MATERIAL SAFETY DATA SHEET M1200C MSDS No.: G1617 Effective Date: 12/01/2007 (month/day/year) Revision: LN11 16 NA ENG Trade Name : M1200C Chemical Name : Adhesives, Elastomer Synonyms : Adhesion Primer CAS Number : Not Applicable - Mixture Company Identification : Veyance Technologies Canada, Inc. 450 Kipling Ave., Toronto, ON M8Z 5E1 Veyance Technologies, Inc. Fairlawn, Ohio 44333 U.S.A. Emergency Phone numbers : Veyance / 24 hour Assistance 330-212-9703 Chemical Transportation Emergency Assistance Chemtrec (USA) 800-424-9300 Canutec (Canada) 613-996-6666 MSDS Information : Technical Assistance 330-664-7243 ISSUED BY - Global Chemical Material Management - Fairlawn, Ohio 44333 2. COMPOSITION / INFORMATION on the COMPONENTS G1617 LN11 NE - Not Established NA - Not Applicable Hazardous Components Percentage by wt. CAS No. ACGIH* OSHA* (TLV-TWA) (PEL-TWA) Xylene 40-70 1330-20-7 100 ppm 100 ppm Ethylbenzene 10-30 100-41-4 100 ppm 100 ppm 125 ppm STEL Diphenyl methane diisocyanate 0.1-1 26447-40-5 0.005 ppm 0.02 ppm C 4,4-Diphenylmethane diisocyanate (MDI) 1-5 101-68-8 0.005 ppm 0.02 ppm C Higher oligomers of MDI (Aromatic polyisocyanates) 1-5 9016-87-9 NE NE Emergency Overview Flammable! Will burn. Ground all items where used. Keep away from heat, sparks, open flames, electric motors, smoking, heaters, sources of static electricity or other ignition sources. Do not weld, cut, grind or drill on or near containers. Vapors can ignite explosively. Irritating to the eyes and skin. May cause allergic respiratory reaction. May cause allergic skin reaction. Breathing of vapors can cause respiratory tract irritation. High vapor exposure can cause central nervous system effects. APPEARANCE : Black liquid
ODOR : Solvent Potential Health Effects --- PRIMARY ROUTES OF ENTRY --Dermal Contact - Inhalation --- SHORT-TERM EXPOSURE --Breathing of vapors (above the exposure limit) can cause nasal and respiratory tract irritation. Central nervous system (CNS) effects, such as, dizziness, nausea, headache, weakness, confusion, and possible unconsciousness may also occur. Repeated and prolonged skin contact can cause irritation and/or dermatitis to occur. Contact with eyes causes irritation. If swallowed, gastrointestinal irritation, vomiting, and diarrhea can occur; CNS effects may also develop. Aspiration of liquid material into the lungs can cause chemical pneumonitis (lung damage).. Inhalation of MDI vapors at concentrations above 0.005 ppm can produce irritation of the mucous membranes in the respiratory tract, runny nose, sore throat, productive cough, and a reduction in lung function. Exposure well above the TLV may lead to bronchitis, bronchial spasm and pulmonary edema (fluid in the lungs). Chemical or hypersensitive pneumonitis, with flu-like symptoms (e.g. fever, chills) has also been reported. Polymeric MDI can cause skin irritation and discoloration. May cause eye irritation. --- LONG-TERM EXPOSURE --Overexposure to xylene over an extended period of time may cause central nervous system depression, and possible liver and kidney effects. Severe overexposure may cause heart abnormalities. Repeated vapor exposure can cause reversible damage to the cornea of the eyes. Animal studies have found that xylene causes liver, kidney, spleen and lung damage and can affect the heart. Several animal studies have indicated embryo/fetotoxic effects for rodents exposed to xylene at doses toxic to the pregnant females. Other studies in rats indicate evidence of developmental toxicity in offspring with no signs of maternal toxicity.. As a result of previous repeated exposures or a single large dose, certain individuals develop isocyanate sensitization (chemical asthma) which will cause them to react to later exposures to isocyanate at levels well below the TLV. Symptoms can include chest tightness, wheezing, cough, shortness of breath, or asthma attack, all of which can occur immediately and/or several hours after exposure. There are some studies that show that overexposure to isocyanates causes lung damage (including decrease in lung function) which may be permanent. Repeated skin contact with MDI has also caused skin sensitization in humans.. Animal studies in which pregnant rats were exposed to 600/1000 ppm ethylbenzene, resulted in toxic effects in the offspring, including defects in skeleton formation. These effects were seen at levels slightly toxic to pregnant females. --- EYE CONTACT --Flush thoroughly and continuously with copious amounts of water. Seek immediate medical attention after flushing. --- SKIN CONTACT --SKIN: Remove contaminated clothing. Wash skin thoroughly with soap and water. If irritation persists, seek medical attention. --- INHALATION --Inhalation - Remove to fresh air. If breathing is difficult give oxygen. If not breathing, give artificial respiration. Get medical attention. --- INGESTION --INGESTION - Do not induce vomiting. Get immediate medical attention. --- FLASH POINT and METHOD --77F (25C) Setaflash Closed Cup --- FLAMMABLE LIMITS --LEL : 1.1% (Xylene) UEL : 7.0% (Xylene) --- EXTINGUISHING MEDIA --CO2, dry chemical, foam Water fog --- SPECIAL FIRE-FIGHTING PROCEDURES --Do not enter confined fire space without helmet with face shield, bunker coat, gloves, rubber boots, and a positive-pressure, approved, self-contained breathing apparatus. --- UNUSUAL FIRE AND EXPLOSION HAZARD --Flammable! Vapors can ignite explosively. Do not use a direct stream of water. Solvent will float and can be reignited on the surface of water. Vapors concentrated in a confined, poorly ventilated area can be ignited upon contact with a spark, flame, or high intensity heat. Containers exposed to intense heat may rupture due to vapor pressure buildup. Vapors are heavier than air and may travel a considerable distance to a source of ignition and flash back. Thermal decomposition will produce: Oxides of carbon Oxides of nitrogen Hydrogen cyanide Health Fire Reactivity Specific NFPA Rating 231 Hazard Rating: 0=Insignificant, 1=Slight, 2=Moderate, 3=High, 4=Extreme ---AFTER SPILLAGE/LEAKAGE --- (methods for cleaning up) Wear personal protective equipment. Eliminate all ignition sources and provide ventilation. Dike area to contain spill. Prevent spill from entering sanitary sewers and waterways.
Ground and bond equipment. Absorb with sand, earth, or other noncombustible absorbent material. --- PRECAUTIONS --Use with adequate ventilation. Keep vapors away from heat, sparks, open flame and other sources of ignition in all containers, vessels and associated piping. Vapors may spread long distances and ignite explosively. Ground and bond all transfer and storage equipment: use non-sparking tools and equipment. Do not reuse container. Emptied containers may be hazardous due to residual product. --- HANDLING --Avoid eye contact. Avoid inhalation Avoid skin contact. --- SKIN PROTECTION --Wear appropriate clothing to prevent contact with the skin. Remove contaminated clothing and launder before wearing again. --- VENTILATION PROTECTION --There should be enough fresh air flowing past the user to maintain exposure levels below those listed. Solvent vapors are heavier than air and collect in lower levels of the work area. Sufficient ventilation should be provided to prevent flammable vapor/air mixtures from accumulating. --- RESPIRATION PROTECTION --If exposure levels exceed those listed, approved respiratory protection should be used. --- EYE PROTECTION --Safety glasses with side shields or Chemical splash goggles --- PROTECTIVE GLOVES --Milled nitrile Neoprene or Rubber gloves if contact is expected --- OTHER PROTECTION --Employees who have prolonged contact with this material should practice good personal hygiene by frequent washing of hands and arms with soap and water. APPEARANCE : Black liquid ODOR : Solvent DENSITY : 7.81 lbs/gal SOLUBILITY IN WATER : Insoluble MELT POINT : Not Applicable --- FLASH POINT and METHOD --- 77F (25C) Setaflash Closed Cup SPECIFIC GRAVITY : 0.94 VAPOR DENSITY : >1 % VOLATILE BY VOLUME : 82.5% INITIAL BOILING POINT : 277-282F (136-139C) VAPOR PRESSURE : Not established --- MATERIALS TO AVOID --Acids Amines Water Hydroxyl or active hydrogen compounds. --- CONDITIONS TO AVOID --High temperature, sources of ignition. --- HAZARDOUS DECOMPOSITION PRODUCTS --Hydrogen cyanide Oxides of nitrogen Monomeric isocyanate Carbon monoxide Carbon dioxide --- SPECIAL SENSITIVITY -- None
ORAL LD50 :Species-mouse 2.2g/kg :(4-4-diphenylmethane diisocyanate). :Species-rat 6700ppm :(xylene). :(ethylbenzene). DERMAL LD50 :Species-rabbit >10g/kg :(4-4-diphenylmethane diisocyanate). :Species-rabbit >1.7g/kg :(xylene). :(ethylbenzene). INHALATION LC50 :Species-rat 369-490mg/m3 (aerosol - 4 hour) :(4-4-diphenylmethane diisocyanate). :Species-rat 6700ppm (4 hour) :(xylene). :(ethylbenzene). --- OTHER --This product has not been tested for ecological (physical and/or biological) hazards or the data is not available or not known. --- DISPOSAL --Treat in accordance with applicable environmental control regulations. Recycle if possible. United States --- BASIC DESCRIPTION --Adhesive, 3, UN1133, III --- FREIGHT DESCRIPTION --Adhesive, NOI. NMFC 4620 Sub5 PRIMARY HAZARD CLASS : 3 SUBSIDIARY HAZARD CLASS : NA LABELS REQUIRED : Flammable Liquid --- REPORTABLE QUANTITY --- Xylene = 100 lbs --- ADDITIONAL SHIPPING INFORMATION --This product is regulated as a hazardous substance when shipped in individual packages that contain reportable quantities of material. STCC Number: UN No: Packing Group: 4910411AB UN1133 III The components of this mixture are included in the US EPA Toxic Substance Control Act(TSCA) "Chemical Substances Inventory" and the Canadian "Domestic Substances List". This material is considered hazardous under the OSHA Hazard Communication Standard CFR Title 29, Part 1910.1200 and the WHMIS Canadian legislation. --- WHMIS CLASSIFICATION --Class B, Division 2 Class D, Division 2, Subdivision A Class D, Division 2, Subdivision B Class D, Division 1, Subdivision A --- SARA 311/312 CLASSIFICATION --Delayed (chronic) Fire Immediate (acute) --- OTHER LOCAL, STATE & FEDERAL -- CAS No. & CHEMICAL 1330-20-7: Xylene SARA S- 313 Toxic Chemical(s)
100-41-4: Ethylbenzene SARA S-313 Toxic Chemical(s) 101-68-8: 4,4-Diphenylmethane diisocyanate (MDI) SARA S-313 Toxic Chemical(s) 9016-87-9: Higher oligomers of MDI (Aromatic polyisocyanates) SARA S-313 Toxic Chemical(s) Veyance Technologies, Inc. provides the information herein to comply with applicable law. The data and information is provided without any warranty, express or implied. It is the responsibility of the user to determine safe conditions for use of this product. --- END of DOCUMENT --