Ferrocene-based Compartmental Ligand for the Assembly
|
|
|
- Gladys Gardner
- 5 years ago
- Views:
Transcription
1 Ferrocene-based Compartmental Ligand for the Assembly of Neutral Zn II /Ln III Heterometallic Complexes Vadapalli Chandrasekhar *, a,b AmitChakraborty, a E. Carolina Sañudo c a Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur , India; b Tata Institute of Fundamental Research, Centre for Interdisciplinary Sciences, 21 Brundavan Colony, Narsingi, Hyderabad , India; c Departament de Química Inorgànica i Institut de Nanociència i Nanotecnologia, Universitat de Barcelona, Diagonal 645, 08028, Barcelona,Spain
2 Figure S1.Molecular structure of 3. Hydrogen atoms are omitted for clarity.
3 Figure S2. Molecular structure of [LZn(μ-OAc)Gd(NO 3 ) 2, 2CHCl 3 ](4).Hydrogen atoms and solvent molecules are omitted for clarity.
4 Figure S3.Molecular structure of LZn(μ-OAc)Er(NO 3 ) 2 (5). Hydrogen atoms are omitted for clarity.
5 Figure S4. Molecular structure of LZn(μ-OAc)Ho(NO 3 ) 2 (6). Hydrogen atoms are omitted for clarity.
6 Figure S5.Molecular structure of LZn(μ-OAc)Eu(NO 3 ) 2 (7). Hydrogen atoms are omitted for clarity
7 (a) (b) Figure S6.Views showing supramoleculaer interactions in 2 (a) hydrogen bonding and π π stacking (b) molecular packing diagram. Some hydrogen atoms have been omitted for the sake of
8 clarity. The metric parameters involved are: C8 H8 O7, (61) Å; C8 H8 O7, (57) ; C10 H10 O7, (10) Å; C10 H10 O7, (68) ; π π, (15) Å; C25 H25B π, (10) Å; C25 H25B π, (65) ; Symmetry transformations used to generate equivalent atoms: #1 -x+1, -y, -z + 1; #2 -x+1, -y, -z+1; #3 x+1, -y, -z, #4 x, 1+y, z. Mass spectroscopy Figure S7.ESI-MS mass spectrum of H 2 L showing the parent ion at m/z 589.1
9 (a) (b) Figure S8.ESI-MS mass spectrum of 3showing the species [LZnTb(NO 3 ) 2 +CH 3 CN] + (a) theoretical simulation (b) experimental spectrum. (a) (b) Figure S9.ESI-MS mass spectrum of4showing the species[lzngd(oac)(no 3 )+CH 3 CN+H 2 O] + (a) theoretical simulation (b) experimental spectrum.
10 (a)(b) Figure S10. ESI-MS mass spectrum of 5showing the species[lzner(oac)+ome] + (a) theoretical simulation (b) experimental spectrum. (a) (b) Figure S11.ESI-MS mass spectrum of 6showing the fragment [LZnHo(NO 3 ) 2 +CH 3 CN] + : (a) theoretical simulation (b) experimental spectrum.
11 (a)(b) Figure S12. ESI-MS mass spectrum of 7 showing the species [LZnEu(OAc) 2 ] + (a) theoretical simulation, (b) experimental spectrum.
12 Electrochemistry Figure S13. Cyclic voltammogram of [LZn(μ-OAc)Tb(NO 3 ) 2 ] in CH 2 Cl 2 using a Glassy-Carbon working electrode and TBAP as supporting electrolyte(scan rate 100mV/s).
13 Figure S14. Cyclic voltammogram of [LZn(μ-OAc)Gd(NO 3 ) 2 ] in CH 2 Cl 2 using Glassy-Carbon working electrode and TBAP as supporting electrolyte(scan rate 100mV/s).
14 Figure S15. Cyclic voltammogram of [LZn(μ-OAc)Er(NO 3 ) 2 ] in CH 2 Cl 2 using Glassy-Carbon working electrode and TBAP as supporting electrolyte(scan rate 100mV/s).
15 Figure S16. Cyclic voltammogram of [LZn(μ-OAc)Ho(NO 3 ) 2 ] in CH 2 Cl 2 using Glassy-Carbon working electrode and TBAP as supporting electrolyte(acan rate 100mV/s).
16 Figure S17. Cyclic voltammogram of [LZn(μ-OAc)Eu(NO 3 ) 2 ] in CH 2 Cl 2 using Glassy-Carbon working electrode and TBAP as supporting electrolyte(scan rate 100mV/s).
![Table S1. Bond Parameters in 3 Coordination environment around Tb(III) ion Bond lengths around Tb[Å] Tb(1)-O(3) 2.292(5) Tb(1)-O(6) 2.310(5) Tb(1)-O(1) 2.330(4) Tb(1)-O(10) 2.446(5) Tb(1)-O(11) 2.](/docs-images/95/125081216/images/17-0.jpg "447(5) Tb(1)-O(9) 2.448(5) Tb(1)-O(7) 2.455(5) Tb(1)-O(2) 2.509(5) Tb(1)-O(4) 2.557(5) Tb(1)-Zn(1) 3.4554(9) Bond Angles around Tb[ ] O(3)-Tb(1)-O(6) 80.13(17) O(3)-Tb(1)-O(1) 66.")
17 Table S1. Bond Parameters in 3 Coordination environment around Tb(III) ion Bond lengths around Tb[Å] Tb(1)-O(3) 2.292(5) Tb(1)-O(6) 2.310(5) Tb(1)-O(1) 2.330(4) Tb(1)-O(10) 2.446(5) Tb(1)-O(11) 2.447(5) Tb(1)-O(9) 2.448(5) Tb(1)-O(7) 2.455(5) Tb(1)-O(2) 2.509(5) Tb(1)-O(4) 2.557(5) Tb(1)-Zn(1) (9) Bond Angles around Tb[ ] O(3)-Tb(1)-O(6) 80.13(17) O(3)-Tb(1)-O(1) 66.53(16) O(6)-Tb(1)-O(1) 77.02(17) O(3)-Tb(1)-O(10) (17) O(6)-Tb(1)-O(10) 75.68(19) O(1)-Tb(1)-O(10) (19) O(3)-Tb(1)-O(11) (19) O(6)-Tb(1)-O(11) 74.51(18) O(1)-Tb(1)-O(11) (17) O(10)-Tb(1)-O(11) 51.67(17) O(3)-Tb(1)-O(9) (17) O(6)-Tb(1)-O(9) (17) O(1)-Tb(1)-O(9) (17) O(10)-Tb(1)-O(9) 83.74(18) O(11)-Tb(1)-O(9) 74.15(17) O(3)-Tb(1)-O(7) 85.87(17) O(6)-Tb(1)-O(7) (17) O(1)-Tb(1)-O(7) 80.26(16) O(10)-Tb(1)-O(7) (17) O(11)-Tb(1)-O(7) (17) O(9)-Tb(1)-O(7) 52.31(16)
18 Coordination environment around Zn(II) ion Bond lengths around Zn [Å] Zn(1)-O(5) 1.989(5) Zn(1)-O(3) 2.052(4) Zn(1)-O(1) 2.093(4) Zn(1)-N(4) 2.110(6) O(3)-Tb(1)-O(2) (15) O(6)-Tb(1)-O(2) 97.07(17) O(1)-Tb(1)-O(2) 64.49(15) O(10)-Tb(1)-O(2) (16) O(11)-Tb(1)-O(2) 70.78(17) O(9)-Tb(1)-O(2) 74.01(17) O(7)-Tb(1)-O(2) 77.84(16) O(3)-Tb(1)-O(4) 64.64(15) O(6)-Tb(1)-O(4) (18) O(1)-Tb(1)-O(4) (15) O(10)-Tb(1)-O(4) 67.60(17) O(11)-Tb(1)-O(4) (17) O(9)-Tb(1)-O(4) 73.92(17) O(7)-Tb(1)-O(4) 71.52(17) O(2)-Tb(1)-O(4) (16) Bond angle containing both Tb and Zn[ ] Zn(1)-O(3)-Tb(1) (19) Zn(1)-O(1)-Tb(1) (19) Bond Angles around Zn[ ] O(5)-Zn(1)-O(3) (19) O(5)-Zn(1)-O(1) 95.37(19) O(3)-Zn(1)-O(1) 75.41(18) O(5)-Zn(1)-N(4) 109.8(2)
![444(6) Gd(1)-O(9) 2.477(5) Gd(1)-O(4) 2.529(6) Gd(1)-O(7) 2.529(5) Gd(1)-O(2) 2.559(6) Gd(1)-Zn(1) 3.4933(10) Bond Angles around Gd[ ] O(6)-Gd(1)-O(3) 76.22(19) O(6)-Gd(1)-O(1) 78.](/docs-images/95/125081216/images/19-1.jpg "8(2) O(3)-Gd(1)-O(1) 65.06(17) O(6)-Gd(1)-O(11) 75.9(2) O(3)-Gd(1)-O(11) 151.65(19) O(1)-Gd(1)-O(11) 104.52(19) O(6)-Gd(1)-O(10) 74.9(2) O(3)-Gd(1)-O(10) 122.21(19) O(1)-Gd(1)-O(10) 149.")
19 Zn(1)-N(2) 2.115(5) O(3)-Zn(1)-N(4) 88.4(2) O(1)-Zn(1)-N(4) 152.5(2) O(5)-Zn(1)-N(2) 100.7(2) O(3)-Zn(1)-N(2) 152.5(2) O(1)-Zn(1)-N(2) 86.7(2) N(4)-Zn(1)-N(2) 99.0(2) Table S2. Bond Parameters of 4 Coordination environment around Gd(III) ion Bond lengths around Gd [Å] Gd(1)-O(6) 2.340(6) Gd(1)-O(3) 2.355(5) Gd(1)-O(1) 2.365(5) Gd(1)-O(11) 2.417(6) Gd(1)-O(10) 2.444(6) Gd(1)-O(9) 2.477(5) Gd(1)-O(4) 2.529(6) Gd(1)-O(7) 2.529(5) Gd(1)-O(2) 2.559(6) Gd(1)-Zn(1) (10) Bond Angles around Gd[ ] O(6)-Gd(1)-O(3) 76.22(19) O(6)-Gd(1)-O(1) 78.8(2) O(3)-Gd(1)-O(1) 65.06(17) O(6)-Gd(1)-O(11) 75.9(2) O(3)-Gd(1)-O(11) (19) O(1)-Gd(1)-O(11) (19) O(6)-Gd(1)-O(10) 74.9(2) O(3)-Gd(1)-O(10) (19) O(1)-Gd(1)-O(10) (19) O(11)-Gd(1)-O(10) 53.6(2) O(6)-Gd(1)-O(9) (19) O(3)-Gd(1)-O(9) (18) O(1)-Gd(1)-O(9) (18) O(11)-Gd(1)-O(9) 82.39(18)
20 O(10)-Gd(1)-O(9) 72.98(19) O(6)-Gd(1)-O(4) 97.5(2) O(3)-Gd(1)-O(4) 64.48(17) O(1)-Gd(1)-O(4) (17) O(11)-Gd(1)-O(4) (19) O(10)-Gd(1)-O(4) 71.08(19) O(9)-Gd(1)-O(4) 75.41(18) O(6)-Gd(1)-O(7) (18) O(3)-Gd(1)-O(7) 81.29(17) O(1)-Gd(1)-O(7) 90.53(18) O(11)-Gd(1)-O(7) (18) O(10)-Gd(1)-O(7) (18) O(9)-Gd(1)-O(7) 51.33(17) O(4)-Gd(1)-O(7) 73.76(18) O(6)-Gd(1)-O(2) 117.7(2) O(3)-Gd(1)-O(2) (18) O(1)-Gd(1)-O(2) 63.26(17) O(11)-Gd(1)-O(2) 69.10(19) O(10)-Gd(1)-O(2) (19) O(9)-Gd(1)-O(2) 74.72(19) O(4)-Gd(1)-O(2) (18) O(7)-Gd(1)-O(2) 73.21(18)
![Coordination environment around Zn(II) ion Bond lengths around Zn [Å] Zn(1)-O(5) 1.995(6) Zn(1)-O(1) 2.041(5) Zn(1)-O(3) 2.094(5) Zn(1)-N(4) 2.101(6) Zn(1)-N(2) 2.](/docs-images/95/125081216/images/21-0.jpg "107(6) Bond angle containing both Gd and Zn[ ] Zn(1)-O(1)-Gd(1) 104.7(2) Zn(1)-O(3)-Gd(1) 103.3(2) Bond Angles around Zn[ ] O(5)-Zn(1)-O(1) 105.0(2) O(5)-Zn(1)-O(3) 94.6(2) O(1)-Zn(1)-O(3) 75.")
21 Coordination environment around Zn(II) ion Bond lengths around Zn [Å] Zn(1)-O(5) 1.995(6) Zn(1)-O(1) 2.041(5) Zn(1)-O(3) 2.094(5) Zn(1)-N(4) 2.101(6) Zn(1)-N(2) 2.107(6) Bond angle containing both Gd and Zn[ ] Zn(1)-O(1)-Gd(1) 104.7(2) Zn(1)-O(3)-Gd(1) 103.3(2) Bond Angles around Zn[ ] O(5)-Zn(1)-O(1) 105.0(2) O(5)-Zn(1)-O(3) 94.6(2) O(1)-Zn(1)-O(3) 75.7(2) O(5)-Zn(1)-N(4) 100.5(2) O(1)-Zn(1)-N(4) 149.8(2) O(3)-Zn(1)-N(4) 86.4(2) O(5)-Zn(1)-N(2) 103.0(2) O(1)-Zn(1)-N(2) 88.4(2) O(3)-Zn(1)-N(2) 158.9(2) N(4)-Zn(1)-N(2) 101.5(2) Table S3. Bond parameters of 5 Coordination environment around Er(III) ion Bond lengths around Er[Å] Er(1)-O(6) 2.260(6) Er(1)-O(3) 2.279(5) Er(1)-O(1) 2.302(5) Er(1)-O(9) 2.407(5) Er(1)-O(7) 2.414(6) Bond Angles around Er[ ] O(6)-Er(1)-O(3) 80.59(19) O(6)-Er(1)-O(1) 76.7(2) O(3)-Er(1)-O(1) 67.62(18) O(6)-Er(1)-O(9) (19) O(3)-Er(1)-O(9) (18)
22 Er(1)-O(10) 2.415(6) Er(1)-O(11) 2.428(6) Er(1)-O(2) 2.480(5) Er(1)-O(4) 2.539(5) Er(1)-Zn(1) (14) O(1)-Er(1)-O(9) (19) O(6)-Er(1)-O(7) (19) O(3)-Er(1)-O(7) 85.59(19) O(1)-Er(1)-O(7) 79.33(18) O(9)-Er(1)-O(7) 53.42(18) O(6)-Er(1)-O(10) 75.0(2) O(3)-Er(1)-O(10) (19) O(1)-Er(1)-O(10) 151.3(2) O(9)-Er(1)-O(10) 85.03(19) O(7)-Er(1)-O(10) (18) O(6)-Er(1)-O(11) 73.7(2) O(3)-Er(1)-O(11) 148.1(2) O(1)-Er(1)-O(11) (19) O(9)-Er(1)-O(11) 74.58(19) O(7)-Er(1)-O(11) (18) O(10)-Er(1)-O(11) 52.58(19) O(6)-Er(1)-O(2) 96.6(2) O(3)-Er(1)-O(2) (18) O(1)-Er(1)-O(2) 65.54(16) O(9)-Er(1)-O(2) 73.39(17) O(7)-Er(1)-O(2) 77.97(18) O(10)-Er(1)-O(2) (18) O(11)-Er(1)-O(2) 70.23(18)
23 O(6)-Er(1)-O(4) 119.2(2) O(3)-Er(1)-O(4) 64.99(17) O(1)-Er(1)-O(4) (17) O(9)-Er(1)-O(4) 72.74(17) O(7)-Er(1)-O(4) 71.70(18) O(10)-Er(1)-O(4) 66.71(19) O(11)-Er(1)-O(4) (19) O(2)-Er(1)-O(4) (17) Coordination environment around Zn(II) ion Bond lengths around Zn [Å] Zn(1)-O(5) 1.985(6) Zn(1)-O(3) 2.061(5) Zn(1)-O(1) 2.082(5) Zn(1)-N(2) 2.102(6) Zn(1)-N(4) 2.109(6) Bond angle containing both Erand Zn[ ] Zn(1)-O(1)-Er(1) 102.7(2) Zn(1)-O(3)-Er(1) 104.2(2) Bond Angles around Zn[ ] O(5)-Zn(1)-O(3) 100.9(2) O(5)-Zn(1)-O(1) 95.0(2) O(3)-Zn(1)-O(1) 75.9(2) O(5)-Zn(1)-N(2) 100.8(2) O(3)-Zn(1)-N(2) 152.8(2) O(1)-Zn(1)-N(2) 86.1(2) O(5)-Zn(1)-N(4) 110.6(2) O(3)-Zn(1)-N(4) 87.7(2) O(1)-Zn(1)-N(4) 152.0(2)
![N(2)-Zn(1)-N(4) 99.8(2) Table S4. Bond Parameters of 6 Coordination environment around Ho(III) ion Bond lengths around Ho [Å] Ho(1)-O(1) 2.279(7) Ho(1)-O(6) 2.288(8) Ho(1)-O(3) 2.319(7) Ho(1)-O(10) 2.](/docs-images/95/125081216/images/24-0.jpg "414(8) Ho(1)-O(11) 2.419(7) Ho(1)-O(9) 2.426(7) Ho(1)-O(7) 2.437(8) Ho(1)-O(4) 2.487(7) Ho(1)-O(2) 2.556(7) Ho(1)-Zn(1) 3.4416(13) Bond Angles around Ho[ ] O(1)-Ho(1)-O(6) 80.9(3) O(1)-Ho(1)-O(3) 67.")
24 N(2)-Zn(1)-N(4) 99.8(2) Table S4. Bond Parameters of 6 Coordination environment around Ho(III) ion Bond lengths around Ho [Å] Ho(1)-O(1) 2.279(7) Ho(1)-O(6) 2.288(8) Ho(1)-O(3) 2.319(7) Ho(1)-O(10) 2.414(8) Ho(1)-O(11) 2.419(7) Ho(1)-O(9) 2.426(7) Ho(1)-O(7) 2.437(8) Ho(1)-O(4) 2.487(7) Ho(1)-O(2) 2.556(7) Ho(1)-Zn(1) (13) Bond Angles around Ho[ ] O(1)-Ho(1)-O(6) 80.9(3) O(1)-Ho(1)-O(3) 67.2(2) O(6)-Ho(1)-O(3) 77.0(3) O(1)-Ho(1)-O(10) 103.4(3) O(6)-Ho(1)-O(10) 75.7(3) O(3)-Ho(1)-O(10) 152.3(3) O(1)-Ho(1)-O(11) 148.8(3) O(6)-Ho(1)-O(11) 74.1(3) O(3)-Ho(1)-O(11) 123.0(3) O(10)-Ho(1)-O(11) 52.7(2) O(1)-Ho(1)-O(9) 128.1(3) O(6)-Ho(1)-O(9) 148.5(3) O(3)-Ho(1)-O(9) 122.2(3) O(10)-Ho(1)-O(9) 84.5(3) O(11)-Ho(1)-O(9) 74.5(3) O(1)-Ho(1)-O(7) 85.0(3) O(6)-Ho(1)-O(7) 155.9(3) O(3)-Ho(1)-O(7) 79.6(2)
25 Coordination environment around Zn(II) ion Bond lengths around Zn [Å] O(10)-Ho(1)-O(7) 126.9(2) O(11)-Ho(1)-O(7) 124.5(3) O(9)-Ho(1)-O(7) 52.9(2) O(1)-Ho(1)-O(4) 131.7(2) O(6)-Ho(1)-O(4) 96.1(3) O(3)-Ho(1)-O(4) 65.3(2) O(10)-Ho(1)-O(4) 122.6(2) O(11)-Ho(1)-O(4) 70.3(2) O(9)-Ho(1)-O(4) 74.1(3) O(7)-Ho(1)-O(4) 78.9(3) O(1)-Ho(1)-O(2) 64.5(2) O(6)-Ho(1)-O(2) 119.0(3) O(3)-Ho(1)-O(2) 124.6(2) O(10)-Ho(1)-O(2) 66.6(2) O(11)-Ho(1)-O(2) 112.4(2) O(9)-Ho(1)-O(2) 72.9(3) O(7)-Ho(1)-O(2) 70.9(3) O(4)-Ho(1)-O(2) 144.5(3) Bond angle containing both Ho and Zn[ ] Zn(1)-O(1)-Ho(1) 104.5(3) Zn(1)-O(3)-Ho(1) 102.6(3) Bond Angles around Zn[ ]
26 Zn(1)-O(5) 2.007(8) Zn(1)-O(1) 2.071(7) Zn(1)-N(4) 2.074(9) Zn(1)-O(3) 2.087(7) Zn(1)-N(2) 2.105(9) O(5)-Zn(1)-O(1) 101.9(3) O(5)-Zn(1)-N(4) 100.3(3) O(1)-Zn(1)-N(4) 152.6(3) O(5)-Zn(1)-O(3) 95.6(3) O(1)-Zn(1)-O(3) 75.4(3) N(4)-Zn(1)-O(3) 86.6(3) O(5)-Zn(1)-N(2) 110.5(3) O(1)-Zn(1)-N(2) 88.2(3) N(4)-Zn(1)-N(2) 98.9(3) O(3)-Zn(1)-N(2) 151.7(3) Table S5. Bond Parameters of 7 Coordination environment around Eu(III) ion Bond lengths around Eu[Å] Eu(1)-O(6) 2.317(4) Eu(1)-O(1) 2.337(3) Eu(1)-O(3) 2.353(4) Eu(1)-O(10) 2.468(4) Eu(1)-O(7) 2.478(4) Eu(1)-O(11) 2.479(4) Eu(1)-O(9) 2.484(4) Eu(1)-O(4) 2.526(4) Eu(1)-O(2) 2.564(4) Bond Angles around Eu[ ] O(6)-Eu(1)-O(1) 79.79(13) O(6)-Eu(1)-O(3) 76.51(13) O(1)-Eu(1)-O(3) 66.34(12) O(6)-Eu(1)-O(10) 76.24(14) O(1)-Eu(1)-O(10) (13) O(3)-Eu(1)-O(10) (14) O(6)-Eu(1)-O(7) (13) O(1)-Eu(1)-O(7) 86.40(13) O(3)-Eu(1)-O(7) 80.65(13)
27 Eu(1)-Zn(1) (12) O(10)-Eu(1)-O(7) (13) O(6)-Eu(1)-O(11) 75.39(13) O(1)-Eu(1)-O(11) (14) O(3)-Eu(1)-O(11) (13) O(10)-Eu(1)-O(11) 51.43(13) O(7)-Eu(1)-O(11) (12) O(6)-Eu(1)-O(9) (13) O(1)-Eu(1)-O(9) (13) O(3)-Eu(1)-O(9) (13) O(10)-Eu(1)-O(9) 83.51(14) O(7)-Eu(1)-O(9) 51.61(13) O(11)-Eu(1)-O(9) 73.89(13) O(6)-Eu(1)-O(4) 96.99(13) O(1)-Eu(1)-O(4) (12) O(3)-Eu(1)-O(4) 64.32(11) O(10)-Eu(1)-O(4) (12) O(7)-Eu(1)-O(4) 77.47(12) O(11)-Eu(1)-O(4) 70.90(13) O(9)-Eu(1)-O(4) 74.36(12) O(6)-Eu(1)-O(2) (14) O(1)-Eu(1)-O(2) 64.13(12) O(3)-Eu(1)-O(2) (12) O(10)-Eu(1)-O(2) 67.73(13)
![Coordination environment around Zn(II) ion Bond lengths around Zn[Å] Zn(1)-O(5) 1.993(4) Zn(1)-O(1) 2.065(4) Zn(1)-O(3) 2.092(3) Zn(1)-N(2) 2.103(4) Zn(1)-N(4) 2.103(4) O(7)-Eu(1)-O(2) 72.](/docs-images/95/125081216/images/28-0.jpg "10(13) O(11)-Eu(1)-O(2) 113.11(13) O(9)-Eu(1)-O(2) 74.41(12) O(4)-Eu(1)-O(2) 145.66(13) Bond angle containing both Eu and Zn[ ] Zn(1)-O(1)-Eu(1) 104.28(14) Zn(1)-O(3)-Eu(1) 102.")
28 Coordination environment around Zn(II) ion Bond lengths around Zn[Å] Zn(1)-O(5) 1.993(4) Zn(1)-O(1) 2.065(4) Zn(1)-O(3) 2.092(3) Zn(1)-N(2) 2.103(4) Zn(1)-N(4) 2.103(4) O(7)-Eu(1)-O(2) 72.10(13) O(11)-Eu(1)-O(2) (13) O(9)-Eu(1)-O(2) 74.41(12) O(4)-Eu(1)-O(2) (13) Bond angle containing both Eu and Zn[ ] Zn(1)-O(1)-Eu(1) (14) Zn(1)-O(3)-Eu(1) (14) Bond Angles around Zn[ ] O(5)-Zn(1)-O(1) (15) O(5)-Zn(1)-O(3) 95.15(15) O(1)-Zn(1)-O(3) 76.23(14) O(5)-Zn(1)-N(2) (16) O(1)-Zn(1)-N(2) 87.72(15) O(3)-Zn(1)-N(2) (16) O(5)-Zn(1)-N(4) (16) O(1)-Zn(1)-N(4) (16) O(3)-Zn(1)-N(4) 86.49(15) N(2)-Zn(1)-N(4) 98.99(17)
29 UV-vis Spectra: UV-Vis and emission spectra of all compound was recorded in CHCl 3 at 10-5 M concentration (Figure S18) and the observed λ max and corresponding ε max are given in Table S6. The free ligand H 2 L exhibit absorption band around 306 and 364 nm whereas the metal complex shows strong absorptionaround 286 and 360 nm. Absorption in case of the metal complex is assigned as ligand centered spin allowed π-π* transition. All the compound 1-7 shows emission at 403 and 426nm in CHCl 3 solution(c~1.0x10-6 ) (Figure S18). The solution state quantum yield was calculated S1 using 8,1-ANS [8-(phenylamino)- 1 -naphthalenesulfonate ] in water as standard, (Table S6). S2 (a) (b) Figure S18. (a) UV/Vis absorption spectra of 1-7. (b) Emission spectra of 1-7.
30 Table S6: Spectroscopic data for 1-7recorded in CHCl3 Complex ligand Zn-Dy Zn-Tb Zn-Gd Zn-Er Zn-Ho Zn-Eu λ max (10-4 ε max ) 306(2.24), 287(10.49), 288(9.33), 286(8.99), 289(9.31), 286(6.39), 286(9.60), 364(1.00), 353(4.23), 352(4.05), 354(3.69), 352(4.17), 355(3.03), 355(4.00), 469(0.14) 453(0.22) 450(0.25) 451(0.15) 467(0.28) 451(0.16) 449(0.21) Solution state 1.74X X X X X X X10-3 Quantum yield(φ) References S1. J. R. Lakowicz, Principles of Fluorescence Spectroscopy, third ed., Springer, New York. S2. J. Lee and G. W. Robinson, J. Am. Chem. Soc., 1985, 107, 6153.
DEPARTMENT OF CHEMISTRY AND CHEMICAL ORGANIC CHEMISTRY II 202-BZG-05 03
DEPARTMENT OF CHEMISTRY AND CHEMICAL TECHNOLOGY ORGANIC CHEMISTRY II 202-BZG-05 03 TEST 1 11 MARCH 2010 INSTRUCTOR: I. DIONNE PRINT YOUR NAME: Answers INSTRUCTIONS: Answer all questions in the space provided.
A pillar[2]arene[3]hydroquinone which can self-assemble to a molecular zipper in the solid state
![A pillar[2]arene[3]hydroquinone which can self-assemble to a molecular zipper in the solid state](/thumbs/86/93673402.jpg "A pillar[2]arene[3]hydroquinone which can self-assemble to a molecular zipper in the solid state")
A pillar[2]arene[3]hydroquinone which can self-assemble to a molecular zipper in the solid state Mingguang Pan, Min Xue* Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China Fax:
Supplementary Material
10.1071/CH15728_AC The Authors 2016 Australian Journal of Chemistry 2016, 69(8), 846-855 Supplementary Material Structural Diversity and Properties of Six Zn II /Cd II Coordination Polymers Based on a
CHEM 242 UV-VIS SPECTROSCOPY, IR SPECTROSCOPY, CHAP 13A ASSIGN AND MASS SPECTROMETRY C 8 H 17 A B C
CEM 242 UV-VIS SPECTRSCPY, IR SPECTRSCPY, CAP 13A ASSIGN AND MASS SPECTRMETRY 1. Which choice matches the max of each steroid in the order given? C 8 17 C 8 17 C 8 17 A B C A. 209 nm 241 nm 284 nm B. 241
Christophe Lincheneau, Bernard Jean-Denis and Thorfinnur Gunnlaugsson* Electronic Supplementary Information
Self-assembly formation of mechanically interlocked [2]- and [3]catenanes using lanthanide ion [Eu(III)] templation and ring closing metathesis reactions Christophe Lincheneau, Bernard Jean-Denis and Thorfinnur
Supporting Information
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Supporting Information A new ICT and CHEF based visible light excitable fluorescent probe easily
Supplementary. A multi-analyte responsive chemosensor vanilinyl Schiff base: fluorogenic. sensing to Zn(II), Cd(II) and I -
Electronic Supplementary Material (ESI) for ew Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre ational de la Recherche Scientifique 2018 Supplementary A multi-analyte
Topic 6 Structure Determination Revision Notes
1) Introduction Topic 6 Structure Determination Revision Notes Mass spectrometry, infrared spectroscopy and NMR spectroscopy can be used to determine the structure of unknown compounds 2) Mass spectrometry
Supplementary data file. Three-in-one type fluorescent sensor based on pyrene pyridoxal cascade for the selective
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2017 Supplementary data file Three-in-one type fluorescent sensor based on pyrene pyridoxal
Identification of Aromatic Fatty Acid Ethyl Esters
Chapter 3.2 Identification of Aromatic Fatty Acid Ethyl Esters The only use of gas chromatography is not sufficient to determine which compounds are eluting from the catalytic bed. At the beginning of
Supporting Information:
Supporting Information: ESI-MS Studies and Calculations on 2 nd Generation Grubbs and on Hoveyda-Grubbs thenium Olefin Metathesis Catalysts Hao-Yang Wang a, Wai-Leung Yim b, Yin-Long Guo a, and Jürgen
Abstract. Keywords: Zinc Oxide, Eu doped ZnO, Dy doped ZnO, Thin film INTERNATIONAL JOURNAL OF INFORMATION AND COMPUTING SCIENCE ISSN NO:
Synthesis and Structural study of Rare Earth activated ZnO Thin film Pawan Kumar Department of Physics, University Institute of Sciences, Chandigarh University, Gharuan (Mohali), Punjab (India) e-mail-pawan.uis@cumail.in
A 3D Porous Metal-Organic Framework Exhibiting Selective. Adsorption of Water over Organic Solvents
Supporting Information for A 3D Porous Metal-Organic Framework Exhibiting Selective Adsorption of Water over Organic Solvents Jin-Zhong Gu, Long Jiang, Wen-Guan Lu, Hong-Cai Zhou, and Tong-Bu Lu* Table
Chapter 12: Mass Spectrometry: molecular weight of the sample
Structure Determination: hapter 12: Mass Spectrometry- molecular weight of the sample; formula hapter 12: Infrared Spectroscopy- indicated which functional groups are present hapter 13: Nuclear Magnetic
Supporting Information. for
Supporting Information for Syntheses, Structures and Properties of thenium Complexes of Tridentate Ligands: Isolation and Characterization of a Rare Example of thenium itrosyl Complex Containing {O} 5
Naoya Takahashi, Keiya Hirota and Yoshitaka Saga* Supplementary material
Supplementary material Facile transformation of the five-membered exocyclic E-ring in 13 2 -demethoxycarbonyl chlorophyll derivatives by molecular oxygen with titanium oxide in the dark Naoya Takahashi,
Photon upconversion via triplet triplet annihilation
Photon upconversion via triplet triplet annihilation Photon upconversion: the process wherein light of long wavelength is frequency converted to photons of higher energy. Triplet triplet annihilation (TTA)
Supplementary Information. Intramolecular 5-exo, 7-endo-dig Transition Metal-Free Cyclization
Electronic Supplementary Material (ESI) for Green Chemistry. This journal is The Royal Society of Chemistry Supplementary Information Intramolecular -exo, -endo-dig Transition Metal-Free Cyclization Sequence
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 4-(4-Pyridyl)pyridinium bis(pyridine-2,6- dicarboxylato)chromium(iii) tetrahydrate Janet Soleimannejad,
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 catena-poly[{di-l-isonicotinato-bis- [diaquaisonicotinatoeuropium(iii)]}-l- isonicotinato-[diisonicotinatocopper(ii)]-
CHM 424L Organic Laboratory, Dr. Laurie S. Starkey Introduction to Mass Spectrometry
CM 424L rganic Laboratory, Dr. Laurie S. Starkey Introduction to Mass Spectrometry Mass spectrometry is used to determine a sample's molecular mass and molecular formula. Some structural information can
Supporting Information. A Two-In-One Fluorescent Sensor With Dual Channels to. Discriminate Zn 2+ and Cd 2+
Electronic Supplementary Material (ESI) for RS Advances Supporting Information A Two-In-One Fluorescent Sensor With Dual hannels to Discriminate Zn 2 and d 2 Li-Kun Zhang, a Guang-Fu Wu, a Ying Zhang,
Self-organization of dipyridylcalix[4]pyrrole into a supramolecular cage for dicarboxylates
![Self-organization of dipyridylcalix[4]pyrrole into a supramolecular cage for dicarboxylates](/thumbs/94/118164746.jpg "Self-organization of dipyridylcalix[4]pyrrole into a supramolecular cage for dicarboxylates")
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information Self-organization of dipyridylcalix[4]pyrrole into a supramolecular
Zn 2+ Triggered Amide Tautomerization Produces a Highly Zn 2+ Selective, Cell Permeable and Ratiometric Fluorescent Sensor
Supporting Information For Zn 2+ Triggered Amide Tautomerization Produces a Highly Zn 2+ Selective, Cell Permeable and Ratiometric Fluorescent Sensor Zhaochao Xu,*,, Kyung-Hwa Baek, Ha Na Kim, Jingnan
Supporting Information
Supporting Information Enhanced visible-light photocatalytic activity of g-c 3 N 4 /Zn 2 GeO 4 heterojunctions with effective interfaces based on band match Liming Sun, Yue Qi, Chun-Jiang Jia, Zhao Jin,
Your Name: Question 1. Spectrum Prediction I: Ethyl Acetoacetate. (15 points) ppm ppm ppm ppm. J(A,D) = 8 Hz = 0.
Question 1. Spectrum Prediction I: Ethyl Acetoacetate. (15 points) A B C D 4.202 ppm 3.451 ppm 2.273 ppm 1.288 ppm J(A,D) = 8 Hz = 0.08 ppm (in CDCl 3 ) Draw the 100 MHz H-NMR spectrum to scale. Draw splitting
Development of Pyridine Based o-aminophenolate Zinc Complexes as Structurally Tunable Catalysts for CO 2 Fixation into Cyclic Carbonates
Electronic Supplementary Material (ESI) for New Journal of Chemistry. This journal is The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2017 Electronic Supporting Information
Final Exam, Page 1 of 15. Your full signature
Final Exam, Page 1 of 15 Your full signature Print your full name Your SID If you are making up an I grade Indicate the semester you took the course Name of the instructor for that course: This exam has
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 2-(2-Pyridyl)pyridinium bis(pyridine-2,6- dicarboxylato-j 3 O,N,O 0 )aluminate(iii) trihydrate Janet Soleimannejad,
Electrochemical Behavior of Cu 2+ -Histidine Complexes on a Glassy Carbon Electrode
Electrochemical Behavior of Cu 2+ -Histidine Complexes on a Glassy Carbon Electrode Yu-Ching Weng and Tian-Hao Cheng Department of Chemical Engineering, Feng Chia University, Taichung, Taiwan, 407 Reprint
Reagent-Free Electrophoretic Synthesis of Few-Atom- Thick Metal Oxide Nanosheets
Supporting Information Reagent-Free Electrophoretic Synthesis of Few-Atom- Thick Metal Oxide Nanosheets Chengyi Hou,*,, Minwei Zhang, Lili Zhang, Yingying Tang, Hongzhi Wang, and Qijin Chi*, State Key
2. Experimental Crystal data
data reports Metal-organic coordination complexes of N,N 0 -bis(salicylidene)ethylenediamine (salen) Schiff-base derivatives have been studied extensively within the fields of homogeneous catalysis (Wezenberg
A novel quinoline-based two-photon fluorescent probe for detecting Cd 2+ in vitro and in vivo
Supporting Information A novel quinoline-based two-photon fluorescent probe for detecting Cd 2+ in vitro and in vivo Yiming Li, a,b Hanbao Chong, a Xiangming Meng,* a Shuxin Wang, a Manzhou Zhu a and Qingxiang
The peculiar behavior of Picha in the formation of metallacrown complexes with Cu(II), Ni(II) and Zn(II), in aqueous solution
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 15 Supplementary Information for the paper The peculiar behavior of Picha in the formation
Engineering of Ministry of Education, Institute of Molecular Science, Shanxi University, Taiyuan , China.
Indicator approach to develop a chemosensor for the colorimetric sensing of thiol-containing in water and its application for the thiol detection in plasma Fang-Jun Huo, a Yu-Tao Yang, b Jing Su, b Yuan-Qiang
Electronic Supplementary Material
Electronic Supplementary Material PAMAM Dendrimers Bearing Electron-Donating Chromophores: Fluorescence and Electrochemical Properties Bing-BingWang a, Xin Zhang a, Ling Yang a, Xin-Ru Jia* a, Yan Ji a,
bio-mof-1 DMASM Wavenumber (cm -1 ) Supplementary Figure S1 FTIR spectra of bio-mof-1, DMASMI, and bio-mof-1 DMASM.
bio-mof-1 Transmittance bio-mof-1 DMASM DMASMI 2000 1500 1000 500 Wavenumber (cm -1 ) Supplementary Figure S1 FTIR spectra of bio-mof-1, DMASMI, and bio-mof-1 DMASM. Intensity (a.u.) bio-mof-1 DMASM as
Electronic Supporting Information for
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2015 Electronic Supporting Information for Rhodamine based Turn-On Fluorescent Probe for Pb(II)
Supporting Information
Supporting Information R6G/8-AQ co-functionalized Fe 3 O 4 @SiO 2 nanoparticles for fluorescence detection of trace Hg 2+ and Zn 2+ in aqueous solution Yao Gu 1,2, Guowen Meng 1,3*, Meiling Wang 1, Qing
Electronic Supplementary Information
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2016 Electronic Supplementary Information MnO 2 -induced synthesis of fluorescent polydopamine nanparticles
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Dichlorido(4,4 0 -di-tert-butyl-2,2 0 -bipyridine-j 2 N,N 0 )palladium(ii) dimethyl sulfoxide monosolvate
= (3) = (3) = (4) V = (4) Å 3 Z =2. Data collection. Refinement
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 = 95.181 (3) = 112.830 (3) = 106.243 (4) V = 948.7 (4) Å 3 Z =2 Mo K radiation = 0.07 mm 1 T = 298 (2) K 0.41
Supporting Information. Magnetic Field and Chirality Effects on Electrochemical Charge Transfer Rates: Spin. Dependent Electrochemistry
Supporting Information Magnetic Field and Chirality Effects on Electrochemical Charge Transfer Rates: Spin Dependent Electrochemistry Prakash Chandra Mondal, 1 Claudio Fontanesi, 1,2 David H. Waldeck,
Department of Biochemistry, Midnapur Medical College and Hospital, Midnapore , India
Analytical Methods in Chemistry Volume 212, Article ID 198, pages doi:1.1/212/198 Research Article Identification of Medicinally Active Ingredient in Ultradiluted Digitalis purpurea: Fluorescence Spectroscopic
Supporting Information
Supporting Information A single design strategy for dual sensitive ph probe with a suitable range to map ph in living cells Kang-Kang Yu, Ji-Ting Hou, Kun Li, * Qian Yao, Jin Yang, Ming-Yu Wu, Yong-Mei
Lysoquinone-TH1, a new polyphenolic tridecaketide produced by expressing the lysolipin minimal PKS II in Streptomyces albus
Supplemental Information Lysoquinone-TH1, a new polyphenolic tridecaketide produced by expressing the lysolipin minimal PKS II in Streptomyces albus Torben Hofeditz, 1 Claudia Eva-Maria Unsin 2, Jutta
Porphyrins: Chemistry and Biology
Porphyrins: Chemistry and Biology 20.109 Lecture 6 24 February, 2011 Goals Explore some essential roles of heme in biology Appreciate how ature has used the same cofactor to achieve diverse functions Gain
Chemical Surface Transformation 1
Chemical Surface Transformation 1 Chemical reactions at Si H surfaces (inorganic and organic) can generate very thin films (sub nm thickness up to µm): inorganic layer formation by: thermal conversion:
Your Name: Answer Key Question 1. Standard Fragmentations in Mass Spectrometry. (20 points)
MU, hemistry 8160, FS08, Dr. Glaser Your ame: Answer Key Question 1. Standard Fragmentations in Mass Spectrometry. (20 points) For (b) (d), draw the complete structure of the substrate (all atoms, lone
Supplementary Materials for
advances.sciencemag.org/cgi/content/full/2/12/e1601838/dc1 Supplementary Materials for General and programmable synthesis of hybrid liposome/metal nanoparticles Jin-Ho Lee, Yonghee Shin, Wooju Lee, Keumrai
Supporting Information
Supporting Information Self-hydroxylation of perbenzoic acids at a nonheme iron(ii) center Na Young Oh, a Mi Sook Seo, a Mi Hee Lim, a Mark B. Consugar, b Mi Joo Park, a Jan-Uwe Rohde, b Jaehong Han, a
Asian Journal of Pharmaceutical Analysis and Medicinal Chemistry Journal home page:
Banu Rekha J and Jaykar. / Asian Journal of Pharmaceutical Analysis and Medicinal Chemistry. 3(2), 2015, 76-81. Research Article CODEN: AJPAD7 ISSN: 2321-0923 Asian Journal of Pharmaceutical Analysis and
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Bis{3-amino-1-carbamothioyl-5-[(2-{[(5- methyl-1h-imidazol-3-ium-4-yl)methyl]- sulfanyl}ethyl)amino]-1h-1,2,4-triazol-4-
Supporting Information. 58 Pages. 6 Figures 4 Tables
Light-Source-Dependent Effects of Main Water Constituents on Photodegradation of Phenicol Antibiotics: Mechanism and Kinetics Linke Ge, Jingwen Chen, * Xianliang Qiao, Jing Lin, Xiyun Cai Key Laboratory
SUPPORTING INFORMATION. Lysine Carbonylation is a Previously Unrecognized Contributor. to Peroxidase Activation of Cytochrome c by Chloramine-T
Electronic Supplementary Material (ESI) for Chemical Science. This journal is The Royal Society of Chemistry 2019 SUPPORTING INFORMATION Lysine Carbonylation is a Previously Unrecognized Contributor to
Copyright 2016 Dan Dill 1
carbonate These solutions are mixed and a precipitate forms. After the precipitation, the solution 1. will be positively charged 2. will be electrically neutral 3. will be negatively charged 4. More information
Synthesis, Characterization and Evaluation of Anti-Inflammatory Activity of Acetaminophen Complexes of Copper (II) and Zinc (II) Ions
International Journal of Biomedical Materials Research 2017; 5(6): 78-83 http://www.sciencepublishinggroup.com/j/ijbmr doi: 10.11648/j.ijbmr.20170506.13 ISSN: 2330-7560 (Print); ISSN: 2330-7579 (Online)
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Diaquabis{4-[(pyridin-2-yl)methylideneamino]benzenesulfonato-j 2 N,N 0 }- nickel(ii) tetrahydrate Chao-Zhu
J-Type Hetero-Exciton Coupling Effect on an Asymmetric
Supporting Information J-Type Hetero-Exciton Coupling Effect on an Asymmetric Donor Acceptor Donor-Type Fluorophore Yuichi Kitagawa *, Ryuto Yachi, Takayuki Nakanishi, Koji Fushimi, and Yasuchika Hasegawa
Supplementary Material to Oxidative properties of FeO2+: electronic structure and solvation effects.
Supplementary Material to Oxidative properties of FeO2+: electronic structure and solvation effects. Manuel J. Louwerse and Evert Jan Baerends Theoretical Chemistry, Vrije Universiteit Amsterdam, De Boelelaan
Electronic Supporting Information
Electronic Supporting Information Detection of Hg 2+ by Cyanobacteria in Aqueous media. Moorthy Suresh, Sanjiv K. Mishra, Sandhya Mishra* and Amitava Das* Contents 1. Absorption spectrum of C-Phycocyanin
Graphene Quantum Dots-Band-Aids Used for Wound Disinfection
Supporting information Graphene Quantum Dots-Band-Aids Used for Wound Disinfection Hanjun Sun, Nan Gao, Kai Dong, Jinsong Ren, and Xiaogang Qu* Laboratory of Chemical Biology, Division of Biological Inorganic
C. K. Manju, Jyoti Sarita Mohanty, Depanjan Sarkar, Sudhakar Chennu and Thalappil Pradeep a *
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2018 Electronic supplementary information (ESI): Towards atomically precise
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 (Benzoato-j 2 O,O 0 )(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-j 4 N,N 0,N 00,N 000 )nickel(ii)
Metal swap between Zn 7 metallothionein 3 and amyloid β Cu protects against amyloid β toxicity
Metal swap between Zn 7 metallothionein 3 and amyloid β Cu protects against amyloid β toxicity Supplementary Information Gabriele Meloni 1, Vanessa Sonois 2,3, Tamara Delaine 2, Luc Guilloreau 2, Audrey
Singlet oxygen photosensitisation by the fluorescent probe Singlet Oxygen Sensor Green
Singlet oxygen photosensitisation by the fluorescent probe Singlet Oxygen Sensor Green Xavier Ragàs, Ana Jiménez-Banzo, David Sánchez-García, Xavier Batllori and Santi Nonell* Grup d Enginyeria Molecular,
SYNTHESIS, SPECTROSCOPIC AND FUNGICIDAL STUDIES OF COPPER SOAPS DERIVED FROM MUSTARD AND SOYABEAN OILS AND THEIR UREA COMPLEXES
Int. J. Chem. Sci.: 10(1), 2012, 143-149 ISSN 0972-768X www.sadgurupublications.com SYNTHESIS, SPECTROSCOPIC AND FUNGICIDAL STUDIES OF COPPER SOAPS DERIVED FROM MUSTARD AND SOYABEAN OILS AND THEIR UREA
Available online Research Article
Available online www.jocpr.com Journal of Chemical and Pharmaceutical Research, 2015, 7(12):519-523 Research Article ISSN : 0975-7384 CDEN(USA) : JCPRC5 Characterization of cyanidin 3-(6-acetylglucoside)-5-(3
Supplementary Information
Supplementary Information for Chemical Synthesis of Blue-emitting Metallic Zinc Nano-hexagons Nguyen T. Mai, Trinh T. Thuy, Derrick M. Mott and Shinya Maenosono* School of Materials Science, Japan Advanced
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Chlorido(2-chloronicotinato)triphenylantimony(V) Li Quan, Handong Yin* and Daqi Wang College of Chemistry
Development of a near-infrared fluorescent probe for monitoring hydrazine in serum and living cells
Supporting Information for Development of a near-infrared fluorescent probe for monitoring hydrazine in serum and living cells Sasa Zhu, Weiying Lin,* Lin Yuan State Key Laboratory of Chemo/Biosensing
Supporting Information
Supporting Information Complete Series of {FeNO} 8, {FeNO} 7 and {FeNO} 6 complexes stabilized by a tetracarbene macrocycle Claudia Kupper, Julian A. Rees, Sebastian Dechert, Serena DeBeer, Δ and Franc
Experimental. Crystal data. C 32 H 25 NO 5 M r = Monoclinic, C2=c a = (6) Å b = (2) Å c = (3) Å = 96.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Methyl 9-hydroxy-15-methyl-2-oxo-11- (pyren-1-yl)-10-oxa-15-azatetracyclo- [7.6.0.0 1,12.0 3,8 ]pentadeca-3(8),4,6-
Electronic Supplementary Information. High-Yield Bottom-Up Synthesis of 2D Metal Organic Frameworks
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry A. This journal is The Royal Society of Chemistry 2017 Electronic Supplementary Information High-Yield Bottom-Up Synthesis of
Copyright Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2003 Chem. Eur. J Supporting Information. for
Copyright Wiley-VCH Verlag GmbH & Co. KGa, 69451 Weinheim, 2003 Chem. Eur. J. 2003 Supporting Information for Kinetics of quation and nation of Ruthenium(II) rene nticancer Complexes, cidity and X-ray
Enhanced NIR-I Emission from Water-Dispersible NIR-II Dye-sensitized Core/Active Shell Upconverting Nanoparticles
Electronic Supplementary Material (ESI) for Journal of Materials Chemistry C. This journal is The Royal Society of Chemistry 2018 Supporting Information Enhanced NIR-I Emission from Water-Dispersible NIR-II
Supplementary Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2018 Supplementary Information Oxidative Tandem Annulation of 1 (2 Ethynylaryl)prop 2 en 1 ones Catalyzed
Electronic Supporting Information for. Self-sorting of Dynamic Metallosupramolecular Libraries via. Metal-Driven Selection
Electronic Supporting Information for Self-sorting of Dynamic Metallosupramolecular Libraries via Metal-Driven Selection Istvan Kocsis, a,b Dan Dumitrescu, a Yves-Marie Legrand, a Arie van der Lee, a Ion
Supporting Information
This journal is The Royal Society of Chemistry 011 Supporting Information Vertically-Aligned ZnO Nanorods Doped with Lithium for Polymer Solar Cells: Defect Related Photovoltaic Properties Pipat Ruankham,
An Investigative Study of Reactions Involving Glucosinolates and Isothiocyanates
An Investigative Study of Reactions Involving Glucosinolates and Isothiocyanates Alzea Chrisel H. Alea 1, Diane Elaine T. Co 2 and Marissa G Noel 3* 1,2,3Chemistry Department, De La Salle University, 2401
Transparent ALD-grown Ta2O5 protective layer for highly stable ZnO photoelectrode in solar water splitting
Electronic Supplementary Material (ESI) for Chemical Communications. This journal is The Royal Society of Chemistry 2015 Transparent ALD-grown Ta2O5 protective layer for highly stable ZnO photoelectrode
3/27/2011. Chapter 8 Reactions of Alkenes and Alkynes. Alkene Addition Reactions. 8.1 Preparing Alkenes: A Preview of Elimination Reactions
John E. McMurry http://www.cengage.com/chemistry/mcmurry Chapter 8 Reactions of Alkenes and Alkynes Richard Morrison University of Georgia, Athens Alkene Addition Reactions Alkene addition reactions Addition
Fig.S1 ESI-MS spectrum of reaction of ApA and THPTb after 16 h.
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Experiment Cleavage of dinucleotides Dinucleotides (ApA, CpC, GpG, UpU) were purchased from
Supporting information for the article
Supporting information for the article S1 Exceptional behavior of Ni 2 O 2 species revealed by ESI-MS and MS/MS studies in solution. Application of superatomic core to facilitate new chemical transformations
Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2
Chapter 20: Carboxylic Acids and Nitriles شیمی آلی 2 Dr M. Mehrdad University of Guilan, Department of Chemistry, Rasht, Iran m-mehrdad@guilan.ac.ir Based on McMurry s Organic Chemistry, 7 th edition The
metal-organic compounds
metal-organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 catena-poly[[bis[aqua(1,10-phenanthroline)lead(ii)]-bis(l 3-2-hydroxy-5-sulfonatobenzoato)] acetic acid
Supporting Information
Electronic Supplementary Material (ESI) for ChemComm. This journal is The Royal Society of Chemistry 2015 Supporting Information A Nonheme Manganese(IV)-Oxo Species Generated in Photocatalytic Reaction
Electronic Supplementary Information
Electronic Supplementary Information A Novel and Facile Zn-mediated Intramolecular Five-membered Cyclization of β-tetraarylporphyrin Radicals from β-bromotetraarylporphyrins Dong-Mei Shen, Chao Liu, Qing-Yun
Experimental. Crystal data
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 Bis[8-ethyl-5-oxo-2-(piperazin-4-ium-1- yl)-5,8-dihydropyrido[2,3-d]pyrimidine- 6-carboxylic acid] 2,5-dicarboxybenzene-1,4-dicarboxylate
Laboratoire de Chimie et Biologie des Métaux, Université Grenoble Alpes, CNRS UMR 5249, CEA, 17 rue des Martyrs, F Grenoble, Cedex, France
Electronic upplementary Material (EI) for Chemical cience. This journal is The Royal ociety of Chemistry 2018 Electronic upporting Information for Insights into Mechanism and Aging of a noble-metal free
Mechanochemical Doping of a Non-Metal Element into Zinc Oxide
Chemistry for Sustainable Development 15 (2007) 249 253 249 Mechanochemical Doping of a Non-Metal Element into Zinc Oxide J. WANG, J. F. LU, Q. W. ZHANG, S. YIN, T. SATO and F. SAITO Institute of Multidisciplinary
S. Bakkialakshmi et al Int. J. Chem. Pharm. Sci., 2013,Vol.1(1) Available online at
S. Bakkialakshmi et al Int. J. Chem. Pharm. Sci., 3,Vol.() Available online at www.pharmaresearchlibrary.com Pharma Research Library International Journal of Chemistry and Pharmaceutical Sciences 3, Vol.
Bio Ionic Liquids: Room Temperature Ionic Liquids Composed Wholly of Biomaterials
SUPPORTING INFORMATION Bio Ionic Liquids: Room Temperature Ionic Liquids Composed Wholly of Biomaterials Yukinobu Fukaya a, Yoshiki Iizuka a, Kenta Sekikawa a, and Hiroyuki Ohno a * a Department of Biotechnology,
This exam consists of two parts. Part I is multiple choice. Each of these 25 questions is worth 2 points.
MBB 407/511 Molecular Biology and Biochemistry First Examination - October 1, 2002 Name Social Security Number This exam consists of two parts. Part I is multiple choice. Each of these 25 questions is
Electronic Supporting Information
Electronic Supplementary Material (ESI) for Materials Chemistry Frontiers. This journal is the Partner Organisations 2018 Electronic Supporting Information Tetraphenylpyrazine-based luminogens with full-colour
Mass Spectrometry Introduction
Mass Spectrometry Introduction Chem 744 Spring 2013 What MS is and is not MS is NOT a spectroscopic method. Molecules are not absorbing EM radiation MS is the generation, separation and characterization
Supporting Materials
Electronic Supplementary Material (ESI) for Dalton Transactions. This journal is The Royal Society of Chemistry 2018 Supporting Materials A bifunctional cationic metal-organic framework based on nonanuclear
Tunable surface plasmon resonance and enhanced electrical. conductivity of In doped ZnO colloidal nanocrystals
Electronic Supplementary Material (ESI) for Nanoscale. This journal is The Royal Society of Chemistry 2014 Abs (normalised) Electronic Supplementary Information : Tunable surface plasmon resonance and
Identification of novel endophenaside antibiotics produced by Kitasatospora sp. MBT66
SUPPORTING INFORMATION belonging to the manuscript: Identification of novel endophenaside antibiotics produced by Kitasatospora sp. MBT66 by Changsheng Wu 1, 2, Gilles P. van Wezel 1, *, and Young Hae
Experimental. Crystal data. C 24 H 25 NOSi M r = Monoclinic, P2 1 =c a = (3) Å b = (19) Å c = (6) Å = 124.
organic compounds Acta Crystallographica Section E Structure Reports Online ISSN 1600-5368 N-[(9H-Fluoren-9-ylidene)(2-methoxyphenyl)methyl]-1,1,1-trimethylsilanamine Zhong-Yuan Li, Peng Wang and Xia Chen*