Date of issue: 12/03/2014 Revision date: 02/06/2015 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name : Mixture : 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Bisco, Inc. 1100 W. Irving Park Rd. Schaumburg, IL 60193 T 847.534.6000 - F 847.891.5049 sales@bisco.com - www.bisco.com 1.4. Emergency telephone number : For professional use only. Emergency number : 1-703-527-3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2A H319 Resp. Sens. 1 H334 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : Irritant ; Sensitizer GHS08 : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation : P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P403+P235 - Store in a well-ventilated place. Keep cool P264 - Wash hands thoroughly after handling P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P501 - Dispose in a safe manner in accordance with local/national regulations. 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture 02/06/2015 EN (English US) Page 1
Name Product identifier % Classification (GHS-US) Glass filler (CAS No) 65997-18-4 50-75 Skin Irrit. 2, H315 Eye Irrit. 2B, H320 Resp. Sens. 1, H334 Fused Silica (CAS No) 60675-86-0 10-30 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Resp. Sens. 1, H334 STOT SE 3, H335 bisphenol A glycidylmethacrylate (CAS No) 1565-94-2 5-10 Eye Dam. 1, H318 Skin Sens. 1, H317 Urethane Dimethacrylate (CAS No) 72869-86-4 5-10 Skin Irrit. 2, H315 Resp. Sens. 1, H334 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). If skin irritation or rash occurs: : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. : Causes skin irritation. : Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 02/06/2015 EN (English US) 2/7
6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eat, drink or smoke and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Avoid breathing mist, vapors. Use only outdoors or in a well-ventilated area. : Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container tightly closed. Incompatible products : Strong bases. strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters bisphenol A glycidylmethacrylate (1565-94-2) 8.2. Exposure controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : Wear suitable protective clothing. : In case of inadequate ventilation wear respiratory protection. : When using, do not eat, drink or smoke. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Paste. Color : tooth 02/06/2015 EN (English US) 3/7
Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point : acrylic Flash point : > 38 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LD50 oral rat LD50 dermal rat LD50 dermal rabbit 02/06/2015 EN (English US) 4/7
LC50 inhalation rat (ppm) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity : Causes skin irritation. : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. IARC group IARC group 4 - Probably Not Carcinogenic 4 - Probably Not Carcinogenic IARC group 4 - Probably Not Carcinogenic Reproductive toxicity Specific target organ toxicity (single exposure) : May cause respiratory irritation. LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEL (inhalation,rat,gas) LOAEL (inhalation,rat,vapour ) LOAEL (inhalation,rat,dust/mist/fume) LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEL (inhalation,rat,gas) LOAEL (inhalation,rat,vapour ) LOAEL (inhalation,rat,dust/mist/fume) mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h LOAEL (oral,rat) LOAEL (dermal,rat/rabbit) LOAEL (inhalation,rat,gas) LOAEL (inhalation,rat,vapour ) LOAEL (inhalation,rat,dust/mist/fume) Specific target organ toxicity (repeated exposure) mg/kg body weight mg/kg body weight ppmv/4h mg/l/4h mg/l/4h LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) LOAEL (inhalation,rat,dust/mist/fume,90 days) LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day 02/06/2015 EN (English US) 5/7
LOAEL (inhalation,rat,dust/mist/fume,90 days) mg/l/6h/day LOAEL (oral,rat,90 days) LOAEL (dermal,rat/rabbit,90 days) LOAEL (inhalation,rat,gas,90 days) LOAEL (inhalation,rat,vapour,90 days) LOAEL (inhalation,rat,dust/mist/fume,90 days) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information 12.1. Toxicity mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day : Based on available data, the classification criteria are not met. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. : Causes skin irritation. : Causes serious eye irritation. 12.2. Persistence and degradability Persistence and degradability bisphenol A glycidylmethacrylate (1565-94-2) Persistence and degradability Biodegradability in water: no data available. 12.3. Bioaccumulative potential Bioaccumulative potential bisphenol A glycidylmethacrylate (1565-94-2) Log Pow Bioaccumulative potential 4.94 (Estimated value) No bioaccumulation data available. 12.4. Mobility in soil 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. 02/06/2015 EN (English US) 6/7
ADR Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 H315 Eye Dam. 1 H318 Resp. Sens. 1 H334 Skin Sens. 1 H317 STOT SE 3 H335 Full text of H-phrases: see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations 15.3. US State regulations SECTION 16: Revision date : 02/06/2015 : None. Full text of H-phrases: ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Eye Irrit. 2B Serious eye damage/eye irritation Category 2B ------ Resp. Sens. 1 Respiratory sensitisation Category 1 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ Skin Sens. 1 Skin sensitization Category 1 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H315 Causes skin irritation ------ H317 May cause an allergic skin reaction ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H320 Causes eye irritation ------ H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled ------ H335 May cause respiratory irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 02/06/2015 EN (English US) 7/7