Page 1 of 8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture Dosage: 10 give ml on 1 litre of water, well mix. 1.. Details of the supplier of the safety data sheet Company name: Street: Place: Post-office box: Marburger Str. 5 604 Alsfeld 1261 6292 Alsfeld Telephone: 0661-96880 Telefax: 0661-9688-96 e-mail: Contact person: Internet: Responsible Department: info@finnsa.de Uwe Helm finnsa.de Verkauf 1.4. Emergency telephone number: 0611 19240 Giftinformationszentrum (GIZ) der Länder Rheinland-Pfalz und Hessen SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Indications of danger: Xi - Irritant R phrases: Flammable. Irritating to eyes. May cause sensitisation by skin contact. Vapours may cause drowsiness and dizziness. GHS classification Hazard categories: Flammable liquid: Flam. Liq. Serious eye damage/eye irritation: Eye Irrit. 2 Respiratory/skin sensitization: Skin Sens. 1 Specific target organ toxicity - single exposure: STOT SE Hazard Statements: Flammable liquid and vapour. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. 2.2. Label elements Hazardous components which must be listed on the label propan-2-ol; isopropyl alcohol; isopropanol Methylester Signal word: Pictograms: Warning GHS02-GHS07
Page 2 of 8 Hazard statements H226 H17 H19 H6 Flammable liquid and vapour. May cause an allergic skin reaction. Causes serious eye irritation. May cause drowsiness or dizziness. Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P2 Keep container tightly closed. P261 Avoid breathing smoke. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves/protective clothing/eye protection/face protection. P0+P61+P5 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P+P1 If skin irritation or rash occurs: Get medical advice/attention. P52 Wash with plenty of water. P6 Wash contaminated clothing before reuse. P04+P40 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P12 Call a POISON CENTER/doctor if you feel unwell. P05+P51+P8 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P7+P1 If eye irritation persists: Get medical advice/attention. P70+P78 In case of fire: Use CO2 to extinguish. P25 Keep cool. P40+P2 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Special labelling of certain mixtures EUH208 Contains propan-2-ol; isopropyl alcohol; isopropanol, Methylester. May produce an allergic reaction. SECTION : Composition/information on ingredients.2. Mixtures
Page of 8 Hazardous components EC No CAS No Index No REACH No 200-661-7 67-6-0 60-117-00-0 22-268-1 8000-41-7 Chemical name Classification GHS classification propan-2-ol; isopropyl alcohol; isopropanol F - Highly flammable, Xi - Irritant R11-6-67 Flam. Liq. 2, Eye Irrit. 2, STOT SE ; H225 H19 H6 Terpineol Xi - Irritant R8 Quantity 40 - < 45 % 1 - < 5 % 200-456-2 60-12-8 2-Phenylethanol Xi - Irritant R6 1 - < 5 % 22-476-2 8050-15-5 20-75-0 106-22-9 201-289-8 80-54-6 20-212- 104-54-1 Methylester Xi - Irritant R4 Skin Sens. 1; H17 Citronellol Xi - Irritant, N - Dangerous for the environment R8-4-51-5 Skin Irrit. 2, Skin Sens. 1, Aquatic Chronic 2; H15 H17 H411 2-(4-tertiär-Butylbenzyl)propionaldehyd Xn - Harmful, Xi - Irritant R22-62-8-4-51-5 Acute Tox. 4, Skin Irrit. 2, Skin Sens. 1, Repr. 2, Aquatic Chronic 2; H02 H15 H17 H61f H411 trans--phenyl-2-propen1-ol Xi - Irritant R4 Skin Sens. 1; H17 1 - < 5 % < 1 % < 1 % < 1 % 20-77-1,7-Dimthylocta-2,6-dien-1-ol 106-24-1 Xi - Irritant R8-4 Skin Irrit. 2, Eye Dam. 1, Skin Sens. 1; H18 H15 H17 Full text of R and H phrases: see Section 16. < 1 % SECTION 4: First aid measures 4.1. Description of first aid measures General information If victim is at risk of losing consciousness, position and transport on their side. After inhalation Provide fresh air. Seek medical attention if problems persist. After contact with skin After contact with skin, wash immediately with: Water and soap. After contact with eyes In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. In case of troubles or persistent symptoms, consult an ophthalmologist. After ingestion Seek medical attention if problems persist.
Page 4 of 8 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Carbon dioxide (CO2), Dry extinguishing powder, Foam. Unsuitable extinguishing media Full water jet. 5.2. Special hazards arising from the substance or mixture In case of fire and/or explosion do not breathe fumes. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Remove all sources of ignition. 6.2. Environmental precautions Do not allow to enter into surface water or drains. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Use only in well-ventilated areas. Keep away from sources of ignition. - No smoking. Advice on protection against fire and explosion Take precautionary measures against static discharge. 7.2. Conditions for safe storage, including any incompatibilities Requirements for storage rooms and vessels Keep container tightly closed and in a well-ventilated place. Further information on storage conditions Keep away from heat. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Exposure limits (EH40) CAS No Substance ppm mg/m³ fibres/ml Category Origin 67-6-0 Propan-2-ol 400 999 TWA (8 h) WEL 500 1250 STEL (15 min) WEL 57-55-6 Propane-1,2-diol, particulates - 10 TWA (8 h) WEL 8.2. Exposure controls - - STEL (15 min) WEL Protective and hygiene measures Keep away from food, drink and animal feedingstuffs. Take off immediately all contaminated clothing. Eye/face protection.tightly sealed safety glasses. Hand protection Before using check leak tightness / impermeability. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals
Page 5 of 8 of the protective gloves mentioned above together with the supplier of these gloves. Respiratory protection Respiratory protection necessary at: insufficient ventilation.work in well-ventilated zones or use proper respiratory protection. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state: Colour: Odour: liquid: colourless characteristic ph-value (at 20 C): 5-6 Test method Changes in the physical state Melting point: Initial boiling point and boiling range: Sublimation point: Flash point: Explosive properties not Explosive. Lower explosion limits: Vapour pressure: Vapour pressure: Density: Water solubility: No data available 24 C 0,880 g/cm³ 0 g/l SECTION 10: Stability and reactivity 10.4. Conditions to avoid 10.6. Hazardous decomposition products Further information No risks worthy of mention. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Irritant effect on the skin: Not an irritant. Irritant effect on the eye: Not an irritant.
Page 6 of 8 CAS No Chemical name Exposure routes Method Dose Species Source 67-6-0 propan-2-ol; isopropyl alcohol; isopropanol oral dermal 106-22-9 Citronellol LD50 4570-5045 mg/kg LD50 12800-1400 mg/kg Rat. Rabbit inhalative vapour LC50 0-46,5 mg/l Rat. oral LD50 450 mg/kg Ratte 80-54-6 2-(4-tertiär-Butylbenzyl)propionaldehyd oral ATE 500 mg/kg Sensitising effects weakly sensibilizing. Additional information on tests The evaluation was carried out according to the calculation method of the Preparations Directive. Irritant. - Mutagen - Carcinogenicity - Teratogen - Phototoxicity SECTION 12: Ecological information 12.2. Persistence and degradability No information available. 12.. Bioaccumulative potential No information available. 12.4. Mobility in soil No information available. 12.5. Results of PBT and vpvb assessment not applicable 12.6. Other adverse effects No information available. Further information 1 slightly hazardous to water (WGK 1) Do not allow to enter into surface water or drains. SECTION 1: Disposal considerations 1.1. Waste treatment methods Advice on disposal Do not allow to enter into surface water or drains. Contaminated packaging Dispose of waste according to applicable legislation.
Page 7 of 8 Cleaning agent. Water (with cleaning agent). SECTION 14: Transport information Land transport (ADR/RID) 14.1. UN number: UN 199 14.2. UN proper shipping name: 14.. Transport hazard class(es): 14.4. Packing group: Hazard label: Classification code: Limited quantity: Hazard No: Tunnel restriction code: FLAMMABLE LIQUID, N.O.S. (ISOPROPANOL (ISOPROPYL ALKOHOL)) III F1 LQ7 D/E Other applicable information (land transport) Special provisions: 274 601 640H E1 Transport category: Marine transport (IMDG) 14.1. UN number: UN 199 14.2. UN proper shipping name: 14.. Transport hazard class(es): 14.4. Packing group: Hazard label: Marine pollutant: Limited quantity: EmS: FLAMMABLE LIQUID, N.O.S. (ISOPROPANOL (ISOPROPYL ALCOHOL)) III 5 L F-E, S-E Other applicable information (marine transport) Special provisions: 22, 0, 274, 944, 955 E1 Air transport (ICAO) 14.1. UN number: UN 199 14.2. UN proper shipping name: 14.. Transport hazard class(es): 14.4. Packing group: Hazard label: Limited quantity Passenger: IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: IATA-max. quantity - Cargo: Other applicable information (air transport) E1 Y09 Special provisions: A 14.5. Environmental hazards ENVIRONMENTALLY HAZARDOUS: FLAMMABLE LIQUID, N.O.S. III 10 L no 09 60 L 10 220 L
Page 8 of 8 14.6. Special precautions for user Flammable liquids 14.7. Transport in bulk according to Annex II of MARPOL7/78 and the IBC Code not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture National regulatory information Water contaminating class (D): 1 - slightly water contaminating SECTION 16: Other information Full text of R phrases referred to under Sections 2 and 10 Flammable. 11 Highly flammable. 22 Harmful if swallowed. 6 Irritating to eyes. 8 Irritating to skin. 4 May cause sensitisation by skin contact. 51 Toxic to aquatic organisms. 5 May cause long-term adverse effects in the aquatic environment. 62 Possible risk of impaired fertility. 67 Vapours may cause drowsiness and dizziness. Full text of H statements referred to under Sections 2 and H225 Highly flammable liquid and vapour. H226 Flammable liquid and vapour. H02 Harmful if swallowed. H15 Causes skin irritation. H17 May cause an allergic skin reaction. H18 Causes serious eye damage. H19 Causes serious eye irritation. H6 May cause drowsiness or dizziness. H61f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)