Material Safety Data Sheet Revision Date: 01/30/2008 Issue date: 01/30/2008 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product name: PL460 PAIL/ 5 GAL Item No. : AO3100019 / IDH No. 921745 Product type: Adhesive for the Aerospace Industry Region: United States Company address: Henkel Loctite Aerospace 2850 Willow Pass Road Bay Point, California 94565 Contact Information: Telephone: 860.571.5100 Emergency telephone: 860.571.5100 Internet: www.loctite.com 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components % ACGIH TLV OSHA PEL OTHER 60-100 10-30 1 fiber/cm3 TWA respirable fibers: length > 5 µm, aspect ratio equal to or greater than 3:1, as determined by the membrane filter method at 400-450X magnification (4-mm objective), using phase-contrast illumination. 5 mg/m³ TWA inhalable fraction 0.1 mg/m 3 TWA 1-5 1-5 10mg/m³ Inhalable fraction, 3mg/m³ Respirable fraction, TWA 5mg/m³ Respirable dust, 15mg/m³ Total dust 1-5 1-5 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Solid HEALTH: 2* Color: Amber FLAMMABILITY: 1 Odor: Slight PHYSICAL HAZARD: 0 Personal Protection: See Section 8 WARNING: MAY CAUSE ALLERGIC SKIN REACTION. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY CAUSE GASTROINTESTINAL IRRITATION IF SWALLOWED. Relevant routes of exposure: Skin, Inhalation, Eyes Potential Health Effects 1 of 5
Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May cause respiratory tract irritation. May cause allergic respiratory reaction. May cause irritation. May cause allergic skin reaction. May cause severe eye irritation. May cause mechanical irritation. May cause gastrointestinal tract irritation if swallowed. Eye, skin, and respiratory disorders. Liver disorders. Kidney disorders. See Section 11 for additional toxicological information. 4. FIRST AID MEASURES Inhalation: Skin contact: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention. Remove contaminated clothing and shoes. Immediately flush skin with plenty of water (using soap, if available). Get medical attention if symptoms develop and persist. Remove contaminated clothing and shoes. Wash clothing before reuse. Eye contact: Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Ingestion: Notes to physician: DO NOT induce vomiting unless directed to do so by medical personnel. Give a conscious person several glasses of water. Never give anything by mouth to an unconscious person. Get medical attention if symptoms develop and persist. Treat symptomatically and supportively. 5. FIRE-FIGHTING MEASURES Flash point: Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Product is a solid. Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Oxides of nitrogen. 6. ACCIDENTAL RELEASE MEASURES Environmental precautions: Clean-up methods: Prevent product from entering drains or open waters. Evacuate personnel to safe areas. Ensure adequate ventilation. Wear suitable respiratory protection. Wear suitable protective clothing, gloves and eye/face protection. Sweep up spilled material. Avoid creating dust. Use non-sparking tools for clean-up. Store in a closed metal container until ready for disposal. 2 of 5
7. HANDLING AND STORAGE Handling: Storage: Incompatible products: Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Keep container closed. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. reasonably foreseeable. For information on product shelf life contact Henkel Customer Service at (800) 243-4874. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering controls: Respiratory protection: Skin protection: Eye/face protection: Use local ventilation if general ventilation is insufficient to maintain vapor concentration below established exposure limits. Use a NIOSH approved respirator if ventilation is inadequate. Use impermeable gloves and protective clothing as necessary to prevent skin contact. Chemical splash goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. Physical state: Solid Color: Amber Odor: Slight Vapor pressure: ph: Not applicable Boiling point/range: Melting point/range: Specific gravity: 1.0 Vapor density: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: <1%; <10 grams/liter See Section 2 for exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable at normal conditions Will not occur. Oxides of carbon. Oxides of nitrogen. Strong oxidizers. Strong acids. Strong bases. Storage with incompatible materials. 11. TOXICOLOGICAL INFORMATION Carcinogen Status 3 of 5
Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen Suspect Carcinogen Group 2B Yes Literature Referenced Target Organ & Other Health Effects Hazardous components Health Effects/Target Organs Allergen, Irritant Allergen, Respiratory Allergen, Central nervous system, Eyes, Irritant Irritant Irritant Allergen, Central nervous system, Irritant, Respiratory, Liver 12. ECOLOGICAL INFORMATION Ecological information: 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Dispose of according to Federal, State and local governmental regulations. Not a RCRA hazardous waste. U.S. Department of Transportation Ground (49 CFR): Hazard class or division: International Air Transportation (ICAO/IATA): Hazard class or division: 14. TRANSPORT INFORMATION WaterTransportation (IMO/IMDG): Hazard class or division: 4 of 5
15. REGULATORY INFORMATION United States Regulatory Information TSCA 8 (b) Inventory Status: TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory... Immediate Health Hazard, Delayed Health Hazard above reporting de minimus. This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Domestic Substances List. D.1.B, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: Revised to new format. Prepared by: C.J. Michaels, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. 5 of 5