Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 1 0 Health Hazard Fire Hazard 1 0 See Section 15. Section 1. Chemical Product and Company Identification Common Name/ Trade Name Manufacturer Oxsol 100 Commercial Name(s) Oxsol 100 Synonym Chemical Name SPECTRUM LABORATORY PRODUCTS INC. 144 S. SAN PEDRO STREET GARDENA, CA Chloro-4-(trifluoromethyl)benzene; 4-Chlorobenzotrifluoride Toluene, p-chloro-alpha, alpha, alpha-trifluoro- Catalog Number(s). CAS# RTECS TSCA CI# C16, YY XS TSCA 8(b) inventory: Oxsol 100 IN CASE OF EMERGENCY CHEMTREC (4hr) Page Number: 1 Chemical Family Chemical Formula Supplier C7-H4-Cl-F3 SPECTRUM LABORATORY PRODUCTS INC. 144 S. SAN PEDRO STREET GARDENA, CA 9048 CALL (310) Section.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight 1) Oxsol Toxicological Data on Ingredients Oxsol 100: ORAL (LD50): DERMAL (LD50): Acute: mg/kg [Rat] mg/kg [Mouse]. Acute: >700 mg/kg [Rabbit]. Section 3. Hazards Identification Potential Acute Health Effects Slightly hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance may be toxic to kidneys, liver, central nervous system (CNS). Repeated or prolonged exposure to the substance can produce target organs damage.

2 Oxsol 100 Page Number: Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation Ingestion Serious Ingestion If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Seek medical attention. Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Flammable. >500 C (93 F) CLOSED CUP: C (109 F). (Tagliabue.) LOWER: 0.9% UPPER: 10.5% These products are carbon oxides (CO, CO), halogenated compounds. Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Never direct a water jet in the container in order to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion. Section 6. Accidental Release Measures Small Spill Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Flammable liquid, insoluble in water. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

3 Oxsol 100 Page Number: 3 Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses. Lab coat. Gloves (impervious). Personal Protection in Case of a Large Spill Exposure Limits Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Fish. Molecular Weight ph (1% soln/water) g/mole Not applicable. Taste Color Clear Colorless. Boiling Point 136 C (76.8 F) C. Melting Point -36 C (-3.8 F) Critical Temperature Specific Gravity (Water = 1) Vapor Pressure 0.7 kpa (@ 0 C) Vapor Density 6.3 (Air = 1) Volatility 100% (w/w). Odor Threshold <1 ppm Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility The product is more soluble in oil; log(oil/water) = 3.7 Very slightly soluble in cold water. Solubility in Water: 9 3 C. Section 10. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Heat, ignition sources (sparks, flames), incompatible materials Reactive with oxidizing agents.

4 Oxsol 100 Page Number: 4 Strongly exothermic reaction with dimethylsulfonate Corrosivity Polymerization Will not occur. Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. Inhalation. Acute oral toxicity (LD50): mg/kg [Mouse]. Acute dermal toxicity (LD50): >700 mg/kg [Rabbit]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: kidneys, liver, central nervous system (CNS). Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. Lethal Dose/Conc. 50% Kill: LC50[Rat] - Route: Inhalation; Dose: g/m3 LC50[Mouse] - Route: Inhalation; Dose: 0 gm/m3 May affect genetic material Acute Potential Health Effects: Skin: May cause skin irritation. It can be absorbed through the skin. Eyes: May cause eye irritation. Inhalation: May cause respiratory tract irritation. May affect behavior/central nervous system and produce symptoms of central nervous system depression including headache, dizziness loss of balance, drowsiness, and nausea. It may also cause bronchitis, pneumonia, and pulmonary edema. Ingestion: May cause gastrointestinal tract irritation. May cause damage to lining of gastrointestinal tract. May affect behavior/central nervous system with symptoms to that of inhalation. Chronic Potential Health Effects: Ingestion and Inhalation: Repeated or prolonged breathing or ingestion may cause liver and kidney damage and may also affect the blood, metabolism, and urinary system based on animal studies. It may also affect behavior/central nervous with symptoms similar to that of acute inhalation and ingestion. Section 1. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Ecotoxicity in water (LC50): 13.5 mg/l 96 hours [Fish (Trout)]. 1 mg/l 96 hours [Fish (Blue gill sunfish)]. 1.4 mg/l 48 hours [daphnia]. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are more toxic than the product itself. Section 13. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations.

5 Oxsol 100 Page Number: 5 Section 14. Transport Information DOT Classification Identification CLASS 3: Flammable liquid. UNNA: 34 : Chlorobenzotrifluoride PG: III Special Provisions for Transport DOT Section 15. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Oxsol 100 TSCA 8(d) H and S data reporting: Oxsol 100: Effective: 4/9/83; Sunset: 4/9/93 California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. OSHA: Hazardous by definition of Hazard Communication Standard (9 CFR ). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS B-3: Combustible liquid with a flash point between 37.8 C (100 F) and 93.3 C (00 F). CLASS D-B: Material causing other toxic effects (TOXIC). DSCL (EEC) R10- Flammable. R36/37/38- Irritating to eyes, respiratory system and skin. S9- Keep container in a well-ventilated place. S16- Keep away from sources of ignition - No smoking. S6- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S33- Take precautionary measures against static discharges. S37- Wear suitable gloves. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 1 0 a National Fire Protection Association (U.S.A.) Health 1 0 Flammability Specific hazard WHMIS (Canada)

6 Oxsol 100 Page Number: 6 DSCL (Europe) TDG (Canada) 3 ADR (Europe) Protective Equipment Not applicable. Lab coat. Not applicable. Safety glasses. Section 16. Other Information MSDS Code References Other Special Considerations YY849 Validated by Sonia Owen on 10/9/007. Verified by Sonia Owen. Printed 1/16/008. CALL (310) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.