Safety Data Sheet. according to Regulation (EC) No 1907/2006. Endomice Mouse Killer

Transcription

1 Page 1 of 6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture biocides; IE/BPA 70305; Amateur use 1.3. Details of the supplier of the safety data sheet Company name: Street: Place: Dr.-Werner-Freyberg-Straße 11 D Laudenbach Telephone: Telefax: Emergency telephone number: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture sicherheitsdatenblaetter@detia-freyberg.de Classification according to Directive 67/548/EEC or 1999/45/EC Giftinformationszentrum (GIZ) Universitätsklinikum Mainz Tel.: This mixture is not classified as hazardous according to Directive 1999/45/EC. Classification according to Regulation (EC) No. 1272/2008 [CLP] This mixture is not classified as hazardous according to Regulation (EC) No. 1272/ Label elements Precautionary statements P273 Avoid release to the environment. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor. P280 Wear suitable gloves. P501 Dispose of waste according to applicable legislation. P405 Store locked up. P404 Store in a closed container. P270 Do not eat, drink or smoke when using this product. P220 Keep/Store away from clothing/combustible materials. P103 Read label before use. P270 Do not eat, drink or smoke when using this product. P102 Keep out of reach of children. SECTION 3: Composition/information on ingredients 3.2. Mixtures

2 Page 2 of 6 Hazardous components EC No CAS No Index No REACH No Chemical name Classification according to Directive 67/548/EEC Classification according to Regulation (EC) No. 1272/2008 [CLP] Quantity (3-biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4-hydroxycoumarin, difenacoum 0,005 % X Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1. Description of first aid measures After inhalation Provide fresh air. T+ - Very toxic, T - Toxic, N - Dangerous for the environment R28-48/ Acute Tox. 2, STOT RE 1, Aquatic Acute 1 (M-Factor = 10), Aquatic Chronic 1 (M-Factor = 10); H300 H372 ** H400 H410 After contact with skin After contact with skin, wash immediately with: Water. Change contaminated clothing. After contact with eyes Rinse immediately carefully and thoroughly with eye-bath or water. After ingestion If swallowed, immediately drink: Water Most important symptoms and effects, both acute and delayed Symptoms can occur only after several hours. Symptoms / delayed effects : 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Antidotal dispensation. : Vitamin K1 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. Unsuitable extinguishing media High power water jet Special hazards arising from the substance or mixture Carbon monoxide. In case of fire and/or explosion do not breathe fumes Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Do not allow water used to extinguish fire to enter drains or waterways. Remove product from area of fire. Contaminated fire-fighting water must be collected separately. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid generation of dust. Wear personal protection equipment. Provide adequate ventilation. See protective measures under point 7 and Environmental precautions Do not allow to enter into surface water or drains. Retain contaminated washing water and dispose it.

3 Page 3 of Methods and material for containment and cleaning up Take up mechanically. Treat the recovered material as prescribed in the section on waste disposal Reference to other sections See protective measures under point 7 and 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Keep locked up. It is recommended to design all work processes always so that the following is excluded: skin contact. Do not breathe dust. Use only in well-ventilated areas. Keep away from food, drink and animal feedingstuffs. Further information on handling Avoid release to the environment. Refer to special instructions/safety data sheets Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container dry. Keep container tightly closed. Advice on storage compatibility Keep away from food, drink and animal feedingstuffs Specific end use(s) Technical measures and the application of suitable work processes have priority over personal protection equipment. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Protective and hygiene measures Change contaminated clothing. Wash hands before breaks and after work. When using do not eat or drink. Eye/face protection Eye protection: not required. Hand protection Wear suitable gloves. eg. Hygostar nitrile Professional 0.4 mm thick made??of nitrile, AQL 1.5. Skin protection For the protection against direct skin contact, body protective clothing is essential (in addition to the usual working clothes). Respiratory protection With correct and proper use, and under normal conditions, breathing protection is not required. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: ph-value: solid red odourless Test method

4 Page 4 of 6 Changes in the physical state Melting point: Initial boiling point and boiling range: Sublimation point: Flash point: Flammability Solid: Explosive properties not explosive. Auto-ignition temperature Solid: Oxidizing properties Not oxidizing. Vapour pressure: Vapour pressure: Density: Water solubility: Solubility in other solvents sparingly soluble. Viscosity / dynamic: Viscosity / kinematic: Flow time: Vapour density: Solvent separation test: 9.2. Other information This information is not available. Not oxidising. No ignition, explosion, self-heating or visible decomposition. insoluble SECTION 10: Stability and reactivity Reactivity No data available Chemical stability The product is stable under storage at normal ambient temperatures Possibility of hazardous reactions No hazardous reaction when handled and stored according to provisions Conditions to avoid Protect against direct sunlight. Keep away from heat Incompatible materials Oxidizing agents, strong. Strong acid, Base Hazardous decomposition products No known hazardous decomposition products. SECTION 11: Toxicological information Information on toxicological effects

5 Page 5 of 6 Acute toxicity CAS No Chemical name Exposure routes Method Dose Species (3-biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4-hydroxycoumarin, difenacoum oral dermal LD50 1,8-2,45 mg/kg LD50 17,2-27,4 mg/kg Rat Kaninchen Source Additional information on tests The classification was carried out according to the calculation method of the Preparations Directive (1999/45/EC). SECTION 12: Ecological information Toxicity CAS No Chemical name Aquatic toxicity Method Dose [h] [d] Species Source 3-(3-biphenyl-4-yl-1,2,3,4-tetrahydro-1-naphthyl)-4-hydroxycoumarin, difenacoum Acute fish toxicity Acute crustacea toxicity LC50 0,1 mg/l 96 h Leuciscus idus EC50 0,52 mg/l 48 h Daphnia magna Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects Further information Classification according to Regulation (EC) No. 1272/2008 [CLP] SECTION 13: Disposal considerations Waste treatment methods Advice on disposal Dispose of waste according to applicable legislation. Waste disposal number of waste from residues/unused products MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS; separately collected fractions (except 15 01); pesticides Classified as hazardous waste. Waste disposal number of used product WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by dangerous substances Classified as hazardous waste.

6 Page 6 of 6 Waste disposal number of contaminated packaging WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately collected municipal packaging waste); packaging containing residues of or contaminated by dangerous substances Classified as hazardous waste. Contaminated packaging Water (with cleaning agent). Completely emptied packages can be recycled. SECTION 14: Transport information Land transport (ADR/RID) Other applicable information (land transport) Inland waterways transport (ADN) Other applicable information (inland waterways transport) Marine transport (IMDG) Other applicable information (marine transport) Air transport (ICAO) Other applicable information (air transport) SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 1 - slightly water contaminating Additional information The requirements of TRGS 401 and TRGS 523 (Technischen Regeln für Gefahrstoffe 532 (risk of skin contact, identification - evaluation - measures) and 401 ( biological pest control with very toxic, toxic and harmful substances and preparations)) are to be considered. SECTION 16: Other information Relevant R-phrases (Number and full text) 28 Very toxic if swallowed. 48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed. 50 Very toxic to aquatic organisms. 53 May cause long-term adverse effects in the aquatic environment. Relevant H- and EUH-phrases (Number and full text) H300 Fatal if swallowed. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)