Revision Date: 07/26/2011 Issuing Date: 07/26/2011 SAFETY DATA SHEET (1907/2006) PLASDONE K-90 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Identification of the substance or preparation Product Code: Product Name: PLASDONE K-90 Formula: Company/Undertaking Identification: (C6H9NO)x ISP CHEMICALS LLC, Rt. 95 Industrial Area, 455 N. Main Street, Calvert City, Kentucky 42029 Distributed By: ISP (Great Britain) Co. Ltd. Waterfield, Tadworth Surrey KT20 5HQ, United Kingdom Tel: +44 1737 377 000 E-mail Address: Emergency Telephone: INCI Name(s): Prepared By: Product Use Description: EU Classification: MSDS@ISPCORP.COM +32.3.575.55.55 (SGS) PVP Product Stewardship Oral Care 2. HAZARDS IDENTIFICATION This preparation is not classified as dangerous according to European Union Legislation Hazard Summary Target Organs: Primary Routes of Entry: Acute Health Hazard: Chronic Health Hazard: Symptoms of Overexposure Eye Contact: Skin contact: Ingestion: Inhalation: Respiratory System Eyes. Skin. Ingestion. Inhalation. May cause respiratory tract irritation. None known Not hazardous Not hazardous Not hazardous May cause respiratory tract irritation. Page 1 of 6
3. COMPOSITION/INFORMATION ON INGREDIENTS Components: Weight % Directive 67/548/EECREACH Classification 2-Pyrrolidinone, 1-ethenyl-, homopolymer 9003-39-8 ECC Number 2006/1907/EC 95 NA N/A NA Eye Contact: Skin Contact: Ingestion: Inhalation: Suitable Extinguishing Media: Combustion/Explosion Hazards: 4. FIRST AID MEASURES Flush with plenty of water. Wash off with soap and water. Do not induce vomiting. If conscious, give 2 glasses of water. Get immediate medical attention. If inhaled, remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Get medical attention. 5. FIRE-FIGHTING MEASURES Use extinguishing measures that are appropriate to local circumstances and the surrounding environment May form explosive dust-air mixture. This product has a value less than Pittsburgh coal dust Special Protective Equipment For Wear self-contained breathing apparatus and protective suit. Fire-Fighters: Personal Precautions: Environmental Precautions: Methods for Cleaning Up: Handling: 6. ACCIDENTAL RELEASE MEASURES Wear suitable protective equipment. None known. Clean up promptly by scoop or vacuum. Avoid dust formation. Avoid dust accumulation in enclosed space. 7. HANDLING AND STORAGE Avoid dust formation. Avoid dust accumulation in enclosed space. Avoid breathing dust. Wash thoroughly after handling. Storage: Keep container tightly closed. Keep in a dry, cool place. Keep away from direct sunlight. Page 2 of 6
Engineering Measures: Respiratory Protection: Hand Protection: Eye Protection: Environmental Controls: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Use only in well-ventilated areas. Use with adequate ventilation. In case of insufficient ventilation wear suitable respiratory equipment Wear protective gloves. Safety glasses.. Components: 2-Pyrrolidinone, 1-ethenyl-, homopolymer 9003-39-8 (95) German Exposure Limits (MAK): UK Workplace Exposure Limits (WELs): Belgium - Italy - France - Not Determined Not Determined Not Determined Respirable dust Physical State: Color: ph: Boiling Point ( F): Melting/Freezing Point ( F): Vapor Pressure: Solubility: Chemical Stability: Conditions to Avoid: Materials to Avoid: Hazardous decomposition products: Belgium - 3mg/m³ (respirable particles) 10mg/m³ (inhalable particles) 9. PHYSICAL AND CHEMICAL PROPERTIES Powder White/creamy white 4.0-7.0 (5% solution) Highly soluble in water 10. STABILITY AND REACTIVITY Stable under normal conditions. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid dust formation. Avoid dust accumulation in enclosed space. Strong oxidizing agents Strong reducing agents nitrogen oxides (NOx) Page 3 of 6
Toxicity Test: Acute Oral Toxicity (LD50): Acute Dermal Toxicity (LD50): Eye Irritation: Skin Irritation: Sensitization: Mutagenicity: Reproductive/Developmental Toxicity: Carcinogenicity: 11. TOXICOLOGICAL INFORMATION >10000 mg/kg (Rat) Not Determined No eye irritation (rabbit) No skin irritation Patch test on human volunteers did not demonstrate sensitization properties Negative: In vitro gene mutation study in bacteria Negative: Chromosome aberration test in vitro Negative: In vitro gene mutation study in mammalian cells Animal testing did not show any effects on fetal development Animal testing did not show any effects on fertility Exposure of dogs and various rodent species to PVP via the diet, injection and implant at up to 10% produced no signs of carcinogenic activity. Exposure up to 10% in the diets of rats and dogs produced no signs of toxicity or carcinogenic potential. No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. Other Information: Sub-Chronic Oral Toxicity: Exposure up to 10% in the diets of rats produced no signs of toxicity. Exposure up to 10% in the diet of dogs produced no signs of toxicity. Persistence and Degradability: Ecotoxicity: Bioaccumulative Potential: Mobility: Waste Disposal Methods: 12. ECOLOGICAL INFORMATION Not readily biodegradable ( 11% after 28 days) Juvenile Turbot: 96-hr. LC50 >1,000 mg/l (PVP) Corophium Volutator; 10-Day LC50 >1,000 mg/l (PVP) Marine Algae; 72-hr. EC50 >1,000 mg/l (PVP) Salmon; PVP at up to 5% in the diet during smolt produced no signs of toxicity. Salmon; PVP at up to 5% in the diet for 112 days did not produce any signs of toxicity. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations. Page 4 of 6
Land Transport: DOT (Non-Bulk): DOT (Bulk): Air Transport (IATA): Sea Transport (IMO): ADR: Tunnel restriction code: Classification: 14. TRANSPORT INFORMATION Not regulated DOT Not regulated IATA Not regulated IMDG Not regulated ADR None 15. REGULATORY INFORMATION This substance is not classified as dangerous according to European Union legislation TSCA DSL NDSL ENCS AICS EINECS ELINCS NZIoC KECI PICCS IECSC Inventories Status Not Not California Proposition 65 Carcinogens & Reproductive Toxicity (CRT) List: This product does not contain any chemicals known to State of California to cause cancer, birth, or any other reproductive defects. Germany VCI Assigned Classification into Water Endangering Classes (WGK) List: Components: 2-Pyrrolidinone, 1-ethenyl-, homopolymer 9003-39-8 Germany VCI Assigned Classification into Water Endangering Classes (WGK) List: Annex 3: 2082 Page 5 of 6
Prepared By: 16. OTHER INFORMATION Product Stewardship Revision Date: 07/26/2011 MSDS sections updated: This data sheet contains changes from the previous version in section(s) 2,4,8,11,14 Legend: Disclaimer: N.Av.= Not Available; N.A.= Not Applicable For purposes of this MSDS, International Specialty Products, as responsible party, provides the information herein which is intended for use by persons who have or should obtain professional knowledge and experience in the subjects discussed. ISP s industrial products are used as materials in the production of products by industrial customers. ISP usually has only limited information about the products of its customers and their composition, methods of manufacture and use. Accordingly, ISP MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY, COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF, ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers independently test and evaluate its products and their products and processes in which ISP products are used in order to decide their safety and effectiveness. ***End of Safety Data Sheet*** Page 6 of 6