HEALTH HAZARDS WHEN GETTING IN CONTACT WITH CHEMICALS
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- Cassandra Osborne
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1 HEALTH HAZARDS WHEN GETTING IN CONTACT WITH CHEMICALS The ancient Civilizations already knew the effects for human health of certain chemical substances To poison their enemies In the XVIII century some illnesses were connected to certain professional activities Cancer Silicosis Lead poisoning Chimney sweeps Coal minning Lead industries J.L. Sanz
2 Knowledge about Health Hazards of chemical substances is HIGH MAIN SOURCES Animal Experimentation Essays in vitro Studies with humans Methods without essay Directive 86/609/CEE Researches using cells or cell tissues Epidemiological studies; accidental poisoning; and human experimentation Q(SAR) methods; FULL information Scientifical literature, data bases, internet, etc.
3 The information can be used to classify and inform about health hazards to every agent who takes part in the supply chain Producers Importers Suppliers Downstream users The final objetive: To protect humans from the hazardous effects of chemicals Adopts the GHS on Classification, Labelling and Packaging of substances and mixtures The Regulation (EC) No 1272/2008 (CLP) The aim is the use all around the world of the same criteria to classify the hazardous substances and to inform about this classification
4 LABELLING Simple and easy way to comunícate chemical hazards According to CLP The Label has to include the following four elements 1. Pictograms Health Hazards 1. Hazard pictograms 2. Signal words 3. Hazard Statements 4. Precautionary Statements Specifically 2. Signal words: Danger Warning 3. Hazard Statements: H Precautionary Statements P200. for advises P300. for replaies P400. for stored P500. for waste elimination
5 CLASSIFICATION Related to Health hazards, CLP classifies the hazardous substances and mixtures according to the following 10 properties. 1. Acute toxicity 6. Carcinoginicity 2. Skin corrosión/irritation 7. Reproductive toxicity 3. Serious eye damage/ eye irritation 8. Specific target organ toxicity- (single ex.) 4. Respiratory or skin sensitisation 9. Specific target organ toxicity- (repeated ex.) 5. Germ cell mutagenicity 10. Aspiration hazard 1. Acute toxicity No substance is a poison by itself, it s the dose which turns a substance into a poison. Paracelso (s. XV) Acute toxicity: The ability of chemical agent to cause the death of the half of all laboratory animals (DL50) under essay after the administration of a DOSE. DOSE ACUTE TOXICITY J.L.Sanz
6 Category 1 Category 2 Category 3 Category 4 According to the DOSE needed, 4 toxicity categories NaCN Danger Danger Danger Warning Fatal Fatal Toxic Harmful H300, H310, H330 H300, H310, H330 H301, H3011, H331 H302, H312, H Skin corrosion/irritation 3. Serious eye damage/eye irritation CORROSIVES These chemicals cause irreversible damage to the skin Danger IRRITANTS These chemicals cause reversible damage to the skin Warning H314 (skin) H318 (eye) H315 (skin) H319 (eye) Alkali/Acids NaOH, H2SO4 Organic solvents xilene, toluene, etc.
7 4. Respiratory or skin sensitization A respiratory sensitizer substances are those that will cause Danger H334 Asthma Breathing problems A skin sensitizer substances are those that will lead to an allergic response following skin contact Isocyanates, mineral oil Warning H Germ Cell Mutagenicity 6. Carcinogenicity. 7. Reproductive toxicity MUTAGENS Mutations in human germ cells that can be transmitted to the progeny. CARCINOGENS Induce Cancer or increase its incidence REPRODUCTIVE TOXICANTS Adverse effect on sexual function and fertility or on develop. in humans
8 Category 1: chemicals may cause the effect (mutation, cancer or reproductive toxicity) Category 1 1A or 1B Category 2 1A Positive evidence from human epidemiological studies 1B Positive evidence from studies with laboratory animals Category 2: chemicals suspected to cause the effect (mutation, cancer or reproductive toxicity) Danger Warning Mutagens H340 H341 Carcinogens H350 H351 Reproductive H360 H361 Toxicants But not convincing evidences Vinyl chloride, benzene, formaldehyde, Chromiun VI compounds 8. Specific target organ toxicity (s. exp.) 9. Specific target organ toxicity (rep. exp) Include chemicals that cause a significant toxic effect in an organ or biological system, apart from the effects talked about previously, from a single exposure or from repeated exposures.
9 In both cases chemicals are classified in two categories according with the dose needed and the severity of the effect. Category 1 Category 2 Danger Warning Single exposure H370 H371 Metals and metal compounds of Cd, Pb H372 Repeated exp. H372 H373 But for single exposure there is a third category that includes narcotical and respiratory irritating substances and mixtures. Category 3 Warning NOx Acrolein H335 Organic solvents H336 Respiratory irritanting Narcotic H336 H335
10 10. Aspiration Hazard This hazard is connected with aerosol substances, usually dispensed in selfpressurized containers. The key to classifying these products is if a pool of product is formed in the mouth or nose which then may be aspirated The aspiration may cause acute effects as pneumonia, pulmonary injury or death Classification criteria = viscosity Category 1 Danger H304 hydrocarbons, turpentine and pine oil. CLASSIFICATION COMUNICATION PHYSICAL HAZARDS ENVIROMENTAL HAZARDS
11 ThaT s all folks Danke für Ihre Aufmerksamkeit Txelis Sanz 31/01/2018
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Date of issue: 27/06/2013 Revision date: 03/12/2014 Supersedes: 16/12/2009 Version: 6.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product
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SECTION 1: Identification of the hazardous chemical and of the supplier Product name : Product code : 000000609659 Type of product : liquid Manufacturer or supplier's details Company : Sika Kimia Sdn.
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Azur A
Azur A CAS No 531-53-3 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Azur A CAS-No. : 531-53-3
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SECTION 1: Identification of the hazardous chemical and of the supplier Product name : Product code : 000000611895 Type of product : liquid Manufacturer or supplier's details Company : Sika Kimia Sdn.