Conform to regulations 1907/2006/EC and 1272/2008/EC MSDS AMP 2 MG 23/03/12- Page 1/5 1. PRODUCT AND COMPANY MATERIAL SAFETY DATA SHEET Product : Use Company : AMP 2 MG Biocide insecticid product (PT18) Microgranules based on acetamiprid (MG) Kwizda-France S.A. 30 avenue de l'amiral Lemonnier 78160 Marly-le-Roi Tel. 01.39.16.09.69 Fax 01.39.16.47.07 ah@kwizda-france.com Emergency call Antipoison center of Paris, Tel : +33 (0)1 39 16 09 69 2. HAZARDS IDENTIFICATION Identification symbol and letter EC: Exempted from classification. Main hazards :None Wise precautions : S2 Store out of reach of children. S13 Store away from food and drink, including animal feed. S20/21 Do not eat, do not drink and do no smoke during usage. S22 Do not breathe dust. S46 If swallowed, seek medical advice immediately and show this container or lable. 3. COMPOSITION / INFORMATION ON COMPONENTS hazardous ingredients Name N CAS Concentration Active ingredient(s) Acetamiprid Other components Sulfuric acid mono- C12-14-alkyl esters, sodium salts 160430-64-8 2 g/kg 0,2% (w/w) Classification 67/548/EEC 85586-07-8 < 1% (w/w) Xn, R22, R38, R41 CLP Classification (R1272/2008) Xn, R 20/22-52/53 GHS07, H302, H412 GHS05, GHS07, H318, H400, H302, H312, H335, H315
Conform to regulations 1907/2006/EC and 1272/2008/EC MSDS AMP 2 MG 23/03/12- Page 2/5 4. FIRST AID MEASURES General information: No special measures required. After skin contact: In general the product is not irritant to skin but it is recommended to wash affected skin areas with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. 5. FIRE FIGHTING MEASURES Protective equipment: If necessary wear self-contained respiratory equipment and dependent on dimensions of fire wear fully protective suit. 6. ACCIDENTAL RELEASE MEASURE Person-related safety precautions: Please notice instructions for person-related safety precautions and wear protective equipment (see 8.) Measures for environmental protection: No special measures required. Measures for cleaning/collecting: Pick up mechanically. Send for recovery or disposal in suitable receptacles. 7. HANDLING AND STORAGE Handling: Information for safe handling: While handling pay attention to the usually precaution for chemicals. Comply with instructions for use. Do not eat, drink or smoke at work. Information about fire - and explosion protection: No special measures required. Storage: Requirements to be met by storerooms and receptacles: Store in tightly closed containers in a cool, well ventilated and dry place. Information about storage in one common storage facility: Keep away from food, beverages and animal feeding stuffs. Further information about storage conditions: None.
Conform to regulations 1907/2006/EC and 1272/2008/EC MSDS AMP 2 MG 23/03/12- Page 3/5 8. EXPOSURE CONTROL / PERSONNAL PROTECTION Additional information about design of technical facilities: No further data; see item 7. Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: Based on actual legally binding lists. Personal protective equipment: General protective and hygienic measures: Avoid unnecessary contact with the product. Do not eat, drink or smoke at workplace and keep it tidy. Respiratory protection: Not required. Protection of hands: Not required. Eye protection: Not required. Body protection: Not required. 9. PHYSICAL AND CHEMICAL PROPERTIES General Information Form: Solid Colour: white Odour: Odourless Change in condition Melting point/melting range: No data. Boiling point/boiling range: No data. Flash point: Not applicable. Flammability (solid, gaseous): No information. Self-igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Solubility in/miscibility with water: dispersible ph-value at 20 C: 6,5 8,3 (1 % H20) Density : 900-1100 kg/m 3 Particles size : 63 800 µm 10. STABILITY AND REACTIVITY Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Dangerous reactions No hazardous reactions known if used according to specifications. Dangerous decomposition products: No dangerous decomposition products known. 11. TOXICOLOGICAL INFORMATION Acute toxicity: LD/LC50 values relevant for classification: No data are available for the preparation. All information on acute toxicity is related to the pure active substance(s).
Conform to regulations 1907/2006/EC and 1272/2008/EC MSDS AMP 2 MG 23/03/12- Page 4/5 160430-64-8 Acetamiprid Oral LD50 417 mg/kg (rat (male)) 314 mg/kg (rat (female)) Dermal LD50 >2000 mg/kg (rat) Inhalative LC50/4h 1.15 mg/l (rat) Primary irritant effect: on the skin: No data. on the eye: No data. Sensitization: No data. Additional toxicological information: The product is not subject to classification according to the calculation method of the "Dangerous preparation directive" as issued in the latest version. According to our experiences and all available information provided to us, the product does not have any harmful effects when used and handled according to specifications. 12. ECOLOGICAL INFORMATION Ecotoxical effects: Acquatic toxicity: For the product there are no ecotoxicological data available. All data refer to the active ingredient(s). 160430-64-8 Acetamiprid EC 50/96h >100 mg/l (rainbow trout) EC50/48h 49.8 mg/l (Daphnia magna) IbC50/72h >98.3 mg/l (Scenedesmus subspicatus (Alge)) General notes: Regarding the ecotoxicological profile of the ingredients according to our actual knowledge no detrimental effects on the environment are expected. 13. DISPOSAL CONSIDERATIONS For professionals: Unused product should be disposed of as hazardous waste under the full responsibility of the holder of the waste. The packaging may be disposed of as non-hazardous waste under the responsibility the holder of the waste. Do not empty into drains and waterways. For consummer Dispose of unused product in accordance with the requirements of Regulation municipal waste disposal, such a contribution in waste collection center, recycling Packaging will be outlawed in this case. Do not empty into drains and waterways. Dispose of empty packaging and rinsed according to the requirements of Regulation municipal waste disposal, for example by the chain of collection of household packaging waste if the packaging complies with the guidelines for sorting.
Conform to regulations 1907/2006/EC and 1272/2008/EC MSDS AMP 2 MG 23/03/12- Page 5/5 14. INFORMATIONS RELATIVES AU TRANSPORT RID/ADR Not regulated MARITIME Not regulated AIR Not regulated 15. INFORMATIONS REGLEMENTAIRES This formulation is beyond the scope of Regulation (EC) No 2037/2000 of European Parliament and the Council of 29 June 2000 on substances that deplete the ozone layer. This formulation is beyond the scope of Regulation (EC) No 850/2004 of the European Parliament and the Council of 29 April 2004 on persistent organic pollutants and amending Directive 79/117/EEC. This formulation is beyond the scope of Regulation (EC) No 689/2008 of the European Parliament and the Council of 17 June 2008 concerning the export and import of dangerous chemicals. This formulation is not subject to special provisions for the protection of human health or the environment at Community level. 16. OTHER INFORMATIONS Risk phrases of paragraph 3 : (Do not linked to the product itself) R20/22 Harmful by inhalation and if swallowed. R38 Irritating to skin. R41 Risk of serious damage to eyes. R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. H302 H312 H315 H318 H335 H400 H412 Harmful if swallowed. Harmful in contact with skin Causes skin irritation Causes serious eye damage May cause respiratory irritation Very toxic to aquatic life Harmful to aquatic life with long lasting effects. Updates: This document differs from the previous version in the following areas: -Section 2; Hazards Identification; -Section 3, adding CLP classification of Acetamiprid and Sulfuric acid mono-; -Section 4, Ingestion; skin contact -Section 11, Repeated or prolonged Exposure, -Section 13, disposal considerations, -Section 15 : according the regulation 453/2010, -Section 16, risk phrases have been updated. Also refer to technical instructions for use. The information given in this data sheet has been introduced in accordance with the guidelines established by article 10 of EEC directive, dated march 5,1991. This data sheet complements the user s instructions, but does not replace them. The information it contains is based on the knowledge availlable about the product concerned at the time it was compiled. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The required information complies with current EEC legislation. Addressees are requested to apply any additional national requirements.