Zinc T mg/l Zn Zincon

Transcription

1 Zinc T mg/l Zn Zincon 400 Instrument specific information The test can be performed on the following devices. In addition, the required cuvette and the absorption range of the photometer are indicated. Instrument Type Cuvette λ Measuring Range MD 600, MD 610, MD 640, ø 24 mm 610 nm mg/l Zn MultiDirect SpectroDirect, XD 7000, XD 7500 ø 24 mm 616 nm mg/l Zn Material Required material (partly optional): Reagents Packaging Unit Part Number Copperr/Zinc LR Tablet / BT Copperr/Zinc LR Tablet / BT EDTA in presence of copper Tablet / BT EDTA in presence of copper Tablet / BT Dechlor in presence of chlorine Tablet / BT Application List Waste Water Treatment Raw Water Treatment Cooling Water Galvanization Preperation 1. In the case of high levels of residual chlorine, perform the analysis with a dechlorinated water sample. To dechlorinate the sample, add a DECHLOR tablet to a 24mm vial with the water sample. Then add the Copper/Zinc LR tablet (point 2) and continue with the test procedure as described. 2. Strong alkaline or acidic water samples should be adjusted between to about ph 9 before the analysis (use 1 mol/l Sulphuric acid or 1 mol/l Sodium hydroxide). NL EN Handboek Handbook van of Methoden Methods 05/18

2 Notes 1. When using the copper/zinc LR tablets, the Zincon indicator reacts with both the zinc and the copper. Therefore, the specified measuring range may possibly refer to the total concentration of both ions. 2. The addition of an EDTA tablet during the second step of the analysis ensures that any copper presence is not measured. NL EN Handboek Handbook van of Methods Methoden 05/18 05/18

3 Implementation of the provision Zinc with Tablet Select the method on the device 10 ml Fill 24 mm vial with 10 ml sample. Add COPPER/ ZINK LR tablet. 24 mm Crush tablet(s) by rotating slightly. Close vial(s). Dissolve tablet(s) by inverting. 5 min Sample Place sample vial in the sample chamber. Pay attention to the positioning. Zero Press the ZERO button. Wait for 5 minute(s) reaction time. Once the reaction period is finished, the measurement takes place automatically. NL EN Handboek Handbook van of Methoden Methods 05/18

4 Remove the vial from the sample chamber. Add EDTA tablet. 24 mm Crush tablet(s) by rotating slightly. Close vial(s). Dissolve tablet(s) by inverting. Sample Place sample vial in the sample chamber. Pay attention to the positioning. Test Press the TEST (XD: START) button. The result in mg/l Zinc appears on the display. NL EN Handboek Handbook van of Methods Methoden 05/18 05/18

5 Chemical Method Zincon Appendix Interferences Removeable Interferences If there is a presence of interfering metals, pre-isolation of zinc is recommended by means of an ion exchanger, precipitation of the metals with ammonia, pre-extraction of the zinc from hydrochloric acid medium using methyldioctylamine or triisooctylamine solution in methyl isobutyl ketone, etc.. Concentrations above 1 mg/l urea can lead to results within the measuring range. A plausibility test (dilution of the sample) is recommended. Interference from / [mg/l] Cu 2E-3 Co 0,03 Ni 0,02 Al 0,005 Fe 0,01 Cd 0,001 Mn 0,01 Derived from Hach Method 8009 US EPA approved for Wastewater a) determination of free, combined and total b) Reactor is necessary for COD (150 C), TOC (120 C) and total -chromium, - phosphate, -nitrogen, (100 C) c) MultiDirect: Adapter is necessary for Vacu-vials (Order code ) d) Spectroquant is a Merck KGaA Trademark e) alternative reagent, used instead of DPD No.1/No.3 in case of turbidity in the water sample caused by high concentration of calcium and/or high conductivity f) additionally required for determination of bromine, chlorine dioxide and ozone in the presence of chlorine g) Reagent recovers most insoluble iron oxides without digestion h) additionally required for samples with hardness values above 300 mg/l CaCO 3 i) high range by dilution # including stirring rod, 10 cm NL EN Handboek Handbook van of Methoden Methods 05/18

6 NL EN Handboek Handbook van of Methods Methoden 05/18 05/18 Zinc T / 400