Safety Data Sheet Revision Number: 003.0 Issue date: 01/15/2015 1. PRODUCT AND COMPANY IDENTIFICATION Product name: LOCTITE ABLESTIK 2025D known as Ablebond 2025D (14g) Product type: Adhesive Restriction of Use: identified Region: United States Company address: Contact information: Henkel Electronic Materials LLC 14000 Jamboree Road Irvine, CA 92606 Telephone: +1 (888) 943-6535 MEDICAL EMERGENCY Phone: Poison Control Center 1-877-671-4608 (toll free) or 1-303-592-1711 TRANSPORT EMERGENCY Phone: CHEMTREC 1-800-424-9300 (toll free) or 1-703-527-3887 Internet: www.henkel.com/electronics Contains one or more components for which a Toxic Substances Control Act (TSCA) Low Volume Exemption (LVE) applies. See Section 15. 2. HAZARDS IDENTIFICATION WARNING: EMERGENCY OVERVIEW CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. HAZARD CLASS HAZARD CATEGORY SKIN IRRITATION 2 EYE IRRITATION 2A SKIN SENSITIZATION 1 PICTOGRAM(S) Precautionary Statements Prevention: Response: Storage: Disposal: Avoid breathing vapors, mist, or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear eye and face protection. Wear protective gloves. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. If skin irritation or rash occurs: Get medical attention. If eye irritation persists: Get medical attention. Take off contaminated clothing. Not prescribed Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS). See Section 11 for additional toxicological information. Page 1 of 6
3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Component(s) CAS Number Percentage* Silica, amorphous, treated 68909-20-6 30-60 Bismaleimide monomer Unknown 10-30 Silicon dioxide 7631-86-9 10-30 Acrylate monomer Proprietary 5-10 Epoxy resin Unknown 5-10 Additive Proprietary 5-10 Epoxy resin Proprietary 0.1-1 Subsituted Silane Proprietary 0.1-1 23996-25-0 0.1-1 * Exact percentage is a trade secret. Concentration range is provided to assist users in providing appropriate protections. 4. FIRST AID MEASURES Inhalation: Skin contact: Move to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Remove contaminated clothing and footwear. Immediately flush skin with plenty of water (using soap, if available). If symptoms develop and persist, get medical attention. Wash clothing before reuse. Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention. Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention. Symptoms: See Section 11. 5. FIRE FIGHTING MEASURES Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Use water spray to keep fire exposed containers cool and disperse vapors. Closed containers may rupture (due to build up of pressure) when exposed to extreme heat. Oxides of carbon. Oxides of nitrogen. Toxic and irritating vapors. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Do not allow product to enter sewer or waterways. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up spilled material and place in a closed container for disposal. Page 2 of 6
7. HANDLING AND STORAGE Handling: Storage: Use only with adequate ventilation. Wear suitable protective clothing, gloves and eye/face protection. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. For information on product shelf life, please review labels on container or check the Technical Data Sheet. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER Silica, amorphous, treated 10 mg/m3 TWA Inhalable dust. 6 mg/m3 TWA Bismaleimide monomer Silicon dioxide 6 mg/m3 TWA 20 MPPCF TWA 3 mg/m3 TWA 0.8 mg/m3 TWA Respirable fraction. Acrylate monomer Epoxy resin Additive Epoxy resin Subsituted Silane Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use a NIOSH approved air-purifying respirator if the potential to exceed established exposure limits exists. Safety goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Safety showers and eye wash stations should be available. Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Liquid Color: Red Odor: Slight Odor threshold: ph: Vapor pressure: Boiling point/range: Melting point/ range: Specific gravity: 1.4 Vapor density: Flash point: > 93 C (> 199.4 F) Estimated Flammable/Explosive limits - lower: Flammable/Explosive limits - upper: Autoignition temperature: Evaporation rate: Solubility in water: Insoluble Partition coefficient (n-octanol/water): VOC content: < 1 % Viscosity: Page 3 of 6
Decomposition temperature: 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Reactivity: Conditions to avoid: Stable under recommended storage conditions. under normal processing. Oxides of carbon. Oxides of nitrogen. Irritating organic vapours. Strong oxidizing agents. Strong acids and strong bases. High temperatures. Heat, flames, sparks and other sources of ignition. Store away from incompatible materials. 11. TOXICOLOGICAL INFORMATION Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects/Symptoms Inhalation: Skin contact: Eye contact: Ingestion: May cause respiratory tract irritation. Coughing. Shortness of breath. Causes skin irritation. May cause allergic skin reaction. Causes serious eye irritation. Redness. Tearing. May cause gastrointestinal tract irritation if swallowed. Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects Silica, amorphous, treated No Target Organs Bismaleimide monomer No Data Silicon dioxide Oral LD50 (RAT) = > 22,500 mg/kg Nuisance dust Acrylate monomer Allergen, Irritant Epoxy resin No Data Additive No Records Epoxy resin Allergen, Irritant Subsituted Silane Irritant, Allergen Allergen, Reproductive Hazardous Component(s) NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) Silica, amorphous, treated No No No Bismaleimide monomer No No No Silicon dioxide No No No Acrylate monomer No No No Epoxy resin No No No Additive No No No Epoxy resin No No No Subsituted Silane No No No No No No 12. ECOLOGICAL INFORMATION Ecological information: Page 4 of 6
13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. Not a RCRA hazardous waste. 14. TRANSPORT INFORMATION The transport information provided in this section only applies to the material/formulation itself, and is not specific to any package/configuration. U.S. Department of Transportation Ground (49 CFR) Proper shipping name: Not regulated Hazard class or division: Identification number: Packing group: International Air Transportation (ICAO/IATA) Proper shipping name: Hazard class or division: Identification number: Packing group: Water Transportation (IMO/IMDG) Proper shipping name: Hazard class or division: Identification number: Packing group: Not regulated Not regulated 15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA Section 313: California Proposition 65: All components of this product are listed on the U.S. Toxic Substances Control Act (TSCA) inventory or are exempt from listing because a Low Volume Exemption (LVE) has been granted in accordance with 40 CFR 723.50. above reporting de minimis above reporting de minimis Immediate Health, Delayed Health above reporting de minimis This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. 16. OTHER INFORMATION This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format. Prepared by: Timothy Pratt, Regulatory Affairs Specialist Issue date: 01/15/2015 Page 5 of 6
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation and its affiliates ( Henkel ) does not assume responsibility for any results obtained by persons over whose methods Henkel has no control. It is the user s responsibility to determine the suitability of Henkel s products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any Henkel s products. In light of the foregoing, Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel s products. Henkel further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 6 of 6