: LESSIVE LIQUIDE ULTRA CONCENTREE ECOLABEL TECHLINE

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1 LESSIVE LIQUIDE ULTRA CONCENTREE Date first issue: Review date: 26/03/2015 Supersedes: 03/07/2012 Edition: 5.00 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : LESSIVE LIQUIDE ULTRA CONCENTREE Product code : 1129 Product group : Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Main use category Description/Application : Professional use : Laundry detergent Uses advised against 1.3. Details of the supplier of the safety data sheet Christeyns France S.A. rue de la Maladrie 31 F VERTOU - FRANCE T +33 (0) F +33 (0) health-security@christeyns.fr Emergency telephone number Country Organisation/Company Address Emergency number France INRS United Kingdom SECTION 2: Hazards identification National Poisons Information Service Medical Toxicology Unit 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Eye Irrit. 2 H319 Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : CLP Signal word Hazard statements (CLP) Precautionary statements (CLP) EUH-statements GHS07 : Warning : H319 - Causes serious eye irritation : P264 - Wash hands thoroughly after handling P280 - Wear eye protection P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention : EUH208 - Contains Subtilisin ( ). May produce an allergic reaction 2.3. Other hazards 06/06/2016 EN (English) 1/8

2 SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Alcohols C10-16,ethoxylated 3-7 EO (CAS-no) (REACH-no) exemption polymer 5-10 Xn; R22 Xi; R41 Alcohols, ethoxylated, sulfates, sodium salts (CAS-no) (REACH-no) Propan-2-ol (CAS-no) (Einecs nr) (EG annex nr) (REACH-no) Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts (CAS-no) (Einecs nr) < 5 Xi; R41 Xi; R38 < 5 F; R11 Xi; R36 R67 < 5 Xn; R22 Xi; R41 Xi; R38 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Alcohols C10-16,ethoxylated 3-7 EO (CAS-no) (REACH-no) exemption polymer Alcohols, ethoxylated, sulfates, sodium salts (CAS-no) (REACH-no) Propan-2-ol (CAS-no) (Einecs nr) (EG annex nr) (REACH-no) Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts (CAS-no) (Einecs nr) Acute Tox. 4 (Oral), H302 Eye Dam. 1, H318 < 5 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Chronic 3, H412 < 5 Flam. Liq. 2, H225 Eye Irrit. 2, H319 STOT SE 3, H336 < 5 Acute Tox. 4 (Oral), H302 Skin Irrit. 2, H315 Eye Dam. 1, H318 Name Product identifier Specific concentration limits Alcohols, ethoxylated, sulfates, sodium salts (CAS-no) (REACH-no) Full text of R- and H-statements: see section 16 ( 5,01 =<C < 10) Eye Irrit. 2, H319 ( 10 =<C < 100) Eye Dam. 1, H318 SECTION 4: First aid measures 4.1. Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion : In case of doubt or persistent symptoms, consult always a physician. For symptom description, see item 11. : In case of malaise, seek medical advice. : Take off contaminated clothes. Wash off with plenty of water. : Rinse immediately and plentifully with water and take medical advice. : If swallowed, seek medical advice immediately and show this container or label Most important symptoms and effects, both acute and delayed Acute effects inhalation. Acute effects skin. Acute effects eyes : Causes serious eye irritation. Acute effects oral route Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : The product itself does not burn. Foam, powder, carbon dioxide (CO2), water spray Special hazards arising from the substance or mixture 5.3. Advice for firefighters Protection during firefighting : Use a self-contained breathing apparatus and also a protective suit. 06/06/2016 EN (English) 2/8

3 SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment : Concerning personal protective equipment to use, see section For emergency responders 6.2. Environmental precautions Prevent liquid from entering sewers, watercourses, underground or low areas Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections : Rinse with water. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Avoid contact with the skin and the eyes. Shower, eyes shower and water point in proximity. : Always wash hands after handling the product. Do not eat, drink or smoke in areas where product is used Conditions for safe storage, including any incompatibilities Storage conditions Storage temperature : 5-40 C Material(s) to avoid 7.3. Specific end use(s) : Store in original container. : Not determined. SECTION 8: Exposure controls/personal protection 8.1. Control parameters EU IOELV STEL (mg/m³) 980 mg/m³ EU IOELV STEL (ppm) 400 ppm France VLE (mg/m³) 980 mg/m³ France VLE (ppm) 400 ppm United Kingdom WEL TWA (mg/m³) 999 mg/m³ United Kingdom WEL TWA (ppm) 400 ppm United Kingdom WEL STEL (mg/m³) 1250 mg/m³ United Kingdom WEL STEL (ppm) 500 ppm Alcohols, ethoxylated, sulfates, sodium salts ( ) DNEL/DMEL (Workers) Long-term - systemic effects, dermal 2750 mg/kg bodyweight/day Long-term - systemic effects, inhalation 175 mg/m³ DNEL/DMEL (General population) Long-term - systemic effects,oral 15 mg/kg bodyweight/day Long-term - systemic effects, inhalation 52 mg/m³ Long-term - systemic effects, dermal 1650 mg/kg bodyweight/day PNEC (Water) PNEC aqua (freshwater) 0,24 mg/l PNEC aqua (marine water) 0,024 mg/l PNEC (Sediment) PNEC sediment (freshwater) 0,9168 mg/kg dwt PNEC sediment (marine water) 0,09168 mg/kg dwt PNEC (Soil) PNEC soil 0,946 mg/kg dwt DNEL/DMEL (Workers) Long-term - systemic effects, dermal Long-term - systemic effects, inhalation 888 mg/kg bodyweight/day 500 mg/m³ 06/06/2016 EN (English) 3/8

4 DNEL/DMEL (General population) Long-term - systemic effects,oral Long-term - systemic effects, inhalation Long-term - systemic effects, dermal PNEC (Water) PNEC aqua (freshwater) PNEC aqua (marine water) PNEC (Soil) PNEC soil PNEC (STP) PNEC sewage treatment plant 8.2. Exposure controls Hand protection 26 mg/kg bodyweight/day 89 mg/m³ 319 mg/kg bodyweight/day 140,9 mg/l 140,9 mg/l 28 mg/kg dwt 2251 mg/l : not required. Eye protection : safety goggles (EN 166). Protective equipment Respiratory protection : No special required clothing. : Not required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Physical state/form Colour Odour Odour threshold : Liquid : Liquid. : Blue. : perfumed. ph : 9-9,9 (100%) Relative evaporation rate (butylacetate=1) Melting point/range Freezing point Boiling point/boiling range Flash point Autoignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C : Not determined Relative density : 1-1,06 Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity Reactivity Chemical stability : Water: 100% (20 C) Stable in use and storage conditions as recommended in item Possibility of hazardous reactions 06/06/2016 EN (English) 4/8

5 10.4. Conditions to avoid Temperatures below 0 C Incompatible materials Do not mix with other products Hazardous decomposition products Hazardous decomposition products may be released during prolonged heating like smokes, carbon monoxide and dioxide. nitrogen oxides (NOx). SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Alcohols, ethoxylated, sulfates, sodium salts ( ) LD50 oral rat > 5000 mg/kg OCDE 401 LD50 dermal rat > 5000 mg/kg OCDE 402 Alcohols C10-16,ethoxylated 3-7 EO ( ) LD50 oral rat > 2000 mg/kg ATE CLP (oral) 500,000 mg/kg LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) 5840 mg/kg mg/kg > 25 mg/l/4h Benzenesulfonic acid, C10-13-alkyl derivs., sodium salts ( ) ATE CLP (oral) 500,000 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity ph: 9-9,9 (100%) : Causes serious eye irritation. (According tests based on the experimental protocol in accordance with the O.E.C.D guideline N 438 : In accordance with the Regulation(EC) 1272/2008, GREEN'R ULTRA WASH does not have to be classified in category 1 "Irreversible effects on the eye". The signal "Danger" and hazard statement H318 "Causes serious eye damage" are not required) ph: 9-9,9 (100%) Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information Toxicity Ecology - general according 1272/2008/CE. Alcohols, ethoxylated, sulfates, sodium salts ( ) LC50 fish 1 > 10 (10-100) mg/l EC50 Daphnia 1 > 10 mg/l ErC50 (algae) > 100 mg/l NOEC (chronic) 1-10 mg/l NOEC chronic fish > 1 mg/l NOEC chronic algae > 0,1 mg/l LC50 fish 1 EC50 Daphnia 1 ErC50 (algae) 9640 mg/l 9714 mg/l > 100 mg/l 06/06/2016 EN (English) 5/8

6 12.2. Persistence and degradability LESSIVE LIQUIDE ULTRA CONCENTREE Persistence and degradability The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Alcohols C10-16,ethoxylated 3-7 EO ( ) Persistence and degradability Readily biodegradable. Persistence and degradability Bioaccumulative potential Readily biodegradable Mobility in soil Results of PBT and vpvb assessment Alcohols, ethoxylated, sulfates, sodium salts ( ) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vpvb criteria of REACH regulation, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods Waste treatment methods Waste / unused products SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN UN number No dangerous good in sense of transport regulations.(adr, RID, IMDG, IATA ) UN proper shipping name Transport hazard class(es) Packing group : Dispose of in accordance with relevant local regulations. : Avoid undiluted product to come into sewer or superficial water Environmental hazards Other information : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 06/06/2016 EN (English) 6/8

7 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations Contains no REACH substances with Annex XVII restrictions Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances CESIO recommendations : The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No.648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. Detergent Regulation : Labelling of contents: Component % anionic surfactants, Soap, Non-ionic surfactants 5-15% Polycarboxylates <5% Enzymes Optical brighteners BENZISOTHIAZOLINONE perfumes National regulations Chemical safety assessment SECTION 16: Other information Indication of changes: 2.1 Classification Added according to Regulation (EC) No. 1272/2008 [CLP] 2.2 Label elements Modified 3.2 Composition/informati Modified on on ingredients 4.2 Modified 8 Modified 11 Modified 12. Modified 15.1 Modified 16 Modified Other information : It is recommended to pass the information of this safety data sheet, eventually in an appropriated form, to the users. Such information is actually to be best of our knowledge and believes accurate as reliable. This information relates to the specific material designated and may not be valid in combination with other product(s). Classification according to directives 67/548/EEC and 1999/45/EEC et sequens. EC Regulation 1272/2008 and its amendments. Full text of R-, H- and EUH-statements: Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category 3 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Flam. Liq. 2 Flammable liquids, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Narcosis H225 Highly flammable liquid and vapour H302 Harmful if swallowed H315 Causes skin irritation 06/06/2016 EN (English) 7/8

8 H318 H319 H336 H412 EUH208 Causes serious eye damage Causes serious eye irritation May cause drowsiness or dizziness Harmful to aquatic life with long lasting effects Contains. May produce an allergic reaction It is the user's responsibility to take mentioned precaution measures and ensure that this information is complete and sufficient for the use of this product 06/06/2016 EN (English) 8/8