Date of issue: 04/23/2015 Revision date: 06/27/2017 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Trade name Product code : : Mixture : 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use 1.3. Details of the supplier of the safety data sheet Supplier : Perfumes, Fragrances 1.4. Emergency telephone number Emergency number - : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye Irrit. 2 H319 Skin Sens. 1 H317 Full text of H statements : see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation : P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear cold insulating gloves, eye protection, face protection, face shield, protective clothing, protective gloves P302+P352 - If on skin: Wash with plenty of water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P363 - Wash contaminated clothing before reuse P501 - Dispose of contents/container in accordance with local/national laws and regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable. SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 06/27/2017 EN (English) Page 1
3.2. Mixtures Name Product identifier % GHS-US classification Benzyl benzoate (CAS-No.) 120-51-4 20-40 Acute Tox. 4 (Oral), H302 Linalool (CAS-No.) 78-70-6 2.1018-8.8818 Linalyl acetate (CAS-No.) 115-95-7 1.1904-5.0304 Butylphenyl methylpropional (CAS-No.) 80-54-6 0.6324-2.6724 Flam. Liq. 4, H227 Eye Irrit. 2A, H319 Skin Sens. 1B, H317 Flam. Liq. 4, H227 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Dihydromyrcenol (CAS-No.) 18479-58-8 0.558-2.358 Flam. Liq. 4, H227 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Phenylacetaldehyde dimethyl acetal (CAS-No.) 101-48-4 0.558-2.358 Flam. Liq. 4, H227 Eye Irrit. 2A, H319 Coumarin crystals (CAS-No.) 91-64-5 0.3534-1.4934 Allergen report available upon request. Full text of H-statements: see section 16 Acute Tox. 4 (Oral), H302 Skin Sens. 1B, H317 Aquatic Acute 2, H401 Aquatic Chronic 2, H411 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. Assure fresh air breathing. Allow the victim to rest. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see supplemental first aid instruction on this label). Wash contaminated clothing before reuse. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. If skin irritation occurs: Get medical advice/attention. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persists. : Call a poison center or a doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after inhalation : May cause an allergic skin reaction. Symptoms/effects after skin contact : Causes skin irritation. Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Reactivity : The product is non-reactive under normal conditions of use, storage and transport. 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire fighting water from entering the environment. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection. 06/27/2017 EN (English) 2/8
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Ventilate spillage area. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Evacuate unnecessary personnel. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections : Collect spillage. : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. : Dispose of materials or solid residues at an authorized site. For further information refer to section 13. See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials Storage temperature : 25 C Storage area Special rules on packaging Packaging materials 7.3. Specific end use(s) : Ensure good ventilation of the work station. Avoid breathing dust, fume, gas, mist, spray, vapours. Avoid contact with skin and eyes. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. : Store in a well-ventilated place. Keep cool. Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. : Store in a well-ventilated place. Store away from heat. : Store in a closed container. : Do not store in corrodable metal. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Ensure good ventilation of the work station. : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves. : Safety glasses. Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. 06/27/2017 EN (English) 3/8
Environmental exposure controls : Avoid release to the environment. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : light yellow amber Odour : Floral Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point : Not applicable Freezing point Boiling point Flash point : > 93.33 C (closed cup) ASTM D7094 Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density : 0.95 Solubility : Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation 06/27/2017 EN (English) 4/8
Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/effects after inhalation Symptoms/effects after skin contact Symptoms/effects after eye contact SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Causes serious eye irritation. : May cause an allergic skin reaction. : Based on available data, the classification criteria are not met. : May cause an allergic skin reaction. : Causes skin irritation. Irritation. May cause an allergic skin reaction. : Eye irritation. : Toxic to aquatic life with long lasting effects. 12.2. Persistence and degradability Persistence and degradability 12.3. Bioaccumulative potential Bioaccumulative potential 12.4. Mobility in soil 12.5. Other adverse effects Effect on ozone layer Effect on the global warming Not established. Not established. : : No known effects from this product. : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods Product/Packaging disposal recommendations Ecology - waste materials : Dispose of contents/container in accordance with licensed collector s sorting instructions. : Dispose of contents/container in accordance with local/national laws and regulations. Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea 06/27/2017 EN (English) 5/8
Air transport SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. 15.2. International regulations CANADA Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) Coumarin crystals (91-64-5) Dihydromyrcenol (18479-58-8) Butylphenyl methylpropional (80-54-6) Linalool (78-70-6) Phenylacetaldehyde dimethyl acetal (101-48-4) EU-Regulations Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) Coumarin crystals (91-64-5) Dihydromyrcenol (18479-58-8) Butylphenyl methylpropional (80-54-6) Linalool (78-70-6) Phenylacetaldehyde dimethyl acetal (101-48-4) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not determined Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations 06/27/2017 EN (English) 6/8
Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) Coumarin crystals (91-64-5) Dihydromyrcenol (18479-58-8) Butylphenyl methylpropional (80-54-6) Linalool (78-70-6) 06/27/2017 EN (English) 7/8
Phenylacetaldehyde dimethyl acetal (101-48-4) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Revision date : 09/07/2016 : None. Full text of H-statements: ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H315 Causes skin irritation ------ H317 May cause an allergic skin reaction ------ H319 Causes serious eye irritation ------ H401 Toxic to aquatic life ------ H411 Toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Materials that, under emergency conditions, can cause significant irritation. : 1 - Materials that must be preheated before ignition can occur. : 0 - Material that in themselves are normally stable, even under fire conditions. FCF SDS US HAZCOM2012*1 The data contained in this is accurate to the best knowledge of Wellington Fragrance applies to the product as supplied by Wellington Fragrance and does not relate to use in combination with any other material or in any process. Data and information is furnished without warranty expressed or implied, nor does Wellington Fragrance assume responsibility for use or reliance upon this data. This SDS is current to the date listed above. However, the GHS classifications may change due to hazard communication updates by the overseeing governing body. For the most current SDS information please contact SDS@frenchcolor.com 06/27/2017 EN (English) 8/8