09/08/208 Page sur 9 Section. Identification of the substance or the mixture and of the supplier. Product Identifier Product identifier: Other identifiers: (Contains:Cinnamic aldehyde, eugenol, geraniol, safrole) None.2 Relevant identified uses of the substance of mixture and uses advised against Product uses: Fragrances.3 Details of the supplier of the safety data sheet Company name: Company address: Contact: E-Mail address: Aromateasy 37/4 zone d activité nord, 5377 Baillonville, Belgium Pierre Saad contact@aromateasy.net Company phone: 0032/84.2.30.43.4 Emergency telephone number Emergency phone: 0032/84.2.30.43 Section 2. Hazards identification 2. Classification of the substance or mixture Classification under Regulation (EC) No 272/2008 Class and category of danger: Skin Corrosion / Irritation Category 2 Eye Damage / Irritation Category 2 Sensitization - Skin Category Carcinogenicity Category B Hazardous to the Aquatic Environment - Long-term Hazard Category 2 H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H350, May cause cancer (exposure route). H4, Toxic to aquatic life with long lasting effects. Classification under Directive 999/45/EC Hazard symbols: T, Toxic. N, Dangerous for the environment.
09/08/208 Page 2 sur 9 Risk phrases: R36, Irritating to the eyes. R43, May cause sensitisation by skin contact. R45, May cause cancer. R5/53, Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements Signal word: Danger Hazard statements: H35, Causes skin irritation. H37, May cause an allergic skin reaction. H39, Causes serious eye irritation. H350, May cause cancer (exposure route). H4, Toxic to aquatic life with long lasting effects. Supplemental Information: Precautionary statements: EUH208, Contains citronellol, hexyl cinnamic aldehyde, cinnamic alcohol, ALPHA DAMASCONE, ALDEHYDE C6 (STRAWBERRY PURE), hydroxycitronellal, Ligustral. May produce an allergic reaction. P202, Do not handle until all safety precautions have been read and understood. P26, Avoid breathing vapour or dust. P264, Wash hands and other contacted skin thoroughly after handling. P272, Contaminated work clothing should not be allowed out of the workplace. P273, Avoid release to the environment. P280, Wear protective gloves/eye protection/face protection. P302/352, IF ON SKIN: Wash with plenty of soap and water. P305/35/338, IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/33, IF exposed or concerned: Get medical advice/attention. P333/33, If skin irritation or rash occurs: Get medical advice/attention. P337/33, If eye irritation persists: Get medical advice/attention. P362, Take off contaminated clothing and wash before reuse. P39, Collect spillage. P405, Store locked up. P50, Dispose of contents/container to approved disposal site, in accordance with local regulations. Pictograms: Other hazards: None
09/08/208 Page 3 sur 9 Section 3. Composition / information on ingredients 3.2 Mixtures Contains: Name CAS EC REACH Registration No. Xn-N ; R0-R38-R43-R65- limonene 5989-27-5 227-83-5 0.02% R50/53 Substances with Community workplace exposure limits, not listed above: Myrcene 23-35-3 204-622-5 <0.00% Xn ; R0-R38-R65 Name CAS EC % DEP 84-66-2 20-550-6 38.30% % Classification for (DSD) 67/548/EEC Classification for (CLP) 272/2008 ORTHO TERIARY BUTYL CYCLO 88-4-5 20-828-7 8.96% N ; R5/53 EH C2;H4,- HEXYL ACETATE GALAXOLIDE 50 DEP 222-05-5 24-946-9 8.74% N ; R50/53 EH A-EH C;H40,- eugenol 97-53-0 202-589- 8.5% Xi ; R36-R43 EDI 2-SS B;H37-H39,- hexyl cinnamic aldehyde 0-86-0 202-983-3 5.36% Xi-N ; R38-R43-R50/53 Cinnamic aldehyde 04-55-2 203-23-9 5.2% Xn ; R2-R38-R43 citronellol 06-22-9 203-375-0 3.44% Xi-N ; R38-R43-R5/53 GAMMA UNDECALACTONE SS B-EH A-EH C2;H37- H400-H4,- ATD 4-SCI 2-EDI 2-SS A; H32-H35-H37-H39,- SCI 2-EDI 2-SS B;H35- H37-H39,- 04-67-6 203-225-4 2.9% N ; R5/53 EH C3;H42,- geraniol 06-24- 203-377- 2.58% Xi ; R38-R4-R43 SCI 2-EDI -SS ;H35- H37-H38,- cinnamic alcohol 04-54- 203-22-3.68% Xi ; R43 SS B;H37,- benzyl alcohol 00-5-6 202-859-9.62% Xn ; R36-R20/22 JASMOPYRANE FORTE AB (JESSEMAL ex IFF) try blacks ATO 4-ATI 4-EDI 2;H302- H39-H332,- 887-4-2 242-640-5.05% - ; R52/53 EH C3;H42,- HEXYL ACETATE 42-92-7 205-572-7 0.67% N ; R0-R5/53 FL 3;H226,- benzyl benzoate 20-5-4 204-402-9 0.47% Xn-N ; R22-R5/53 Ligustral 68039-49-6 268-264- 0.45% Xi ; R43-R36/38-R52/53 ATO 4-EH A-EH C2; H302-H400-H4,- SCI 2-EDI 2-SS B-EH C3; H35-H37-H39-H42,- hydroxycitronellal 07-75-5 203-58-7 0.42% Xi ; R36-R43 EDI 2-SS B;H37-H39,- ALDEHYDE C6 (STRAWBERRY 77-83-8 20-06-8 0.28% Xi-N ; R43-R5/53 SS B-EH C2;H37-H4,- PURE) Cinnamaldehyde 437-0-9 203-23-9 0.23% Xn ; R2-R38-R43 -;-,- safrole 94-59-7 202-345-4 0.23% T ; R22-R45-R68 ATO 4-MUT 2-CAR B; H302-H34-H350,- ALPHA DAMASCONE 43052-87-5 245-845-8 0.22% Xn ; R22-R43 ATO 4-SS B;H302-H37,- PATCHONE 98-52-2 202-676-4 0.7% N ; R5/53 EDI 2;H39,- FL 3-SCI 2-SS B-AH -EH A-EH C;H226-H304- H35-H37-H40,- FL 3-SCI 2-EDI 2-AH ; H226-H304-H35-H39,-
09/08/208 Page 4 sur 9 Substances that are persistent, bioaccumulative and toxic or very persistent and very bioaccumulative, greater than 0.%: Not Applicable 4. Description of first aid measures Section 4. First-aid measures IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. 4.2 Most important symptoms and effects, both acute and delayed Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause cancer (exposure route). 4.3 Indication of any immediate medical attention and special treatment needed None expected, see Section 4. for further information. 5. Extinguishing media SECTION 5: Firefighting measures Suitable media: Carbon dioxide, Dry chemical, Foam. 5.2 Special hazards arising from the substance or mixture In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds. 5.3 Advice for fire fighters: In case of insufficient ventilation, wear suitable respiratory equipment. Section 6. Accidental release measures 6. Personal precautions, protective equipment and emergency procedures: Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8. 6.2 Environmental precautions: Keep away from drains, surface and ground water, and soil.
09/08/208 Page 5 sur 9 6.3 Methods and material for containment and cleaning up: Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations. 6.4 Reference to other sections: Also refer to sections 8 and 3. 7. Precautions for safe handling: Section 7. Handling and storage Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate ventilation Do not eat, drink or smoke when using this product. 7.2 Conditions for safe storage, including any incompatibilities: Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. 7.3 Specific end use(s): Fragrances: Use in accordance with good manufacturing and industrial hygiene practices. Section 8. Exposure controls/personal protection 8. Control parameters Workplace exposure limits: Ingredient CAS EC Description Reference DEP 84-66-2 20-550- 6 Long-term exposure limit (8-hour TWA reference period) Short-term exposure limit (5- minute reference period) - 5-0 UK EH40 Oct 2007 UK EH40 Oct 2007 8.2 Exposure Controls Eye / Skin Protection Wear protective gloves/eye protection/face protection Respiratory Protection Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and to ensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use, the following engineering controls may be required as additional protective measures: a) Isolate mixing rooms and other areas where this material is used or openly handled. Maintain these areas under negative air pressure relative to the rest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respirator with organic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanks and other open sources of potential exposures in order to avoid excessive inhalation, including places where this material is
09/08/208 Page 6 sur 9 openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate or reduce possible worker exposures. d) Use closed systems for transferring and processing this material. Also refer to Sections 2 and 7. Section 9. Physical and chemical properties 9. Information on basic physical and chemical properties Appearance: Odour: ph: Initial boiling point / range: Flash point: > 60 C Vapour pressure: Relative density: Solubility(ies): 9.2 Other information: None available Section 0. Stability and reactivity 0. Reactivity: Presents no significant reactivity hazard, by itself or in contact with water. 0.2 Chemical stability: Good stability under normal storage conditions. 0.3 Possibility of hazardous reactions: Not expected under normal conditions of use. 0.4 Conditions to avoid: Avoid extreme heat. 0.5 Incompatible materials: Avoid contact with strong acids, alkalis or oxidising agents. 0.6 Hazardous decomposition products: Not expected.. Information on toxicological effects Section. Toxicological information This mixture has not been tested as a whole for health effects. The health effects have been calculated using the methods outlined in Regulation (EC) No 272/2008 (CLP).
09/08/208 Page 7 sur 9 Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause cancer (exposure route). Assumed Toxicity Value (LD50 or ATE) for Acute Oral Toxicity: >5000 Assumed Toxicity Value (LD50 or ATE) for Acute Dermal Toxicity: >5000 Assumed Toxicity Value (LC50 or ATE) for Acute Inhalation Toxicity: Not Available Inhalation Route: Not Available Information about hazardous ingredients in the mixture Ingredient CAS EC LD50/ATE Oral LD50/ATE Dermal LC50/ATE Inhalation LC50 Route Cinnamic aldehyde 04-55-2 203-23-9 2500 00 Not available Not available benzyl alcohol 00-5-6 202-859-9 620 2500 Vapour Refer to Sections 2 and 3 for additional information. Section 2. Ecological information 2. Toxicity: Toxic to aquatic life with long lasting effects. 2.2 Persistence and degradability: Not available 2.3 Bioaccumulative potential: Not available 2.4 Mobility in soil: Not available 2.5 Results of PBT and vpvb assessment: This substance does not meet the PBT/vPvB criteria of REACH, annex XIII. 2.6 Other adverse effects: Not available 3. Waste treatment methods: Section 3. Disposal considerations Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken to an approved waste handling site for recycling or disposal. Section 4. Transport information 4. UN number: UN3082 4.2 UN Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (GALAXOLIDE 50 DEP, ORTHO TERIARY BUTYL CYCLO HEXYL
09/08/208 Page 8 sur 9 ACETATE) 4.3 Transport hazard class(es): 9 Sub Risk: - 4.4. Packing Group: III 4.5 Environmental hazards: This is an environmentally hazardous substance. 4.6 Special precautions for user: None additional 4.7 Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Section 5. Regulatory information 5. Safety, health and environmental regulations/legislation specific for the substance or mixture None additional 5.2 Chemical Safety Assessment A Chemical Safety Assessment has not been carried out for this product. Section 6. Other information Concentration % Limits: EH C2=24.59% EH C3=2.45% EH C4=92.52% SCI 2=89.06% EDI 2=22. 63% SS =.92% CAR B=42.93% Total Fractional Values: EH C2=4.07 EH C3=40.83 EH C4=.08 SCI 2=.2 EDI 2=4.42 SS =52. 08 CAR B=2.33 Key to revisions: Not applicable Key to abbreviations: Abbreviation Meaning AH Aspiration Hazard Category ATD 4 Acute Toxicity - Dermal Category 4 ATI 4 Acute Toxicity - Inhalation Category 4 ATO 4 Acute Toxicity - Oral Category 4 CAR B Carcinogenicity Category B EDI Eye Damage / Irritation Category EDI 2 Eye Damage / Irritation Category 2 EH A Hazardous to the Aquatic Environment - Acute Hazard Category EH C Hazardous to the Aquatic Environment - Long-term Hazard Category EH C2 Hazardous to the Aquatic Environment - Long-term Hazard Category 2 EH C3 Hazardous to the Aquatic Environment - Long-term Hazard Category 3 FL 3 Flammable Liquid, Hazard Category 3 H226 Flammable liquid and vapour. H302 Harmful if swallowed.
09/08/208 Page 9 sur 9 H304 H32 H35 H37 H38 H39 H332 H34 H350 H400 H40 H4 H42 May be fatal if swallowed and enters airways. Harmful in contact with skin. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Harmful if inhaled. Suspected of causing genetic defects (exposure route). May cause cancer (exposure route). Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. MUT 2 Germ Cell Mutagenicity Category 2 P202 P20 P233 P240 P24 P242 P243 P26 P264 P270 P27 P272 P273 P280 P28 Do not handle until all safety precautions have been read and understood. Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing vapour or dust. Wash hands and other contacted skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/eye protection/face protection. Use personal protective equipment as required. P30/30 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P30/32 IF SWALLOWED: call a POISON CENTER or doctor/physician if you feel unwell. P302/352 IF ON SKIN: Wash with plenty of soap and water. P303/36/353 IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305/35/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308/33 IF exposed or concerned: Get medical advice/attention. P30 P32 P330 P33 Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTRE or doctor/physician if you feel unwell. Rinse mouth. Do not induce vomiting. P332/33 If skin irritation occurs: Get medical advice/attention. P333/33 If skin irritation or rash occurs: Get medical advice/attention.
09/08/208 Page 0 sur 0 P337/33 If eye irritation persists: Get medical advice/attention. P362 P363 Take off contaminated clothing and wash before reuse. Wash contaminated clothing before reuse. P370/378 In case of fire: Use carbon dioxide, dry chemical, foam for extinction. P39 Collect spillage. P403/235 Store in a well-ventilated place. Keep cool. P405 P50 Store locked up. SCI 2 Skin Corrosion / Irritation Category 2 SS Sensitization - Skin Category SS A SS B Dispose of contents/container to approved disposal site, in accordance with local regulations. Sensitization - Skin Category A Sensitization - Skin Category B The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions, recommendations and/or suggestions are made without guarantee. 37/4 zone d activité Nord- 5377 BAILLONVILLEE Tel depuis la Belgique : 084/2.30.43 Tel depuis l étranger : 0032/84.2.30.43 E mail : contact@aromateasy.net