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Transcription:

I. PRODUCT AD COMPAY IDETIFICATIO Product ame: EPOXY RESI GRAY Document ID: M70714-02 Company: EOGARD - a Division of JOES-BLAIR Company 2728 Empire Central Dallas, TX 75235 1-214-353-1600 Revision umber: 4 Prior Version Date: 02-14-2008 Chemical Family: Epoxy Coating Intended use: Industrial Maintenance Floor Coating Emergency Contact: ChemTrec Center Emergency Phone: 1-800-424-9300 International: 703-527-3887 II. HAZARDS IDETIFICATIO EMERGECY OVERVIEW: Routes of Entry: Ingestion Skin contact Eye contact Inhalation Target Organs Potentially Affected by Exposure: WARIG! May cause allergic skin reaction. Causes eye irritation. May be harmful if absorbed through skin. Harmful if inhaled. Skin Eyes Respiratory Tract Medical Conditions Aggravated by Exposure: Skin disorders. Respiratory disorders, including but not limited to asthma and bronchitis. Immediate (Acute) Health Effects by Route of Exposure: Inhalation Irritation: Causes lung irritation. Causes nose and throat irritation. Inhalation of dusts produced during cutting, grinding or sanding of this product may cause irritation of the respiratory tract. Skin Contact: Causes skin irritation. May cause allergic skin reaction. Eye Contact: Causes eye irritation. Ingestion Toxicity: Harmful if swallowed. Long-Term (Chronic) Health Effects: Carcinogenicity: Contains Titanium Dioxide which is listed by IARC as possibly carcinogenic to humans (Group 2B). This listing is based on inadequate evidence with respect to humans and sufficient evidence in experimental animals. Possible cancer hazard. Contains carbon black which may cause cancer based on animal data. (Risk of cancer depends on duration and level of exposure.) Skin Contact: Prolonged contact may cause an allergic skin reaction. III. COMPOSITIO/IFORMATIO O IGREDIETS Chemical ame % CAS # Oxirane based epoxy homopolymer 40-60 25085-99-8 Page 1 of 5

Talc 10-30 14807-96-6 Oxirane, mono[(c12-14-alkyloxy)methyl] 5-10 68609-97-2 derivatives Titanium dioxide 5-10 13463-67-7 Carbon black 0.1-1 1333-86-4 IV. FIRST-AID MEASURES Inhalation: Remove to fresh air. If breathing is difficult, have a trained individual administer oxygen. Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin Contact: Wash with soap and water. Remove contaminated clothing and launder. Get medical attention if irritation develops or persists. Thoroughly wash or discard clothing and shoes before reuse. Ingestion: If swallowed, do not induce vomiting. Get medical attention immediately. V. FIRE FIGHTIG MEASURES Extinguishing Media: Fire and/or Explosion Hazards: Fire Fighting Methods and Protection: Hazardous Combustion Products: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Material may be ignited only if preheated to temperatures above the high flash point, for example in a fire. Do not enter fire area without proper protection including self- contained breathing apparatus and full protective equipment. Do not enter fire area without proper protection including self- contained breathing apparatus and full protective equipment. Carbon dioxide, Carbon monoxide, Aldehydes Flash Point ( F/ C): 201 / 94 VI. ACCIDETAL RELEASE MEASURES Personal Precautions and Equipment: Methods for Clean-up: Follow personal protective equipment recommendations found in Section VIII of this MSDS. Additional precautions may be necessary based on special circumstances created by the spill including the material spilled, the quantity of the spill, the area in which the spill occurred. See MSDS sections III, XIII and XV for disposal considerations. Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Dike with suitable absorbent material. Gather and store in a sealed container pending disposal. VII. HADLIG AD STORAGE Handling Technical Measures and Precautions: Storage Technical Measures and Conditions: Overexposure may be harmful. As with all chemicals, good industrial hygiene practices should be followed when handling this material. Store in a cool dry place. Keep container(s) closed. VIII. EXPOSURE COTROLS/PERSOAL PROTECTIO Engineering Measures: Local exhaust ventilation or other engineering controls may be required when handling or using this product to avoid overexposure. Respiratory Protection: General or local exhaust ventilation is the preferred means of protection. In cases where ventilation is inadequate, respiratory protection may be required to avoid overexposure. Follow respirator manufacturer's directions for respirator use. Eye Protection: Wear chemically resistant safety glasses with side shields when handling this product. Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid, or airborne Page 2 of 5

Skin Protection: material. Have an eye wash station available. Avoid all skin contact by covering as much of the exposed skin area as possible with appropriate clothing to prevent skin contact. Wash hands and other exposed areas with mild soap and water before eating, drinking, and when leaving work. Clothing suitable to prevent skin contact. Wear chemical resistant gloves. Control Parameters: Chemical ame ACGIH TLV-TWA ACGIH STEL OSHA PEL-TWA Talc 20 mppcf TWA 2mg/m³ (Respirable Dust) Titanium dioxide 10 mg/m³ TWA 15 mg/m³ TWA (total dust) Carbon black 3.5 mg/m3 TWA 3.5 mg/m3 TWA IX. PHYSICAL AD CHEMICAL PROPERTIES Physical State: Liquid Boiling Point - High ( F): 300.0 Vapor Pressure: < 13.3 PA @ 77 F (25 C) VOC (g/l) (Regulatory, Calculated): 10.68 (Actual, Calculated): 10.68 Viscosity: 1800-2400 CPS Solubility in Water: Minimal; 1-9% Octanol/Water Partition Coefficient: ot Available Volatiles, % by Volume (Calculated): 1.41 Volatiles, % by weight (Calculated): 0.88 Densty: 10.73-10.93 lbs./gal. Physical and Chemical Properties are calculated target or range values for single packaged items and do not represent compliance values for multi-component (mixed) systems. X. STABILITY AD REACTIVITY Stability: Conditions to Avoid: Materials to Avoid/Chemical Incompatibility: Polymerization: Hazardous Decomposition Products: Stable under normal conditions. Temperatures above the high flash point of this combustible material in combination with sparks, open flames, or other sources of ignition. Contamination. Oxidizing agents, Acids, Amines, Caustics (bases, alkalis) Will not occur. Carbon dioxide, Carbon monoxide, Aldehydes XI. TOXICOLOGICAL IFORMATIO Component Toxicology Data: Chemical ame CAS umber LD50/LC50 Oxirane based epoxy homopolymer 25085-99-8 Oral LD50 Rat > 5000 mg/kg Dermal LD50 Rabbit 4000 mg/kg Oxirane, mono[(c12-14- alkyloxy)methyl] derivatives 68609-97-2 Oral LD50 Rat > 2000 mg/kg Dermal LD50 > 2000 mg/kg Inhalation LC50 > 5 mg/l Titanium dioxide 13463-67-7 Oral LD50 Rat > 25 g/kg Dermal LD50 Rabbit > 10 g/kg Inhalation LC50 (4h) Rat > 6.82 mg/l Carcinogens: Chemical ame CAS umber IARC TP OSHA Titanium dioxide 13463-67-7 2B Carbon black 1333-86-4 2B XII. ECOLOGICAL IFORMATIO Page 3 of 5

Toxicity data, if available, are listed below. XIII. DISPOSAL COSIDERATIOS Disposal Methods: Refer to other sections of this MSDS to determine the toxicity and physical characteristics of the material to determine the proper waste identification and disposal in compliance with applicable regulations. XIV. TRASPORTATIO IFORMATIO This section provides basic shipping classification information and does not contain all regulatory transportation details. Refer to all applicable regulations for domestic, international, air, vessel and ground transportation requirements and restrictions. DOT Basic Description: Paint, ot-regulated XV. REGULATORY IFORMATIO United States Federal Regulations: TSCA Status All components of this product are either listed on the TSCA Inventory; or, are not subject to the inventory notification requirements. SARA EHS Chemicals CAS # % Epichlorohydrin 106-89-8 < 10 ppm CERCLA ot applicable SARA 313 ot applicable SARA 311/312 Health (Acute): Health (chronic): Fire (Flammable): Pressure: Reactivity: Y Y U. S. State Regulations: California Prop 65 Chemicals Cancer CAS # % Carbon Black 1333-86-4 0.1-1 Ethyl Benzene 100-41-4 0.001-0.01 Phenyl glycidyl ether 122-60-1 < 10 ppm 1-Chloro-2,3-epoxypropane 106-89-8 < 10 ppm Benzene 71-43-2 < 10 ppb Reproductive Toluene 108-88-3 < 1 ppm Benzene 71-43-2 < 10 ppb Canadian Regulations: CEPA DSL: WHMIS Hazard Class: The components of this product ARE listed on the Canadian Domestic Substances List. D2A XVI. ADDITIOAL IFORMATIO Prepared By: Regulatory Department Page 4 of 5

Disclaimer: This MSDS has been prepared in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) and Canada's Controlled Product Regulations (CPR). To the best of our knowledge the information contained herein is accurate. Determination of safe handling, application and use of this material is the responsibility of the end user. This information is furnished without warranty, expressed or implied. Print Date: March 17, 2011 Page 5 of 5