Page 1 of 1. Identification of the substance/preparation and of the company/undertaking Identification of the substance or preparation Use of the substance/preparation General chemicals, as they are used in many ways in the chemical industry.. Company/undertaking identification Company name: Street: Place: Im Ennepetal 19-21 D-5135 Hagen Telephone: 0049-2331-45671 Telefax: 0049-2331-4173 e-mail: koenigswarter@t-online.de Contact person: Herr Abel Telephone: 0049-2331-45671 e-mail: Internet: Emergency telephone: Further Information For industrial purposes only. 2. Hazards identification koenigswarter@t-online.de www.ke-nickel.com 022-19240 Classification Indications of danger : Toxic, Irritant, Dangerous for the environment R-phrases: May cause cancer by inhalation. Irritating to eyes and skin. May cause sensitization by inhalation and skin contact. Toxic: danger of serious damage to health by prolonged exposure through inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. GHS: Hazard Statements: May be corrosive to metals. Toxic if swallowed. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause cancer by swallowing. May damage the unborn child. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Explication of special hazards for human health and environment Mind restrictions concerning juveniles and pregnant as well as nursing women handling the product. 3. Composition/information on ingredients Chemical characterization ( Mixture ) nickelphosphate - in aqueous solution
Page 2 of Hazardous components EC-No. Chemical name CAS-No. Classification Index No. GHS classification REACH-No. 242-522-3 nickel bis(dihydrogen phosphate) 171-11-1 Carc. Cat. 1, T, N R49-4/23-42/43-50-53 02-032-00-0 Carc. 1A, STOT RE 1, Resp. Sens. 1, Skin Sens. 1, Aquatic Acute 1, Aquatic Chronic 1; H350i H372 ** H334 H317 H400 H410 231-633-2 phosphoric acid... %, orthophosphoric acid... % 7664-3-2 C R34 015-011-00-6 Skin Corr. 1B; H314 Quantity > 25 % 5-10 % Full text of R- and H-phrases: see section 16. 4. First aid measures General information First aid assistant: Pay attention to self-protection! After inhalation Provide fresh air. In case of breathing difficulties administer oxygen. No mouth-to-mouth or mouth-to-nose resuscitation.use respiratory bag or oxygen resuscitation apparatus. Immediately get medical attention. After contact with skin After contact with skin, wash immediately with: Water. Subsequently wash again with: Polyethylene glykol 400. Take off immediately all contaminated clothing. Medical treatment necessary. After contact with eyes If product gets into the eye, keep eyelid open and rinse immediately with large quantities of water, for at least 5 minutes. Subsequently consult an ophthalmologist. After ingestion Rinse mouth immediately and drink large quantities of water. Do not induce vomiting. Medical treatment necessary. 5. Fire-fighting measures Suitable extinguishing media Extinguishing materials should be selected according to the surrounding area. Special protective equipment for fire-fighters Wear a self-contained breathing apparatus and chemical resistant suit. Additional information Use a water spray jet to knock down vapours/gases/mists. Contaminated fire-fighting water must be collected separately. Do not empty into drains or the aquatic environment. 6. Accidental release measures Personal precautions Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eye and clothing. Wear personal protection equipment. Environmental precautions Do not empty into drains or the aquatic environment. Methods for cleaning up/taking up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the assimilated material according to the section on waste disposal. Absorb with liquid-binding
Page 3 of 7. Handling and storage Handling material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Advice on safe handling In case of open handling equipment with built-in suction must be used. Do not breathe gas/fumes/vapour/spray. Measures to prevent aersol and dust accumulation: Storage Requirements for storage rooms and vessels Keep container tightly closed. Keep locked up. Store in a place accessible only to authorized persons. Keep container in a well-ventilated place. Storageclass (VCI):. Exposure controls/personal protection Exposure limit values Exposure limits (EH40) 6.1B CAS-No. Chemical name ml/m³ mg/m³ F/ml Category Origin 7664-3-2 Orthophosphoric acid - 1 TWA ( h) WEL Exposure controls - 2 STEL (15 min) WEL Occupational exposure controls In case of open handling equipment with built-in suction must be used. Do not breathe gas/fumes/vapour/spray. Protective and hygiene measures Take off immediately all contaminated clothing. Protect skin by using skin protective cream. After work, wash hands and face. When using do not eat or drink. Respiratory protection Respiratory protection required in case of: insufficient ventilation. Hand protection Recommended protective gloves brand: Butyl rubber. NBR (Nitrile rubber). (0,11 mm) Eye protection Tightly sealed safety glasses. 9. Physical and chemical properties General information Physical state: Colour: Odour: crystalline green odourless Important health, safety and environmental information ph-value (at 20 C): 1,4 Changes in the physical state Melting point: Boiling point: Sublimation point: -2 - -26 C > 100 C Test method
Page 4 of Flash point: Flammability Solid: Gas: Explosive properties Ignition temperature: Oxidizing properties Vapour pressure: Density (at 20 C): Water solubility: (at 20 C) Solubility in other solvents: Partition coefficient: Solvent content: Other information Auto-ignition temperature Solid: 10. Stability and reactivity 1,46-1,5 g/cm³ miscible. Conditions to avoid Additional information stable under normal conditions 11. Toxicological information Acute toxicity Toxic. Acute toxicity, inhalant. Corrosive and irritant effects Irritating to eyes. After skin contact: irritant. Sensitising effects May cause sensitization by inhalation and skin contact. Severe effects after repeated or prolonged exposure Danger of serious damage to health by prolonged exposure. Carcinogenic/mutagenic/toxic effects for reproduction May cause cancer. Additional information on tests The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). 12. Ecological information Ecotoxicity Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Data apply to the component with the highest toxicological risk.: Nickel Acute fish toxicity: LC50: (96h) : 40 mg/l
Page 5 of LC50: crustacae (4h) :,5 mg/l EC50: crustacae (4h) : 1 mg/l Persistence and degradability No data available Results of PBT assessment No data available Further information Do not empty into drains or the aquatic environment. The classification was undertaken in accordance with the calculation method governed by the Preparations Directive (1999/45/EC). 13. Disposal considerations Advice on disposal Do not empty into drains or the aquatic environment. Waste disposal according to official state regulations. Waste disposal number of waste from residues/unused products 060104 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of acids; phosphoric and phosphorous acid Classified as hazardous waste. Waste disposal number of contaminated packaging 060104 WASTES FROM INORGANIC CHEMICAL PROCESSES; wastes from the manufacture, formulation, supply and use (MFSU) of acids; phosphoric and phosphorous acid Classified as hazardous waste. Contaminated packaging Cleaned containers may be recycled. Handle contaminated packaging in the same way as the substance itself. 14. Transport information Environmental hazards Dangerous for the environment: yes Land transport (ADR/RID) UN number: ADR/RID class: Classification code: Warning plate Hazard-no.: Hazard label: 3264 C1 0 ADR/RID packing group: Limited quantity: Tunnel restriction code: II LQ22 Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. E
Page 6 of Other applicable information (land transport) Special provisions: 274 E2 Transport category: 2 Inland waterways transport UN number: ADNR class: Classification code: Hazard label: 3264 C1 Packing group: Limited quantity: II LQ22 Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Other applicable information (inland waterways transport) Special provisions: 274 E2 Marine transport UN number: IMDG code: Hazard label: 3264 IMDG packing group: EmS: Limited quantity: II F-A, S-B 1 L Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Other applicable information (marine transport) Special provisions: 274 E2 Air transport UN/ID number: ICAO/IATA-DGR: Hazard label: 3264 ICAO packing group: Limited quantity Passenger: II 0.5 L IATA-packing instructions - Passenger: IATA-max. quantity - Passenger: IATA-packing instructions - Cargo: 0 1 L 12
Page 7 of IATA-max. quantity - Cargo: Description of the goods CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. Other applicable information (air transport) E2 Y0 Special provisions: A3 15. Regulatory information 30 L Labelling Danger symbols: T - Toxic; N - Dangerous for the environment T - Toxic N - Dangerous for the environment Hazardous components which must be listed on the label nickel bis(dihydrogen phosphate) R phrases 49 May cause cancer by inhalation. 36/3 Irritating to eyes and skin. 42/43 May cause sensitization by inhalation and skin contact. 4/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S phrases 53 Avoid exposure - obtain special instructions before use. 24 Avoid contact with skin. 37 Wear suitable gloves. 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Special labelling for certain preparations Restricted to professional users. GHS labelling Signal word: Pictograms: Danger exclamation mark; health hazard; environment Hazard statements H290 H301 H319 H315 H317 H350 May be corrosive to metals. Toxic if swallowed. Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. May cause cancer by swallowing.
Page of H360D H372 H410 May damage the unborn child. Causes damage to organs through prolonged or repeated exposure. Very toxic to aquatic life with long lasting effects. Precautionary statements P260 Do not breathe dust/fume/gas/mist/vapours/spray. P21 Use personal protective equipment as required. P314 Get medical advice/attention if you feel unwell. P273 Avoid release to the environment. P201 Obtain special instructions before use. National regulatory information Water contaminating class (D): 16. Other information 3 - highly water contaminating Full text of R-phrases referred to under sections 2 and 3 34 Causes burns. 36/3 Irritating to eyes and skin. 42/43 May cause sensitization by inhalation and skin contact. 4/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. 49 May cause cancer by inhalation. 50 Very toxic to aquatic organisms. 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 53 May cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3 H290 May be corrosive to metals. H301 Toxic if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350 May cause cancer by swallowing. H350i May cause cancer by inhalation. H360D May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. Further Information The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material. (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety data sheet.)