DARACLEAN 200 Section 1: IDENTIFICATION 1.1 PRODUCT IDENTIFIER Product Name: Daraclean 200 Product Code: 1.2 RECOMMENDED USE OF CHEMICAL AND RESTRICTIONS ON USE Use: 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET Name/Address: Non-Destructive Testing. Magnaflux 155 Harlem Avenue, Glenview, Illinois 60025 Telephone Number: 847-657-5300 1.4 EMERGENCY TELEPHONE NUMBER Emergency Telephone Number: CHEMTREC 800-424-9300 Date of Preparation: November 3, 2014 Version #: 1.2 Section 2: HAZARD(S) IDENTIFICATION 2.1 CLASSIFICATION OF THE CHEMICAL ACCORDING TO OSHA HAZCOM 2012 Skin corrosion 1B Serious eye damage 1 Skin Sensitization 1 Carcinogenicity 2 Reproductive Toxicity 1B 2.2 LABEL ELEMENTS ACCORDING TO OSHA HAZCOM 2012 Hazard Pictogram: Hazard class Signal Word: Hazard Statement: Danger Causes severe skin burns and eye damage. May cause an allergic skin reaction. 1 Page
Prevention: Response: Storage: Disposal: 2.3 ADDITIONAL INFORMATION Suspected of causing cancer. May damage fertility or the unborn child. Do not breathe dusts or mists. Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. If exposed or concerned: Get medical advice/attention. If swallowed: Rinse mouth. Do NOT induce vomiting. Immediately call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Immediately call a poison center/doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center/doctor. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified: Not applicable. 3 % of the mixture consists of ingredient(s) of unknown acute toxicity. This product is a hazardous chemical as defined by NOM-018-STPS-2000. Mexico Classification: Blue = Health Red = Flammability Yellow = Reactivity White = Special Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme WHMIS Classification(s): Class D2A - Carcinogenicity Class D2A - Reproductive Toxicity Class E - Corrosive Material 2 Page
WHMIS Hazard Symbols: WHMIS Signal Word: DANGER Section 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1 MIXTURES Ingredient UN # H / F/ R / * CAS No Wt. % Sodium xylenesulphonate 1300-72-7 5-10 Potassium hydroxide UN1814 3/0/1 1310-58-3 1-5 Diethanolamine 111-42-2 0.5-1.5 Alcohols, C8-10, ethoxylated propoxylated 68603-25-8 0.5-1.5 Boric acid 10043-35-3 0.5-1.5 Monoethanolamine UN2491 3/2/0 141-43-5 0.5-1.5 Citrus extracts (citrus terpenes) 94266-47-4 0.1-1 Benzyl chloride UN1738 3/2/1 100-44-7 <0.1 1,4-Dioxane UN1165 2/3/1 123-91-1 <0.1 Ethylene oxide UN1040 3/4/3 75-21-8 <0.1 Propylene oxide UN1280 3/4/2 75-56-9 <0.1 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of 1910.1200. * Per NOM-018-STPS-2000 Section 4: FIRST- AID MEASURES 4.1 DESCRIPTION OF THE FIRST AID MEASURE Eye: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. Skin: Inhalation: Ingestion: In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention immediately. If inhaled, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention immediately. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. 3 Page
Get medical attention immediately. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED Eye: Skin: Inhalation: Ingestion: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Causes severe skin burns. Symptoms may include irritation, redness, pain, blisters, serious skin burns. May cause sensitization by skin contact. Irritating to respiratory system. May be harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause burns. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENTS NEEDED Note to Physicians: Specific Treatments: Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). Section 5: FIRE-FIGHTING MEASURES 5.1 FLAMMABILITY Flammability: 5.2 EXTINGUISHING MEDIA Suitable Extinguishing Media: Unsuitable Extinguishing Media: 5.3 SPECIAL HAZARDS ARISING FROM THE CHEMICAL Products of Combustion: Explosion Data: Sensitivity to Mechanical Impact: Sensitivity to Static Discharge: Not flammable by WHMIS/OSHA/NOM-018-STPS-2000 criteria. Powder, foam, carbon dioxide. Do not use water. 5.4 SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE FIGHTERS May include, and are not limited to: oxides of carbon, oxides of nitrogen. Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool. Floor will become slippery if material is released. Section 6: ACCIDENTAL RELEASE MEASURES 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Avoid contact with skin and eyes. 4 Page
6.2 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING - UP Methods for Containment: Methods for Cleaning-Up: Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Scoop up material and place in a disposal container. Spilled material may present a slipping hazard. Provide ventilation. Section 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Handling: General Hygiene Advice: 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Storage: Do not get in eyes, on skin, or on clothing. Do not swallow. Do not breathe dust/fume/gas/mist/vapours/spray. Use only in well-ventilated areas. Handle and open container with care. Do not eat, drink or smoke when using this product. (See section 8) Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. Keep out of the reach of children. Keep container tightly closed and in a wellventilated place. Store locked up. Store between 4 C (40 F) and 38 C (100 F). (See section 10) Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTROL PARAMETERS Exposure Guidelines Occupational Exposure Limits Ingredient OSHA-PEL ACGIH-TLV Sodium xylenesulphonate Potassium hydroxide 2 mg/m 3 2 mg/m 3 Diethanolamine 1 mg/m 3 (vapor) Alcohols, C8-10, ethoxylated propoxylated Boric acid 2 mg/m 3 Monoethanolamine 3 ppm 3 ppm Citrus extracts (citrus terpenes) Not available Benzyl chloride 1 ppm; 5 mg/m 3 1 ppm 1,4-Dioxane 100 ppm 20 ppm Ethylene oxide 1 ppm 1 ppm Propylene oxide 100 ppm; 240 mg/m 3 2 ppm 5 Page
8.2 EXPOSURE CONTROLS Engineering Controls: 8.3 INDIVIDUAL PROTECTIVE MEASURES Personal Protective Equipment: Eye/Face Protection: Skin Protection: Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). Hand Protection: Body Protection: Respiratory Protection: General Health and Safety Measures: Wear chemical resistant gloves. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Section 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear. Color: Yellow. Odor: Odor Threshold: Physical State: Liquid. ph: 13.0 Melting Point/Freezing Point: Initial Boiling Point and Boiling Range: ~ 100 C (212 F) Flash Point: None. Evaporation Rate: 1.0 (water = 1.0) Flammability: Lower Flammability/Explosive Limit: Upper Flammability/Explosive Limit: Vapor Pressure: Not flammable. 24 mmhg @ 20 C (68 F) 6 Page
Vapor Density: Relative Density/Specific Gravity: ~ 1.0 Solubility: Complete. Partition coefficient: n-octanol/water: Auto-ignition Temperature: Decomposition Temperature: Viscosity: Oxidizing Properties: Explosive Properties: Section 10: STABILITY AND REACTIVITY 10.1 REACTIVITY No dangerous reaction known under conditions of normal use. 10.2 CHEMICAL STABILITY Stable under normal storage conditions. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS No dangerous reaction known under conditions of normal use. 10.4 CONDITIONS TO AVOID Heat. Incompatible materials. 10.5 INCOMPATIBLE MATERIALS Nitrites. Acids. Strong oxidizers. 10.6 HAZARDOUS DECOMPOSITION PRODUCTS May include, and are not limited to: oxides of carbon, oxides of nitrogen. Section 11: TOXICOLOGICAL INFORMATION 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS Likely Routes of Exposure: Symptoms related to physical/chemical/toxicological characteristics: Eye: Skin: Skin contact, skin absorption, eye contact, inhalation, and ingestion. Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Causes severe skin burns. Symptoms may include irritation, redness, pain, blisters, serious 7 Page
Ingestion: Inhalation: skin burns. May cause sensitization by skin contact. May be harmful if swallowed. May cause stomach distress, nausea or vomiting. May cause burns. Irritating to respiratory system. Acute Toxicity: Ingredient IDLH LC50 LD50 Sodium xylenesulphonate Oral > 7000 mg/kg, rat; Dermal > 2000 mg/kg, rabbit Potassium hydroxide Oral 214 mg/kg, rat Diethanolamine Oral 620 µl/kg, rat Dermal 7640 µl/kg, rabbit Alcohols, C8-10, ethoxylated propoxylated Boric acid Inhalation > 2.12 mg/l 4h, rat Oral 2660 mg/kg, rat; Dermal >2000 mg/kg, rabbit Monoethanolamine 30 ppm Oral 1720 mg/kg, rat Citrus extracts (citrus terpenes) Benzyl chloride 10 ppm Inhalation 150 ppm 2h, rat Oral 340 mg/kg, rat 1,4-Dioxane Ca [500 ppm] Inhalation 48.5 mg/l 4h, rat Oral 4200 mg/kg, rat Dermal 7600 mg/kg, rabbit Ethylene oxide Ca [800 ppm] Inhalation 800 ppm 4h, rat Oral 72 mg/kg, rat Propylene oxide Ca [400 ppm] Inhalation 4000 ppm 4h, rat; 1740 ppm 4h, mouse Oral 380 mg/kg, rat; Dermal 1244 mg/kg, rabbit Calculated overall Chemical Acute Toxicity Values LC50 (inhalation) LD50 (oral) LD50 (dermal) > 20 mg/l 4h, rat > 2000 mg/kg, rat > 2000 mg/kg, rabbit Ingredient Sodium xylenesulphonate Potassium hydroxide Diethanolamine Alcohols, C8-10, ethoxylated propoxylated Boric acid Monoethanolamine Citrus extracts (citrus terpenes) Chemical Listed as Carcinogen or Potential Carcinogen (NTP, IARC, OSHA, ACGIH, CP65)* Not listed. Not listed. G-A3, I-2B, CP65 Not listed. G-A4 Not listed. Not listed. 8 Page
Benzyl chloride G-A3, I-2A, CP65 1,4-Dioxane G-A3, I-2B, N-2, CP65 Ethylene oxide O, G-A2, I-1, N-1, CP65 Propylene oxide G-A3, I-2B, N-2, CP65 * See Section 15 for more information. 11.2 DELAYED, IMMEDIATE, AND CHRONIC EFFECTS OF SHORT- AND LONG-TERM EXPOSURE Skin Corrosion/Irritation: Causes severe skin burns. Serious Eye Damage/Irritation: Causes serious eye damage. Respiratory Sensitization: Skin Sensitization: May cause an allergic skin reaction. STOT-Single Exposure: Chronic Health Effects: Carcinogenicity: Germ Cell Mutagenicity: Reproductive Toxicity: Developmental: Teratogenicity: Embryotoxicity: Fertility: STOT-Repeated Exposure: Aspiration Hazard: Toxicologically Synergistic Materials: Other Information: Suspected of causing cancer. May damage the unborn child. May damage fertility. Section 12: ECOLOGICAL INFORMATION 12.1 ECOTOXICITY Acute/Chronic Toxicity: 12.2 PERSISTENCE AND DEGRADABILITY Biodegradable. 12.3 BIOACCUMULATIVE POTENTIAL Bioaccumulation: 12.4 MOBILITY IN SOIL May cause long-term adverse effects in the aquatic environment. 9 Page
12.5 OTHER ADVERSE EFFECTS Section 13: DISPOSAL CONSIDERATIONS 13.1 WASTE TREATMENT METHODS Disposal Method: Other disposal recommendations: This material must be disposed of in accordance with all local, state, provincial, and federal regulations. Section 14: TRANSPORT INFORMATION DOT IATA IMDG UN1760, Corrosive liquids, n.o.s. (Potassium Hydroxide; Monoethanolamine), 8, II Prohibited UN1760, Corrosive liquids, n.o.s. (Potassium Hydroxide; Monoethanolamine), 8, II Section 15: REGULATORY INFORMATION 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/ LEGISLATIONS SPECIFIC FOR THE CHEMICAL Canada: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the SDS contains all the information required by the Controlled Products Regulations. US: SDS prepared pursuant to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 Mexico: SDS prepared pursuant to NOM-018-STPS-2000. Ingredient SARA Title III Section 302 (EHS) TPQ (lbs.) Section 304 EHS RQ (lbs.) CERCLA RQ (lbs.) Section 313 Sodium xylenesulphonate Not listed. Not listed. Not listed. Not listed. Potassium hydroxide Not listed. Not listed. 1000 Not listed. Diethanolamine Not listed. Not listed. 100 313 Alcohols, C8-10, ethoxylated propoxylated Not listed. Not listed. Not listed. Not listed. Boric acid Not listed. Not listed. Not listed. Not listed. Monoethanolamine Not listed. Not listed. Not listed. Not listed. Citrus extracts (citrus terpenes) Not listed. Not listed. Not listed. Not listed. Benzyl chloride 500 100 100 313 1,4-Dioxane Not listed. Not listed. 100 313 Ethylene oxide 1000 10 10 313 Propylene oxide 10000 100 100 313 10 Page
California Proposition 65: State Regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. Global Inventories: Ingredient Canada DSL/NDSL Sodium xylenesulphonate DSL Yes. Potassium hydroxide DSL Yes. Diethanolamine DSL Yes. Alcohols, C8-10, ethoxylated propoxylated DSL Yes. Boric acid DSL Yes. Monoethanolamine DSL Yes. Citrus extracts (citrus terpenes) DSL Yes. Benzyl chloride DSL Yes. 1,4-Dioxane DSL Yes. Ethylene oxide DSL Yes. Propylene oxide DSL Yes. NFPA-National Fire Protection Association: Health: 3 Fire: 1 Reactivity: 0 HMIS-Hazardous Materials Identification System: Health: 3* Fire: 1 Physical Hazard: 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: CP65 California Proposition 65 OSHA (O) ACGIH (G) IARC (I) Occupational Safety and Health Administration. American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. USA TSCA International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient 11 Page
evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. NTP (N) National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Date of Preparation: November 3, 2014 Expiry Date: November 3, 2017 Version: 1.2 Revision Date: June 9, 2015 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. Prepared by: Prepared for: Nexreg Compliance Inc. Phone: (519) 488-5126 www.nexreg.com Magnaflux End of Safety Data Sheet 12 Page