Page 1 of 5 1.0 Introduction Statement of Hazardous Nature: Company Details: Company: Street Address: Postal Address: Telephone No: (09) 277-7770 Emergency Telephone No: 0800 200 162 Classified for acute toxicity (6.1D), as a skin irritant (6.3A), eye irritant (6.4A), respiratory sensitiser (6.5A), contact sensitiser (6.5B), containing suspected human development/reproductive toxicant (6.8B), toxic to human target organs or systems (6.9A), harmful in the aquatic environment (9.1B) and as harmful to terrestrial vertebrates (9.3C) according to the criteria of the HSNO Act 1996. Not classified as hazardous according to the criteria of NZS 5433:1999. New Zealand 14 Mayo Road, Wiri, Auckland, New Zealand PO Box 88-048, Clendon Town, Auckland, New Zealand 2.0 Product Identification Product Name: Protim FrameSaver Other Names: Boracol 200RH UN Number: None allocated Dangerous Goods Class: Miscellaneous Dangerous Good Class 9 Hazchem Code: 2Z Subsidiary Risk: Toxic Substances Schedule: Poison, Third Schedule (monoethylene glycol) NFPA: (Health: 2) - (Flammability: 0) - (Reactivity: 0) Packaging Group: IMDG: Manufacturer: New Zealand Use: Algaecide/fungicide and insecticide for treatment of timber, brick and other masonry finishes.
Page 2 of 5 Physical Description/Properties: Appearance: Clear colourless liquid with a sweet smell. Form: Liquid Boiling Point: >100 C Melting Point: <0 C Vapour pressure: Negligible Vapour density: Volatile Component: Not available Specific gravity: 1.232 g/ml @ 20ºC ph 7.0 Flash Point: Flammability Limits: Autoignition Temp: >400 C Solubility in water: 100% Ingredients: Chemical Entity CAS. no. Proportion (w/w) Disodium Octaborate Tetrahydrate 12008-41-2 10-30% Benzalkonium Chloride 8001-54-5 <10% Mono Ethylene glycol 107-21-1 <65% Water 7732-18-5 To 100% 3.0 HEALTH HAZARD INFORMATION Acute Effects: Swallowed: Harmful if swallowed. May cause nausea, vomiting, diarrhoea and abdominal pain. Central nervous system stimulation followed by depression may occur following ingestion of large quantities. Eye: Irritating to eyes. Skin: Harmful in contact with skin. Irritant and sensitising effects to skin. Prolonged or repeated exposure may lead to defatting of the skin which could cause secondary dermatitis. Inhaled: Irritant. Inhalation of mist may cause headache, nausea and irritation or sensitising effects of the throat and respiratory tract.
Page 3 of 5 Chronic Effects: Kidney and liver damage may result from chronic exposure. Chronic exposure may cause hair loss, weight loss and diarrhoea. May have adverse reproductive or development effects as results of exposure. First Aid: Swallowed: Eye: Skin: Inhaled: Never give anything by mouth to an unconscious person. If swallowed, and if more than 15 minutes from a hospital, induce vomiting, preferably using Ipecac syrup APF. If poisoning occurs, contact a doctor or Poisons Information Centre (0800 764 766). Hold eyelids open and flush eyes with running water for at least 15 minutes. Contact a doctor or Poisons Information Centre (0800 764 766). Remove contaminated clothing. Wash affected skin immediately with soap and water. Seek medical assistance if large area involved or irritation persists. Remove victim to fresh air. Loosen tight clothing and remove any contaminated clothing. Keep victim warm and at rest until recovered. If breathing has stopped, ensure airway is clear and apply resuscitation. Obtain immediate medical attention. First Aid Facilities: Ensure an eye-wash and safety showers are available and ready for use. Advice to Doctor: Treat symptomatically. Early diagnosis and treatment of ingestion is important. Ensure emesis is satisfactory. Test for correct metabolic acidosis and hypocalcaemia. If evidence of renal insufficiency apply rapid and sustained diuresis with the use of hypertonic mannitol. Evaluate renal status and begin haemodialysis if indicated. Exposure Standards: 4.0 PRECAUTIONS FOR USE Workplace exposure standards: TWA WES-C Mono ethylene glycol 60 mg/m³ 50ppm (127mg/ m 3 ) Borax 1mg/ m 3
Page 4 of 5 Engineering Controls: Good Ventilation required. Local exhaust should be provided if handled in confined areas. Personal Protection: Wear eye protection in the form of goggles, PVC or rubber gloves, PVC boots and overalls should be worn when manufacturing or handling the concentrated product. An organic vapour respirator should be used during any spraying operations. After using product always wash hands before smoking, eating, drinking or using the toilet. Flammability: Not flammable. 5.0 SAFE HANDLING INFORMATION Storage and Transport: Road Transport: Not listed in NZS 5433:1999 Sea Transport: Not listed in IMDG code 1990 Storage: Store in a dry place away from foodstuffs at all times. Store away from sources of heat or ignition. Spills and Disposal: Wear protective clothing as above. Do not allow into drains or water-courses. Contain spill by absorbing with sand, earth or other absorbent material. Notify Police or local Health Protection if there is any risk of contamination of water courses Wash down spill area with copious quantities of water but ensure wash off liquid can be safely contained. Waste and empty containers must be disposed on it accordance with local government regulations. Dispose of by liaising with a waste disposal company or by disposing at a site approved by relevant local authorities. Reactivity Data: Stable. Avoid strong acids and oxidising agents.
Page 5 of 5 Fire/Explosion Hazard: Not flammable but will burn in a fire. Use water spray to cool containers exposed to heat. Use alcohol foam, water fog, dry chemical or carbon dioxide to extinguish fire. 6.0 ADDITIONAL INFORMATION Toxicity Data: Product: Oral LD 50 (rat) 6216 mg/kg Disodium octaborate Oral LD 50 (rat) 2000 mg/kg tetrahydrate: Oral LD 50 (guinea pig) 5300 mg/kg Benzalkonium chloride: Oral LD 50 (rat) 240mg/kg Skin LD 50 (rat) 1560 mg/kg Human eye 50µg SEV Mono ethylene glycol: Oral LD 50 (rat) 4700 mg/kg Lower lethal dose (human) 786 mg/kg Environment: Prevent spillages from entering waterways. Harmful to animal and plant life. Toxic to fish and other aquatic life forms. CONTACT POINTS: OSMOSE HEAD OFFICE NORMAL HOURS: (09) 277-7770 OSMOSE 24 HOUR EMERGENCY NUMBER: 0800 200 162 IN AN EMERGENCY, DIAL 111 - FIRE OR POLICE 24 hr Emergency No: National Poisons Centre Phone: 0800 764 766