SAFETY DATA SHEET Clean Hands

Transcription

1 Clean Hands Page 1 of 9 SAFETY DATA SHEET Clean Hands The safety data sheet is in accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) SECTION 1: Identification of the substance / mixture and of the company / undertaking Date issued Product identifier Product name Clean Hands 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/preparation Detergent Details of the supplier of the safety data sheet Company name Postal address Postcode City Tel Fax Website Swiech & Co AB Birger Jarlsgatan 18 A S Stockholm +46 (0) info@swiech.se Emergency telephone number Emergency telephone Description: Dial for acute emergency: 112 SECTION 2: Hazards identification 2.1. Classification of substance or mixture Classification according to Regulation (EC) No 1272/2008 [CLP / GHS] Flam. Liq. 3; H226 Skin Sens. 1; H317 STOT SE2; H Label elements Hazard Pictograms (CLP) Composition on the label A mixture of: 5-chloro-2-methyl-4-isothiazolin-3-one [EC no ] and 2-methyl-2H - isothiazol-3-one [EC no ] (3:1) 0,05 %, Etanol 13 %

2 Clean Hands Page 2 of 9 Signal word Hazard statements Precautionary statements Warning H226 Flammable liquid and vapour. H317 May cause an allergic skin reaction. H371 May cause damage to organs P102 Keep out of reach of children. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P260 Do not breathe vapours. P270 Do not eat, drink or smoke when using this product. P333+P313 If skin irritation or rash occurs: Get medical advice / attention. P501 Dispose of contents / container to avfallshanterare 2.3. Other hazards PBT / vpvb Not PBT or vpvb. SECTION 3: Composition/information on ingredients 3.2. Mixtures Substance Identification Classification Contents A mixture of: 5-chloro-2-methyl- 4-isothiazolin-3-one [EC no ] and 2-methyl-2H - isothiazol-3-one [EC no ] (3:1) CAS no.: Index no.: Water CAS no.: EC no.: Glycerol CAS no.: EC no.: Aloe vera extract CAS no.: EC no.: Acute Tox. 3;H331 Acute Tox. 3;H311 Acute Tox. 3;H301 Skin Corr. 1B;H314 Skin Sens. 1;H317 Aquatic Acute 1;H400 Aquatic Chronic 1;H410 0,05 % 37 % 2,7 % 0,4 % Paper 46,7 % Perfume 0,3 % Etanol CAS no.: EC no.: Index no.: Description of the mixture SECTION 4: First aid measures 4.1. Description of first aid measures Flam. Liq. 2; H225 Acute tox. 4; H302 STOT SE2; H371 This product is an aqueous solution in a porous solid material. 13 % General Inhalation Skin contact Eye contact Ingestion Get medical attention if any discomfort continues. Do not give victim anything to drink if he is unconscious. Fresh air and rest. Wash skin with soap and water. Rinse cautiously with water for several minutes. Rinse nose, mouth and throat with water Most important symptoms and effects, both acute and delayed General symptoms and effects

3 Clean Hands Page 3 of Indication of any immediate medical attention and special treatment needed Other Information Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water spray, foam, dry powder or carbon dioxide. Water spray Special hazards arising from the substance or mixture Fire and explosion hazards During fire, gases hazardous to health may be formed Advice for firefighters Personal protective equipment Wear protective gloves / protective clothing / eye protection / face protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures Collect spillage Environmental precautions Environmental precautionary measures Avoid discharge into drains, water courses or onto the ground Methods and material for containment and cleaning up Clean up Collect spillage Reference to other sections Other instructions See section 7, 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handling Avoid contact with eyes and prolonged skin contact Conditions for safe storage, including any incompatibilities Storage Keep out of reach of children. Flammable/combustible Keep away from oxidisers, heat and flames Specific end use(s) Specific use(s) See section 1.2 SECTION 8: Exposure controls/personal protection 8.1. Control parameters Substance Identification Value TWA Year Etanol CAS no.: TWA (8h): 1000 ppm OEL Short Term Value Value: 1920 mg/m³ TWA Year: 1993

4 Clean Hands Page 4 of Exposure controls Hygiene / environmental Specific hygiene measures When using do not eat, drink or smoke. Appropriate environmental exposure control Environmental exposure controls Refer to section 6 and 12. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Colour Odour Odour limit Wet wipes White. Odour of alcohol. ph Value: 6,5 7 Melting point / melting range Freezing point Boiling point / boiling range Value: 100 C : No information. Flash point Value: > 46 C : (liquid) Evaporation rate Value: > 1 Flammability (solid, gas) Lower explosion limit with unit of measurement Upper explosion limit with units of measurement Vapour pressure Vapour density Yes : No information. : No information. Specific gravity Value: > 1 : ( H2O = 1) Solubility Partition coefficient: n- octanol/water Spontaneous combustability Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2. Other information : Partially : Other physical and chemical properties

5 Clean Hands Page 5 of 9 SECTION 10: Stability and reactivity Reactivity Reactivity No known hazardous reactivity under normal handilng and use conditions Chemical stability Stability Stable under normal temperature conditions and recommended use Possibility of hazardous reactions Possibility of hazardous reactions No hazardous reactions known under normal use conditions Conditions to avoid Conditions to avoid Avoid heat, flames and other sources of ignition Incompatible materials Materials to avoid Strong oxidising substances Hazardous decomposition products Hazardous decomposition products During fire, toxic gases (CO, CO2) are formed. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Value: 3450 mg/kg Species: Mouse Value: 7060 mg/kg Effect Tested: LC50 Duration: 4 hour(s) Value: 39 mg/m³ Species: Mouse Value: mg/kg Species: Rat Test reference: Glycerol ( ) Route of exposure: Dermal Value: > mg/kg Species: Rabbit Test reference: Glycerol ( )

6 Clean Hands Page 6 of 9 Value: 100 mg/kg Species: Rat Test reference: PVP Jod ( ) Value: 1040 mg/kg Species: Rabbit Test reference: PVP Jod ( ) Value: > 40 mg/kg Species: Mouse Test reference: PVP Jod ( ) Value: 457 mg/kg Species: Rat Test reference: CMIT/MIT, 3:1 ( ) Duration: 10 hour(s) Value: ppm Species: Rat Other information regarding health hazards Assessment of acute toxicity classification Skin corrosion / irritation, other information Inhalation Skin contact Eye contact Ingestion Sensitisation Mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity SE, human experience Specific target organ toxicity RE, human experience Aspiration hazard, comments The product is classified as Acute Toxic category 4 Harmful if swallowed. Sensitising. The product is classified as Specific target organ toxicity, Single Exposure. SECTION 12: Ecological information Toxicity Acute aquatic, fish Value: mg/l

7 Clean Hands Page 7 of 9 Effect dose concentration : LC50 Exposure time: 96 hour(s) Species: Rainbow trout Value: mg/l Effect dose concentration : LC50 Exposure time: 24 hour(s) Species: Fingerling trout Value: > 5000 mg/l Effect dose concentration : LC50 Species: Goldfish Test reference: Glycerol ( ) Ecotoxicity Value: mg/l Effect dose concentration : LC50 Species: Pimephales promelas Test reference: Glycerol ( ) Not classified as dangerous to the environment Persistence and degradability Persistence and degradability There are no data on the degradability of this product Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation Mobility in soil Mobility No data recorded Results of PBT and vpvb assessment PBT assessment results Not Classified as PBT/vPvB by current EU criteria Other adverse effects Other adverse effects / Remarks SECTION 13: Disposal considerations Waste treatment methods Specify the appropriate methods of disposal Confirm disposal procedures with environmental engineer and local regulations. SECTION 14: Transport information Dangerous goods No UN number The product is not classified as dangerous goods UN proper shipping name

8 Clean Hands Page 8 of Transport hazard class(es) Packing group Environmental hazards Special precautions for user Special safety precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Additional information. Additional information. The product is not classified as dangerous goods. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Legislation and regulations Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (REACH). Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. The List of Wastes (England) (Amendment) Regulations (SI 2005 No. 895). EH40/2005, Workplace exposure limits 2005, with amendments Chemical safety assessment Chemical safety assessment performed No SECTION 16: Other information Supplier's notes List of relevant H-phrases (Section 2 and 3). The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H301 Toxic if swallowed. H302 Harmful if swallowed. H311 Toxic in contact with skin. H314 Causes severe skin burns and eye damage.

9 Clean Hands Page 9 of 9 Classification according to Regulation (EC) No 1272/2008 [CLP / GHS] Key literature references and sources for data H317 May cause an allergic skin reaction. H331 Toxic if inhaled. H371 May cause damage to organs H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Flam. Liq. 3; H226 Skin Sens. 1; H317 STOT SE2; H371 MSDS supplied by the manufacturer