1. IDENTIFICATION OF THE PRODUCT AND THE COMPANY Trade name Intended use ZINC SULPHATE feed grade Mineral feed additive for animals DISTRIBUTOR Name Gambit Humański, Janiszewski sp.j. Add 99-300 Kutno; Spółdzielcza Str. 3 Telephone Fax e-mail address 0048 24 2547073 0048 24 2544880 gambit@gambitkutno.pl Website www.gambitkutno.pl Emergency telephone number +48 (024) 2547073 or +48 (0)601335519 Date of preparation 28.02.2015 2. HAZARDS IDENTIFICATION The product is classified as the hazardous product according to the 6 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. To people: Xn Harmful with risk phrase R22 - Harmful if swallowed Xi Irritant with risk phrase R41 Risk of serious damage to eyes To the environment: N - Hazardous to the environment with risk phrase R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The product is classified as the hazardous product according to the Annex 6 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Hazard class and category code (s) Hazard statement Acute Tox. 4 (*) H302 -. Harmful if swallowed. Skin and eye Sens.1 H314 Causes serious skin burns eye damage Aquatic Chronic 1 H410 - Very toxic to aquatic life with long lasting effects. The packaging should be labelled see section 15. 3. COMPOSITION/INFORMATION ON INGREDIENTS The classification of ingredients according to the table 3.2 from Annex 6 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Name Content % CAS No EINECS No Index No Classification Zinc sulphate, monohydrate ~35,0% (as Zn 2+ ) 7733-02-0 231-793-3 030-006-00-9 Xn; R22 Xi; R41 N; R50/53 The classification of ingredients according to the table 3.1 from Annex 6 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. Zinc sulphate, monohydrate Content: CAS No: EINECS No: Index No: ~35,0% (as Zn 2+ ) 7733-02-0 231-793-3 030-006-00-9 The classification Hazard class and category code (s) Hazard statement Acute Tox. 4 (*) H302 -. Harmful if swallowed. Eye Sens. 1 H318 Causes serious eye damage Skin and eye Sens.1 H314 Causes serious skin burns eye damage Aquatic Acute 1 H400 - Very toxic to aquatic life. Aquatic Chronic 1 H410 - Very toxic to aquatic life with long lasting effects The complete text of the R phrase and hazard statement are given in section 16 of this Safety Data Sheet. ZINC SULPHATE feed grade Page 1 z 6
4. FIRST AID MEASURES General information: Eyes contact Rinse at least 15 minutes with plenty of cool fresh water. Avoid strong stream of water due the risk of mechanical damage to the cornea. Persons exposed to contaminated eyes should be instructed about the necessity and manner of their immediate rinsing. Please provide ophthalmologic. Further proceedings consistent with the recommendations of an eye. Skin contact: Remove contaminated clothing and wash skin with plenty of lukewarm, running water. In case of skin irritation Dermatological consultation indicated. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician immediately. Inhalation: In case of inhalation exposure (the product of dust) move the patient from exposure and provide fresh air. If you stop breathing, administer artificial respiration. In the case of respiratory distress, give oxygen and call a physician immediately. 5. FIRE FIGHTING MEASURES Specific risks. Non-flammable substance. In case of fire emit dangerous gases: oxides of sulfur and zinc oxide fumes. Extinguishing media: Fires in the presence of the product, adjust measures to burning materials. Special protective equipment for firefighters: Wear self-contained breathing apparatus and full protective clothing. Other comments: Do not allow to enter contaminated extinguishing water into groundwater 6. ACCIDENTAL RELEASE MEASURE Personal protection/precautions: The work of eliminating the consequences of failure guided by trained personnel and equipped with appropriate personal protective equipment (protective clothing), eye protection (goggles / tight-fitting goggles), respiratory (breathing mask) and skin (gloves) Environmental precautions: Do not flush into surface water or sanitary sewer system. Do not allow material to contaminated ground water system. Local authorities should be advised if significant spillages couldn t be contained. If the product contaminates rivers, lakes or drains inform respective authorities. Methods for cleaning up: Collect the spilled product dry to a closable plastic container without pollination. Clean the contaminated area. Dispose of in accordance with the recommendations set out in section 13 7. HANDLING AND STORAGE Handling: Take special care because of the irritating properties of the product. Avoid contact with eyes and skin, and inhalation of dust, do not eat, drink, work in a ventilated room, used clothing protection and personal protective equipment. Storage: Keep in a tightly closed container, stored in a cool, dry, ventilated area, away from heat sources. Do not stack pallets. Because of the tendency to dust should be provided the storage temperature is not higher than 20 C, relative humidity, not higher than 70% 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Additional recommendations in the field of engineering: Provide adequate ventilation of production premises and workplaces. Do not breathe dust product. Personal protection: Wash hands before breaks and after work. Avoid contact with skin and eyes. Remove contaminated clothing. Keep away from food, beverages and feed. Do not eat, drink or smoke when using the product. Avoid exposure to eyes and skin. Respiratory protection: There are no specific recommendations in terms of instruction. Applied respiratory protection should meet the requirements of legislation on the basic requirements for personal protective equipment. Skin Protection of hands: Wear suitable gloves. ZINC SULPHATE feed grade Page 2 z 6
8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye protection: Wear goggles or tight-fitting goggles Body protection: Wear standard clothing. WARNING! When the concentration of substance is known, the selection of personal protective equipment should be made taking into account the concentration of the substance present in a given position, exposure time and operations performed by the employee. In an emergency situation, if the concentration of substances in the workplace is not known, use personal protective equipment recommended for the highest protection class. The employer is obliged to ensure that the applicable personal protective equipment and clothing and footwear have protective properties and utility and to ensure adequate washing, maintenance, repair and decontamination. 9. PHYSICAL AND CHEMICAL PROPERTIES Formula Physical form Colour Odour Melting point Boiling point Flash-point Bulk density Specific density Water solubility ZnSO4 x H2O Solid, crystalline White Specific Not applicable Not applicable Not applicable 1,23g/ cm 3 1,03 g/cm 3 577 g/l (25 C) 10. STABILITY AND REACTIVITY Stability: The product is stable under conditions of use in accordance with the instruction manual. Conditions and Materials to be avoided: Strong heating of the product Hazardous decomposition products: Oxides of zinc 11. TOXICOLOGICAL INFORMATION The concentration and the lethal doses and toxic: Threshold odor - no data LD (50) rat, oral) - 2949 mg / kg LC50 (mouse, oral) - 36 mg / kg LD50 (rat, skin) - 210 mg / kg LD50 (human oral) - 66 mg / kg Action dangerous health effects and symptoms associated with: - exposure by inhalation: may cause irritation - ingestion: may cause irritation, abdominal pain, nausea - contact with skin: may cause irritation - eye contact: irritating, the risk of serious eye damage. Additional information: Symptoms of acute poisoning: Irritating to skin, mucous membranes and eyes - causes skin lesions and itching - deep ulcer. Causes intestinal disorders (persistent vomiting), disrupts the function of liver and pancreatic function dust allergy on the skin and respiratory Symptoms of chronic poisoning: no sensitizing properties, may cause inflammation of the skin around the armpit. With long-term impact of possible disorders of the pancreas and liver; general weakness and skin changes. 12. ECOLOGICAL INFORMATION Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The concentration of toxic to aquatic organisms: Toxicity (CL50/96 h) for fish Onchorhynchusw mykiss - 0.43 mg / l (anhydrous substance) Poses a threat to drinking water supply. Do not flush the product into water, waste water or soil. Observe local / local regulations. ZINC SULPHATE feed grade Page 3 z 6
13. DISPOSAL CONSIDERATIONS Do not allow undiluted product or large quantities of it to reach surface water, ground water or sewage system. Handling of wastes Article 1(a) of Council Directive 75/442/EEC on waste and Council Decision 94/904/EC establishing a list of hazardous waste pursuant to Article 1(4) of Council Directive 91/689/EEC on hazardous waste Classification of wastes according to European Directive 2000/532/EC, Council Decision 2001/118/EEC: Not determined. Empty containers: According to European Parliament and Council directive 94/62/EC of 20 December 1994 on packaging and packaging waste. Not determined. Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance with state and local requirements. 14. TRANSPORT INFORMATION Classification of the product in compliance with UN Recommendations ADR/RID transport Class: 9 Code: M7 Packing group: III Label: 9 LQ27 Proper shipping name: Environmentally hazardous substance, solid, n. o. s. (contains zinc sulphate) IMO/IMDG transport (maritime transport): Class: 9 Packing group: III Marine pollutant: Proper shipping name: Environmentally hazardous substance, solid, n. o. s. (contains zinc sulphate). ICAO/IATA transport: Class: 9 Packing group: III Proper shipping name: Environmentally hazardous substance, solid, n. o. s. (contains zinc sulphate). 15. REGULATORY INFORMATION When enforceable, refer to current regulations: Directives 1999/45/EC and 67/548/EEC and relative amendments and additions Directive 2000/39/EC and relative amendments and additions. Directive 1999/13/EC and relative amendments and additions. Directive 1996/82/EC and relative amendments and additions. Directive 2000/60/EC and relative amendments and additions. Directives 91/156/EEC, 91/689/EEC and 94/62/EC and relative amendments and additions Directive 89/391/EEC and relative amendments and additions. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006. Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents. Directive 91/155/EEC as amended by Commission Directive 93/112/EC of 10 December 1993 Commission Directive 2006/8/EC of 23 January 2006 amending, for the purposes of their adaptation to technical progress, Annexes II, III and V to Directive 1999/45/EC of the European Parliament and of the Council concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. ZINC SULPHATE feed grade Page 4 z 6
15. REGULATORY INFORMATION Warning label on the packaging (GHS label elements): Signs and warning notices: H314 Causes serious skin burns eye damage H290 Can corrode metals GHS05 H410 - Very toxic to aquatic life with long lasting effects GHS09 H302 - Harmful if swallowed GHS07 Contains: Zinc sulphate, monohydrate DANGER Precautionary statement: General: P102 P260 P273 P280 Response: P301 + P312 P305 + P351 + P338 P303 + P361 + P353 Storage: P406 Keep out of reach of children. Do not breathe dust Avoid release to the environment Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Remove / Take off all contaminated clothing. Rinse skin with water/ shower Store in a corrosion-resistant packaging /... a resistant liner Disposal: P501 Dispose of contents/container in accordance with local/regional/national/international regulation 16. OTHER INFORMATION The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. The following phrases represent the prescribed R-phrases and hazard statement for the ingredients designated in point 3. R22 - Harmful if swallowed R41 - Risk of serious damage to eyes R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. ZINC SULPHATE feed grade Page 5 z 6
16. OTHER INFORMATION H302 -. Harmful if swallowed. H318 - Causes serious eye damage H314 - Causes serious skin burns eye damage H290 - Can corrode metals H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects Data of issue: 28.02.2015 ZINC SULPHATE feed grade Page 6 z 6