Douglas Leech BA; BSc; CChem, CSci MRSC; CMIOSH; FIIRSM, RSP; AIEMA Technical Director Chemical Business Association Chairman of North Staffs and South Cheshire District
IS EVOLVING REACH CLP BIOCIDES PESTICIDES NANOTECH BIOTECH Copyright CBA 2014 www.chemical.org.uk
DSD/DPD UNDERWENT NUMEROUS UPDATES Copyright CBA 2014 www.chemical.org.uk
THE TRICK IS TO HAVE INTERNAL PROCESSES IN PLACE TO: Monitor The landscape Identify Issues and changes Learn lessons Operational experiences Both internal and external Update Documentation Training Communicate Internally and externally MAY 2014 - Merseyside Branch Copyright CBA 2014 www.chemical.org.uk
June 2014 - NSSC Copyright CBA 2014 www.chemical.org.uk
PURPLE BOOK First edition of the GHS o adopted in December 2002 o published in 2003. Copyright CBA 2014 www.chemical.org.uk
UPDATED EVERY TWO YEARS: GHS Rev.1 Adopted December 2004 Published 2005 GHS Rev.2 Adopted December 2006 Published 2007 GHS Rev.3 Adopted December 2008 Published 2009 GHS Rev.4 Adopted December 2010 Published 2011 GHS Rev.5 Adopted December 2012 published 2013 GHS Rev.6 Biennium started January 2013 Copyright CBA 2014 www.chemical.org.uk
GHS a model framework o No legal standing in any territory o Contains a number of hazard classes and categories 27 Classes 84 Categories o Designed as a Building Block approach Allows territories to choose blocks Includes a standardised SDS format Sixteen headings Copyright CBA 2014 www.chemical.org.uk
Internationally agreed o UN GHS model Not utilised by all countries as yet! o Will change as more adopt GHS formally Copyright CBA 2014 www.chemical.org.uk
KEY Countries/regions that have already implemented GHS Countries/regions where GHS is voluntary Countries/regions that are in the process of implementing GHS Countries/regions where GHS is not implemented or not available Copyright CBA 2014 www.chemical.org.uk
CLASSIFICATION, LABELLING AND PACKAGING REGULATION o (EC) 1272/2008 1 ST amendment (EC) 790/2009 o Direct acting across all EU states Deadlines: o December 2010 Substances o June 2015 Mixtures Page 11 Copyright CBA 2011 www.chemical.org.uk
Classification and labelling 67/548/EEC and 1999/45/EC New Substances 67/548/EEC Existing Substances EC Reg 793/93 Marketing and Use Directive 76/769/EEC Workplace Requirements E.g. 94/28/EEC 2004/37/EC 1996/61/EEC Product Directives, PPPs, Biocides, Medicines, Cosmetics, Food Page 12 Copyright CBA 2011 www.chemical.org.uk
CLP EC Reg 1272/2008 REACH EC Reg 1907/2006 Workplace Requirements E.g. 94/28/EEC 2004/37/EC 1996/61/EEC Product Directives, PPPs, Biocides, Medicines, Cosmetics, Food Page 13 Copyright CBA 2011 www.chemical.org.uk
ADAPTATION TO TECHNICAL PROGRESS (ATP) 1 st ATP 2 nd ATP 3 rd ATP 4 th ATP Introduced changes to Annex VI tables 3.1 & 3.2 Lists of substances Updated CLP to apply changes within the 3 rd revised edition of GHS into CLP Introduced changes to Annex VI tables 3.1 & 3.2 Updated CLP to apply changes within the 4 th revised edition of GHS Copyright CBA 2014 www.chemical.org.uk
ADAPTATION TO TECHNICAL PROGRESS (ATP) 5 th ATP 6 th ATP 7 th ATP 8 th ATP Introduced changes to Annex VI tables 3.1 & 3.2 Revises P210 in line with GHS 5 th rev Will introduce changes to Annex VI tables 3.1 & 3.2 Add Croatian H & P statements Started Feb 2014 Introduces changes to Annex VI tables 3.1 & 3.2 Vote due Sept 2014 Under initial discussions Will align CLP with GHS 5 th edition Copyright CBA 2014 www.chemical.org.uk
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009. o CHIP4 - SI 716/2009 Implements o European Directives on: Dangerous Substances (DSD - 67/548/EEC) Until 1st December 2010 Dangerous Preparations (DPD - 1999/45/EC) Until 1st June 2015 o European Regulation Classification, Labelling and Packaging (CLP 1272/2008) From 6 April 2009 Page 16 Copyright CBA 2011 www.chemical.org.uk
June 2014 - NSSC Copyright CBA 2014 www.chemical.org.uk
PHYSICAL HAZARDS Explosive Flammable o Gases, Liquids & Solids Oxidising o Gases, Liquids & Solids o Organic peroxides Copyright CBA 2013 www.chemical.org.uk
PHYSICAL HAZARDS Explosive Flammable o Gases, Aerosols, Liquids & Solids Oxidising o Gases, Liquids & Solids Gases under Pressure Self Reactive Self Heating Water Reactive Organic peroxides Pyrophoric o Liquids & Solids Corrosive to Metals Copyright CBA 2013 www.chemical.org.uk
HEALTH HAZARDS Toxic Corrosive Irritant Harmful Sensitisers o Respiratory & Skin Carcinogens, Mutagens & Reproductive Toxics Aspiration Copyright CBA 2013 www.chemical.org.uk
HEALTH HAZARDS Acute Toxicity Skin Corrosion & Irritancy Serious Eye Damage & Eye Irritation Sensitisers o o Respiratory Skin Germ Cell Mutagenicity Carcinogens Reproductive Toxicity Specific Target Organ Toxicity o o Aspiration Single Exposure Repeated Exposure Copyright CBA 2013 www.chemical.org.uk
ENVIRONMENTAL Dangerous to the Environment o Toxicity o Log-term adverse effects Copyright CBA 2013 www.chemical.org.uk
ENVIRONMENTAL Acute o Short term Chronic o Long term Ozone Depletion Copyright CBA 2013 www.chemical.org.uk
Two signal words o DANGER o WARNING Danger takes Precedence o if more than one hazard class applicable Page 24 Copyright CBA 2011 www.chemical.org.uk
ANNEX VII o Translation from 67/548/EEC to CLP Hazard Statements only o N; R50 Aquatic Acute 1: H400 o C; R34 Skin Corrosive 1B: H314 o T+; R23, gas Acute Toxicity 3: H331 o T+; R23, vapour Acute Toxicity 2: H330 o T+; R23, dust/mist Acute Toxicity 3: H331 Page 25 Copyright CBA 2011 www.chemical.org.uk
2-Methoxypropyl acetate Flammable. Irritation to the respiratory system. May cause harm to the unborn child. Toxic In case of accident or you feel unwell, seek medical advice immediately (Show label where possible). Avoid exposure obtain special instruction before use XYZ Chemicals Tel: 01234 5678910 Page 26 Copyright CBA 2011 www.chemical.org.uk
XYZ Chemicals Tel: 01234 5678910 2-Methoxypropyl acetate Danger Flammable liquid and vapour. May damage the unborn child. May cause respiratory irritation. Other phrases as necessary Page 27 Copyright CBA 2011 www.chemical.org.uk
Toxic Danger Flammable. Irritation to the respiratory system. May cause harm to the unborn child. 2 Safety Phrases Flammable liquid and vapour. May damage the unborn child. May cause respiratory irritation. 21 Precautionary Phrases Page 28 Copyright CBA 2011 www.chemical.org.uk
June 2014 - NSSC Copyright CBA 2014 www.chemical.org.uk
Relabel/ repackage Relabel/ repackage 1 Dec 2008 1 Dec 2009 1 Dec 2010 1 Dec 2012 1 Jun 2015 1 Jun 2017 Substances Old label allowed or New label ok New label mandatory Mixtures/Preparations Old label Old label allowed or New label allowed New label mandatory ERA Technology Ltd 2009 30
CLP COSHH COMAH Cosmetics TOY SAFETY YOU WILL NEED TO Verify that new SDS are available Review COSHH assessments Retrain staff in new regime o Hazard awareness o Pictogram recognitions Recheck COMAH calculations June 2014 - NSSC Copyright CBA 2014 www.chemical.org.uk