Safety Data Sheet Page 1 of 7 LOCTITE HB S049 known as PURBOND HB S049 MSDS-No. : 350795 V001.0 Date of issue: 17.12.2014 Section 1. Identification of the substance/prepaion and of the company/undertaking Product name: Intended use: LOCTITE HB S049 known as PURBOND HB S049 1-component-polyurethane adhesive Supplier: Henkel Australia Pty Ltd 135-141 Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) 9724 6444 Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER 03 9724 6556 Classification of the substance or mixture GHS Classification: Section 2. Hazards identification Hazard Class Hazard Category Route of Exposure Skin irritation Category 2 Serious eye irritation Category 2 Respiory sensitizer Category 1 Skin sensitizer Category 1 Carcinogenicity Category 2 Specific target organ toxicity - Category 3 Inhalation single exposure Specific target organ toxicity - repeated exposure Category 2 Hazard pictogram: Signal word: Danger
Page 2 of 7 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Storage: Disposal: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiory irritation. H351 Suspected of causing cancer. H373 May cause damage to organs through prolonged or repeated exposure. P202 Do not handle until all safety precautions have been read and understood. P261 Avoid breathing vapours. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/eye protection. P302+P352 IF ON SKIN: Wash with plenty of water. P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to remove. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/ attention. P314 Get medical advice/attention if you feel unwell. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical attention. P342+P311 If experiencing respiory symptoms: Call a POISON CENTER/doctor. P362 Take off contaminated clothing. P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P501 Dispose of waste and residues in accordance with local authority requirements. Classification of material Xn - Harmful Risk phrases: R20 Harmful by inhalation. R36/37/38 Irritating to eyes, respiory system and skin. R40 Limited evidence of a carcinogenic effect. R42/43 May cause sensitization by inhalation and skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. Safety phrases: S23 Do not breathe gas/fumes/vapour/spray. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S36/37 Wear suitable protective clothing and gloves. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Section 3. Composition / information on ingredients General chemical description: Mixture
Page 3 of 7 Identity of ingredients: Chemical ingredients Proportion Isocyanic acid, polymethylenepolyphenylene ester, 915152-15-7 25- <= 60 % polymer with 1,3-diisocyanatomethylbenzene, hydrazine and methyloxirane polymer wi Isocyanic acid, polymethylenepolyphenylene ester < 20 % o-(p-isocyanatobenzyl)phenyl isocyanate < 10 % < 10 % 2,2'-dimorpholinyldiethyl ether 6425-39-4 < 5 % Section 4. First aid measures Ingestion: Skin: Eyes: Inhalation: First Aid facilities: Medical attention and special treatment: DO NOT induce vomiting unless directed to do so by medical personnel. Call a physician immediately. Wash affected area immediately with soap and water. Immediately remove soiled or soaked clothing. Seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If mist or vapor of this product is inhaled, remove person immediately to fresh air. Seek medical attention if symptoms develop or persist. Eye wash and safety shower If breathing is difficult, give oxygen. Treat symptomatically. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Special protective equipment for fire-fighters: Foam, dry chemical or carbon dioxide. High pressure waterjet Thermal decomposition can lead to release of irritating gases and vapors. Oxides of carbon. Isocyanates. Wear self-contained breathing appaus. Wear protective equipment. Section 6. Accidental release measures Personal precautions: Use personal protective equipment as described in Section 8. Avoid contact with skin and eyes. Danger of slipping on spilled product. Keep unprotected persons away. Environmental precautions: Clean-up methods: Do not empty into drains / surface water / ground water. Remove with liquid-absorbing material (sand, peat, sawdust). Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Precautions for safe handling: Avoid skin and eye contact. Use personal protective equipment as described in Section 8. Ensure good ventilation/suction at the workplace.
Page 4 of 7 Conditions for safe storage: Ensure good ventilation/extraction. Store in a cool, dry place. Store at room tempeure. Store in a cool, dry, well-ventilated area. Keep container tightly sealed. Keep away from heat and direct sunlight. Section 8. Exposure controls / personal protection National exposure standards: Ingredient form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. (ppm) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3) Engineering controls: Eye protection: Skin protection: Respiory protection: General protection measures: Provide local and general exhaust ventilation to effectively remove and prevent buildup of any vapors or mists geneed from the handling of this product. Safety goggles or safety glasses with side shields. Use of protective coveralls and long sleeves is recommended. Nitrile rubber gloves should be worn. If inhalation risk exists, wear a respior or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS 1716. Good industrial hygiene practices should be observed. Section 9. Physical and chemical properties Appearance: beige liquid Odor: characteristic Specific gravity: 1.1 Flash point: > 500 C (> 932 F) Density: 1.1 g/cm3 Solubility in water: < 1.00000 g/l Auto ignition: 481 C Decomposition tempeure: VOC content (2004/42/EC) 0 % (VOCV 814.018 VOC regulation CH) VOC content: < 1 g/l Section 10. Stability and reactivity
Page 5 of 7 Stability: Conditions to avoid: Incompatible materials: Stable under recommended storage conditions. Humidity Reaction with water, alcohols, amines. Reacts with water: Pressure built up in closed vessel (CO2). Hazardous decomposition products: At higher tempeures isocyanate may be released. Carbon dioxide is geneed under contact with moisture, leading to pressure in the cans. Danger of cans bursting! Section 11. Toxicological information Health Effects: Ingestion: Skin: Eyes: Inhalation: Aggrevated med. condition: Harmful if swallowed. This product may cause irritation to the skin. Repeated or prolonged skin contact may result in allergic sensitization. Contact with eyes will cause irritation. This product may cause sensitization by inhalation and skin contact. May cause irritation to nose and throat. Pre-existing skin disorders. Acute toxicity: Isocyanic acid, polymethylenepolyphenyl ene ester o-(p- Isocyanatobenzyl)phenyl isocyanate 2,2'-dimorpholinyldiethyl ether 6425-39-4 Value type Value Route of application Exposure time Species Method > 10,000 mg/kg oral OECD Guideline 401 (Acute Oral Toxicity) LC50 > 2,000 mg/kg > 9,400 mg/kg > 2,000 mg/kg > 2.24 mg/l > 9,400 mg/kg 2,025 mg/kg 3,038 mg/kg oral dermal oral inhalation dermal oral dermal rabbit rabbit rabbit EU Method B.1 (Acute Toxicity (Oral)) OECD Guideline 402 (Acute Dermal Toxicity) OECD Guideline 403 (Acute Inhalation Toxicity) OECD Guideline 402 (Acute Dermal Toxicity) Skin corrosion/irritation: 2,2'-dimorpholinyldiethyl ether 6425-39-4 Result Exposure time Species Method irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) not irritating 4 h rabbit OECD Guideline 404 (Acute Dermal Irritation / Corrosion) Serious eye damage/irritation: 2,2'-dimorpholinyldiethyl ether 6425-39-4 Result Exposure time Species Method irritating 24 h rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion)
Page 6 of 7 Respiory or skin sensitization: sensitising Result Test type Species Method Buehler test guinea pig sensitising in vivo guinea pig OECD Guideline 406 (Skin Sensitisation) Germ cell mutagenicity: Result Type of study / Route of administion negative bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Species Method EU Method B.13/14 (Mutagenicity) Repeated dose toxicity: Isocyanic acid, polymethylenepolyphenyl ene ester o-(p- Isocyanatobenzyl)phenyl isocyanate Result NOAEL=0,2 mg/m³ Route of application inhalation: aerosol inhalation: aerosol inhalation: aerosol Exposure time / Frequency of treatment 2 y 6 h per d, 5 d per week main: 2 y; satellite: 1 y 6 h/d; 5 d/w main: 2 y; satellite:1 y 6 h/d; 5 d/w Species Method OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies) OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies) OECD Guideline 453 (Combined Chronic Toxicity / Carcinogenicity Studies) Section 12. Ecological information General ecological information: Do not empty into drains, soil or bodies of water. Section 13. Disposal consideions Waste disposal of product: Recommended cleanser: Disposal for uncleaned package: Collection and delivery to recycling enterprise or other registered elimination institution. Suitable organic solvents Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Section 14. Transport information Road and Rail Transport: Dangerous Goods information: Not classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). General information: Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR.
Page 7 of 7 Section 15. Regulatory information SUSMP Poisons Schedule None Section 16. Other information Abbreviations/acronyms: ADGC - Australian Dangerous Goods Code ASCC - Australian Safety and Compensation Council STEL - Short term exposure limit TWA - Time weighted average Reason for issue: Reviewed MSDS. Reissued with new date. involved chapters: 1-16 Disclaimer: The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accue and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.