Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH)

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Transcription:

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.3 Details of the supplier of the safety data sheet Supplier (manufacturer/importer/only representative/downstream user/distributor) Meffert AG Farbwerke, Werk Erfurt Street : Heckerstieg 4 Postal code/city : D-99085 Erfurt Telephone : +49 361 59073-0 Telefax : +49 361 59073-40 Information contact : email: SDB@meffert.com 1.4 Emergency telephone number 00 800 63333782 Mo-Fr 7.30-20.00 Uhr, Sa 9.00-20.00 Uhr SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. R 10 R 52/53 R 66 Classification according to Regulation (EC) No. 1272/2008 [CLP] Aquatic Chronic 3 ; H412 - Hazardous to the aquatic environment : Category 3 ; Harmful to aquatic life with long lasting effects. Flam. Liq. 3 ; H226 - Flammable liquids : Category 3 ; Flammable liquid and vapour. STOT SE 3 ; H336 - STOT-single exposure : Category 3 ; May cause drowsiness or dizziness. 2.2 Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms Flame (GHS02) Exclamation mark (GHS07) Signal word Warning Hazard components for labelling mixture of naphthenic aliphatics ; CAS No. : 64742-48-9 Hazard statements H226 Flammable liquid and vapour. H336 May cause drowsiness or dizziness. H412 Harmful to aquatic life with long lasting effects. Precautionary statements P102 Keep out of reach of children. Page : 1 / 6

P103 P210 P233 P312 P304+P340 P403+P235 P405 P501 Read label before use. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Call a POISON CENTER/doctor/.../ if you feel unwell. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container to hazardous or special waste collection point. Supplemental Hazard information (EU) EUH066 Repeated exposure may cause skin dryness or cracking. 2.3 Other hazards SECTION 3: Composition / information on ingredients 3.2 Mixtures Hazardous ingredients mixture of naphthenic aliphatics ; REACH registration No. : 01-2119463258-33 ; EC No. : 919-857-5; CAS No. : 64742-48-9 Weight fraction : 15 - < 20 % Classification 67/548/EEC : R10 Xn ; R65 R67 R66 Classification 1272/2008 [CLP] : Flam. Liq. 3 ; H226 Asp. Tox. 1 ; H304 STOT SE 3 ; H336 NAPHTHA (ERDÖL), HYDROBEHANDELT, SCHWER ; REACH registration No. : 01-2119463258-33 ; EC No. : 265-150-3; CAS No. : 64742-48-9 Weight fraction : 1 - < 5 % Classification 67/548/EEC : R10 Xn ; R65 R66 Classification 1272/2008 [CLP] : Flam. Liq. 2 ; H225 Asp. Tox. 1 ; H304 Skin Irrit. 2 ; H315 Eye Irrit. 2 ; H319 STOT SE 3 ; H336 HYDROCARBONS, C10-13, N-ALKANES, ISOALKANES, NAPHTHENES, < 2 % AROMATIC COMPOUNDS ; REACH registration No. : 01-2119457273-39 ; EC No. : 918-481-9 Weight fraction : 1 - < 5 % Classification 67/548/EEC : Xn ; R65 R66 Classification 1272/2008 [CLP] : Asp. Tox. 1 ; H304 ZINC OXIDE ; REACH registration No. : 01-2119463881-32 ; EC No. : 215-222-5; CAS No. : 1314-13-2 Weight fraction : 1 - < 5 % Classification 67/548/EEC : N ; R50/53 Classification 1272/2008 [CLP] : Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410 Additional information Full text of R-, H- and EUH-phrases: see section 16. SECTION 4: First aid measures 4.1 Description of first aid measures No special measures are necessary. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1 Extinguishing media Page : 2 / 6

5.2 Special hazards arising from the substance or mixture 5.3 Advice for firefighters SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures 6.2 Environmental precautions 6.3 Methods and material for containment and cleaning up 6.4 Reference to other sections SECTION 7: Handling and storage 7.1 Precautions for safe handling 7.2 Conditions for safe storage, including any incompatibilities Hints on joint storage Storage class : 3 Storage class (TRGS 510) : 3 7.3 Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1 Control parameters 8.2 Exposure controls No special measures are necessary. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Safety relevant basis data Melting point/melting range : Initial boiling point and boiling range : ( 1013 hpa ) ca. 120 C Decomposition temperature : Flash point : 42 C Lower explosion limit : Upper explosion limit : Vapour pressure : ( 50 C ) < 1 hpa Density : ( 20 C ) 1,34 g/cm 3 Solvent separation test : ( 20 C ) < 3 % Water solubility : ( 20 C ) ph : none Page : 3 / 6

log P O/W : Flow time : ( 20 C ) > 130 s DIN-cup 4 mm Cinematic viscosity : ( 40 C ) > 20,5 mm 2 /s Relative vapour density : ( 20 C ) Vapourisation rate : Maximum VOC content (EC) : 27,5 Wt % Maximum VOC content (Switzerland) : 27,5 Wt % VOC value (Wood coating) : 369,1 g/l DIN EN ISO 11890-1/2 Flammable gases : 9.2 Other information. SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products SECTION 11: Toxicological information 11.1 Information on toxicological effects SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects 12.7 Additional ecotoxicological information Page : 4 / 6

SECTION 13: Disposal considerations 13.1 Waste treatment methods SECTION 14: Transport information 14.1 UN number UN 1263 14.2 UN proper shipping name Land transport (ADR/RID) PAINT Sea transport (IMDG) PAINT Air transport (ICAO-TI / IATA-DGR) PAINT 14.3 Transport hazard class(es) Land transport (ADR/RID) Class(es) : 3 Classification code : F1 Hazard identification number (Kemler No.) : 30 Tunnel restriction code : D/E Special provisions : 640E E 1 Transport in containers with max. 450 litres contents are not subject to the regulations of ADR/RID. Hazard label(s) : 3 Sea transport (IMDG) Class(es) : 3 EmS-No. : F-E / S-E Special provisions : LQ 5 l E 1 IMDG 2.3.2.5 (<= 30 l) Hazard label(s) : 3 Air transport (ICAO-TI / IATA-DGR) Class(es) : 3 Special provisions : E 1 Hazard label(s) : 3 14.4 Packing group III 14.5 Environmental hazards Land transport (ADR/RID) : No Sea transport (IMDG) : No Air transport (ICAO-TI / IATA-DGR) : No 14.6 Special precautions for user SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture National regulations Water hazard class (WGK) Class : 1 (Slightly hazardous to water) Classification according to VwVwS Page : 5 / 6

15.2 Chemical Safety Assessment SECTION 16: Other information 16.1 Indication of changes 02. Classification of the substance or mixture 02. Label elements 02. Labelling according to Regulation (EC) No. 1272/2008 [CLP] 02. Labelling according to Regulation (EC) No. 1272/2008 [CLP] - Hazard components for labelling 02. Special rules for supplemental label elements for certain mixtures 03. Hazardous ingredients 07. Hints on joint storage - Storage class 08. Occupational exposure limit values 15. Technische Anleitung Luft (TA-Luft) 16.2 Abbreviations and acronyms 16.3 Key literature references and sources for data 16.4 Label elements Labelling (67/548/EEC or 1999/45/EC) R-phrases 10 Flammable. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 66 Repeated exposure may cause skin dryness or cracking. S-phrases 61 Avoid release to the environment. Refer to special instructions/safety data sheets. 35 This material and its container must be disposed of in a safe way. 51 Use only in well-ventilated areas. 24 Avoid contact with skin. 16.5 Relevant R-, H- and EUH-phrases (Number and full text) H225 H226 H304 H315 H319 H336 H410 Highly flammable liquid and vapour. Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Very toxic to aquatic life with long lasting effects. 10 Flammable. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 65 Harmful: may cause lung damage if swallowed. 66 Repeated exposure may cause skin dryness or cracking. 67 Vapours may cause drowsiness and dizziness. 16.6 Training advice 16.7 Additional information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. Page : 6 / 6