Date of issue: 20/11/2014 Revision date: 06/03/2015 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : BisCem Base 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : For professional use only 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc. 1100 W Irving Park Road, Schaumburg, IL 60193 USA 1-847-534-6000, during normal business hours www.bisco.com EC Representative: Bisico France, 120, allée de la Coudoulette, 13680 Lançon de Provence, France Telephone: 33-4-90-42-92-92 1.4. Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 Eye Irrit. 2 H315 H319 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: 1-800-424-9300 Outside the U.S.: 1-703-527-3887, collect calls accepted Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Irritant GHS07 : bisphenol A glycidylmethacrylate, tetraethylene glycol dimethacrylate : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H335 - May cause respiratory irritation : P264 - Wash hands thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P403+P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose in a safe manner in accordance with local/national regulations 06/03/2015 EN (English) 1/6
P270 - Do not eat, drink or smoke when using this product 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC tetraethylene glycol dimethacrylate (CAS No) 109-17-1 (EC no) 203-653-1 10-30 Xi; R36/37/38 R43 bisphenol A glycidylmethacrylate (CAS No) 1565-94-2 (EC no) 216-367-7 10-30 Xi; R41 Xi; R37/38 R43 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] tetraethylene glycol dimethacrylate (CAS No) 109-17-1 (EC no) 203-653-1 bisphenol A glycidylmethacrylate (CAS No) 1565-94-2 (EC no) 216-367-7 Full text of R- and H-phrases: see section 16 10-30 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Skin Sens. 1, H317 STOT SE 3, H335 10-30 Eye Dam. 1, H318 Skin Sens. 1, H317 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. : Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). Wash contaminated clothing before reuse. If skin irritation occurs: : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause an allergic skin reaction. May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. 06/03/2015 EN (English) 2/6
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing mist, vapours. Use only outdoors or in a well-ventilated area. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. : Keep container tightly closed. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Avoid all unnecessary exposure. : Wear protective gloves : Chemical goggles or safety glasses : Wear suitable protective clothing : Wear appropriate mask : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste. Colour : tooth. Odour : acrylic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 38 C Auto-ignition temperature 06/03/2015 EN (English) 3/6
Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits n flammable : Insoluble 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential adverse human health effects and symptoms : Causes skin irritation. : Causes serious eye irritation. : May cause an allergic skin reaction. : May cause respiratory irritation. :. SECTION 12: Ecological information 12.1. Toxicity tetraethylene glycol dimethacrylate (109-17-1) LC50 fishes 1 0.097 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Stabilizer) EC50 Daphnia 1 0.09-0.29 mg/l (48 h; Daphnia magna; Stabilizer) 06/03/2015 EN (English) 4/6
12.2. Persistence and degradability BisCem Base Persistence and degradability bisphenol A glycidylmethacrylate (1565-94-2) Persistence and degradability tetraethylene glycol dimethacrylate (109-17-1) Persistence and degradability 12.3. Bioaccumulative potential BisCem Base Bioaccumulative potential bisphenol A glycidylmethacrylate (1565-94-2) Log Pow Bioaccumulative potential tetraethylene glycol dimethacrylate (109-17-1) Bioaccumulative potential 12.4. Mobility in soil Biodegradability in water: no data available. Biodegradability in water: no data available. Biodegradability in soil: no data available. 4.94 (Estimated value) No bioaccumulation data available. No bioaccumulation data available. 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not regulated for transport 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) 14.4. Packing group Packing group (ADR) Packing group (IMDG) 06/03/2015 EN (English) 5/6
Packing group (IATA) Packing group (ADN) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available 14.6. Special precautions for user 14.6.1. Overland transport 14.6.2. Transport by sea 14.6.3. Air transport 14.6.4. Inland waterway transport Not subject to ADN 14.6.5. Rail transport Carriage prohibited (RID) 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no substances with Annex XVII restrictions BisCem Base is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances 15.1.2. National regulations Germany Water hazard class (WGK) : 1 - slightly hazardous to water 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ne. Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H319 Causes serious eye irritation H335 May cause respiratory irritation R36/37/38 Irritating to eyes, respiratory system and skin R37/38 Irritating to respiratory system and skin R43 May cause sensitisation by skin contact Xi Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 06/03/2015 EN (English) 6/6