CORESTA Recommended Methods with history and correspondence with ISO Standards

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CORESTA Recommended with histy and crespondence with Standards DISCLAIMER: This table is made available f the convenience of tobacco researchers and is f infmation purposes only. The precise crelation equivalence between CORESTA Recommended (CRM) and Standards has the potential to vary greatly at any point in time because the CRMs and Standards are revised and updated independently. REF TITLE Version DATE Bulletin N 1 Determination of Dithiocarbamates in Tobacco 3 Nov 1978 1978-2 v1: 1973-1 v2: 1974-2 N 2 Determination of Organochline Pesticide Residues on Tobacco 3 May 1997 1997-1 v1: 1974-2 v2: 1994-3/4 Withdrawn May 2014 6466:1983-4389:2000 v1-1981 ; v2-1997 N 3 Determination of the air permeability of cigarette paper 1 1976 1975-3/4 Replaced by CRM40 - N 4 Determination of Maleic Hydrazide Residues in Tobacco 1 Sept 1976 1976-2 Withdrawn June 2013 N 5 Determination of Carbon Monoxide in the Mainstream Smoke of Cigarettes by Non-Dispersive Infrared Analysis N 6 Measurement of Ventilation : Definitions and Measurement Principles N 7 Determination of Nicotine in the Mainstream Smoke of Cigarettes by Gas Chromatographic Analysis N 8 Determination of Water in the Mainstream Smoke of Cigarettes by Gas Chromatographic Analysis N 9 Determination of Nicotine in Cigarette Filters by Gas Chromatographic Analysis N 10 Machine smoking of cigarettes - Determination of crude and dry smoke condensate 4876:1980 2 Sept 1993 1993-4 v1: 1982-2 8454:2007 v1-1987 ; v2-1995 3 Sept 2016 Web v1: 1983-2/3 v2: 2000-1 9512:2002 v1-1993 2 Aug 1991 1991-3 v1: 1986-3/4 10315:2000 v1-1991 2 Aug 1991 1991-3 v1: 1987-2 10362-1:1999 v1-1991 SG Pesticides TF Gas Phase* TF Filter Ventilation* SG Physical Test * * 2 Apr 2009 CD 28 v1: 1989-2 1 Sept 1968 1969-1 Replaced by CRM23 - N 12 Determination of Alkaloids in Cigarette Smoke Condensate 1 Sept 1968 1969-2 3400:1997 v1-1976 ; v2-1989 Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 1

N 13 Determination of Alkaloid Retention by Cigarette Filters 1 Sept 1968 1969-2 By spectrophotometry 3401:1991 v1-1977 by GC: 3401-2 N 14 Determination of nicotine in ambient air by gas chromatographic analysis N 15 Cigarettes - Determination of Water in Smoke Condensates - Karl Fischer Method 2 Sept 1993 1993-4 v1: 1990-1 Replaced by CRM50 1 Mar 1990 1990-2 10362-2:1994 N 16 Lamina Strip Particle Size Determination 1 Jan 1991 1991-1 12194:1995 TF Tobacco Size* N 17 Stem Content of Lamina Strips 1 Jan 1991 1991-1 12195:1995 TF Tobacco Size* N 18 Materials used as cigarette tipping papers having a perfated zone - Determination of unit air-flow and permeability 1 Jan 1991 1991-1 Replaced by CRM40 - N 20 Determination of Alkaloids in Manufactured Tobacco 1 Sept 1968 1969-2 2881:1992 v1-1974 ; v2-1977 N 21 Atmosphere f Conditioning and Testing Tobacco and N 22 Routine Analytical Cigarette-Smoking Machine: Specifications, Definitions and Standard Conditions N 23 Determination of Total and Nicotine-Free Dry Particulate Matter using a Routine Analytical Cigarette-Smoking Machine Determination of Total Particulate Matter and Preparation f Water and Nicotine Measurements 2 Aug 1991 1991-3 v1: 1989-4 3402:1999 v1-1975 ; v2-1978 ; v3 1991 2 Aug 1991 1991-3 v1: 1989-4 3308:2000 v1-1977 ; v2-1986 ; v3 1991 2 Aug 1991 1991-3 v1: 1989-4 4387:2000 v1-1987 ; v2-1991 N 24 Cigarettes - Sampling 2 Aug 1991 1991-3 v1: 1989-4 8243:2006 v1-1988 ; v2-1991 ; v3 2003 N 25 Ambiant Air-Flow around Cigarettes in Routine Analytical Smoking Machines: Control and Moniting - * * * 1 Aug 1991 1991-3 * Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 2

N 30 Determination of Residues of the Suckercide Flumetralin (Prime Plus, CGA-41065) on Tobacco N 31 Determination of Residues of the Suckercide Pendimethalin (Accotab, Stomp) on Tobacco N 32 Determination of Residues of the Suckercide Off-Shoot-T (N- Alkanol Mixture) on Tobacco Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) 1 Jun 1991 1991-2 Withdrawn May 2014 1 Jun 1991 1991-2 Withdrawn May 2014 1 Jun 1991 1991-2 Withdrawn May 2014 SG Pesticides SG Pesticides SG Pesticides N 33 Determination of Acetate in Cigarette Paper 1 Jan 1993 1992-3/4 20370:2009 TF Burning Additives in Cigarette Paper* N 34 Determination of Citrate in Cigarette Paper 1 Jan 1993 1992-3/4 20369:2009 TF Burning Additives in Cigarette Paper* N 35 Determination of Total Alkaloids (as Nicotine) in Tobacco by Continuous Flow Analysis N 36 Determination of Nitrate in Tobacco and Smokeless Tobacco Products by Reduction to Nitrite and Continuous Flow Analysis N 37 Determination of Reducing Substances in Tobacco by Continuous Flow Analysis N 38 Determination of Reducing Carbohydrates in Tobacco by Continuous Flow Analysis N 39 Determination of the Purity of Nicotine and Nicotine Salts by Gravimetric Analysis - Tungstosilicic Acid Method N 40 Determination of Air Permeability of Materials used as Cigarette Papers, Filter Plug Wrap and Filter Joining Paper including Materials having an Oriented Permeable Zone N 41 Determination of the Draw Resistance of Cigarettes and Filter Rods N 42 Atmosphere f Conditioning and Testing Fine-Cut Tobacco and Fine-Cut Smoking Articles 2 Aug 2010 CD 31 v1: Nov 1994 (1994-3/4) Replaced by CRM85 4 Jan 2015 Web v1: Nov 1994 (1994-3/4) v2: Aug 2010 (CD31) v3: Aug 2011 (Web) 2 Aug 2010 CD 31 v1: Nov 1994 (1994-3/4) 2 Aug 2010 CD 31 v1: Nov 1994 (1994-3/4) 15152:2003 15517:2003 15153:2003 15154:2003 1 Nov 1994 1994-3/4 13276:1997 1 Oct 1994 1994-3/4 Withdrawn Jan 2017 2965:2009 v1-1979 ; v2-1997 2 Jun 2007 CD 24 v1: 1995-1 6565:2002 v1-1983 ; v2-1999 TF Air Permeability Through Paper* TF Pressure Drop* 1 Jun 1997 1997-1 15592-2:2001 TF Roll-Your-Own* N 43 Fine-Cut Tobacco - Sampling 1 Jun 1997 1997-1 15592-1:2001 TF Roll-Your-Own* CORESTA Recommended with histy and crespondence with Standards (December 2018) 3

N 45 Determination of Phosphate in Cigarette Paper 1 Jan 1998 1997-4 TF Burning Additives in Cigarette Paper* N 46 Atmosphere f Conditioning and Testing Cigars of all Sizes and Shapes 2 June 2018 Web v1: 1998-1 SG Cigars* SG Cigar Smoking N 47 Cigars Sampling 1 Jan 2000 2000-1 SG Cigars* N 50 Environmental Tobacco Smoke - Determination of Nicotine and 3-Ethenylpyridine in the Vapour Phase N 51 Environmental Tobacco Smoke - Estimation of its Contribution to Respirable Suspended Particles - Determination of Particulate Matter by Ultraviolet Absbance and by Fluescence N 52 Environmental Tobacco Smoke - Estimation of its Contribution to Respirable Suspended Particles - Method based on Solanesol Determination 1 Jan 2002 CD 13 18145:2003 SG Environmental Tobacco Smoke* 1 Jan 2002 CD 13 15593:2001 SG Environmental Tobacco Smoke* 1 Jan 2002 CD 13 18144:2003 SG Environmental Tobacco Smoke* N 53 Determination of Paper Wrapper Burn Speed 1 May 2002 CD 14 TF Cigarette Paper Combustibility* SG Physical Test N 54 Determination of Nicotine and Nicotine-Free Dry Particulate Matter in Sidestream Smoke using a Fishtail Chimney and a Routine Analytical/Linear Smoking Machine N 55 Determination of Carbon Monoxide in the Vapour Phase of Cigarette Sidestream Smoke using a Fishtail Chimney and a Routine Analytical/Linear Smoking Machine N 56 Determination of Water in Tobacco and by Karl Fischer Method 2 May 2011 CD 32 v1: Jun 2002 (CD15) 20773:2013 2 May 2011 CD 32 v1: Jun 2002 (CD15) 20774:2013 2 Aug 2018 Web v1: Dec 2002 (CD16) v2: May 2011 (CD32) 6488:2004 v1-1981 Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 4

N 57 Determination of Water in Tobacco and by Gas Chromatographic Analysis N 58 Determination of Benzo[a]Pyrene in Cigarette Mainstream Smoke Gas Chromatography-Mass Spectrometry Method N 59 Determination of Triacetin in Filter Rods by Gas Chromatographic Analysis N 60 Determination of 1,2-Propylene Glycol and Glycerol in Tobacco and by Gas Chromatography N 61 Determination of 1,2-Propylene Glycol, Glycerol and Sbitol in Tobacco and by High Perfmance Liquid Chromatography (HPLC) N 62 Determination of Nicotine in Tobacco and by Gas Chromatographic Analysis N 63 Determination of Tobacco Specific Nitrosamines in Cigarette Mainstream Smoke - GC-TEA Method N 64 Routine Analytical Cigar-Smoking Machine - Specifications, Definitions and Standard Conditions N 65 Determination of Total and Nicotine-Free Dry Particulate Matter using a Routine Analytical Cigar-Smoking Machine Determination of Total Particulate Matter and Preparation f Water and Nicotine Measurements N 66 Determination of Nicotine in the Mainstream Smoke of Cigars by Gas Chromatographic Analysis 1 Aug 2018 Web v1: Dec 2002 (CD16) 16632:2003 4 Jan 2018 Web v1: Feb 2004 (CD18) v2: Mar 2013 (Web) v3: July 2014 (Web) 22634/1:2008 SG Smoke 1 June 2004 CD 20 TF Plasticisers in Filter Production* 3 July 2015 Web v1: Feb 2005 (CD20) v2: May 2011 (CD32) 3 July 2015 Web v1: Feb 2005 (CD20) v2: May 2011 (CD32) 1 Feb 2005 CD 20 1 June 2005 CD 20 SG Special 2 May 2018 Web v1: Nov 2005 (CD21) SG Cigars* SG Cigar Smoking 4 June 2010 CD31 v1: Nov 2005 (CD21) v2: Jun 2007 (CD24) v3: Jan 2010 (CD30) SG Cigars* SG Cigar Smoking 1 Nov 2005 CD 21 SG Cigars* Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 5

N 67 Determination of Water in the Mainstream Smoke of Cigars by Gas Chromatographic Analysis N 68 Determination of Carbon Monoxide in the Mainstream Smoke of Cigars by Non-Dispersive Infrared Analysis 1 Nov 2005 CD 21 SG Cigars* 1 Jan 2010 CD 30 SG Cigars* SG Cigar Smoking N 69 Determination of ph in Tobacco and 2 July 2017 CD 31 v1: Jun 2010 (CD31) N 70 Determination of Selected Volatile Organic Compounds in the Mainstream Smoke of Cigarettes - Gas Chromatography- Mass Spectrometry Method 4 Feb 2018 Web v1: Jun 2010 (CD30) v2: Mar 2013 (Web) v3: July 2014 (Web) Proposed Sept 2015 Accepted Dec 2015 New Project 21330 SG Special N 71 Smokeless - Sampling 1 Nov 2011 Web N 72 Determination of Tobacco Specific Nitrosamines in Tobacco and by Liquid Chromatography - Tandem Mass Spectrometry N 73 Determination of Ammonia in Tobacco by Ion Chromatographic Analysis N 74 Determination of Selected Carbonyls in Mainstream Cigarette Smoke by High Perfmance Liquid Chromatography (HPLC) N 75 Determination of Tobacco Specific Nitrosamines in Mainstream Cigarette Smoke by LC-MS/MS 4 July 2017 Web v1: June 2011 (CD32) v2: July 2013 (Web) v3: Feb 2016 (Web) 1 May 2011 CD 32 Superseded by CRM79 - Sept 2015 4 Feb 2018 Web v1: Aug 2011 (Web) v2: Mar 2013 (Web) v3: July 2014 (Web) Proposed June 2016 Accepted Sept 2016 New Project 21766 Proposed Sept 2015 Accepted Dec 2015 New Project 21160 SG Special 2 July 2014 Web v1: Jun 2012 (Web) 19290:2016 SG Special Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 6

N 76 Determination of Moisture Content (Oven Volatiles) of Tobacco and N 77 Determination of Diffusion Capacity by Measurement of CO2 Transfer Rate Through Materials Used as Cigarette Papers and Cigarette Papers having an Oriented Zone of Reduced Diffusion Capacity N 78 Determination of Selected Phenolic Compounds in Mainstream Cigarette Smoke by HPLC-FLD N 79 Determination of Ammonia in Tobacco and by Ion Chromatographic Analysis N 80 Use of the Part-Filter Method f the Estimation of Smokers' Exposure to Nicotine and Nicotine-Free Dry Particulate Matter N 81 Routine Analytical Machine f E-Cigarette Aerosol Generation and Collection - Definitions and Standard Conditions N 82 Determination of Benzo[a]pyrene in by GC-MS N 83 Determination of Ammonia in Mainstream Cigarette Smoke by Ion Chromatography N 84 Determination of Glycerin, Propylene Glycol, Water, and Nicotine in the Aerosol of E-Cigarettes by Gas Chromatographic Analysis 2 July 2017 Web v1: April 2014 (Web) 1 April 2014 Web SG Physical Test 2 December 2018 2 March 2018 Web v1: July 2014 (Web) SG Special Web v1: April 2015 (Web) Proposed Aug 2015 Accepted Nov 2015 New Project 21045 1 Jan 2016 Web SG Smoking Behaviour 1 June 2015 Web 20768:2018 TF E-Cigarettes 4 March 2018 Web v1: March 2016 (Web) v2: June 2016 (Web) v3: July 2017 (Web) 2 May 2017 Web v1: July 2016 (Web) SG Special 2 June 2017 Web v1: Mar 2017 (Web) SG E-Vapour Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 7

N 85 Tobacco - Determination of the Content of Total alkaloids as Nicotine - Continuous-Flow Analysis Method using KSCN/DCIC N 86 Determination of Select Carbonyls in Tobacco and Tobacco Products by UHPLC-MS/MS 1 April 2017 Web Proposed April 2017 Accepted Dec 2017 New Project 22980 1 Jan 2018 Web N 87 Determination of Nicotine in by GC/MS 1 April 2018 Web Tobacco changed to Tobacco (2017) SG Special changed to SG Smoke (2017) CORESTA Recommended with histy and crespondence with Standards (December 2018) 8