Date of issue: 20/03/2015 Revision date: Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Article Product code : 190594 : 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet SCA Hygiene Products UK Ltd Southfields Road LU6 3EJ Dunstable - United Kingdom T +441582677879 charlotte.branwhite@sca.com - www.sca.com : Surface cleaning 1.4. Emergency telephone number Emergency number : +46317460000 (business hours) 112 (24 hour service) applicable to EU countries only SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Ethyl alcohol (CAS No) 64-17-5 (EC no) 200-578-6 (EC index no) 603-002-00-5 2-Methyl-3-isothiazolone (CAS No) 2682-20-4 (EC no) 220-239-6 <11 F; R11 <0,1 T; R24/25 C; R35 Xi; R37 Xi; R41 R43 3-Iodo-2-propynyl butylcarbamate (CAS No) 55406-53-6 (EC no) 259-627-5 (EC index no) 616-212-00-7 <0,05 T; R23 T; R48/23 Xn; R22 Xi; R41 R43 N; R50 20/03/2015 UK(EN) 1/7
Name Product identifier % Classification according to Directive 67/548/EEC Alkyl polyglycoside (CAS No) 68515-73-1 <0,001 Xi; R41 2-Propenoic acid, methyl ester, reaction products with 2-ethyl- 1-hexanamine and sodium hydroxide (CAS No) 68610-44-6 (EC no) 271-865-1 methanol (CAS No) 67-56-1 (EC no) 200-659-6 (EC index no) 603-001-00-X <0,001 Not classified <0,0001 F; R11 T; R23/24/25 T; R39/23/24/25 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Ethyl alcohol (CAS No) 64-17-5 (EC no) 200-578-6 (EC index no) 603-002-00-5 2-Methyl-3-isothiazolone (CAS No) 2682-20-4 (EC no) 220-239-6 3-Iodo-2-propynyl butylcarbamate (CAS No) 55406-53-6 (EC no) 259-627-5 (EC index no) 616-212-00-7 <11 Flam. Liq. 2, H225 <0,1 Acute Tox. 3 (Oral), H301 Acute Tox. 3 (Dermal), H311 Skin Corr. 1A, H314 Eye Dam. 1, H318 Skin Sens. 1, H317 STOT SE 3, H335 Aquatic Acute 1, H400 <0,05 Acute Tox. 3 (Inhalation), H331 Acute Tox. 4 (Oral), H302 STOT RE 1, H372 Eye Dam. 1, H318 Skin Sens. 1, H317 Aquatic Acute 1, H400 (M=10) Aquatic Chronic 1, H410 Alkyl polyglycoside (CAS No) 68515-73-1 <0,001 Eye Dam. 1, H318 2-Propenoic acid, methyl ester, reaction products with 2-ethyl- 1-hexanamine and sodium hydroxide (CAS No) 68610-44-6 (EC no) 271-865-1 methanol (CAS No) 67-56-1 (EC no) 200-659-6 (EC index no) 603-001-00-X Full text of R- and H-phrases: see section 16 <0,001 Not classified <0,0001 Flam. Liq. 2, H225 Acute Tox. 3 (Inhalation), H331 Acute Tox. 3 (Dermal), H311 Acute Tox. 3 (Oral), H301 STOT SE 1, H370 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a poison center or a doctor. : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek medical attention if ill effect or irritation develops. : Rinse mouth immediately and drink plenty of water. Do not induce vomiting without medical advice. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Consult a doctor/medical service if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. 5.2. Special hazards arising from the substance or mixture Fire hazard Hazardous decomposition products in case of fire : Intense heat may cause container to burst. : carbon oxides (CO and CO2). 5.3. Advice for firefighters Protective equipment for firefighters Other information : Extra personal protection: complete protective clothing including self-contained breathing apparatus. : Prevent fire-fighting water from entering environment. 20/03/2015 UK(EN) 2/7
SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Refer to protective measures listed in Sections 7 and 8. 6.1.1. For non-emergency personnel 6.1.2. For emergency responders 6.2. Environmental precautions Do not allow to enter into surface water or drains. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections : Clean with detergents. Avoid solvent cleaners. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Material handling requires no special precaution measures. No special fire protection measures are necessary. For further information refer to section 8 : Exposure-controls/personal protection. : Do not eat, drink or smoke when using this product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials Storage area Special rules on packaging 7.3. Specific end use(s) : Store in a dry place. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Ethyl alcohol (64-17-5) : Strong oxidizing agents. Strong acids. : Ensure adequate ventilation of the storage area. : Keep container tightly closed and dry. United Kingdom WEL TWA (mg/m³) 1920 mg/m³ United Kingdom WEL TWA (ppm) 1000 ppm United Kingdom WEL STEL (mg/m³) 5760 mg/m³ (calculated) United Kingdom WEL STEL (ppm) 3000 ppm (calculated) methanol (67-56-1) EU Notes Skin 8.2. Exposure controls Eye protection : Avoid contact with eyes SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Wet wipes with scents or lotion. Colour Odour : characteristic. Odour threshold ph : 7,5-8,5 Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature 20/03/2015 UK(EN) 3/7
Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : soluble in water. 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity None under normal conditions. 10.2. Chemical stability Stable under normal conditions of use. 10.3. Possibility of hazardous reactions None under normal conditions. 10.4. Conditions to avoid Humidity. Heat. Light. 10.5. Incompatible materials Peroxides. Strong oxidizing agents. Carbon steel. Strong bases. 10.6. Hazardous decomposition products Carbon oxides (CO, CO2). SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms ph: 7,5-8,5 ph: 7,5-8,5 : Repeated or prolonged skin contact may cause dermatitis and defatting. SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability 12.3. Bioaccumulative potential 20/03/2015 UK(EN) 4/7
12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not regulated for transport : Dispose as hazardous waste. Consult the appropriate local waste disposal expert about waste disposal. 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information supplementary information available 14.6. Special precautions for user 14.6.1. Overland transport 14.6.2. Transport by sea 14.6.3. Air transport 14.6.4. Inland waterway transport Carriage prohibited (ADN) Not subject to ADN 20/03/2015 UK(EN) 5/7
14.6.5. Rail transport Carriage prohibited (RID) 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations is not on the REACH Candidate List Contains no substance on the REACH candidate list Other information, restriction and prohibition regulations : Regulation (EC) No. 648/2004 on detergents; Regulations (EC) No. 551/2009 and No. 907/2006, amending Regulation (EC) No. 648/2004 on detergents. 15.1.2. National regulations 15.2. Chemical safety assessment SECTION 16: Other information Other information : This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. It is the user's responsibility to take the mentioned precautionary measures and to ensure that this information is complete and sufficient for the use of this product. Full text of R-, H- and EUH-phrases: Acute Tox. 3 (Dermal) Acute toxicity (dermal) Category 3 Acute Tox. 3 (Inhalation) Acute toxicity (inhalation) Category 3 Acute Tox. 3 (Oral) Acute toxicity (oral), Category 3 Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 Aquatic Acute 1 Hazardous to the aquatic environment Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category 1 Eye Dam. 1 Serious eye damage/eye irritation, Category 1 Flam. Liq. 2 Flammable liquids Category 2 Skin Corr. 1A Skin corrosion/irritation Category 1A Skin Sens. 1 Sensitisation Skin, category 1 STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 STOT SE 1 Specific target organ toxicity (single exposure) Category 1 STOT SE 3 Specific target organ toxicity (single exposure) Category 3 H225 Highly flammable liquid and vapour H301 H302 H311 H314 H317 H318 H331 H335 H370 H372 H400 H410 R11 R22 R23 R23/24/25 Toxic if swallowed Harmful if swallowed Toxic in contact with skin Causes severe skin burns and eye damage May cause an allergic skin reaction Causes serious eye damage Toxic if inhaled May cause respiratory irritation Causes damage to organs Causes damage to organs through prolonged or repeated exposure Very toxic to aquatic life Very toxic to aquatic life with long lasting effects Highly flammable Harmful if swallowed Toxic by inhalation Toxic by inhalation, in contact with skin and if swallowed R24/25 Toxic in contact with skin and if swallowed R35 Causes severe burns 20/03/2015 UK(EN) 6/7
R37 R39/23/24/25 R41 R43 Irritating to respiratory system Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed Risk of serious damage to eyes May cause sensitisation by skin contact R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation R50 Very toxic to aquatic organisms C F N T Xi Xn Corrosive Highly flammable Dangerous for the environment Toxic Irritant Harmful SDS EU (REACH Annex II) SCA This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 20/03/2015 UK(EN) 7/7