TITLE: Evaluation of HMA Moisture Damage in Wisconsin as it Related to Pavement Performance

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Paper No. 06-1605 TITLE: Evaluation of HMA Moisture Damage in Wisconsin as it Related to Pavement Performance AUTHORS: Kunnawee Kanitpong 1 Hussain Bahia 2 1 School of Civil Engineering The Asian Institute of Technology P.O. Box 4, Klong Luang Bangkok, Thailand 12120, (66 2) 524-5513 kanitpon@ait.ac.th 1 Department of Civil and Environmental Engineering The University of Wisconsin Madison 2210 Engineering Hall, 1415 Engineering Dr. Madison, WI 53706, (608) 265-4481 bahia@engr.wisc.edu Paper submitted for presentation and publication at the Transportation Research Board 85th Annual Meeting January 22-26, 2006 Washington, D.C.

Kanitpong and Bahia 2 Evaluation of HMA Moisture Damage in Wisconsin as it Related to Pavement Performance By Kunnawee Kanitpong and Hussain U. Bahia ABSTRACT The Wisconsin Department of Transportation (WisDOT) has been using the Tensile Strength Ratio (TSR) test (ASTM D-4867) to predict the potential susceptibility of asphalt mixture to moisture damage and other associated pavement deterioration. The objectives of this paper are to evaluate the relationship between the performance of asphalt pavements in the field and the TSR values measured in laboratory on the original asphalt mixtures used in constructing pavements, and to evaluate the effect of antistripping additives on field performance. To assess the moisture damage problem in the field, 21 existing WisDOT pavement sections that were built prior to the requirement of TSR parameter was adopted, were selected to cover a wide range of locations and aggregate sources. The TSR and the pavement performance data (Pavement Distress Index or PDI) for these projects were collected from the WisDOT Pavement Management Database. The results indicated no relationship between TSR and field pavement performance as measured by the PDI, and no relationship between TSR and specific pavement distresses that are related to moisture damage (surface raveling and rutting). To evaluate the effect of using anti-stripping additive, a database study and a laboratory study were conducted. The database showed an effect of using anti-stripping additives on the pavement performance and also on the specific pavement distresses that are related to moisture damage. In laboratory testing, anti-stripping additives were not found to change the rheological properties of asphalt binders, nor to improve the rutting and fatigue related properties of asphalt binder as measured by the Dynamic Shear Rheometer (DSR). However, they were found to increase the adhesion of asphalt binder to selected mineral aggregate surfaces, especially when the binder bond is exposed to water. It appears that although TSR values did not correlate with better performance, increased adhesion results in an overall better performance of pavements that were included in this survey. Key words: TSR, moisture damage, pavement performance, PDI, raveling, rutting, antistripping

Kanitpong and Bahia 3 1. INTRODUCTION HMA Moisture damage is a problem that is not unique to Wisconsin. Nation wide the use of a test method to determine the potential of asphalt mixtures for moisture damage is used in specifications for highway construction. In the past many years, several studies have been conducted to evaluate the problem and cause of moisture damage, and also to find test method to measure and predict the resistance of HMA to moisture damage (1-5). In the early 1990s, the Wisconsin Department of Transportation (WisDOT) began to look at requiring the use of a test to predict the potential susceptibility of any given mixture to moisture damage and thus prevent possible associated pavement deterioration. At that time, the Tensile Strength Ratio (TSR) test (ASTM D-4867) was chosen, and the specification criterion required that when the TSR of a mixture at optimum % asphalt content fell below 70%, the contractor was required to add an anti-stripping agent to the mixture. Additionally, if an anti-stripping agent was used, the new TSR value now had to meet or exceed a higher value of 75% (6). Since the implementation of this requirement, a question has been raised as to whether the addition of the anti-strip agents, and the associated costs incurred from using this test has actually helped solve a problem that might not have even existed or has been accounted for by ensuing mixture and aggregate requirements. In 1997 a study was initiated by WisDOT to evaluate the effectiveness of the TSR test in measuring potential for moisture damage. That study raised specific questions about the meaning of the TSR values measured in the laboratory due to test repeatability problems and the lack of clear evidence of a relationship between the TSR values and moisture damage in the field (7). The study could not identify any significant relationship between the conditions of the field test sites selected and the wide range of TSR values measured in the laboratory on original mixtures as well as re-fabricated mixtures. As a follow up to that study, the DOT and the industry in Wisconsin still questioned whether a relationship existed between failing TSRs and poor pavement performance. This resulted in a follow up study to look at pavement performance and the effect of anti-stripping additives on asphalt binders. 2. OBJECTIVES The main objectives of this study are to: 1. Determine if there is a relationship between the pavement performance measures that are known to be affected by moisture damage, and the TSR values measured in the laboratory on original mixes. 2. Evaluate the effects of anti-stripping additives on asphalt mixtures to determine if there is an effect on the pavement performance other than increasing resistance to moisture damage. 3. RESEARCH METHODOLOGY To evaluate the relationship between the pavement performances in the field to the TSR values measured in the laboratory, a total of 21 existing WisDOT pavement sections, that

Kanitpong and Bahia 4 were built to meet the specification prior to 1992 when the requirement of the TSR parameter was added, were selected to cover a wide range of locations and aggregate sources. The TSR data and the pavement condition data for these projects were collected from the TSR database (as developed by WisDOT central office laboratory in anticipation of the pending TSR specification implementation) and the WisDOT Pavement Management Database, respectively. Analysis of this data was conducted to determine the correlation between the TSR values and the overall pavement condition. The pavement condition information as determined by the Performance Distress Index (PDI) and the individual pavement performance measures that are known to be affected by moisture damage, were correlated to the TSR values of the selected projects. The PDI is a mathematical expression for pavement condition rating keyed to observe surface distresses. The PDI of a section is a single number that summarizes the level of distress within the survey segment. The analysis of the relationship between the PDI and the TSR was used to determine if Wisconsin pavements exhibit a moisture damage problem. The moisture damage problem was defined based on selected performance indicators that include the following distress types: surface raveling, visible stripping and rutting, and/or alligator cracking. To evaluate the relative change in performance due to use of the additives, two sets of projects were studied. The first set included mixtures with aggregates that require anti-stripping additives. The other set included mixtures that used identical aggregates but without anti-stripping additive. The pavement condition data for these two sets of projects were collected to evaluate performance of the pavement when anti-stripping additive was used. The most commonly used anti-stripping additive in Wisconsin was selected for evaluating the effect of additive on the asphalt binder properties in the laboratory. The Dynamic Shear Rheometer (DSR) device was utilized to measure different binder properties before and after using the additive at the required concentration. Additionally, this study evaluated the effect of anti-stripping additives on the adhesion property of asphalt binders to selected aggregates. To support this study, the Pneumatic Adhesion Tensile Testing Instrument (PATTI), applied by Youtcheff and Aurilio (8) and Kanitpong and Bahia (9), was used to measure the adhesion property of asphalt binder to selected types of aggregate surfaces. The adhesion property is expected to be directly related to the moisture damage resistance of the binders. 4. RESULTS AND DATA ANALYSIS In this study the surface distresses that are known to be affected by moisture damage were also correlated to the TSR values. These distresses include surface raveling and rutting. According to the database, PDI and severity ratings for surface raveling and rutting vary during the pavement life; therefore, the increase rate of PDI per year (PDI / Year) and the average rates of increase of surface raveling and rutting were calculated and used in the analysis. This was done by dividing the total change in the values of the indicators between initial value and last year of survey value by the number of years. It is recognized that the rate of change is not constant but it was assumed that the average

Kanitpong and Bahia 5 value is the best indicator for the study. Table 1 shows the list of 21 test sections with their PDI rates, surface raveling rates, rutting rates and corresponding TSR values. 4.1 Relationship between TSR and Pavement Performance To correlate the TSR values with the PDI values, a scatter plot was prepared as shown in Figure 1. It is shown that there is no significant relationship between the TSR and the PDI for these test sections. Linear regression analysis was used to fit a simple linear relationship which indicates a negative slope. The trend shows higher TSR with lower PDI rate, as shown in Figure 1. The R 2 value, however, is very low (0.126) which indicates that the relationship between these two parameters is not significant. Since the PDI number is a collective indicator, it was decided to conduct more detailed analysis by relating the TSR values to the specific distresses known to be affected by moisture damage (raveling and rutting). The scatter plots for raveling and rutting versus TSR are shown in Figure 2 and Figure 3 respectively. The R 2 values in both figures do not show any relationship between TSR, surface raveling, and rutting. Thus, the TSR measured in the laboratory on original mixtures does not appear to correlate with the distresses that are believed to be affected by moisture damage in the field. 4.2 Effect of Aggregate Mineralogy on the Pavement Performance The aggregate sources used in the production of HMA mixtures for these 21 projects contained different mineralogical compositions. The geological map of Wisconsin that shows the distribution of the bedrock in the state was used to locate and determine the mineralogy of different aggregate sources. A total of 9 predominant geological formations were identified in the State of Wisconsin with the assistance of the geologists at the Wisconsin Geological and Natural History Survey (WNHS) Department. This guideline was used to group the aggregate used in 21 projects as shown in Table 2. Table 3 summarizes the aggregate sources for 21 projects and their corresponding aggregate mineralogy including the Geo Code. The effect of aggregate mineralogy on the pavement performance (PDI) is shown in Figure 4. As shown in Figure 4, the aggregate with Geo code 2, 6A, and 8 show more change in PDI when comparing with the aggregate with Geo code 3, 6, 7 and 9. However, the scatter of the data is observed to be high even in some of the mineralogy (Geo code = 6A, 8, and 9) that has only two data points. Therefore, the graph could not clearly show a direct relationship between aggregate mineralogy and PDI values. This result could support the previous study by Seemab and Bahia (7), which mentioned that the mineralogy alone does not explain the moisture damage behavior, since the production and construction methods seem to have significant effect as well. 4.3 Effect of Ant-Stripping Additives on Pavement Performance To establish the relationship between the pavement performance and the use of antistripping additives, specific aggregate sources that traditionally require anti-stripping

Kanitpong and Bahia 6 additives in projects in Wisconsin were identified from the WisDOT database. The PDI data for a large number of projects in which their aggregates were used was collected and the average rate of increasing PDI value per year (PDI/year) was calculated for each project. The process of collecting PDI was similar to the data collection process described in the previous section. The PDI values for these projects were compared to PDI values of projects in which the same set of aggregate sources, and/or other sources that are in the same group of aggregate mineralogy were used but without using antistripping additives. The comparison of PDI values between the projects in which the same aggregate sources were used with and without anti-stripping additives is shown in Figure 5. The results show that using anti-stripping additive generally results in lower PDI values in most of aggregate types, especially the aggregate in the group of Precambrian Rock and Glacial Material (Geo code 6A, 7, and 8). The effects on the surface raveling and rutting, when additives were used, were also determined and compared as shown in Figure 6 and Figure 7, respectively. Both figures show that using the additive can reduce the severity of surface raveling and rutting in the field for most of aggregate mineralogy, except the Silurian (Niagara Dolomite) in Geo code 5, which shows higher severity when using additive. The results are correlated well to the effect of additive on PDI rate as shown in Figure 5. High variability of the data observed in Figure 5, 6 and 7 can be explained by the fact that the data was obtained from different projects but with the same aggregate source; therefore, the production and construction methods of different projects could significantly affect the pavement performance. 4.4 Laboratory Study of Rheological and Damage Resistance Properties of Anti- Stripping Additive Modified Asphalt The finding from section 4.3 indicated that using anti-stripping additives has an effect on the pavement performance in the field. To ensure this finding, the asphalt binder was modified by using anti-stripping additive, and then different binder properties as related to the pavement performance were measured, including the adhesion property of asphalt binder. Adhesion is believed to be one of the failure mechanism that causes a loss of bond between asphalt and aggregate and leading to the stripping problem. Morlife 3300 is the additive that was selected in this study since it is widely used in Wisconsin. According to WisDOT s record, the additive was added to the asphalt binder (PG58-28) in the amount of 0.5% by weight of asphalt at mixing temperature 135 C. The following tests were performed to evaluate the effect of anti-stripping additive on the asphalt binder properties. The dynamic shear rheometer (DSR) was used to measure visco-elastic properties, fatigue and rutting resistance at high and intermediate temperatures of the asphalt binder. The analysis presented in this section includes the comparison of the asphalt binder with and without anti-stripping additives using the complex shear modulus (G*), storage modulus (G), loss modulus (G), and fatigue and rutting behavior as measured with the DSR. Based on Table 4, it was very difficult to conclude that there is significant or important effect of anti-stripping additives on the G* parameter. The G*, G, and G

Kanitpong and Bahia 7 values of the binder are marginally reduced when the anti-stripping additives are used. These results were supported by PaveTex Engineering and Testing Inc. study (10). It is indicated from their study that when anti-stripping liquids are used in asphalt binders, they may exhibit little or no change when they were measured for asphalt binder properties. Figure 8 depicts the plots for asphalt binders with and without anti-stripping and shows that fatigue behavior is very closed for both binders. The figure shows the ratio of dissipated energy (Rde) as a function of cycles of load application. The reduction in Rde is a sign of fatigue damage accumulation. The number of cycles to the start of reduction in Rde could be considered as the fatigue life (No. of cycles to failure). These findings, therefore, indicate that there is no significant difference in the fatigue resistance for both asphalt binders. The rutting resistance between the asphalt binder with and without additive was also compared. The measurements include accumulation of permanent strain as a function of cycles. The results of testing are illustrated in Figure 9. The plots show that the asphalt without additive performs better than the asphalt with additives as related to the rutting resistance. However, the difference between the two asphalts is not significant. Therefore, the conclusion that can be made is that the additive does not appear to improve the rutting resistance of the original asphalt binder. 4.5 Laboratory Study of Adhesion Property of Anti-Stripping Additive Modified Asphalt Adhesion is known as a major property that causes the bonding between asphalt and aggregate surface. Moisture or water is believed to affect asphalt adhesion and create a loss of bond between asphalt and aggregate interface. In this study, the adhesion test of asphalt binder was conducted by using the Pneumatic Adhesion Tensile Testing Instrument (PATTI). The Pull-Off Tensile Strength Test of asphalt binders with and without anti-stripping additive was conducted according to the test procedure described by Kanitpong and Bahia (9). The schematic drawing of the pull-off tensile strength test is shown in Figure 10. The asphalt is applied to a pull stub which is placed on the aggregate surface as shown in Figure 10. Air pressure generated by the PATTI is transmitted to the piston which is placed over the pull stub and screwed on the reaction plate. The air pressure induces an airtight seal formed between the piston gasket and the aggregate surface. The pressure at which the pull stub is debonded from the aggregate surface either by cohesive or adhesive failure is measured and converted to the pull-off tensile strength. Asphalt binders with and without anti-stripping additive were measured. For each binder, eight specimens were prepared, four in dry condition and four in water exposed condition at 25C for 24 hours. The aggregate surfaces used in the adhesion test include the aggregate listed in the previous section, which are Platteville, Galena, Silurian, and Prairie Du Chein aggregate. The pull-off strength was measured to represent the adhesion of asphalt binder in dry and water-exposed condition. Figure 11 illustrates the effect of anti-stripping additive and water-exposed condition to the pull-off strength of different aggregates. It was observed from Figure 11 that the pull-off tensile strength values vary between the types of aggregate source used.

Kanitpong and Bahia 8 The specimens under water-exposed condition show lower pull-off tensile strength than the specimens under dry condition, and the failure observed is the adhesion failure or the failure occurred at the interface between asphalt and aggregate. Galena aggregate shows the lowest pull-off strength, while the PDC shows the highest. According to Figure 11, it is obviously seen that the use of anti-stripping additive results in higher pull-off strength for all aggregate samples (Sirulian, Galena, Platteville, and PDC). As a result, it is believed that the anti-stripping additive can improve the adhesion property of the bond between asphalt binder and aggregate surface especially for the bond under the waterexposed condition. 5. SUMMARY OF FINDINGS Based on the results and analysis of this study, the following points provide a summary of findings: 1) There is no relationship between the TSR values and the field pavement performance as measured by the PDI. In addition, the data could not be used to find a relationship between the TSR and specific pavement distresses that are known to be related to the moisture damage (such as surface raveling and rutting). 2) Aggregate mineralogy does not show a relationship to the pavement performance. The pavement performance could be affected by other factors such as the production and construction of the mixture, asphalt binder used, and aggregate gradation. 3) There is an effect of using anti-stripping additives on the pavement performance (as measured by the PDI) and also an effect on the specific pavement distresses that are related to the moisture damage (surface raveling and rutting). Pavements with mixtures containing anti-stripping additives show less increase in rutting and, on average better performance based on PDI values. The cause of such trends are however not clear. 4) Anti-stripping additives were not found either to change the rheological properties of asphalt binders, or to improve the rutting and fatigue behavior of asphalt binder as measured by the DSR. However, they were found to significantly increase the adhesion property of asphalt binder to selected mineral surfaces, especially when the binder bond is exposed to water. 5) It appears that the TSR testing can only show the effect of anti-stripping additives but does not correlate to performance. There could be other tests that are simpler and could effectively indicate the existence of anti-stripping additive or an improved level of adhesion. Improved level of adhesion is hypothesized to be the cause of improved performance.

Kanitpong and Bahia 9 6. ACKNOWLEDGEMENT This work was part of the WHRP project, which is sponsored by the Wisconsin Department of Transportation. The authors gratefully acknowledge the support of Ms. Judie Ryan and Mr. Tom Brokaw for their guidance and useful information regarding the project. 7. REFERENCES 1. Taylor, M.A. and Khosla, N.P., Stripping of Asphalt Pavements: State of the Art, Transportation Research Record 911, 1983. 2. Hicks, R.G., Moisture Damage in Asphalt Concrete, NCHRP Synthesis of Highway Practice 175: TRB, National Research Council, Washington DC, 1991. 3. Graf, P.E., Factors Affecting Moisture Susceptibility of Asphalt Concrete Mixes, Proceedings, Association of Asphalt Paving Technologists, Vol. 55, 1986. 4. Rice, J.M., Relationship of Aggregate Characteristics to the Effect of Water on Bituminous Paving Mixtures, ASTM STP 240, American Society for Testing and Materials, Philadelphia, PA, 1958. 5. Maupin, G.W., The Use of Anti-stripping Agents in Virginia, Proceedings of the Association of Asphalt Paving Technologists, Vol 51, 1982. 6. Standard Specifications for Highway and Structure Construction, Wisconsin Department of Transportation, 1996. 8. Bahia, H.U. and Ahmad, S., Evaluation and Correlation of Lab and Field Tensile Strength Ratio (TSR) Procedures and Values in Assessing the Stripping Potential of Asphalt Mixes, Final Report, Submitted to WHRP 1998. 9. Youtcheff, J. and Aurilio, V., Moisture Sensitivity of asphalt Binders: Evaluation and Modeling of the Pneumatic Adhesion test Results, Canadian Technical Asphalt Association proceedings, 1997. 10. Kanitpong, K. and Bahia, H.U., Roles of Adhesion and Thin Film Tackiness of Asphalt Binders in Moisture Damage of HMA, Proceedings, Association of Asphalt Paving Technologists, Vol. 72, 2003. 11. Liquid Antistrip Agent DSR Test Data. PaveTex Engineering and Testing, Inc., Austin, TX, April 2001.

Kanitpong and Bahia 10 LIST OF TABLES TABLE 1 Comparison of Lab TSR and Rate of Change for PDI, Surface Raveling, and Rutting for 21 Projects TABLE 2 Geological Classifications of Wisconsin Aggregates TABLE 3 List of Aggregate Sources and Corresponding Aggregate Mineralogy TABLE 4 G and G of PG 58-28 without Additive and with Different Additives LIST OF FIGURES FIGURE 1 Relationship between TSR and PDI rate of increase per year. FIGURE 2 Relationship between TSR and surface raveling. FIGURE 3 Relationship between TSR and rutting. FIGURE 4 Effect of aggregate mineralogy on PDI/Year. FIGURE 5 Effect of anti-stripping additive on PDI. FIGURE 6 Effect of anti-stripping additive on surface raveling. FIGURE 7 Effect of anti-stripping additive on rutting. FIGURE 8 Rde Vs. Cycle comparison chart between original binder and binder modified with anti-stripping additive. FIGURE 9 Accumulated strain (mm/mm) Vs. time. FIGURE 10 Schematic drawing of PATTI 110. FIGURE 11 Effect of anti-stripping additive on the Pull-Off Tensile Strength of different aggregate sources.

Kanitpong and Bahia 11 TABLE 1 Comparison of Lab TSR and Rate of Change for PDI, Surface Raveling, and Rutting for 21 Projects NO. PROJECT# PROJECT HWY# TSR PDI Surface Raveling Rutting COUNTY (TESTED VALUE) Increase Increase Increase Rate Rate Rate 1 7182-03-71 Pierce STH 35 38.7 6.03 0 0 2 1401-03-71 Columbia STH 16 54.0 5.21 0 0 3 7030-09-71 Eau Claire USH 10 47.8 12.47 0.167 0 4 7181-07-71 Pierce STH 35 60.7 6.56 0.017 0 5 8111-02-71 Dunn STH 64 55.3 6.33 0 0.213 6 9155-10-70 Langlade STH55 59.5 12.6 0.33 0 7 1614-05-73 Price STH 13 59.9 3.57 0.111 0.034 8 7062-03-71 Jackson STH 27 65.2 4.82 0.094 0 9 9304-03-70 Forest STH 101 60.6 7.26 0.042 0 10 1704-03-72 Rock STH 11 60.8 10.36 0.167 0 11 1525-08-71 Wood STH 73 79.0 4.51 0 0.103 12 1650-01-76 Grant USH 61 64.2 4.44 0.0128 0.023 13 3031-02-71 Dodge STH 67 65.9 5.08 0 0 14 1331-05-74 Waukesha STH 83 76.2 2.26 0 0 15 5511-03-77 Monroe STH 71 70.5 4.4 0.101 0 16 3082-00-71 Jefferson USH 18 68.7 2.24 0 0 17 4100-06-72 Manitowoc USH 151 78.9 9.51 0 0.2 18 1490-11-74 Marinette USH 141 73.3 5.2 0 0 19 9250-07-70 Iron STH 77 82.0 8.91 0.26 0.17 20 5134-08-71 Monroe STH 131 86.0 3.32 0.08 0 21 5271-06-71 Columbia STH 60 86.2 3.21 0 0

Kanitpong and Bahia 12 TABLE 2 Geological Classifications of Wisconsin Aggregates GEOLOGY CODE DESCRIPTION 1 Platteville and Prairie Du Chein Dolomite 2 Platteville Dolomite 3 Galena Dolomite 4 Sinnippee Group (Both Galena and Platteville) 5 Silurian (Niagara Dolomite) 6 Prairie Du Chein Dolomite 6a Pre-cambrian Crystalline Rock 7 Greenbay/Lake Michigan Glacial Lobes (Igneous + Carbonate) Dolomite 8 Langlade/Wisconsin Valley/and Older Glacial Deposits (Igneous Rocks) 9 Chippewa/St. Croix Older Gravel

Kanitpong and Bahia 13 TABLE 3 List of Aggregate Sources and Corresponding Aggregate Mineralogy NO. PROJECT# PROJECT HWY# AGG SOURCE AGG MINEROLOGY GEO COUNTY CODE 1 7182-03-71 Pierce STH 35 PRESCOTT QRY Prairie Du Chien Dolomite 6 2 1401-03-71 Columbia STH 16 KONE/RIO PIT Igneous and Dolomite 7 3 7030-09-71 Eau Claire USH 10 BOONE QRY Precambrian Rock 6A 4 7181-07-71 Pierce STH 35 PETERSON QRY Prairie Du Chien Dolomite 6 5 8111-02-71 Dunn STH 64 AMER.MTRLS#52 Prairie Du Chien Dolomite 6 6 9155-10-70 Langlade STH55 DAVIS PIT Igneous 8 7 1614-05-73 Price STH 13 GUSTAFSON PIT Chippewa Glacial 9 8 7062-03-71 Jackson STH 27 ENDRES QRY Prairie Du Chien Dolomite 6 9 9304-03-70 Forest STH 101 MEYERS PIT Igneous 8 10 1704-03-72 Rock STH 11 BJOINS QRY Platteville Dolomite 2 11 1525-08-71 Wood STH 73 KORGER QRY Precambrian Rock 6A 12 1650-01-76 Grant USH 61 STANTON QRY Galena Dolomite 3 13 3031-02-71 Dodge STH 67 ULLMER PIT Igneous and Dolomite 7 14 1331-05-74 Waukesha STH 83 VULCAN/DOUSMAN Igneous and Dolomite 7 15 5511-03-77 Monroe STH 71 DONSKEY QRY Prairie Du Chien Dolomite 6 16 3082-00-71 Jefferson USH 18 DOUSMAN PIT Igneous and Dolomite 7 17 4100-06-72 Manitowoc USH 151 WAGNER PIT Igneous and Dolomite 7 18 1490-11-74 Marinette USH 141 GABRIEL PIT Igneous and Dolomite 7 19 9250-07-70 Iron STH 77 O'BRIAN LKE PIT Chippewa Glacial 9 20 5134-08-71 Monroe STH 131 O'ROURKE QRY Prairie Du Chien Dolomite 6 21 5271-06-71 Columbia STH 60 KLEMP PIT Igneous and Dolomite 7

Kanitpong and Bahia 14 TABLE 4 G and G of PG 58-28 without Additive and with Different Additives Temp Unmodified 0.5% Morlife G' G" G' G" 16 123726 268300 106829 247952 28 29150 98381 24736 88838 40 1702 13462 1376 11758 52 105 1977 87 1705 64 12 408 11 363

Kanitpong and Bahia 15 14 12 PDI Increase Rate 10 8 6 R 2 = 0.1256 4 2 30 40 50 60 70 80 90 TSR FIGURE 1 Relationship between TSR and PDI rate of increase per year.

Kanitpong and Bahia 16 0.35 0.3 0.25 Surface Ravelling 0.2 0.15 0.1 0.05 R 2 = 0.004 0-0.05 30 40 50 60 70 80 90 TSR FIGURE 2 Relationship between TSR and surface raveling.

Kanitpong and Bahia 17 0.25 0.2 0.15 Rutting 0.1 0.05 R 2 = 0.048 0-0.05 30 40 50 60 70 80 90 TSR FIGURE 3 Relationship between TSR and rutting.

Kanitpong and Bahia 18 Cell Mean for PDI Increased Rate/Year 13 12 11 10 9 8 7 6 5 4 3 n=1 n=1 n=6 n=2 n=7 n=2 n=2 2 3 6 6A 7 8 9 Aggregate Mineralogy FIGURE 4 Effect of aggregate mineralogy on PDI/Year.

Kanitpong and Bahia 19 PDI Increasing Rate 16 14 12 10 8 6 4 2 0 n=1 n=0 n=1 n=0 n=0 n=7 n=1 n=7 n=2 n=9 Additive No Additive 1 2 3 4 5 6 6A 7 8 9 Aggregate Geo Code n=7 n=9 n=5 n=3 n=10 n=9 n=21 n=1 n=0 n=16 FIGURE 5 Effect of anti-stripping additive on PDI.

Kanitpong and Bahia 20 Ravelling Rate 0.6 0.4 0.2 0 Additive No Additive -0.2 1 2 3 4 5 6 6A 7 8 9 Aggregate Geo Code FIGURE 6 Effect of anti-stripping additive on surface raveling.

Kanitpong and Bahia 21 0.8 0.6 Additive No Additive Rutting Rate 0.4 0.2 0-0.2 1 2 3 4 5 6 6A 7 8 9 Aggregate Geo Code FIGURE 7 Effect of anti-stripping additive on rutting.

Kanitpong and Bahia 22 FIGURE 8 Rde Vs. Cycle comparison chart between original binder and binder modified with anti-stripping additive.

Kanitpong and Bahia 23 FIGURE 9 Accumulated strain (mm/mm) Vs. time.

Kanitpong and Bahia 24 FIGURE 10 Schematic drawing of PATTI 110.

Kanitpong and Bahia 25 Dry condition Water-exposed condition at 24 hours Pull-Off tensile Strength (kpa) 1400 1200 1000 800 600 400 PG58-28 0.5% Morlife Pull-Off tensile Strength (kpa) 1400 1200 1000 800 600 400 PG58-28 0.5% Morlife 200 200 0 Platteville Galena Silurian Prairie Du Chein Aggregate Types 0 Platteville Galena Silurian Prairie Du Chein Aggregate Types FIGURE 11 Effect of anti-stripping additive on the Pull-Off Tensile Strength of different aggregate sources.