22 APR 2010 <MSDS_ID>300092</MSDS_ID> MATERIAL SAFETY DATA SHEET <Product> TRIM 9106 ; CUTTING AND GRINDING FLUID CONCENTRATE ; PRODUCT USE : COOLANT AND LUBRICANT IN METAL REMOVAL PROCESSES </Product> Part#: MSDS SECTION I SUPPLIER INFORMATION Common Name : CHEMICAL FLUID/SYNTHETIC FLUID Chemical Name/Chemical Family: LISTED Formula/CAS : LISTED <Supplier> MASTER CHEMICAL CORPORATION </Supplier>#:719 Address : 501 WEST BOUNDARY City, St, Zip: PERRYSBURG OH 43551-1263 Phone: 419-874-7902 *********************** EMERGENCY PHONE #: 419-874-7902 ************************ Date Issued: 10-01-1985 Date Entered: 09-02-2008 Date Revised: 10-01-1995 08-01-2000 01-01-2003 07-01-2007 SECTION II INGREDIENT INFORMATION CAS#: 102-71-6 TRIETHANOLAMINE (30-40%) PEL: TLV: 5 MG/M3 STEL: LISTED OTHER LIMITS RECOM.: CAS#: NO SECTION 313 CHEMICALS PEL: LISTED TLV: LISTED STEL: LISTED SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point : 217 F (103 C) SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued on the next page. Page 1
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 2 MSDS Id #: 300092 SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued from previous page. Specific Gravity (H2O = 1) : 1.120 Melting Point: LISTED Vapor Pressure (mm Hg): LISTED Vapor Density (Air=1): LISTED Evaporation Rate (Butyl Acetate=1): >1 Solubility/Water: 100% **************************** APPEARANCE AND ODOR **************************** COLORLESS LIQUID, ODORLESS. ----------------------------------------------------------------------------- SECTION IV FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- Flash Point: TO BOILING (COC) Auto-Ignition: LISTED LEL: NOT DETERMINED UEL: NOT DETERMINED ************************ HMIS HAZARD CLASSIFICATION SYSTEM ************************ Flammable:0 Health:1 Reactivity:0 Special:A ************************* EXTINGUISHING MEDIA ******************************* AS APPROPRIATE FOR THE SURROUNDING FIRE: WATER (FLOOD WITH WATER), DRY CHEMICAL, CO2 OR "ALCOHOL" FOAM. ********************* SPECIAL FIRE FIGHTING PROCEDURES ********************** ******************** UNUSUAL FIRE AND EXPLOSION HAZARDS ********************* SECTION V REACTIVITY DATA Stability? PRODUCT IS STABLE. Avoid: SECTION V Page 2 REACTIVITY DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 3 MSDS Id #: 300092 SECTION V REACTIVITY DATA is continued from the previous page. ******************* INCOMPATIBILITY (Materials to Avoid) ******************** STRONG ACIDS AND OXIDIZERS ******************* HAZARDOUS DECOMPOSITION OR BY-PRODUCTS ****************** THERMAL DECOMPOSITION (FIRE) MAY PRODUCE CO, CO2, NOX. Polymerization? POLYMERIZATION WILL NOT OCCUR Avoid: SECTION VI HEALTH HAZARD DATA *************************** ADDITIONAL INFORMATION **************************** THE EXACT CHEMICAL IDENTITIES AND PERCENTAGES OF THE RAW MATERIALS USED IN TRIM 9106 ARE TRADE SECRETS. THIS INFORMATION IS BEING WITHHELD AS PROVIDED FOR IN THE OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION'S HAZARD COMMUNICATIONS RULE (29 CFR 1910.1200). EXPOSURE LIMITS: ESTABLISHED BY ACGIH OR OSHA FOR PRODUCT AS WHOLE. REFER TO SECTION 2 ADDITIONAL PHYSICAL AND CHEMICAL PROPERTIES ------------------------------------------- PH OF CONCENTRATE (AS RANGE): 8.2-8.6 TYPICAL OPERATING PH (AS RANGE): 8.2-8.4 FREEZING POINT: 10 F (-12 C) VOC CONTENT (EPA METHOD 24): 0.000 LBS/GAL TOXICOLOGICAL INFORMATION ------------------------- STUDY TEST ANIMAL CONCENTRATE RESULTS 10% SOLUTION ACUTE INHALATION RAT --- NONTOXIC TOXICITY LC50 >227MG/L ACUTE ORAL RAT NONTOXIC NONTOXIC TOXICITY LD50 >5G/KG SECTION VI Page 3 HEALTH HAZARD DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 4 MSDS Id #: 300092 SECTION VI HEALTH HAZARD DATA is continued from the previous page. ACUTE DERMAL RABBIT NONTOXIC NONTOXIC TOXICITY LD50 >2G/KG PRIMARY SKIN RABBIT NONIRRITANT NONIRRITANT IRRITATION PDI INDEX = 0.29 PDI INDEX=0.00 PRIMARY EYE RABBIT NONIRRITANT NONIRRITANT IRRITATION ECOLOGICAL INFORMATION ---------------------- NO DATA AVAILABLE TRANSPORT INFORMATION --------------------- DEPARTMENT OF TRANSPORTATION DOT HAZARD CLASS: TRIM 9016 IS NOT CLASSIFIED AS A HAZARDOUS MATERIAL BY DOT. REGULATORY INFORMATION ---------------------- RESOURCE CONSERVATION AND RECOVERY ACT: EPA HAZARDOUS WASTE NUMBER(S): TRIM 9106 IS NOT CLASSIFIED AS A HAZARDOUS WASTE BY EPA. TOXIC SUBSTANCES CONTROL ACT: ALL TRIM 9106 INGREDIENTS ARE LISTED ON THE TSCA INVENTORY OF CHEMICAL SUBSTANCES. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986: TRIM 9106 DOES NOT CONTAIN ANY SECTION 302/304 EXTREMELY HAZARDOUS SUBSTANCES OR SECTION 313 TOXIC CHEMICALS. HMIS HAZARD INDEX NFPA RATING CONCENTRATE HEALTH H = 1 H = 1 FIRE F = 0 F = 0 REACTIVITY R = 0 R = 0 PERSONAL PROTECTION PP = A (SAFETY GLASSES) SPECIAL HAZARDS = TYPICAL WORKING SOLUTION H = 1 H = 1 SECTION VI Page 4 HEALTH HAZARD DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 5 MSDS Id #: 300092 SECTION VI HEALTH HAZARD DATA is continued from the previous page. F = 0 F = 0 R = 0 R = 0 PP = A (SAFETY GLASSES) SPECIAL HAZARDS = KEY 0 = MINIMAL 1 = SLIGHT 2 = MODERATE 3 = SERIOUS 4 = SEVERE THIS INFORMATION IS INTENDED SOLELY FOR THE USE OF INDIVIDUALS TRAINED IN THE PARTICULAR SYSTEM. ****************************** CARCINOGENICITY ****************************** NTP? NO IARC? NO OSHA? NO LISTED ADDITIONAL INFORMATION ********************* ACUTE AND CHRONIC HEALTH HAZARDS ********************** EMERGENCY OVERVIEW ------------------ COLORLESS LIQUID NO IMMEDIATE HAZARD FIRE MAY PRODUCE CO, CO2, NOX ACUTE EFFECTS OF OVEREXPOSURE: EYE CONTACT: TRANSIENT IRRITATION SKIN CONTACT: POSSIBLE DEFATTING, NONIRRITANT, NONSENSITIZER INHALATION: NONTOXIC INGESTION: NONTOXIC SKIN ABSORPTION: NONTOXIC CHRONIC EFFECTS OF OVEREXPOSURE: CURRENTLY KNOWN ********************* SIGNS AND SYMPTOMS OF EXPOSURE ************************ ************ MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ************* KNOWN SECTION VI Page 5 HEALTH HAZARD DATA is continued on the next page.
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 6 MSDS Id #: 300092 SECTION VI HEALTH HAZARD DATA is continued from the previous page. ******************** EMERGENCY AND FIRST AID PROCEDURES *********************** EYES: FLUSH IMMEDIATELY WITH COOL, CLEAN WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH MILD SOAP AND WARM WATER. INHALATION: MOVE TO FRESH AIR. INGESTION: IF LARGE QUANTITIES ARE INGESTED, CONTACT A PHYSICIAN. IN EVERY CASE GET MEDICAL ATTENTION AS REQUIRED. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE DOT Classification: ********* STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ********* MOP UP OR USE DRY ABSORBENT. ************************** WASTE DISPOSAL METHOD **************************** MUST COMPLY WITH LOCAL, STATE AND FEDERAL REGULATIONS. IF PRE-TREATMENT IS NEEDED, CHEMICAL TREATMENT OR ULTRAFILTRATION MAY BE USED. CONTACT MASTER CHEMICAL TECH LINE (1-800-537-3365) FOR ASSISTANCE. ************** PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE ************** AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED SKIN CONTACT WITH THE CONCENTRATE. WASH THOROUGHLY AFTER HANDLING. DO NOT SWALLOW. REFER TO CONTAINER LABELS. ***************************** OTHER PRECAUTIONS ***************************** THIS PRODUCT CONTAINS AMINE. DO NOT ADD NITRITE OR OTHER NITROSATING AGENTS TO THIS PRODUCT DUE TO THE POTENTIAL FOR NITROSAMINE FORMATION. SECTION VIII CONTROL MEASURES SECTION VIII CONTROL MEASURES is continued on the next page. Page 6
22 APR 2010 MATERIAL SAFETY DATA SHEET Page 7 MSDS Id #: 300092 SECTION VIII CONTROL MEASURES is continued from the previous page. ************************ RESPIRATORY PROTECTION ***************************** ******************************** VENTILATION ******************************** Local Exhaust: NOT NORMALLY REQUIRED Special Exhaust: Mechanical Exhaust: GENERAL ROOM VENTILATION SHOULD BE SUFFICIENT Other: ****************************** OTHER PROTECTION ***************************** Gloves: Eye Protection: SAFETY GLASSES ******************************* CLOTHING ************************************ ************************** WORK/HYGIENE PRACTICES *************************** ALWAYS USE GOOD HYGIENE PRACTICES. ************************* MISCELLANEOUS INFORMATION ************************* THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH AND BELIEVED CURRENT AS OF THE DATE OF THIS MSDS. BECAUSE CONDITIONS OF USE ARE BEYOND OUR CONTROL, NO GUARANTEE, REPRESENTATION OR WARRANTY EXPRESSED OR IMPLIED IS MADE. CONSULT MASTER CHEMICAL CORPORATION FOR FURTHER INFORMATION. CONSULT ORIGINAL MSDS FOR ADDITIONAL INFORMATION. THIS IS THE END OF THE MSDS Id #300092