Fertility Management for Corn on Corn Systems Kyle Freeman. The Mosaic Company

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Fertility Management for Corn on Corn Systems Kyle Freeman The Mosaic Company

Safe Harbor Statement Certain statements contained herein constitute forward-looking statements within the meaning of the Private Securities Litigation Reform Act of 1995. Such statements include, but are not limited to, statements about future financial and operating results. Such statements are based upon the current beliefs and expectations of The Mosaic Company s management and are subject to significant risks and uncertainties. These risks and uncertainties include but are not limited to the predictability and volatility of, and customer expectations about, agriculture, fertilizer, raw material, energy and transportation markets that are subject to competitive and other pressures and the effects of the current economic and financial turmoil; changes in the level of inventories in the distribution channels for crop nutrients; changes in foreign currency and exchange rates; international trade risks; changes in government policy; changes in environmental and other governmental regulation, including greenhouse gas regulation; difficulties or delays in receiving, or increased costs of, necessary governmental permits or approvals; the effectiveness of our processes for managing our strategic priorities; adverse weather conditions affecting operations in Central Florida or the Gulf Coast of the United States, including potential hurricanes or excess rainfall; actual costs of asset retirement, environmental remediation, reclamation or other environmental regulation differing from management s current estimates; accidents and other disruptions involving Mosaic s operations, including brine inflows at its Esterhazy, Saskatchewan potash mine and other potential mine fires, floods, explosions, seismic events or releases of hazardous or volatile chemicals, as well as other risks and uncertainties reported from time to time in The Mosaic Company s reports filed with the Securities and Exchange Commission. Actual results may differ from those set forth in the forward-looking statements. 2

Outline Nutrient Stewardship Corn on Corn Fertility Considerations Primary Nutrients Management Nitrogen Phosphorous Potassium Other Nutrients Considerations Sulfur Zinc Mosaic Products and Research 3

Performance indicators Profit Resource use efficiencies: Energy, Labor, Nutrient, Water Nutrient balance Yield Return on investment Biodiversity Nutrient loss Water & air quality Soil erosion Adoption Stakeholder input Ecosystems services Food security Soil productivity Quality Working conditions Nutrition security

Right Source Scientific Principle: Ensure a balanced supply of each of the essential nutrients in plantavailable form, utilizing all available sources. Practices: Credit nutrients from manures and composts Credit N from previous crops Assess use of enhanced-efficiency sources

Right Rate Scientific Principle: Assess soil nutrient supply and plant demand. Practices: Soil test Balance crop removal Determine crop yield potential Assess price ratios

Right Time Scientific Principle: Assess timing of crop uptake, soil nutrient supply, weather, loss risks and field operation logistics. Practices: Split-application for sandy soils Scouting and tissue sampling Cover crops to capture nutrients Suit tillage and planting operations

Right Place Scientific Principle: Place nutrients where they are accessible to the crop. Practices: Placement near seedlings Within-field management zones Apply soil survey information (drainage, etc.) Band, inject, or incorporate Precision RTK-GPS

Corn on Corn Fertility Considerations

Fertility implications What do I need to do differently do grow continuous corn? Transport of nutrients in corn Nutrient removal Nutrient tie up Use of starter fertilizers P & K management N-timing Starter placement Sulfur/zinc needs

How do plant roots take up nutrients? Soil Diffusion 3 Shoot 2 Mass Flow I Mass Flow Difussion Interception Nitrogen Sulfur Potasium Phosphorus Potasium Zinc Zinc Root 1 Interception Marschner, 1995

Nutrient removal by cropping system Cropping System N (lbs) P2O5 (lbs) K2O (lbs) Corn (180 bu/a) 215 70 50 Soybean credit -45 Soybeans (55 bu/a) 10 45 75 C-S total 180 115 125 Cropping System N (lbs) P2O5 (lbs) K2O (lbs) 1 st year Corn (180 bu/a) 180 70 50 2 nd year Corn (162 bu/a) 190 65 45 Organic matter tie up 30 C-C total 400 135 95 Nutrient removal factors from IPNI

Nutrient tie up from corn on corn system OM shift can cause N, P, S & Zn deficiencies in the short term Corn residues tie up more N than soybeans Compensate by increasing N fertilizer 30-50 #/a If using yield-based calculations of N requirements, adjust yield goals downward 5-8% for C/C More early N is needed until organic N pool becomes available

P & K management in continuous corn Cooler, wetter soils can cause P/K problems Soils with low/deficient soil P & K levels can be a problem Banding preplant P & K is more advantageous in C/C, especially if soils have a higher ph Starter application more advantageous in C/C K levels need to increase as yield potential increases starting to see more stalk lodging problems that could be K deficiency coupled with weaker genetic stalk strength

Starter placement Traditional 2 x 2 is very effective on low P soils, but many growers do not have the equipment 2 x 0 (or drip surface) placement produced similar results in many university studies Fertilizer needs to be applied at least 2 away from the seed row when nitrogen levels in the starter increase Rain is required to move fertilizer into profile

Nitrogen

Nitrogen application timing Need a pool of N early in corn s lifecycle preplant N is beneficial N supplied by previous soybean crop in season must be replaced Very high yielding corn may require additional N prior to tasseling Use of controlled released N products or high clearance N applications prior to tasseling may become more common as growers push for upper level yields

Corn grain yield (bu/acre) Nitrogen response by corn in different rotations: Eudora silt loam 180 160 140 120 100 80 60 40 20 0 Maddux and Barnes, 1998 S C S C C C C 0 50 100 150 200 250 N rate (lb N/acre) Eudora silt loam Average: 1979-1987

Summary Nitrogen requirements Corn following soybean usually requires the least amount of nitrogen Continuous corn usually requires the most amount of nitrogen Nitrogen requirements of second year corn following soybean are somewhere between these two Nitrogen response Corn following soybean is less responsive, allowing a greater margin of error in rate selection Corn following corn is more responsive, allowing a smaller margin of error in rate selection

Phosphorous

The International Plant Nutrition Institute (IPNI) conducts a US Soil Sample Survey every 5 years. Conducted periodically by IPNI, current = 10 th Samples from fall 2009 spring 2010 Data reported: Median P, K, and ph values Relative frequency across soil test ranges for P, K, ph, Mg, S, Zn, Cl - 4.4 million samples Data from 63 public and private labs

Figure 5. Median Bray P-1 equivalent soil test levels, 2010. IPNI, 2010

Change in median Bray P equivalent soil test levels from 2005 to 2010. IPNI, 2010

Soil test P distribution in 2010 compared to 2005 for the Corn Belt (12 states plus Ontario) 30% 2005 2.0 million samples Corn Belt P 25% 2010 3.0 million samples Median 20% (2010) 22 28 (2005) 15% 10% 5% 0% Bray P1 Equivalent, ppm

nugis.ipni.net

Soil Nitrate Levels Phosphorus and Nutrient Utilization Advantage: Phosphorus improves the ability of plants to use all available nutrients Benefits: Best utilization of all inputs Reduced environmental concern 250 200 150 100 50 without P with P 66% reduction in Nitrate 0 0 39 78 118 157 196 N rate, lb/a Optimum N Rate Schlegel, Dhuyvetter, and Havlin, 1996 JPA 9:1

Potassium

K Role in Plants Enzyme Activation Water Relations Energy Relations (ATP) Photosynthesis Translocation Protein Synthesis Stress Resistance

Figure 10. Median soil test K levels in 2010. IPNI, 2010

Figure 13. Change in median soil K level from 2005 to 2010. IPNI, 2010

Corn grain yield (bu/a) The difference non-limiting levels make to nutrient recommendations 220 139 ppm K 200 180 205 lb N/acre optimum 80 ppm K 160 140 120 294 lb N/acre optimum 100 80 0 60 120 180 240 300 360 N rate (lb N/A) Johnson et al. 1997. Better Crops 97:3-5.

Sulfur

Sulfur needs 90% of sulfur comes from OM/residue more S will be tied up with C/C so deficiencies will become more common Sulfur in plant needed for: 3 amino acids: methionine, cysteine, cystine Chlorophyll production Vitamins like thiamine and biotin Glucoside oils like glucosinolates Ferredoxins for assimilatory reduction of N, dinitrogen fixation

Sulfur Deficiency in Corn

Change in Sulfate Ion Concentration In Precipitation from 1985 To 2003 Clean Air Means Less Sulfur in Precipitation 1985 2003 National Atmospheric Deposition Program

Zinc

Zinc needs Zinc is required in cooler soils Zinc deficiencies may begin to show up with more than 2 years of corn in a row Zinc in plant needed for: Protein synthesis Chlorophyll and carbohydrate production Auxin synthesis A driver of many metabolic reactions

Percent of samples testing < 1.0 ppm DTPA equivalent Zn in 2010. 16% < 0.5 ppm IPNI, 2010

Micronutrient Deficiencies are Seldom Uniform Across Fields Zn Deficiency

Zinc deficiency

Phosphorus & Zinc Zn deficiency impairs plant P regulation. High soil P or large amounts of applied P can induce Zn deficiency if Zn supply is marginal. P 2 O 5 Zn Yield Leaf tissue lb/a * bu/a P, % Zn, ppm 0 0 101 0.14 12 0 10 102 0.16 24 80 0 73 0.73 10 80 10 162 0.41 17 80 lb P 2 O 5 10 Zn * P and Zn band-applied Data source: Adriano and Murphy 80 lb P 2 O 5 - Banded 0 Zn 80 lb P 2 O 5 -Broadcast 0 Zn

Mosaic Products and Research

The Next Generation of Fertilizer MicroEssentials SZ (10-40-0-10S-1Zn) MicroEssentials combines nitrogen, phosphorus, sulfur and zinc into one nutritionally balanced granule, creating a single source for balanced crop nutrition. The unique chemistry & precise nutrient ratio of MicroEssentials promotes: Uniform Nutrient Distribution Increased Nutrient Uptake Season-long Sulfur Availability 44

A Breakthrough in Fertilizer MicroEssentials Fusion Technology Through our patented Fusion manufacturing process, nitrogen, phosphorus, sulfur and zinc are fused into one nutritionally balanced granule, creating a single source for balanced crop nutrition. 45

Two Forms of Sulfur Season-Long Availability 50% Sulfate Sulfur for immediate availability to the plant 50% Elemental Sulfur for availability throughout the growing season, after oxidation 46

Uniform Nutrient Distribution Through our patented Fusion manufacturing process: Same analysis within every granule Nutrients delivered evenly across every field Plants have more sites to reach the key nutrients needed for optimal growth Get more from every acre 47

Summary Corn on Corn fertility requires more attention There is less margin for error. Corn on Corn requires more Nitrogen Residue management will impact P and K fertility. 48