Material Safety Data Sheet Revision Number: 004.0 Issue date: 07/18/2013 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Loctite(R) 3621 Chipbonder(R) Adhesive Product type: One-part epoxy Item number: 30846 Region: United States Company address: Contact information: Henkel Electronic Materials LLC 14000 Jamboree Road Irvine, CA 92606 Telephone: 1.888.9.HENKEL (1.888.943.6535) MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkel.com/electronics 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Paste HEALTH: *2 Color: Red FLAMMABILITY: 1 Odor: Epoxy PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED OR INHALED. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May be harmful if inhaled. May cause respiratory tract irritation. May cause irritation to nose and throat. Coughing. Sneezing. May cause allergic skin reaction. May cause severe skin irritation. Repeated or prolonged contact can result in drying of skin. Redness. Rash. Mild eye irritation. Blurred vision. Burning sensation. Swelling. Redness. May be harmful if swallowed. Eye, skin and respiratory disorders. Skin allergies. Dermatitis. Eczema. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). See Section 11 for additional toxicological information. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % Phenol polymer with formaldehyde, glycidyl ether 28064-14-4 10-30 Epichlorohydrin-4,4'-isopropylidene diphenol resin 25068-38-6 10-30 Amine adduct Proprietary 10-30 2,3-Epoxypropyl neodecanoate 26761-45-5 10-30 Treated fumed silica 67762-90-7 5-10 Titanium dioxide 13463-67-7 0.1-1 Page 1 of 6
4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. If symptoms develop and persist, get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Give a conscious person several glasses of water. Never give anything by mouth to an unconscious person. If symptoms develop and persist, get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: 200 C (392 F) Closed cup Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. In case of fire, keep containers cool with water spray. Oxides of carbon. Oxides of nitrogen. Acids. Aldehydes. Phenolics. Hydrocarbons. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Ensure adequate ventilation. Wear suitable protective clothing, gloves and eye/face protection. Scrape up spilled material and place in a closed container for disposal. Flush area with water to remove trace residue. 7. HANDLING AND STORAGE Handling: Storage: Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Do not breathe gas/fumes/vapor/spray. Keep container closed. Wash thoroughly after handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. Page 2 of 6
8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER Phenol polymer with formaldehyde, glycidyl ether Epichlorohydrin-4,4'-isopropylidene diphenol resin Amine adduct 2,3-Epoxypropyl neodecanoate Treated fumed silica Titanium dioxide 10 mg/m3 TWA Inhalable dust. 3 mg/m3 TWA Respirable fraction. 10 mg/m3 TWA 15 mg/m3 TWA Total dust. 5 mg/m3 TWA Respirable fraction. 15 mg/m3 TWA Total dust. Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: Red Odor: Epoxy Odor threshold: ph: Vapor pressure: < 1.0 mm hg (20 C (68 F)) Boiling point/range: Melting point/ range: Specific gravity: 0.95 Vapor density: 0.95 Flash point: 200 C (392 F) Closed cup Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: 5.75 %; 54.67 g/l EPA Method 24 Page 3 of 6
10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable at normal conditions. under normal processing. Oxides of carbon. Oxides of nitrogen. Acids. Aldehydes. Phenolics. Hydrocarbons. Can react vigorously with strong oxidizing agents, strong Lewis or mineral acids, and strong mineral and organic bases, especially primary and secondary aliphatic amines. Reacts with considerable heat release with some curing agents. Mercaptans. Alkalis. Store away from incompatible materials. Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Phenol polymer with formaldehyde, glycidyl ether No No No Epichlorohydrin-4,4'-isopropylidene diphenol resin No No No Amine adduct No No No 2,3-Epoxypropyl neodecanoate No No No Treated fumed silica No No No Titanium dioxide No Group 2B No Hazardous components Phenol polymer with formaldehyde, glycidyl ether Epichlorohydrin-4,4'-isopropylidene diphenol resin Amine adduct 2,3-Epoxypropyl neodecanoate Treated fumed silica Titanium dioxide Health Effects/Target Organs Allergen, Irritant Allergen, Irritant No Records Irritant, Allergen Irritant Irritant, Respiratory, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. This product may contain traces of: D005. Barium. However this product is only classifiable as hazardous waste if it exhibits the characteristics of toxicity as shown by the toxicity characteristic leaching procedure (TCLP). Under RCRA, it is the responsibility of the end user of this product to determine whether it meets this criteria at the time of disposal. 14. TRANSPORT INFORMATION The shipping classifications in this sections are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated (Up to 30 ml max per inner/primary package when shipped as originally packaged only) Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Environmentally hazardous substance, liquid, n.o.s. (Epoxy resin) (Up to 30 ml max per inner/primary package when shipped as originally packaged only) Hazard class or division: 9 Identification number: UN 3082 Packing group: III Water Transportation (IMO/IMDG) Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Epoxy resin) (Up to 30 ml max per inner/primary package when shipped as originally packaged only) Hazard class or division: 9 Identification number: UN 3082 Packing group: III Marine pollutant: Epoxy resin United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimis Immediate Health, Delayed Health above reporting de minimis This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. This product contains a chemical known in the State of California to cause cancer. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: Contains one or more components listed on the Non-Domestic Substances List. All other components are listed on or are exempt from listing on the Domestic Substances List. Components listed on the NDSL must be tracked by all Canadian Importers of Record as required by Environment Canada. They may be imported into Canada in limited quantities. Please contact Regulatory Affairs for additional details. D.2.B Page 5 of 6
16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: This Material Safety Data Sheet contains changes from the previous version in Section(s): 1, 3, 13 Prepared by: Timothy Pratt, Regulatory Affairs Specialist DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6