PRODUCT TECHNICAL DOSSIER MANGANESE SULPHATE MONOHYDRATE Product Code: P1311 Raw Material Full Name: Manganese Sulphate ID Test Manganese: Pass ID Test Sulphate: Pass ID Test LOI: 10 20% Appearance of Solution: Pass Assay (USP): 98 102% Assay (EP): 99 101% Assay (as Manganese) (Calculated): 32.18-32.83% Mesh Test on 60: Max 5% Mesh Test on 100: Report Subst Not Ppt by (NH3)2s: Max 0.5% Residual Solvents: Pass Country of Origin: USA Product Code: P1311 Version: 3 Page 1 of 12
Country of Origin of the Manufacture: USA Base Source/Start Material: Manganese & Sulphuric acid Origin of Product Synthetic, Plant, Mineral, Animal, Fish or Fermented: Synthetic Material is: 100% Compound Ingredients: None Shelf Life from Date of Manufacture: 3 Years Storage Conditions: This material is to be stored in a tightly sealed bag/container and to be kept in a cool place away from moisture and direct sunlight. Appearance: Fine Powder Colour: Pale Pink Flavour/Taste: Characteristic Odour: Characteristic Microbiological Test Total Viable Count: Max 1,000cfu/g Yeast & Moulds: Max 100cfu/g Total Coliforms: Negative Product Code: P1311 Version: 3 Page 2 of 12
Metals Heavy Metals: Max 20ppm Chlorides: Max 100ppm Iron: Max 10ppm Zinc: Max 50ppm Pharmacopeia Standard Used: USP/EP There are no nuts in this recipe and are no nuts on site, however we cannot guarantee that the raw materials entering the site are nut free. Product Code: P1311 Version: 3 Page 3 of 12
INTOLERANCE DATA Free from All Animal Products (Beef, Pork, Poultry or other) Free from Bovine Products or Derivatives by using hormones to increase milk yield in cows Free from Bone Meal Free from Peanuts and Peanut Derivatives (including possible cross contamination) Free from other Nut and Nut Derivatives Free from Nut Derived Oil Free from Sesame Seeds and Sesame Seed Derivatives Free from Poppy Seeds and Poppy Seed Derivatives Free from Sunflower Seeds and Sunflower Seeds Derivatives Free from other Seeds and Seed Derivatives Free from Milk and Milk Derivatives (including lactose) Free from Egg and Egg Derivatives Free from Cereals containing Gluten (wheat / rye / oats / barley/ spelt/ kamut or their hybridised strains) and Derivatives Free from Soya and Soya Derivatives Free from Maize and Maize Derivatives Free from Corn and Corn Derivatives Free from Lupin and Lupin Derivatives Free from Yeast and Yeast Derivatives Free from Cotton Seeds (Flour) and Cotton Seed Derivatives Free from Rice and Rice Derivatives Free from Mustard and Mustard Derivatives Free from Celery or Celery Derivatives Free from Celeriac or Celeriac Derivatives Free from Fruit and Fruit Derivatives Free from Vegetable and Vegetable Derivatives Free from Carrot and Carrot Derivatives Free from Legumes / Pulses Free from Fish and Fish Derivatives Free from Crustaceans / Molluscs and their Derivatives Free from Additives Free from Added Salt Free from Added Sugar Free from Antioxidants Free from Artificial Glutamates Free from Aspartame Free from Azo and Coal Tar Dyes Free from Benzoates (E210 / E219) Free from BHA / BHT (E320 / E321) Free from Caffeine Free from Cinnamon Free from Cocoa Free from Colours (Artificial / Nature Identical / Natural / Smoked) Free from Dextrose Free from Dioxins Free from Ethanol If No please give details Product Code: P1311 Version: 3 Page 4 of 12
INTOLERANCE DATA If No please give details Free from Ethylene Oxide Free from Flavourings (Artificial / Nature Identical / Natural / Smoked) Free from Garlic Free from Gelatine Free from Glutamates (E620 to E625) Free from Histamine Free from Hickory Free from Honey Free from Lactose Free from Latex Free from MSG (Added and Naturally Occurring E621) Free from Nucleotides (E627, E630, E631, E635) Free from Polyols Free from Preservatives Free from Starch Products (Including Maltodextrin) Free from Sorbic Acid (E200, E203) Free from Sulphur Dioxide and Sulphites at levels above 10mg/kg or 10mg/litre expressed as SO 2 Free from Sulphites (E220, E228) Free from Sweeteners Free from Vannillin Suitable for Diabetics Suitable for Coeliacs Suitable for Ovo-Lacto Vegetarians Suitable for Vegans Kosher Certified NO Not Certified Halal Certified NO Not Certified Product Code: P1311 Version: 3 Page 5 of 12
CONFIRMATION OF BSE/TSE STATUS This is to certify that this product complies with all relevant current UK and EU Legislative requirements in regard to Transmissible Spongiform Encephalopathies (TSE) and Bovine Spongiform Encephalopathy (BSE) for human food, and so is free of TSE/BSE. This is also to certify that, during the course of their manufacture, the above-mentioned product did not come into contact with any materials, which could be derived from TSE/BSE risk materials. CONFIRMATION OF GM STATUS This is to certify that this product is not manufactured from GM raw materials and is therefore not subject to labelling under regulations 1829/2003/EC and 1830/2003/EC. CONFIRMATION OF NON IRRADIATION STATUS This is to certify that this product, whole or in part, has not been subjected to Ionising Radiation as per European Directives 1999/2/EC and 1000/3/EC. CONFIRMATION OF NANDROLONE STATUS This is to certify that this product, whole or in part, has not come into contact with Nandrolone or any of its precursors in any way. CONFIRMATION OF IOC PRODUCT STATUS This is to certify that this product, whole or in part, has not come into contact with any product/s, which is banned by the IOC (International Olympics Committee). CONFIRMATION OF ANIMAL TESTING STATUS This is to certify that all the products sold by Cambridge Commodities have not been tested on animals in any part of its manufacture in accordance with regulation 86/609/EEC. CONFIRMATION OF PESTICIDES STATUS This is to certify that the above-mentioned product complies with the regulation (EC) No.396/2005 of 23 rd February 2005 and commission Regulation (EU) No. 559/2011 of 7 th June 2011 amending annexes II and III of the above Regulation. Product Code: P1311 Version: 3 Page 6 of 12
MATERIAL SAFETY DATA SHEET Section 1 Identification of the substance/preparation Product Name: Product Code: Supplier: Manganese Sulphate Monohydrate P1311 Cambridge Commodities Limited Lancaster Way Business Park, Ely, Cambridgeshire, CB6 3NX Tel: 01353 667258. Email: qa@c-c-l.com Section 2 Ingredients/Identity Information Components % in Product CAS Number Formula EINECS Number Manganese Sulphate 100 N/A N/A N/A Section 3 Hazards identification Adverse Human Health Effects: Environmental Effects: Fire or Explosion: Classification of the Product: Danger of serious damage to health by prolonged exposure through inhalation and ingestion. Toxic to aquatic organisms may cause long term effects in the aquatic environment. No specific hazard under normal conditions of use. According to the EU regulations this product is classified as harmful and Dangerous for the Environment. Section 4 Emergency and First Aid Procedures Eyes: Skin: Swallowing: Inhalation: If symptoms develop immediately move individual away from exposure and into fresh air. Rinse with plenty of water for at least 15 minutes while holding eyelids apart. Seek medical attention if irritation persists. Remove contaminated clothing. Wash with soap and copious amounts of Water. In case of redness call a doctor. Give water to drink. If the person is fully conscious try to induce vomiting. Call a doctor immediately. Remove to fresh air. If breathing is difficult, administer oxygen. If person feels unwell call a doctor. Product Code: P1311 Version: 3 Page 7 of 12
Section 5 Fire and Hazard Data Suitable Extinguishing Media: Specific Hazards: Specific Fire Fighting Methods: Protection of fire-fighters: Dry powder, water spray, carbon dioxide (CO2), foam. Not combustible Contain the extinguishing fluids by bonding (the product is hazardous for the environment). Do not attempt to fight the fire without suitable protective equipment such as complete protective clothing and self-contained breathing apparatus. Section 6 Accidental release measures Personal Precautions: Environmental Precautions: Methods for Cleaning up: Avoid contact with skin and eyes, mechanically ventilate the spillage area. Do not allow the product to spread into the environment Do not discharge into drains or rivers. Sweep up or vacuum up the product, collect all the product and place it in a spare container suitably labelled, wash dirty surfaces with water, dispose of contaminated materials in accordance with current regulations. Section 7 Storage Handling: Storage: Incompatible Materials: Ensure good ventilation of the work station dust extraction (suction). Avoid contact with skin and eyes. Avoid the formation or spread of dust in the atmosphere. Ensure there is suitable retention system (tanks). Store the container tightly closed and dry, protect from light in a cool wellventilated area. Strong oxidizing agents, powdered metals. Product Code: P1311 Version: 3 Page 8 of 12
Section 8 Control Methods/Personal Protection Engineering Measures: Occupational Exposure Limits: -France -Germany Surveillance Procedures: Respiratory Protection: Hand/Body Protection: Breakthrough time: Eye Protection: Hygiene Measures: Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below level of overexposure Manganese (dust), Mn: VME = 1 mg/m3 Manganese und its compounds: MAK = 0.5 mg/m3 Atmospheric monitoring at regular intervals. In case of dust production. Dust filter (P2/FFP2) The protective gloves to be used must comply with the specifications of EC directive 89/686/EEC and the resultant standard EN 374 Refer to the recommendations of the supplier. Wear safety glasses in compliance with OSHA regulations. Do not eat drink or smoke during use. Section 9 Physical and Chemical Properties Physical state: Colour: Odour: Solubility in water: Solubility in organic solvents: Powder Pinkish None Soluble Insoluble in alcohols Section 10 Stability and Reactivity Chemical Stability: Materials to Avoid: Hazardous Decomposition Products: Stable at ambient temperatures and under normal conditions of use. Strong oxidising agents. Powdered metals. On thermal decomposition (pyrolysis) releases Sulphur oxides and Manganese oxides. Product Code: P1311 Version: 3 Page 9 of 12
Section 11 Toxicological Information Acute toxicity: Acute symptoms: Local effects: Chronic/long term toxicity: Reproductive toxicity: LD 50 oral (rat): 2150 mg/kg (published data) In case of chronic ingestion: Lethargy and edema On inhalation: Weakness. Central Nervous System depressant. Dust may cause slight irritation to the ocular mucous membranes due to the presence of a foreign body. The dust may be irritating to the respiratory system. Danger of serious damage to health by prolonged exposure through inhalation and ingestion. Tests on animals showed adverse effects on fertility and development. Section 12 Ecological Information Eco-toxicity: Toxic to aquatic organisms. May cause long-term adverse effects in the Aquatic environment. Section 13 Disposal Considerations Waste from Product Prohibition: Destruction/Disposal: Note: Discharging waste into rivers and drains is prohibited. Dispose of in accordance with relevant local regulations. The user s attention is drawn to the possible existence of specific European, national or local regulations regarding disposal. Product Code: P1311 Version: 3 Page 10 of 12
Section 14 Transport Information UN No: 3077 Rail/road (RID/ADR): Class: 9 Classification code: M7 Packing group: III Labelling: 9 Sea (IMO/IMDG): Class: 9 Packing group: III Labelling: 9 Air (ICAO-IATA): Class: 9 Packing group: III Labelling: 9 Note: The above regulation prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transport regulations for hazardous materials in case the present sheet is dating back to more than 12 months ago it would be advisable to check the validity with your commercial agency. Section 15 Regulatory Information Symbols and indications of danger: R phrases: S phrases: Additional phrases: HARMFUL (Xn) DANGEROUS FOR THE ENVIRONMENT (N) R48/20/22 Harmful danger of serious damage to health by prolonged exposure through inhalation and if swallowed. R51/53 Toxic to aquatic organisms may cause long-term adverse effects in the aquatic environment. S2 Keep out of the reach of children. S22 Do not breathe dust. S61 Avoid release to the environment. Refer to special instructions/safety Data sheet. The following must appear on the label. EC Labelling EC N o 232-089-9. Product Code: P1311 Version: 3 Page 11 of 12
Section 16 Other Information This advice is given by Cambridge Commodities Ltd who accepts no legal liability for it. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not therefore be construed as guaranteeing specific properties. Individuals working with chemicals should consider all chemicals to be potentially hazardous even if their individual hazards may be uncharacterised or unknown. We confirm that the information above is sourced from the original manufacturers/suppliers Specification. To be used as per local legislation. Change History Version Change Customer Notification required Yes / No 1 First Issue N/A 2 The Manganese Assay has been added No 3 The method for Assay (as Manganese) has been added No Document Approval Originator Job Title QC Technician Approver Job Title Quality Specialist Adam Mulcahy Adam Mulcahy (Jul 21, 2016) Shannon McKenna (Jul 21, 2016) Product Code: P1311 Version: 3 Page 12 of 12
P1311-Manganese Sulphate Monohydrate-Technical Dossier Adobe Sign Document History 07/21/2016 Created: 07/21/2016 By: Status: Transaction ID: Adam Mulcahy (adam.mulcahy@c-c-l.com) SIGNED CBJCHBCAABAAZmoCr-b2e_-fEqFWz6-fxhPS8VR-FTxV P1311-Manganese Sulphate Monohydrate-Technical Dossier History Document uploaded by Adam Mulcahy (adam.mulcahy@c-c-l.com) from Reader 07/21/2016-9:01:03 PDT - IP address: 81.145.42.226 Document signed in Reader by Adam Mulcahy (adam.mulcahy@c-c-l.com) Signature Date: 07/21/2016-9:01:25 PDT - Time Source: server - IP address: 81.145.42.226 Document emailed to Shannon McKenna (shannon.mckenna@c-c-l.com) for signature 07/21/2016-9:01:26 PDT Document viewed by Shannon McKenna (shannon.mckenna@c-c-l.com) 07/21/2016-9:04:37 PDT - IP address: 81.145.42.226 Document e-signed by Shannon McKenna (shannon.mckenna@c-c-l.com) Signature Date: 07/21/2016-9:05:56 PDT - Time Source: server - IP address: 81.145.42.226 Signed document emailed to Adam Mulcahy (adam.mulcahy@c-c-l.com) and Shannon McKenna (shannon.mckenna@c-c-l.com) 07/21/2016-9:05:56 PDT