Date of issue: 10/12/2015 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Product code : 18399F 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Wellington Fragrance. 33306 Glendale St. Livonia, MI 48150 - USA 734-261-5531 Fax 734-261-5571 : Perfumes, Fragrances 1.4. Emergency telephone number Emergency number : 1-800-255-3924; +01-813-248-0585; China:+400-120-0751; Mexico:+01-800-099-0731; Brazil: +0-800-591-6042; India: +000-800-100-4086 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flam. Liq. 4 H227 Skin Irrit. 2 H315 Skin Sens. 1 H317 Full text of H-statements: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Warning : H227 - Combustible liquid H315 - Causes skin irritation H317 - May cause an allergic skin reaction : P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking P261 - Avoid breathing dust/fume/gas/mist/vapours/spray P264 - Wash hands thoroughly after handling P272 - Contaminated work clothing must not be allowed out of the workplace P280 - Wear protective gloves, protective clothing, face protection, eye protection P302+P352 - If on skin: Wash with plenty of soap, water P332+P313 - If skin irritation occurs: Get medical advice/attention P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P362+P364 - Take off contaminated clothing and wash it before reuse P363 - Wash contaminated clothing before reuse P370+P378 - In case of fire: Use dry extinguishing powder to extinguish P403+P235 - Store in a well-ventilated place. Keep cool P501 - Dispose of contents/container in accordance with local/national laws and regulations 2.3. Other hazards 2.4. Unknown acute toxicity (GHS US) Not applicable 10/12/2015 EN (English) Page 1
SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Benzyl benzoate (CAS No) 120-51-4 10-40 Acute Tox. 4 (Oral), H302 Aquatic Chronic 2, H411 Hexyl cinnamic aldehyde (CAS No) 101-86-0 4.64969-19.64869 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 Linalyl acetate (CAS No) 115-95-7 2.17-9.17 Flam. Liq. 4, H227 Eye Irrit. 2A, H319 Phenylmethanol (CAS No) 100-51-6 1.25116-5.28716 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation), H332 Lemon oil (CAS No) 8008-56-8 1.24-5.24 Flam. Liq. 3, H226 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 1, H410 Orange Oil 5X (natural) (CAS No) 8028-48-6 0.93-3.93 Flam. Liq. 3, H226 Iso E Super (CAS No) 54464-57-2 0.6975-2.9475 Skin Sens. 1B, H317 Aquatic Chronic 2, H411 Coriander oil (Coriandrum sativum L.) (CAS No) 8008-52-4 0.1-1 Flam. Liq. 4, H227 Eye Irrit. 2A, H319 Skin Sens. 1, H317 Asp. Tox. 1, H304 Aquatic Chronic 2, H411 Allergen report available upon request. Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Allow breathing of fresh air. Allow the victim to rest. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see... on this label). If skin irritation or rash occurs: Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : May cause an allergic skin reaction. Symptoms/injuries after skin contact : Causes skin irritation. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Combustible liquid. Explosion hazard : May form flammable/explosive vapour-air mixture. 10/12/2015 EN (English) 2/9
5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed Precautions for safe handling Hygiene measures : Handle empty containers with care because residual vapours are flammable. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. : No open flames. No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials Storage temperature : 25 C Storage area Special rules on packaging Packaging materials 7.3. Specific end use(s) : Proper grounding procedures to avoid static electricity should be followed. : Keep in fireproof place. Keep only in the original container in a cool, well ventilated place away from : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container closed when not in use. : Strong bases. Strong acids. : Heat sources. Sources of ignition. Direct sunlight. : Store in a well-ventilated place. Store away from heat. : Store in a closed container. : Do not store in corrodable metal. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. 10/12/2015 EN (English) 3/9
Eye protection Skin and body protection Respiratory protection Other information : Chemical goggles or safety glasses. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : light yellow amber Odour : Citrus fruits Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : 82.11 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability Combustible liquid. May form flammable/explosive vapour-air mixture. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Open flame. Overheating. Direct sunlight. Heat. Sparks. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products May release flammable gases. fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity 10/12/2015 EN (English) 4/9
Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact : Causes skin irritation. : May cause an allergic skin reaction. : Based on available data, the classification criteria are not met. : May cause an allergic skin reaction. : Causes skin irritation. SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability Persistence and degradability 12.3. Bioaccumulative potential Bioaccumulative potential 12.4. Mobility in soil Not established. Not established. 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming Other information : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Additional information Ecology - waste materials : Dispose of contents/container in accordance with local/national laws and regulations. Dispose in a safe manner in accordance with local/national regulations. : Handle empty containers with care because residual vapours are flammable. : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR Transport by sea 10/12/2015 EN (English) 5/9
Air transport SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR 372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 15.2. International regulations CANADA Phenylmethanol (100-51-6) WHMIS Classification Class B Division 3 - Combustible Liquid Class D Division 2 Subdivision B - Toxic material causing other toxic effects Iso E Super (54464-57-2) Lemon oil (8008-56-8) Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) WHMIS Classification Hexyl cinnamic aldehyde (101-86-0) Coriander oil (Coriandrum sativum L.) (8008-52-4) Orange Oil 5X (natural) (8028-48-6) EU-Regulations Phenylmethanol (100-51-6) Class D Division 2 Subdivision B - Toxic material causing other toxic effects Iso E Super (54464-57-2) Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) Hexyl cinnamic aldehyde (101-86-0) Orange Oil 5X (natural) (8028-48-6) Classification according to Regulation (EC) No. 1272/2008 [CLP] Not determined Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations 10/12/2015 EN (English) 6/9
Phenylmethanol (100-51-6) Listed on the Canadian IDL (Ingredient Disclosure List) Iso E Super (54464-57-2) Lemon oil (8008-56-8) Linalyl acetate (115-95-7) Benzyl benzoate (120-51-4) Listed on the Japanese ISHL (Industrial Safety and Health Law) Hexyl cinnamic aldehyde (101-86-0) Coriander oil (Coriandrum sativum L.) (8008-52-4) Listed on the Japanese ISHL (Industrial Safety and Health Law) 10/12/2015 EN (English) 7/9
Orange Oil 5X (natural) (8028-48-6) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm Phenylmethanol (100-51-6) U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Other information : None. Full text of H-statements: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 ------ Acute Tox. 4 (Inhalation) Acute toxicity (inhal.), Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 ------ Aquatic Chronic 2 Hazardous to the aquatic environment Chronic Hazard, Category 2 ------ Asp. Tox. 1 Aspiration hazard, Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ Flam. Liq. 3 Flammable liquids, Category 3 ------ Flam. Liq. 4 Flammable liquids, Category 4 ------ Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------ Skin Sens. 1 Sensitisation Skin, Category 1 ------ Skin Sens. 1B Sensitisation Skin, category 1B ------ H226 Flammable liquid and vapour ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H304 May be fatal if swallowed and enters airways ------ H312 Harmful in contact with skin ------ H315 Causes skin irritation ------ H317 May cause an allergic skin reaction ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H410 Very toxic to aquatic life with long lasting effects ------ H411 Toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. : 2 - Must be moderately heated or exposed to relatively high temperature before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. FCF SDS US HAZCOM2012 10/12/2015 EN (English) 8/9
The data contained in this Material is accurate to the best knowledge of Wellington Fragrance, applies to the product as supplied by Wellington Fragrance and does not relate to use in combination with any other material or in any process. Data and information is furnished without warranty expressed or implied, nor does Wellington Fragrance assume responsibility for use or reliance upon this data. 10/12/2015 EN (English) 9/9