MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Material name Revision date 01-29-2014 Version # 02 CAS # Mixture Product code FG400055, 200085 Product use Manufacturer/Supplier Consumer product. Telephone number: (540) 667-8700 Rubbermaid Commercial Products LLC 124 Valley Avenue Winchester, VA 22601-2694 Contact Person: Regulatory Manager Emergency 24-Hour Emergency: INFOTRAC: 1-800-55-505 2. Hazards Identification Physical state Appearance Emergency overview Liquid. Semi hazy liquid. Flammable liquid and vapor. Potential hazards that may occur if product is not used according to the consumer label are as follows: Direct contact with the eye may cause irritation. OSHA regulatory status This product is not hazardous according to OSHA 29CFR 1910.1200. Potential health effects Eyes Skin Inhalation Ingestion Potential environmental effects May cause eye irritation. Health injuries are not known or expected under normal use. Not applicable.. Composition / Information on Ingredients No harmful effects expected in amounts likely to be ingested by accident. Not expected to be harmful to aquatic organisms. Components CAS # Percent Alcohols, C9-11, ethoxylated Ethyl alcohol Isopropyl alcohol Cinnamaldehyde 6849-46- -7 64-17-5 1-5 67-6-0 1-5 104-55-2 0.1-1 Composition comments All concentrations are in percent by weight. 4. First Aid Measures First aid procedures Eye contact Skin contact Inhalation Ingestion Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyes wide apart. Get medical attention if symptoms persist. Not applicable. Not applicable. Seek medical advice. 5. Fire Fighting Measures Flammable properties Flammable liquid and vapor. Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance to a source of ignition and flash back. Prevent build-up of vapors or gasses to explosive concentrations. 1 / 6
Extinguishing media Suitable extinguishing media Fire fighting equipment/instructions Water fog. Alcohol foam. Carbon dioxide (CO2). Dry chemical. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Use water spray to keep fire-exposed containers cool. 6. Accidental Release Measures Methods for cleaning up Eliminate all ignition sources. Flush area clean with lots of water. Be aware of potential for surfaces to become slippery. 7. Handling and Storage Handling Storage Observe good industrial hygiene practices. Keep away from heat, sparks, and flame. Keep container closed. Keep at room temperature. Protect from freezing. Keep out of reach of children. 8. Exposure Controls / Personal Protection Occupational exposure limits US. ACGIH Threshold Limit Values Ethyl alcohol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Ethyl alcohol (64-17-5) PEL 1900 mg/m Isopropyl alcohol (67-6-0) PEL 980 mg/m Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Ethyl alcohol (64-17-5) 1880 mg/m Isopropyl alcohol (67-6-0) STEL 984 mg/m 492 mg/m Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Ethyl alcohol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Ethyl alcohol (64-17-5) STEL Isopropyl alcohol (67-6-0) STEL Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Ethyl alcohol (64-17-5) 1880 mg/m Isopropyl alcohol (67-6-0) STEL 120 mg/m 500 ppm 98 mg/m Mexico. Occupational Exposure Limit Values Ethyl alcohol (64-17-5) 1900 mg/m 2 / 6
Mexico. Occupational Exposure Limit Values Isopropyl alcohol (67-6-0) STEL 1225 mg/m 500 ppm 980 mg/m Engineering controls Personal protective equipment Eye / face protection Skin protection Respiratory protection 9. Physical & Chemical Properties Appearance Color Odor Odor threshold Physical state Form No special requirements under ordinary conditions of use and with adequate ventilation. No protection is ordinarily required under normal conditions of use. No protection is ordinarily required under normal conditions of use. No protection is ordinarily required under normal conditions of use. Semi hazy liquid. Pale yellow. Not assigned. Liquid. Liquid. ph 4.5-5.2 at 25 C Melting point Freezing point Boiling point Flash point Evaporation rate Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density 120 F (48.9 C) Specific gravity 0.98-0.99 at 25 C Solubility (water) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature 10. Chemical Stability & Reactivity Information Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Possibility of hazardous reactions 11. Toxicological Information Acute effects Sensitization Chronic effects Carcinogenicity Material is stable under normal conditions. Contact with incompatible materials. Keep away from heat, sparks, and flame. Strong oxidizing agents. Strong acids. Strong bases. Carbon oxides. Sodium oxides. Will not occur. May cause eye irritation on direct contact. None known. None known. None known. / 6
ACGIH Carcinogens A4 Not classifiable as a human carcinogen. 12. Ecological Information Ecotoxicity Persistence and degradability Bioaccumulation / Accumulation Partition coefficient (noctanol/water) Mobility in environmental media Not expected to be harmful to aquatic organisms. 1. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Collect in marked containers and deliver to approved depot. Dispose of waste and residues in accordance with local authority requirements. Since emptied containers retain product residue, follow label warnings even after container is emptied. 14. Transport Information Product Specific Note: DOT IATA IMDG TDG Hazard class Labels required Additional information: Special provisions Packaging exceptions Packaging non bulk Packaging bulk ERG number Hazard class Additional information: ERG code Hazard class EmS No. This product meets the limited quantities exception as follows: DOT / IATA / IMDG / TDG: Limited Quantities if inner packaging not exceeding 5.0 L, outer packaging not exceeding 0 Kg. Otherwise, the following descriptions apply: UN199 Flammable liquids, n.o.s. (Ethy Alcohol, Isopropyl Alcohol) B1, B52, IB, T4, TP1, TP29 150 20 242 128 199 Flammable liquid, n.o.s. (Ethy Alcohol, Isopropyl Alcohol) L 199 FLAMMABLE LIQUID, N.O.S. (Ethy Alcohol, Isopropyl Alcohol) F-E, S-E* FLAMMABLE LIQUID, N.O.S. (Ethy Alcohol, Isopropyl Alcohol) 4 / 6
Hazard class Marine pollutant Additional information: Special provisions UN199 16 15. Regulatory Information US federal regulations This product is not hazardous according to OSHA 29CFR 1910.1200. This material is not listed on the US TSCA 8(b) Inventory, therefore it may only be used for TSCA Exempt purposes such as R&D or Food, Drug or Cosmetic use. TSCA Section 12(b) Export Notification(40 CFR 707, Subpt. D) Not regulated. US EPCRA (SARA Title ) Section 1 - Toxic Chemical: De minimis concentration 1.0 % US EPCRA (SARA Title ) Section 1 - Toxic Chemical: Listed substance CERCLA (Superfund) reportable quantity (lbs) (40 CFR 02.4) Isopropyl alcohol: 100 Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 02 extremely hazardous substance (40 CRF 55, Appendix A) Section 11/12 (40 CFR 70) Drug Enforcement Administration (DEA) (21 CFR 108.11-15) Canadian regulations WHMIS status WHMIS classification WHMIS labeling Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No No Yes Not controlled This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. Controlled B2 - Flammable/Combustible D2B - Other Toxic Effects-TOXIC Inventory status Country(s) or region Inventory name On inventory (yes/no)* Australia Australian Inventory of Chemical Substances (AICS) No Canada Domestic Substances List (DSL) No Canada Non-Domestic Substances List (NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) No Europe European Inventory of Existing Commercial Chemical No Substances (EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) No New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances No (PICCS) 5 / 6
Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory No *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) State regulations US - California Hazardous Substances (Director's): Listed substance US - Massachusetts RTK - Substance: Listed substance US - New Jersey Community RTK (EHS Survey): Reportable threshold US - New Jersey RTK - Substances: Listed substance 500 LBS US - Pennsylvania RTK - Hazardous Substances: Listed substance 16. Other Information Further information HMIS ratings Health: 2 Flammability: 2 Physical hazard: 0 NFPA ratings Health: 2 Flammability: 2 Instability: 0 Disclaimer Issue date 11-2-2011 HMIS is a registered trade and service mark of the NPCA. To the best of our knowledge, the information contained herein is accurate. However no warranty, guarantee or representation is made as to its accuracy, reliability or completeness. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of suitability to assure proper use, disposal, and safety of these materials. Rev 02: Reviewed and changed date. 6 / 6