Pre-Feasibility Report M/s. Shri Hari Chemicals - 0 -
1. INTRODUCTION M/s. Shree Hari Chemicals is a working unit situated at Plot 78/5, Phase-I, GIDC Vatva, Ahmedabad, manufacturing Pharma intermediates. Unit has now proposed expansion of existing products as well as manufacturing of other Products. After expansion Production capacity will be 82. The proposed expansion will be carried out within the same premises. The unit is promoted by Mr. Prahladbhai Patel. 2. COST OF PROJECT Existing cost of project is Rs. 4 crores. Cost for proposed expansion will be Rs. 2 crore. Out of which 0.4 Crore will be used for EMS. 3. LAND REQUIREMENT The unit is already developed at Plot 78/5, Phase-I, GIDC Vatva, Ahmedabad, consists of a total area of 800 m 2. 4. PRODUCTION CAPACITY No Production capacity is prescribe below: List of Products Name of Products CAS Number Quantity (MT/month) Existing Proposed Total 1. Para Nitro Benzoic 62-12-7 4.00 38.00 42.00 2. Meta Nitro Benzoic 121-92-6 0.0 3. Para chloro benzoic 74-11-3 4. 2 chloro 4 nitro benzoic 5. 2,4 - Di chloro benzoic 99-60-5 50-84-0 6. Ortho Chloro Benzoic 118-91-2 Acid 7. Para amino Benzoic 150-13-0 0.0 24.0 24.0 8. Meta amino Benzoic 99-05-8 9. 3,5 - Diamino benzoic 535-87-5 10. 3- amino 4 - chloro benzoic 11. Para amino benzoic Methyl Ester 2840-28-0 12. Para amino benzoic 94-09-7 619-45-4 0.0 8.0 8.0 M/s. Shri Hari Chemicals - 1 -
Ethyl Ester 13. Para nitro benzoic Methyl Ester 14. Para nitro benzoic Ethyl Ester 15. Sodium salt of 4 Amino benzoic 16. Potassium salt of 4 Amino benzoic 17. Sodium salt of 4 nitro benzoic 18. Potassium salt of 4 nitro benzoic 19. Ammonium salt of 4 Nitro benzoic 619-50-1 99-77-4 555-06-6 0.0 8.0 8.0 138-84-1 3847-57-2 15922-01-7 19416-70-7 Total: 4.0 78.0 82.0 5. LIST OF RAW MATERIALS Name of Products Name of Raw Materials Quantity MT/MT 1. Para Nitro Benzoic Nitric Acid 1.80 Pera Nitro Toluene 1.00 2. Meta Nitro Benzoic Nitric Acid 1.70 Meta Nitro Toluene 1.00 3. Para chloro benzoic Nitric Acid 1.60 Pera Chloro Toluene 1.00 4. 2 chloro 4 nitro benzoic 2 - Chloro - 4 - Nitro Toluene 0.90 Nitric Acid 1.50 5. 2,4 - Di chloro benzoic 2,4 - Di Chloro Toluene 1.00 Nitric Acid 1.10 6. Ortho Chloro Benzoic Acid Nitric Acid 1.30 Ortho Chloro Toluene 0.90 7. Para amino Benzoic PNBA 1.40 Iron Powder 2.34 Acetic Acid 0.04 Sodium Hydroxide 0.23 HCl 0.53 8. MNBA 1.40 Iron Powder 2.34 Meta amino Benzoic Acetic Acid 0.04 Sodium Hydroxide 0.23 HCl 0.53 9. 3,5 - Diamino benzoic 3,5 Di Nitro benzoic 1.53 M/s. Shri Hari Chemicals - 2 -
Name of Products Name of Raw Materials Quantity MT/MT Catalyst 0.01 Hydrogen 0.06 Sulphuric 0.37 Nitrogen 0.02 10. 3- amino 4 - chloro benzoic 3 Nitro 4 Chlro benzoic 1.22 Catalyst 0.01 Hydrogen 0.03 Sulphuric 0.37 Nitrogen 0.02 11. Para amino benzoic Methyl Para Amino benzoic Ester 0.90 Methanol 0.12 Sulphuric 0.38 12. Para amino benzoic Ethyl Para Amino benzoic Ester 0.90 Ethanol 0.13 Sulphuric 0.38 13. Para nitro benzoic Methyl Ester Para Nitro benzoic 0.90 Methanol 0.12 Sulphuric 0.38 14. Para nitro benzoic Ethyl Ester Para Nitro benzoic 0.90 Ethanol 0.13 Sulphuric 0.36 15. Sodium salt of 4 Amino benzoic Para Amino benzoic 0.80 Salt 0.42 Sodium Hydroxide 0.14 16. Potassium salt of 4 Amino benzoic Para Amino benzoic 0.80 Salt 0.31 Potassium Hydroxide 0.24 17. Sodium salt of 4 nitro benzoic 18. Potassium salt of 4 nitro benzoic 19. Ammonium salt of 4 Nitro benzoic Para Nitro benzoic 0.80 Salt 0.32 Sodium Hydroxide 0.24 Para Nitro benzoic 0.80 Salt 0.28 Potassium Hydroxide 0.14 Para Amino benzoic 0.80 Salt 0.52 Ammonium Hydroxide 0.24 M/s. Shri Hari Chemicals - 3 -
MANUFACTURING PROCESS Pl. refers Annexure-II of Form 1 for process description, chemical reaction & mass balance of all products. 5. Details of manpower Present 14 nos. of skilled and unskilled persons are employed by the unit. After expansion, total manpower requirement at all level of plant will be increase up to 28. 6. Water Consumption & Waste Water Generation Source Water Consumption Water Consumption Existing (KL/day) Water Consumption After expansion (KL/day) 1. Domestic 0.6 2.0 2. Green Belt -- 1.0 3. Industrial A Water treatment 0.0 0.5 B Process 3.0 8.0 C Scrubber 1.0 5.5 D Boiler 0.0 3.0 Washing 2.0 5.0 Total Industrial 6.0 22.0 TOTAL (1 +2 + 3) 6.6 25.0 Recycle water -- 5.8 Fresh water requirements 6.6 19.2 M/s. Shri Hari Chemicals - 4 -
Source Wastewater Generation W/w Generation Existing (KL/day) W/w Generation After expansion (KL/day) 1. Domestic 0.5 1.6 2. Industrial A Water treatment 0.0 0.5 B Process 1.9 4.5 C Scrubber 0.1 0.3 D Boiler 0.0 0.5 E Washing 3.0 5.0 7. Source of Pollution Total Industrial 5.0 10.8 TOTAL (1 +2) 5.5 12.4 Details of Air Pollution The main source of emission will be of flue gas emission. Proper Stack height and APC measure will be provided in order to achieve norms prescribed by statutory authority. At present the main source of gaseous emission is flue gas due to combustion of Diesel for boiler & Thermic Fluid heater. The flue gas emission contains SPM, SO 2 and NO x as air pollutants. The process gas stack is attached to SO 2 scrubber having stack height of 15 m. The process gas emission contains SO 2 as air pollutants. After expansion, additional source will be one stack for additional boiler, where agro briquettes will be used as a fuel and other one is for process vent. Two stage ic and one stage alkaline Scrubber systems will be provided to recover Sodium Nitrite (25%) and meeting the emission norms laid down by GPCB. The details of stacks are given below: M/s. Shri Hari Chemicals - 5 -
Stack attached to Existing Flue Gas Stacks 1. Thermo Pack Boiler ( 5 Lakhs Kcal/h) Process Gas Stacks Fuel Type Diesel (80 Lt/h) Stack Height, in m APC measures Probable emission 11 ---- PM:150 mg /Nm 3 SO2:100 PPM NO x :50 PPM 1. Reactor Vessel ---- 18 Three Stage Alkali Rubber Proposed addition after expansion NO x: 25 mg /Nm 3 Flue Gas Stacks 1 Boiler(500 Kg/H) Process Gas Stacks Agro Briquettes (1.5 Mt/Day) 21 Cyclone & Bag filter PM:150 mg /Nm 3 SO2:100 PPM NO x :50 PPM 1. Reactor Vessel ----- 18 Two stage ic and one stage alkaline Scrubber NO x: 25 mg /Nm 3 Source of wastewater Greater quantity of wastewater generation due to use Water retain with products. Out of total wastewater generation, 5 KLD water will be primary treated in premises and then it will be sent for final treatment and final disposal to CETP-GESCSL, Vatva. And 5.8 KLD RO permeate will be reused in plant activity. Domestic wastewater will be disposed through soak pit. Source and disposal of Hazardous wastes There will be six types of hazardous waste generation i.e. ETP sludge, used oil, Iron sludge, discarded containers/liners, Distillation Residue, Spent Catalyst, and sodium nitrite from scrubber. ETP sludge will be disposed off at TSDF site, used oil will be disposed by selling to authorized recycler and discarded containers/liners will be disposed by selling to registered recyclers. Iron Sludge will be sell to cement manufacturer. Distillation Residue will be disposed at CHWIF or co- M/s. Shri Hari Chemicals - 6 -
processing. Spent Catalyst will be return back to supplier for regeneration. Sodium nitrite will be sell to the actual user. Detail of hazardous waste is given below: Type of Waste 1. ETP Waste 2. Iron Sludge 2. Discarded Containers / Liners Category as per HWM rules, 2016 35.3 12 28.1 0 33.1 30 Nos./year Quantity Existing Proposed Total 50 kg/month 3. Used Oil 5.1 10 liter/year 4. Distillation Residue 5. Spent Catalyst 6. Sodium Nitrite (25%) (From Scrubber) 8 90 470 Nos./year 450 kg/month 30 liter/year 20.3 -- 0.15 Mt/Month 28.2-0.800 Mt/Year --- -- 30 Mt/ Month 20 90 500 Nos./year 500 kg/month 40 liter/year 0.15 Mt/Month 0.800 Mt/Year 30 Mt/ Month Method of Disposal Disposal at TSDF approved by board. sell to cement manufacturer. Disposal by selling to authorized recycler. Disposal by selling to authorized recycler. storage & disposal at CHWIF or coprocessing. storage & return back to supplier for regeneration. sell to actual user. M/s. Shri Hari Chemicals - 7 -
FUNDS FOR POLLUTION CONTROL MEASURES The management is quite conscious of its responsibility for maintaining clear environment adequate funds can be provided for the pollution control measures as financing part of overall project. Necessary provision for Environmental management system is in practice. 8. MONITORING FACILITIES Air sampling will be done by outside agency and will be part of practice in future expansion projects. 9. CONCLUSION On the basis of information presented in the pre-feasibility report on pollution control measures and after its implementation, there will be no discharge of effluent and air emission from the plant beyond the norms specified by the Board as per the provisions of Air (Prevention and Control of Pollution) Act, 1981 and Water (Prevention and Control of Pollution) M/s. Shri Hari Chemicals - 8 -