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1 Page 1/11 * 1 Identification of the substance/mixture and of the company/undertaking. Product identifier.. Article number: CAS Number: EINECS Number: Index number: Registration number Relevant identified uses of the substance or mixture and uses advised against For some uses this substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18(4) for transported isolated intermediates. The uses are specified in the attached dokument. Application of the substance / the preparation Raw material. Details of the supplier of the safety data sheet. Manufacturer/Supplier: RÜTGERS Novares GmbH Varziner Straße 49 resins@ruetgers-group.com D Duisburg Tel : Fax : Information: see: Section 16 (Contact) MSDS@ruetgers-group.com. Emergency telephone number: see: Manufacturer/Supplier * 2 Hazards identification. Classification of the substance or mixture. Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 3 H226 Flammable liquid and vapour. GHS08 health hazard Muta. 1B Carc. 1A Asp. Tox. 1 H340 May cause genetic defects. H350 May cause cancer. H304 May be fatal if swallowed and enters airways. GHS09 environment Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects. GHS07

2 Page 2/11 Skin Irrit. 2 H315 Causes skin irritation.. Classification according to Directive 67/548/EEC or Directive 1999/45/EC T; Toxic R45-46: May cause cancer. May cause heritable genetic damage. Xn; Harmful R65: Harmful: may cause lung damage if swallowed. Xi; Irritant R38: Irritating to skin. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R10: Flammable.. Classification system: The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information furnished by supplier companies.. Label elements. Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation.. Hazard pictograms GHS02, GHS07, GHS08, GHS09. Signal word Danger. Hazard-determining components of labelling: benzene naphthalene Naphtha (petroleum), steam-cracked middle arom.. Hazard statements H226 Flammable liquid and vapour. H315 Causes skin irritation. H340 May cause genetic defects. H350 May cause cancer. H304 May be fatal if swallowed and enters airways. H411 Toxic to aquatic life with long lasting effects.. Precautionary statements P234 Keep only in original container. P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P273 Avoid release to the environment. P308+P313 IF exposed or concerned: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/ shower. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P403+P235 Store in a well-ventilated place. Keep cool. P501 Dispose of contents/container in accordance with local/regional/national/international regulations.. Other hazards. Results of PBT and vpvb assessment. PBT: Not applicable.

3 Page 3/11. vpvb: Not applicable. * 3 Composition/information on ingredients. Chemical characterization: Substances. CAS No. Designation: Naphtha (petroleum), steam-cracked middle arom.. Identification number(s):. EINECS Number: Index number: Description: Solvent mixture.. Dangerous components: CAS: EINECS: CAS: EINECS: CAS: EINECS: CAS: EINECS: CAS: EINECS: CAS: EINECS: CAS: EINECS: Reg.-Nr.: styrene Xn R20; Xi R36/38 R10 GHS02 Flam. Liq. 3, H226; GHS07 Acute Tox. 4, H332; Skin Irrit. 2, H315; Eye Irrit. 2, H319 xylene, mixed isomers Xn R20/21; Xi R38 R10 GHS02 Flam. Liq. 3, H226; GHS07 Acute Tox. 4, H312; Acute Tox. 4, H332; Skin Irrit. 2, H315 indene GHS02 Flam. Liq. 3, H226 2-phenylpropene Xi R36/37; N R51/53 R10 GHS02 Flam. Liq. 3, H226; GHS09 Aquatic Chronic 2, H411; GHS07 Eye Irrit. 2, H319; STOT SE 3, H335 Vinyltoluene Xn R20; Xi R36/37 R10 GHS02 Flam. Liq. 3, H226; GHS07 Acute Tox. 4, H332; Eye Irrit. 2, H319; STOT SE 3, H335 indan R10 GHS02 Flam. Liq. 3, H226 naphthalene Xn R22-40; N R50/53 Carc. Cat. 3 GHS08 Carc. 2, H351; GHS09 Aquatic Acute 1, H400; Aquatic Chronic 1, H410; GHS07 Acute Tox. 4, H302 < 20% < 20% < 10% < 10% < 10% < 10% < 10%

4 Page 4/11 CAS: EINECS: CAS: EINECS: CAS: EINECS: Reg.-Nr.: toluene Xn R48/ ; Xi R38; F R11 R67 Repr. Cat. 3 GHS02 Flam. Liq. 2, H225; GHS08 Repr. 2, H361d; STOT RE 2, H373; Asp. Tox. 1, H304; GHS07 Skin Irrit. 2, H315; STOT SE 3, H336 ethylbenzene Xn R20; F R11 GHS02 Flam. Liq. 2, H225; GHS07 Acute Tox. 4, H332 benzene T Carc. Cat. 1, Muta. Cat. 2 R /23/24/25; Xn R65; Xi R36/38; F R11 GHS02 Flam. Liq. 2, H225; GHS08 Muta. 1B, H340; Carc. 1A, H350; STOT RE 1, H372; Asp. Tox. 1, H304; GHS07 Skin Irrit. 2, H315; Eye Irrit. 2, H319. Additional information For the wording of the listed risk phrases refer to section 16. < 5% < 5% < 5% 4 First aid measures. Description of first aid measures. General information Instantly remove any clothing soiled by the product. Remove breathing apparatus only after soiled clothing has been completely removed. In case of irregular breathing or respiratory arrest provide artificial respiration.. After inhalation Supply fresh air; consult doctor in case of symptoms.. After skin contact Instantly wash with water and soap and rinse thoroughly. Seek medical treatment.. After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.. After swallowing Do not induce vomiting; instantly call for medical help.. Information for doctor Therapeutically measures: basic help, decontamination, symptomatic treatment. 5 Firefighting measures. Extinguishing media. Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fire with foam.. For safety reasons unsuitable extinguishing agents Water with a full water jet.. Special hazards arising from the substance or mixture Can be released in case of fire Carbon monoxide (CO). Advice for firefighters. Protective equipment: Do not inhale explosion gases or combustion gases. Wear self-contained breathing apparatus. 6 Accidental release measures. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away.. Environmental precautions: Do not allow product to reach sewage system or water bodies.

5 Page 5/11. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Dispose of contaminated material as waste according to item 13. Ensure adequate ventilation.. Reference to other sections See Section 8 for information on personal protection equipment. 7 Handling and storage. Handling. Precautions for safe handling Open and handle container with care. Keep breathing equipment ready.. Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect against electrostatic charges.. Conditions for safe storage, including any incompatibilities. Storage. Requirements to be met by storerooms and containers: Store in cool location.. Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. * 8 Exposure controls/personal protection. Additional information about design of technical systems: No further data; see item 7.. Control parameters. Components with limit values that require monitoring at the workplace: styrene WEL () Short-term value: 1080 mg/m³, 250 ppm Long-term value: 430 mg/m³, 100 ppm xylene, mixed isomers WEL () Short-term value: 441 mg/m³, 100 ppm Long-term value: 220 mg/m³, 50 ppm Sk; BMGV indene WEL () Short-term value: 72 mg/m³, 15 ppm Long-term value: 48 mg/m³, 10 ppm phenylpropene WEL () Short-term value: 491 mg/m³, 100 ppm Long-term value: 246 mg/m³, 50 ppm toluene WEL () Short-term value: 384 mg/m³, 100 ppm Long-term value: 191 mg/m³, 50 ppm Sk

6 Page 6/ ethylbenzene WEL () Short-term value: 552 mg/m³, 125 ppm Long-term value: 441 mg/m³, 100 ppm benzene WEL () Long-term value: 1 ppm Carc; Sk. PNECs naphthalene PNEC STP 2.9 mg/kg (-) PNEC aqua 2.4 ug/l (freshwater) 50 ug/l (intermittent release) 2.4 ug/l (marine water) PNEC sediment 67.2 mgkg (freshwater) 67.2 mgkg (marine water) PNEC soil 53.3 mg/kg (-). Exposure controls. Personal protective equipment. General protective and hygienic measures Keep away from foodstuffs, beverages and food. Special rooms for washing, showering and changing are required. Wash hands during breaks and at the end of the work. Store protective clothing separately.. Breathing equipment: In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air.. Protection of hands: Only use chemical-protective gloves with CE-labelling of category III (EN 374).. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.. Penetration time of glove material The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.. For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable: Nitril rubber, NBR Butyl rubber, BR e.g. glove of Fa. KCL, (sitemap): Camatril (art.-no. 731, 730, level 2, >30min), Butoject (art.-no.: 898, level 2, >30min). As protection from splashes gloves made of the following materials are suitable: Nitril rubber,nbr e.g. oneway gloves fa. KCl Dermatril (Art.-No. 740). Eye protection: Tightly sealed safety glasses. Gauze goggles. Body protection: Solvent resistant protective clothing

7 Page 7/11 * 9 Physical and chemical properties. Information on basic physical and chemical properties. General Information. Appearance: Form: Fluid Colour: Yellowish. Odour: aromatic. Change in condition Melting point/melting range: < -30 C Boiling point/boiling range: C. Flash point: 43 C (DIN EN 22719). Ignition temperature: ca. 500 C. Self-inflammability: Product is not selfigniting.. Danger of explosion: Vapours may form explosive mixtures with air.. Critical values for explosion: Lower: Upper: 1.2 Vol % (Benzene) 8.0 Vol % (Benzene). Density at 20 C 0.91 g/cm3. Solubility in / Miscibility with Water: Not miscible or difficult to mix. Viscosity: kinematic at 25 C: 1 mm²/s (DIN ). Other information The data in this chapter cover product groups. For product-specific data see the corresponding Technical Information. 10 Stability and reactivity. Reactivity. Chemical stability. Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.. Possibility of hazardous reactions No dangerous reactions known. Hazardous decomposition products: No dangerous decomposition products known * 11 Toxicological information. Information on toxicological effects. Acute toxicity:. LD/LC50 values that are relevant for classification: styrene Oral LD mg/kg (mouse)

8 Page 8/ mg/kg (rat) Inhalative LC50 (4h) 11.9 mg/l (rat) naphthalene Oral LD50 > 2000 mg/kg (rat) (OECD Guideline 401) Dermal LD50 > 2000 mg/kg (rat) (OECD Guideline 402) Sensitisation Skin Sens. not sensitising (guinea pig) (OECD Guideline 406) benzene Oral LD mg/kg (rat) Dermal LD mg/kg (mouse) Inhalative LC50 (4h) 44.5 mg/l (mouse). Components Type Value Species styrene EC mg/l (daphnia) LC mg/l (fish) benzene EC mg/l (algae) LC mg/l (daphnia) mg/l (fish). Primary irritant effect:. on the skin: Irritations of the skin are possible naphthalene Irritation of skin Irr. not irritating (rabbit) (similar OECD 404). on the eye: Irritations of the mucous membranes are possible naphthalene Irritation of eyes Irr. not irritating (guinea pig) (similar OECD 405). Sensitization: No sensitizing effect known.. CMR effects (carcinogenity, mutagenicity and toxicity for reproduction) Carc. Cat. 2, Muta. Cat Ecological information. Toxicity. Acquatic toxicity: naphthalene EC50 (48h) mg/l (daphnia) (OECD Guideline 202) LC50 (96h) 1.6 mg/l (fish) (OECD Guideline 203). Persistence and degradability No further relevant information available.. Additional ecological information:. General notes: Do not allow product to reach ground water, water bodies or sewage system, even in small quantities. Danger to drinking water if even extremely small quantities leak into soil.

9 Page 9/11. Results of PBT and vpvb assessment. PBT: Not applicable.. vpvb: Not applicable. 13 Disposal considerations. Waste treatment methods. Recommendation Remove according to local authority recommendations, e.g. convey to a suitable incinerator.. European waste catalogue The waste code classification is to be carried out according to the European Waste Catalogue (EWC) specifically for each branch of industry and each type of process.. Uncleaned packagings:. Recommendation: Disposal must be made according to official regulations. * 14 Transport information. Land transport ADR/RID (cross-border). ADR/RID Class: 3 Flammable liquids.. Hazard Index Number: 30. Substance Index Number: Packaging group: III. Label: 3. Special marking: Symbol (fish and tree). UN proper shipping name: 3295 HYDROCARBONS, LIQUID, N.O.S.. Excepted quantities (EQ): E1. Limited quantities (LQ) LQ7. Tunnel restriction code D/E. Inland shipping ADN/ADNR:. ADN/ADNR Class: 3. Substance Index Number: Designation of goods: 3295 HYDROCARBONS, LIQUID, N.O.S. (XYLENE). Maritime transport IMDG:. IMDG Class: 3. UN Number: Label 3. Packaging group: III. EMS Number: F-E,S-D. Marine pollutant: -. Correct technical name: HYDROCARBONS, LIQUID, N.O.S.. Air transport ICAO-TI and IATA-DGR:. ICAO/IATA Class: 3. UN/ID Number: Label 3. Packaging group: III. Correct technical name: HYDROCARBONS, LIQUID, N.O.S.. UN "Model Regulation": UN3295, HYDROCARBONS, LIQUID, N.O.S., 3, III

10 Page 10/11. Special precautions for user Warning: Flammable liquids. 15 Regulatory information. Safety, health and environmental regulations/legislation specific for the substance or mixture. National regulations. Information about limitation of use: Employment restrictions concerning young persons must be observed. Employment restrictions concerning pregnant and lactating women must be observed.. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information This data is based on our present knowledge. However, it shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship.. Relevant phrases H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H302 Harmful if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H350 May cause cancer. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. R10 Flammable. R11 Highly flammable. R20 Harmful by inhalation. R20/21 Harmful by inhalation and in contact with skin. R22 Harmful if swallowed. R36/37 Irritating to eyes and respiratory system. R36/38 Irritating to eyes and skin. R38 Irritating to skin. R40 Limited evidence of a carcinogenic effect. R45 May cause cancer. R46 May cause heritable genetic damage. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. R48/23/24/25 Toxic: danger of serious damage to health by prolonged exposure through inhalation, in contact with skin and if swallowed.

11 Page 11/11 R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63 Possible risk of harm to the unborn child. R65 Harmful: may cause lung damage if swallowed. R67 Vapours may cause drowsiness and dizziness.. Department issuing data specification sheet: Product Safety Department Tel.: Contact: Tel.: Fax.: Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) PNEC: Predicted No-Effect Concentration (REACH) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent. Sources GESTIS Stoffdatenbank ( CEFIC-ERI-Card ( REACH Dossier (European Regulation Dossier). * Data compared to the previous version altered. Replaces material safety data sheet from *