Page 1/8 1 Identification of the substance/mixture and of the company/undertaking Product identifier Article number: VLPMMA10 Relevant identified uses of the substance or mixture and uses advised against Application of the substance / the preparation primer Details of the supplier of the safety data sheet Manufacturer/Supplier: bredent GmbH & Co.KG Weißenhorner Straße 2 89250 Senden Tel: +49 (0) 7309/872-0 Fax: +49 (0) 7309/872-24 Further information obtainable from: R & D e-mail: R.D@bredent.com Emergency telephone number: (001) 352 323 3500 2 Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS02 flame Flam. Liq. 2 H225 Highly flammable liquid and vapour. GHS08 health hazard Repr. 2 H361 Suspected of damaging fertility or the unborn child. GHS07 Skin Irrit. 2 Eye Irrit. 2 Skin Sens. 1 STOT SE 3 H315 Causes skin irritation. H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H335 May cause respiratory irritation. Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R36/37/38: Irritating to eyes, respiratory system and skin. Xi; Sensitising R43: May cause sensitisation by skin contact. F; Highly flammable R11: Highly flammable. R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. (Contd. on page 2)
Page 2/8 (Contd. of page 1) Classification system: The classification is according to the latest editions of the EU-lists, and extended by company and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: Xi Irritant F Highly flammable Hazard-determining components of labelling: methyl methacrylate pentaerythritol triacrylate pentaerythritol tetraacrylate Risk phrases: 11 Highly flammable. 36/37/38 Irritating to eyes, respiratory system and skin. 43 May cause sensitisation by skin contact. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: 9 Keep container in a well-ventilated place. 24 Avoid contact with skin. 37/39 Wear suitable gloves and eye/face protection. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: CAS: 80-62-6 EINECS: 201-297-1 CAS: 3524-68-3 EINECS: 222-540-8 CAS: 4986-89-4 EINECS: 225-644-1 CAS: 75980-60-8 methyl methacrylate Xi R37/38 Xi R43 F R11 Flam. Liq. 2, H225 Skin Irrit. 2, H315; Skin Sens. 1, H317; STOT SE 3, H335 pentaerythritol triacrylate Xi R36/38 Xi R43 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 pentaerythritol tetraacrylate Xi R36/38 Xi R43 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 diphenyl(2,4,6,-trimethylbenzoyl)-phosphineoxide Xn R62 N R51/53 Repr. 2, H361 Aquatic Chronic 2, H411 50-100% 2.5-10% 2.5-10% 1-5% (Contd. on page 3)
Page 3/8 Additional information: For the wording of the listed risk phrases refer to section 16. (Contd. of page 2) 4 First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Take affected persons into fresh air and keep quiet. After skin contact: Immediately rinse with water. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Do not induce vomiting; call for medical help immediately. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Foam Fire-extinguishing powder Carbon dioxide For safety reasons unsuitable extinguishing agents: Water Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Additional information Cool endangered receptacles with water spray. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective clothing. Keep away from ignition sources. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Pick up mechanically. Dispose of the material collected according to regulations. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling: Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: Keep ignition sources away - Do not smoke. When heatet the product forms flammable fumes. (Contd. on page 4)
Page 4/8 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Store away from oxidizing agents. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Store receptacle in a well ventilated area. Specific end use(s) No further relevant information available. (Contd. of page 3) 8 Exposure controls/personal protection Control parameters Ingredients with limit values that require monitoring at the workplace: 80-62-6 methyl methacrylate WEL () Short-term value: 416 mg/m³, 100 ppm Long-term value: 208 mg/m³, 50 ppm Exposure controls Personal protective equipment: General protective and hygienic measures: Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. Immediately remove all soiled and contaminated clothing Use skin protection cream for skin protection. Respiratory protection: Short term filter device: Filter A/P2 Protection of hands: Solvent resistant gloves Eye protection: Safety glasses 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Fluid Colour: Colourless Odour: Pungent Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: 100 C (bei 1013 hpa) Flash point: 10 C (DIN 51755) Ignition temperature: 430 C (DIN 51794) Self-igniting: Product is not selfigniting. Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures are possible. Explosion limits: Lower: 2.1 Vol % Upper: 12.5 Vol % Vapour pressure at 20 C: 40 hpa (Contd. on page 5)
Page 5/8 Density at 20 C: 1.1 g/cm³ Solubility in / Miscibility with water at 20 C: 6 g/l Other information No further relevant information available. (Contd. of page 4) 10 Stability and reactivity Possibility of hazardous reactions Reacts with reducing agents. Reacts with heavy metals. Reacts with peroxides and other radical forming substances. Exothermic polymerization. Conditions to avoid No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: 80-62-6 methyl methacrylate Oral LD50 >5000 mg/kg (rat) Dermal LD50 >5000 mg/kg (rabbit) Inhalative LC50/4h 29.4 mg/l (rat) NOEL 400 ppm (rat) 75980-60-8 diphenyl(2,4,6,-trimethylbenzoyl)-phosphineoxide Oral LD50 >5000 mg/kg (rat) Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: Sensitization possible through skin contact. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant 12 Ecological information Toxicity Aquatic toxicity: 80-62-6 methyl methacrylate EC0 100 mg/l (pseudomonas putida) EC50 (48 h) 69 mg/kg (daphnia) EC50 (96 h) 170 mg/l (selenastrum capricornutum) LC50 / 96 h >79 mg/l (Oncorhynchus mykiss) Persistence and degradability No further relevant information available. Behaviour in environmental systems: Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. (Contd. on page 6)
Page 6/8 Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. (Contd. of page 5) 13 Disposal considerations Waste treatment methods Recommendation Must be specially treated adhering to official regulations. Uncleaned packaging: Recommendation: Packaging may be reused or recycled after cleaning. Packagings that may not be cleansed are to be disposed of in the same manner as the product. * 14 Transport information UN-Number ADR, IMDG, IATA UN1247 UN proper shipping name ADR 1247 METHYL METHACRYLATE MONOMER, STABILIZED IMDG, IATA METHYL METHACRYLATE MONOMER, STABILIZED Transport hazard class(es) ADR Class 3 Flammable liquids. Label 3 IMDG, IATA Class 3 Flammable liquids. Label 3 Packing group ADR, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for user Warning: Flammable liquids. Danger code (Kemler): 339 EMS Number: F-E,S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. (Contd. on page 7)
Page 7/8 Transport/Additional information: ADR Tunnel restriction code D/E (Contd. of page 6) UN "Model Regulation": UN1247, METHYL ME THA CR YLA TE M ONOME R, STABILIZED, 3, II * 15 Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: Xi Irritant F Highly flammable Hazard-determining components of labelling: methyl methacrylate pentaerythritol triacrylate pentaerythritol tetraacrylate Risk phrases: 11 Highly flammable. 36/37/38 Irritating to eyes, respiratory system and skin. 43 May cause sensitisation by skin contact. 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: 9 Keep container in a well-ventilated place. 24 Avoid contact with skin. 37/39 Wear suitable gloves and eye/face protection. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H361 Suspected of damaging fertility or the unborn child. H411 Toxic to aquatic life with long lasting effects. R11 Highly flammable. R36/38 Irritating to eyes and skin. R37/38 Irritating to respiratory system and skin. R43 May cause sensitisation by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. Department issuing MSDS: R & D Contact: R & D (Contd. on page 8)
Page 8/8 (Contd. of page 7) Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association ICAO: International Civil Aviation Organization GHS: Globally Harmonized System of Classification and Labelling of Chemicals LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent * Data compared to the previous version altered.