi označivanja Označavanje u skladu s odredbom (EU) br. 1272/2008 [CLP] Piktogrami opasnosti (CLP) : Karakteristična riječ (CLP) Oznake upozorenja (CLP) : Opasnost GHS02 GHS07 GHS09 : H222 - Vrlo lako zapaljivi aerosol H229 - Spremnik pod tlakom: može se rasprsnuti ako se grije H319 - Uzrokuje jako nadraživanje oka H335 - Može nadražiti dišni sustav H336 - Može izazvati pospanost ili vrtoglavicu H411 - Otrovno za vodeni okoliš s dugotrajnim učincima 03/07/2015 HR (Hrvatski) 1/8
2 EUH fraze Oznake obavijesti (CLP) : EUH066 - Ponavljano izlaganje može prouzročiti sušenje ili pucanje kože : P261 - Izbjegavati udisanje aerosol, pare P280 - Nositi zaštita očiju P271 - Rabiti samo na otvorenom ili u dobro prozračenom prostoru P102 - Čuvati izvan dohvata djece P210 - Čuvati odvojeno od topline, vrućih površina, iskri, otvorenih plamena i ostalih izvora paljenja. Ne pušiti P211 - Ne prskati u otvoreni plamen ili drugi izvor paljenja P251 - Ne bušiti, niti paliti čak niti nakon uporabe P410+P412 - Zaštititi od sunčevog svjetla. Ne izlagati temperaturi višoj od 50 C/122 F 2.3. Ostale opasnosti ODJELJAK 3: Sastav/informacije o sastojcima 3.1. Tvar Nije primjenjivo 3.2. Smjese Naziv Identifikacija proizvoda % w Klasifikacija prema Direktivi 67/548/EEZ hydrocarbons, C9, aromatics (EZ-br) (REACH-br) R10 Xi; R37 N; R51/53 Xn; R65 R66 R67 Butane n- (CAS br) (EZ-br) (INDEKS br) (REACH-br) Propane (CAS br) (EZ-br) (INDEKS br) (REACH-br) butoxyethanol (CAS br) (EZ-br) (INDEKS br) (REACH-br) Acetone (CAS br) (EZ-br) (INDEKS br) (REACH-br) F+; R F+; R Xn; R20/21/22 Xi; R36/ F; R11 Xi; R36 R66 R67 Naziv Identifikacija proizvoda % w Razvrstavanje sukladno uredbi (EZ-a) br. 1272/2008 [CLP] hydrocarbons, C9, aromatics (EZ-br) (REACH-br) Butane n- (CAS br) (EZ-br) (INDEKS br) (REACH-br) Propane (CAS br) (EZ-br) (INDEKS br) (REACH-br) butoxyethanol (CAS br) (EZ-br) (INDEKS br) (REACH-br) Acetone (CAS br) (EZ-br) (INDEKS br) (REACH-br) Puni tekst R i H oznaka dan je u Odjeljku Flam. Liq. 3, H226 STOT SE 3, H335 STOT SE 3, H336 Asp. Tox. 1, H304 Aquatic Chronic 2, H Flam. Gas 1, H Flam. Gas 1, H Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 03/07/2015 HR (Hrvatski) 2/8
3 ODJELJAK 4: Mjere prve pomoći 4.1. Opis mjera prve pomoći Opće mjere prve pomoći Mjere prve pomoći nakon udisanja Mjere prve pomoći nakon dodira s kožom Mjere prve pomoći nakon dodira s očima Mjere prve pomoći nakon gutanja 4.2. Najvažniji simptomi i učinci, akutni i odgođeni Simptomi/ozljede Simptomi/ozljede nakon udisanja Simptomi/ozljede nakon kontakta s kožom Simptomi/ozljede nakon kontakta s očima 4.3. Hitna liječnička pomoć i posebna obrada ODJELJAK 5: Mjere gašenja požara 5.1. Sredstva za gašenje Prikladna sredstva za gašenje Neprikladna sredstva za gašenje : Provjerite vitalne funkcije. Držite unesrećenog u mirnom polu-uspravnom položaju. Žrtva nije pri svijesti: održavati odgovarajuće disanje i dotok zraka. Prestanak disanja: umjetno disanje ili kisik. Srčani zastoj: započnite s oživljavanjem. Victim in shock: on his back with legs slightly raised. Povraćanje: spriječiti gušenje/aspiracijsku upalu pluća. Nastavite pratiti žrtvu. Pružiti psihološku pomoć. Spriječiti pothlađivanje pokrivanjem žrtve (ne zagrijavanjem). Držite unesrećenog mirno, izbjegavati fizički napor. Obratiti se liječniku, ako je potrebno. : U slučaju otežanog disanja premjestiti unesrećenog na svježi zrak, umiriti ga i postaviti u položaj koji olakšava disanje. U slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA ili liječnika. : U slučaju dodira s kožom odmah skinuti natopljenu odjeću a kožu odmah oprati s puno vode i sapuna. U slučaju nadražaja ili osipa na koži: zatražiti savjet/pomoć liječnika. : U SLUČAJU DODIRA S OČIMA: oprezno ispirati vodom nekoliko minuta. Ukloniti kontaktne leće ukoliko ih nosite i ako se one lako uklanjaju. Nastaviti ispiranje. Ako nadražaj oka ne prestaje: zatražiti savjet/pomoć liječnika. : Isprati usta. U slučaju zdravstvenih tegoba nazvati CENTAR ZA KONTROLU OTROVANJA ili liječnika. As it is a spray can packaging it is most unlikely that large quantities will be swallowed. : Pare mogu uzrokovati pospanost i omamljenost. : Depresija središnjeg živčanog sustava, glavobolja, vrtoglavica, pospanost, gubitak koordinacije. Mučnina. Može nadražiti dišni sustav. : nadraženost kože i crvenilo. Ponavljano izlaganje može prouzročiti sušenje ili pucanje kože. : Uzrokuje jako nadraživanje oka. : Vodeni mlaz. AFFF pjena. ABC-prah. : Ne koristi snažan tok vode Posebne opasnosti koje proizlaze iz tvari ili smjese Opasnost od požara Opasnost od eksplozije Reaktivnost : Vrlo lako zapaljivi aerosol. Zagrijavanje može uzrokovati požar ili eksploziju. : No direct explosion hazard. : Kod spaljivanja: oslobađanje ugljičnog monoksida - ugljičnog dioksida Savjeti za gasitelje požara Mjere za suzbijanje požara Neprikladno sredstva : Physical explosion risk: extinguish/cool from behind cover. Za hlađenje izloženih spremnika koristite raspršeni mlaz vode ili magle. : Ne ulaziti u požarom zahvaćeno područje bez odgovarajuće zaštitne opreme, uključujući zaštitu dišnih organa. ODJELJAK 6: Mjere kod slučajnog ispuštanja 6.1. Osobne mjere opreza, zaštitna oprema i postupci u slučaju opasnosti Za osobe koje se ne ubrajaju u interventno osoblje Zaštitna oprema Planovi za prvu pomoć : protective clothing. Large spills/in enclosed spaces: compressed air apparatus. Rukavice. Zaštitne naočale. : Označiti opasno područje. Exposure to fire/heat: keep upwind. Zaustaviti motore i zabranjeno pušenje. Bez otvorenog plamena, iskri i pušenja. Close doors and windows of adjacent premises. Seal off low-lying areas. Koristiti pribor te opremu za rasvjetu s kojom ne postoji opasnost od iskre/eksplozije. Large spills/in enclosed spaces: compressed air apparatus. Velika izlijevanja/u skučenim prostorima: razmotriti evakuaciju. Onečišćenu odjeću je potrebno oprati Za interventno osoblje Planovi za prvu pomoć : Prozračiti područje. 03/07/2015 HR (Hrvatski) 3/8
4 6.2. Mjere zaštite okoliša Spriječite zagađenje tla i vode. Izbjegavati ispuštanje u okoliš Metode i materijal za sprečavanje širenja i čišćenje Za zadržavanje Postupci čišćenja 6.4. Uputa na druge odjeljke ODJELJAK 7: Rukovanje i skladištenje 7.1. Mjere opreza za sigurno rukovanje Mjere opreza za sigurno rukovanje Higijenske mjere : Sakupiti proliveno/rasuto. : Male količine prolivene tekućine: sakupiti nezapaljivim upijajućim materijalom i lopatom premjestiti u spremnik radi odlaganja. Sakupiti sakupljenu tvar u spremnike s poklopcem. Nakon upotrebe očistiti opremu i odjeću. : Sukladno s propisima. Osigurati dobro prozračivanje radnog prostora kako bi se spriječilo stvaranje pare. Koristiti pribor te opremu za rasvjetu s kojom ne postoji opasnost od iskre/eksplozije. Čuvati odvojeno od topline, vrućih površina, iskri, otvorenih plamena i ostalih izvora paljenja. Ne pušiti. : Koristiti dobru praksu osobne higijene. IF ON SKIN: Wash with plenty of soap and water. Oprati zagađenu odjeću prije ponovne uporabe Uvjeti sigurnog skladištenja, uzimajući u obzir moguće nespojivosti Skladišna temperatura : 45 C Izvori topline i zapaljenja Zabrane vezane uz miješanu pohranu Područje pohrane Posebni propisi za pakovanje Materijali za pakovanje 7.3. Posebna krajnja uporaba ili uporabe See product bulletin for detailed information. : Držati podalje od otvorenog plamena - ne pušiti. : Držati podalje od snažnih kiselina i snažnih oksidirajućih sredstava. : Sukladno s propisima. Vatrootporno spremište. Zaštititi od vrućine i neposredne izloženosti suncu. Keep container tightly closed in a cool, well-ventilated place. Skladištiti na suhom mjestu. Prozračivanje po podu. : Sukladno s propisima. correctly labelled. : Pressurised small gas containers (aerosol cans). ODJELJAK 8: Nadzor nad izloženošću/osobna zaštita 8.1. Nadzorni parametri Butane n- ( ) Belgija Granična vrijednost (ppm) 1000 ppm Propane ( ) Belgija Granična vrijednost (ppm) 1000 ppm 2-butoxyethanol ( ) EZ IOELV TWA (mg/m³) 98 mg/m³ EZ IOELV TWA (ppm) 20 ppm EZ IOELV STEL (mg/m³) 246 mg/m³ EZ IOELV STEL (ppm) 50 ppm Belgija Granična vrijednost (mg/m³) 98 mg/m³ Belgija Granična vrijednost (ppm) 20 ppm Belgija Kratkoročna vrijednost (mg/m³) 246 mg/m³ Belgija Kratkoročna vrijednost (ppm) 50 ppm Belgija Napomena (BE) D Nizozemska Grenswaarde TGG 8H (mg/m³) 100 mg/m³ Nizozemska Grenswaarde TGG 8H (ppm) 20 ppm Nizozemska Grenswaarde TGG 15MIN (mg/m³) 246 mg/m³ Nizozemska Grenswaarde TGG 15MIN (ppm) 50 ppm Acetone ( ) EZ IOELV TWA (mg/m³) 1210 mg/m³ EZ IOELV TWA (ppm) 500 ppm Belgija Granična vrijednost (mg/m³) 1210 mg/m³ Belgija Granična vrijednost (ppm) 500 ppm Belgija Kratkoročna vrijednost (mg/m³) 2420 mg/m³ Belgija Kratkoročna vrijednost (ppm) 1000 ppm 03/07/2015 HR (Hrvatski) 4/8
5 8.2. Nadzor nad izloženošću Prikladni tehnički kontrolni uređaji Osobna zaštitna oprema : U neposrednoj blizini mjesta s bilo kakvom potencijalnom izloženošću bi trebali biti postavljeni sigurnosni tuševi za hitno ispiranje očiju. Ne zahtijeva nikakve posebne ili pojedine tehničke mjere. : Sigurnosna stakla. Rukavice od neoprena ili obične gume. Zaštita ruku Ostale informacije : nitrile. Neopren. Choosing the proper glove is a decision that depends not only on the type of material, but also on other quality features, which differ for each manufacturer. Vrijeme prodiranja određuje proizvođač rukavica. : Vrijeme prodiranja: >30'. Thickness of the glove material >0,1 mm. ODJELJAK 9: Fizikalna i kemijska svojstva 9.1. Informacije o osnovnim fizikalnim i kemijskim svojstvima Agregatno stanje Izgled Boja Miris Prag mirisa ph : Relativna stopa isparavanja (butilacetatom=1) refraction index : : Tekućina : Aerosol. : mirisno. : 5,6 Talište : < -20 C Točka solidifikacije Vrelište : C Plamište : -18 C Temperatura samozapaljenja : 230 C Temperatura raspadanja Zapaljivost (kruta tvar, plin) Tlak pare Relativna gustoća pare kod 20 C Relativna gustoća C Topljivost Log Pow Log Kow Viskoznost, C Viskoznost, C Viskoznost Viskoznost Index : Eksplozivna svojstva Oksidacijska svojstva : 8530 hpa : 860 kg/m³ : Partially soluble. : 1 C Granice eksplozivnosti : 0,8-13 vol % 9.2. Ostale informacije HOS sadržaj : 90,25 % dodatne obavijesti ODJELJAK 10: Stabilnost i reaktivnost Reaktivnost Kod spaljivanja: oslobađanje ugljičnog monoksida - ugljičnog dioksida. : The physical and chemical data in this section are typical values for this product and are not intended as product specifications. 03/07/2015 HR (Hrvatski) 5/8
6 10.2. Kemijska stabilnost Vrlo lako zapaljivi aerosol. Stabilan pod normalnim uvjetima Mogućnost opasnih reakcija Uvjeti koje treba izbjegavati Inkompatibilni materijali Opasni proizvodi raspada ODJELJAK 11: Toksikološki podatci Informacije o toksikološkim učincima akutna toksičnost 2-butoxyethanol ( ) ATE CLP (oralno) ATE CLP (kožni) ATE CLP (prah, maglica) Nagrizanje/nadraživanje kože Ozbiljno oštećenje/nadraživanje očiju Izazivanje preosjetljivosti dišnih putova ili kože Mutageni učinak na spolne stanice Kancerogenost Reproduktivna toksičnost TCO jednokratno izlaganje TCO ponavljano izlaganje opasnost od aspiracije 500,000 mg / kg tjelesne težine 1100,000 mg / kg tjelesne težine 1,500 mg/l/4h : Uzrokuje jako nadraživanje oka. : Može nadražiti dišni sustav. Može izazvati pospanost ili vrtoglavicu. ODJELJAK 12: Ekološke informacije Toksičnost Ekologija - opšte Postojanost i razgradivost Bioakumulacijski potencijal Pokretljivost u tlu Rezultati ocjenjivanja svojstava PBT i vpvb Ostali štetni učinci ODJELJAK 13: Zbrinjavanje Metode obrade otpada Preporuke za odlaganje otpada : Spremnik pod tlakom. Ne bušiti ili spaljivati čak ni nakon upotrebe. Uklonite u postrojenje ovlašteno za obradu otpada. 03/07/2015 HR (Hrvatski) 6/8
7 ODJELJAK 14: Informacije o prijevozu U skladu sa zahtjevima ADR / RID / IMDG / IATA / ADN UN broj UN br. (ADR) : Ispravno otpremno ime UN ( Proper Shipping Name ) Vlastiti otpremni naziv (ADR) Opis dokumenata za transport (ADR) Prijevozni razred(i) opasnosti Klasa (ADR) : 2 Dodatna opasnost (IMDG) : 2.1 Dodatna opasnost (IATA) : 2.1 Oznake opasnosti (ADR) : 2.1 : AEROSOLS : UN 1950 AEROSOLS, 2.1, (D), OPASNO ZA OKOLIŠ Skupina pakiranja Nije primjenjivo Opasnosti za okoliš Opasno za okoliš : Ostale informacije : Posebne mjere opreza za korisnika Transport kopnom Šifra razvrstavanja (ADR) : 5F Posebna odredba (ADR) : 190, 327, 344, 625 Kategorija transporta (ADR) : 2 Oznaka ograničenja pri transportu kroz tunele (ADR) Ograničene količine (ADR) : D : 1l Prijevoz morem EmS (1) : F-D, S-U Zračni prijevoz Uputa "teret" (CAO) : 203 Uputa "putnik" (ICAO) : 203/Y Prijevoz u razlivenom stanju u skladu s Prilogom II. Konvenciji MARPOL i Kodeksom IBC Nije primjenjivo ODJELJAK 15: Informacije o propisima Propisi u području sigurnosti, zdravlja i okoliša/posebno zakonodavstvo za tvar ili smjesu EZ-propisi Ne sadrži tvari u pogledu ograničenju Priloga XVII Diesel EGR 3 (Aerosol) nije na popisu kandidata REACH Ne sadrži tvari na popisu kandidata REACH Ne sadrži tvari iz REACH Priloga XIV HOS sadržaj : 90,25 % 03/07/2015 HR (Hrvatski) 7/8
8 Nacionalni propisi Klasa ugroženosti vode (WGK) : 2 - koji ugrožava vodu Ocjenjivanje kemijske sigurnosti ODJELJAK 16: Ostale informacije Puni tekst ili R-, H- i EUH-fraze: Acute Tox. 4 (Dermal) Acute Tox. 4 (Inhalation:dust,mist) Acute Tox. 4 (Oral) Aerosol 1 Aquatic Chronic 2 Asp. Tox. 1 Eye Irrit. 2 Flam. Gas 1 Flam. Liq. 2 Flam. Liq. 3 Skin Irrit. 2 STOT SE 3 STOT SE 3 H220 H222 H225 H226 H229 H302 H304 H312 H315 H319 H332 H335 H336 H411 R10 R11 R12 R20/21/22 R36 Akutna toksičnost (preko kože), 4. kategorija opasnosti Akutna toksičnost (udisanje: prašina, maglica), 4. kategorija opasnosti Akutna toksičnost (gutanje), 4. kategorija opasnosti Aerosol, 1. kategorija opasnosti Opasno za vodeni okoliš kronična opasnost, 2. kategorija Opasnost od aspiracije, 1. kategorija opasnosti Teška ozljeda oka/nadražujuće za oko, 2. kategorija opasnosti Zapaljivi plinovi, 1. kategorija opasnosti Zapaljive tekućine, 2. kategorija opasnosti Zapaljive tekućine, 3. kategorija opasnosti Nagrizajuće/nadražujuće za kožu, 2. kategorija opasnosti Specifična toksičnost za ciljane organe jednokratno izlaganje, 3. kategorija opasnosti, nadraživanje dišnog trakta 3.8. Specifična toksičnost za ciljane organe jednokratno izlaganje, 3. kategorija opasnosti, narkoza Vrlo lako zapaljivi plin Vrlo lako zapaljivi aerosol Lako zapaljiva tekućina i para Zapaljiva tekućina i para Spremnik pod tlakom: može se rasprsnuti ako se grije Štetno ako se proguta Može biti smrtonosno ako se proguta i uđe u dišni sustav Štetno u dodiru s kožom Nadražuje kožu Uzrokuje jako nadraživanje oka Štetno ako se udiše Može nadražiti dišni sustav Može izazvati pospanost ili vrtoglavicu Otrovno za vodeni okoliš s dugotrajnim učincima Zapaljivo Lako zapaljivo Vrlo lako zapaljivo Štetno ako se udiše, u dodiru s kožom i ako se proguta Nadražuje oči R36/38 Nadražuje oči i kožu R37 Nadražuje dišni sustav R51/53 Otrovno za organizme koji žive u vodi, može dugotrajno štetno djelovati u vodi R65 Štetno: može izazvati oštećenje pluća ako se proguta R66 Učestalo izlaganje može prouzročiti sušenje ili pucanje kože R67 Pare mogu izazvati pospanost ili vrtoglavicu F Lako zapaljivo F+ Vrlo lako zapaljivo N Opasno za okoliš Xi Nadražujuće Xn Štetno Ova je informacija temeljena na našem trenutnom znanju i namjera joj je opisati proizvod samo za zdravstvene, sigurnosne i ekološke uvjete. Stoga se je treba tumačiti kao jamstvo za bilo koje specifično svojstvo proizvoda 03/07/2015 HR (Hrvatski) 8/8
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