HENNA POWDER Date: 1/18/17 1. Identification of the substance/preparation and the company TRADE NAME: UTILIZATION: SUPPLIER COMPANY IDENTIFICATION: Henna powder; Item# s: 9999500; 9999501; JAC9500 Ingredient for natural staining Rupert, Gibbon & Spider, Inc. 1147 Healdsburg Avenue Healdsburg, CA 95448 Tel: 800-442-0455 DATE ISSUED: 1/18/17 Emergency: CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 International CHEMTREC, call: 1-703-527-3887 For non-emergency assistance, call: 800-442-0455 2. Hazards Identification CLASSIFICATION: (GHS) SIGNAL WORD: ROUTES OF EXPOSURE EFFECTS OF OVEREXPOSURE EYES: SKIN: INHALATION: INGESTION: Not Classified Not hazardous INHALATION of powder/dust EYE or SKIN contact with the product, powder/dust Irritation None expected Irritation of the upper respiratory system. None expected SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. CANCER INFORMATION For complete discussion of toxicology data refer to Section 11. HEALTH 0 FLAMMABILITY 0 REACTIVITY 0 1
3. Composition Information on Ingredients INCI-NAME: Lawsonia inermis leaf CAS-NUMBER: 84988-66-9 EINECS-NUMBER: 284-854-1 This material is not hazardous, as defined by the Department of Labor. 4. First Aid GENERALLY: FIRST AID AFTER INHALATION: FIRST AID AFTER SKIN CONTACT: FIRST AID AFTER EYE CONTACT: FIRST AID AFTER INGESTION: MOST IMPORTANT SYMPTOMS AND EFFECTS, ACUTE/DELAYED: No special measures required. A medical examination is not necessary. Move to fresh air. Seek medical advice if necessary. In general product is not skin-irritating. Wash skin with soap and water. If irritation persists, seek medical attention. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. No special measures required. In the event of unintentional swallowing, do not force vomiting. Seek medical attention if necessary, showing the label. No symptoms known. 5: Fire-fighting Measures SUITABLE EXTINGUISHING MEDIA: UNSUITABLE EXTINGUISHING MEDIA: PROTECTIVE EQUIPMENT: FIRE AND EXPLOSION PROTECTION: Foam,C02, dry extinguishing powder. Nothing to report Keep away from sources of ignition. Do not smoke. Respiratory and eye protection required for fire crews when exposed to smoke or fumes. This product is made up of inflammable material with low risk. The product may form ignitable mixtures or burn only upon heating above the flash point. 6: Accidental Release Measures PERSONAL PRECAUTIONS: ENVIRONMENTAL PRECAUTIONS: METHODS FOR CLEANING UP: Ensure adequate ventilation. No special measures required. Clean up mechanically. Avoid dust formation. 2
7.Handling and Storage PRECAUTIONS FOR SAFE HANDLING: CONDITIONS FOR SAFE STORAGE: Apply good manufacturing practice & industrial hygiene practices. Observe good personal hygiene, and do not eat, drink or smoke whilst handling. Avoid dust formation. Store the product a well-ventilated environment, protect from direct sunlight, in a cool, dry place. 8: Exposure Controls and Personal Protection HAND PROTECTION: RESPIRATORY PROTECTION: EYE PROTECTION: PHYSICAL PROTECTION: OCCUPATIONAL EXPOSURE LIMIT: 9: Physical and Chemical Properties APPEARANCE: COLOR: ODOR: MELTING /FREEZING POINT: INITIAL BOILING POINT & RANGE: FLASH POINT: SOLUBILITY: AUTO-IGNITION TEMPERATURE: FLAMMABILITY: EXPLOSIVE PROPERTIES: DECOMPOSITION TEMPERATURE: UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS: VAPOR PRESSURE: ODOR THRESHOLD: VAPOR DENSITY: PH: RELATIVE DENSITY: EVAPORATION RATE: PARTITION COEFFICIENT: N-OCTAL/WATER: VISCOSITY: Gloves Do not inhale dust. Protective Mask in case of formation of dust. Protective glasses Use usual individual protective equipment No special measures required powder yellowish brown plant matter not available not available not determined partially soluble in water, oils not determined not available 3
10: Stability and Reactivity Data REACTIVITY: CHEMICAL STABILITY: POSSIBILITY OF HAZARDOUS REACTIONS: CONDITIONS TO AVOID: SUBSTANCES TO AVOID: HAZARDOUS DECOMPOSITION PRODUCTS: It presents no significant reactivity hazards, by itself or in contact with water. The product is stable under normal conditions It presents no significant hazardous reaction. Keep away from open flames. Nothing to report Nothing to report 11: Toxicological Information Not classified as hazardous. If the product is used properly it will not cause any injuries to health. ACUTE TOXICITY: In compliance with generally accepted uses and LDSO oral: not determined LDSO dermal: not determined LCSO: not determined Inhalation: There is not expected negative impact. Ingestion: There is not expected negative impact. Skin contact: There is not expected negative impact. Eye contact: There is not expected negative impact. SKIN CORROSION/IRRITATION: SERIOUS EYE DAMAGE/IRRITATION: RESPIRATORY /SKIN SENSITIZATION: GERM CELL MUTAGENICITY: CARCIGENICITY REPRODUCTIVE TOXICITY STOT-SINGLE EXPOSURE STOT-REPEATED EXPOSURE ASPIRATION HAZARD In compliance with generally accepted uses and In compliance with generally accepted uses and In compliance with generally accepted uses and Deep inhalation may cause respiratory troubles such as watering, sneezing, irritation. There is not expected negative impact. There is not expected negative impact. There is not expected negative impact. No information available No information available No information available 4
12: Ecological Information 12.1. ECOTOXICITY: Nothing to report. Natural product. Environmentally not hazardous. 12.2. MOBILITY IN SOIL: passive natural product 12.3. DEGRADABILITY: Biologically well degradable 12.4. BIOACCUMULATION POTENTIAL: 12.5 VARIOUS HARMFUL EFFECTS: 13: Disposal Considerations RECOMMENDATION: Collect and dispose of waste product in conformity with local disposal regulations. Is a natural biodegradable product. 14: Transport Information GENERAL: Not classified as a dangerous good under transport regulations. Protect against humidity. RECOMMENDATIONS: not classified ROAD (ADR/RID): not classified AIR (IATA/ICAO): not classified SEA (IMDG): not classified SPECIAL PRECAUTIONS FOR USER: See section 6-8 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC: Not defined 15: Additional Regulatory Information SARA312: IMMEDIATE (ACUTE) HEALTH HAZARD: DELAYED (CHRONIC) HEALTH HAZARD: FIRE HAZARD: SUDDEN RELEASE OF PRESSURE: REACTIVITY: SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES): TSCA (TOXIC SUBSTANCES CONTROL ACT): PROPOSITION 65 (CALIFORNIA) CHEMICALS KWN TO CAUSE CANCER: CHEMICALS KWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES: CHEMICALS KWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES: CHEMICALS KWN TO CAUSE DEVELOPMENTAL TOXICITY: CARCIGENIC CATEGORIES EPA (ENVIRONMENTAL PROTECTION AGENCY): IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER): TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH): NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH): EU CLASSIFICATION: No. 1272/2008. This product is not subject to the German Ordinance that bans certain azo dyes or the 19th Amendment 5 of the Council Directive 76/769/EEC. Not subject to classification according to CLP Regulation (EC)
16: Other Information Rupert, Gibbon & Spider, Inc. warrants that this product conforms to the chemical description on the label and is reasonably fit for the specific purposes referred to in its directions for use, subject to the inherent risks referred to in the material safety data sheet for this product. Rupert, Gibbon & Spider, Inc. makes no other expressed or implied warranty of fitness or merchantability or any other expressed or implied warranty. In no case shall Rupert, Gibbon & Spider, Inc. be liable for consequential, special, or indirect damages resulting from the use or handling of this product. Revision date: January 18, 2017 6