Product Name: Product Number: Product Use: Manufacturer/Supplier: MATERIAL SAFETY DATA SHEET Section 1: PRODUCT AND COMPANY IDENTIFICATION 4700C Cleaner. NAPA P. O. Box 421268, Indianapolis IN, 46241 Phone Number: (888) 827-NAPA (6272) Emergency Phone: CHEMTREC (800) 424-9300 Date of Preparation: MAY 1, 2012 EMERGENCY OVERVIEW WARNING Section 2: HAZARDS IDENTIFICATION HARMFUL BY INHALATION. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. CONTENTS UNDER PRESSURE. CONTAINER MAY EXPLODE IF HEATED. HARMFUL: MAY CAUSE LUNG DAMAGE IF SWALLOWED. Potential Health Effects: See Section 11 for more information. Likely Routes of Exposure: Skin contact, skin absorption, eye contact, inhalation and ingestion. Eye: Skin: Ingestion: Inhalation: May irritate eyes. May irritate skin. Not a normal route of exposure. Harmful: may cause lung damage if swallowed. May cause stomach distress, nausea or vomiting. May cause respiratory tract irritation. Aspiration of material into lungs can cause chemical pneumonitis. Chronic Effects: Hazardous by WHMIS criteria. Repeated exposure may cause skin dryness or cracking. Signs and Symptoms: Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Medical Conditions Aggravated By Exposure: Asthma. Allergies. Target Organs: Eyes, skin, respiratory system, gastrointestinal tract. Potential Environmental Effects: This product is not expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. See Section 12 for more information. Section 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS # Wt. % Perchloroethylene 127-18-4 60-100 Carbon dioxide 124-38-9 1-5 Page 1 of 6
Eye Contact: MATERIAL SAFETY DATA SHEET Section 4: FIRST AID MEASURES Flush with cool water. Remove contact lenses, if applicable, and continue flushing. Obtain medical attention if irritation persists. Skin Contact: After contact with skin, wash immediately with plenty of water. Remove and wash contaminated clothing before re-use. If irritation persists, get medical attention. Inhalation: Ingestion: If breathed in, move person into fresh air. If symptoms persist, obtain medical attention. If breathing has stopped, trained personnel should administer CPR immediately. If swallowed, call a Poison Control Centre or doctor immediately. DO NOT induce vomiting. If swallowed, rinse mouth with water (only if the person is conscious). General Advice: In case of accident or if you feel unwell, seek medical advice immediately (show the label or MSDS where possible). Note to Physicians: Symptoms may be delayed. Section 5: FIRE FIGHTING MEASURES Flammability: Not flammable by WHMIS criteria. Means of Extinction: Suitable Extinguishing Media: Powder, water spray, foam, carbon dioxide. Unsuitable Extinguishing Media: Products of Combustion: Oxides of carbon. Oxides of chlorine. Oxides of phosgene. Explosion Data: Sensitivity to Mechanical Impact: Sensitivity to Static Discharge: Protection of Firefighters: Pressurized container may explode when exposed to heat or flame. In case of fire and/or explosion do not breathe fumes. Firefighters should wear full protective clothing including self contained breathing apparatus. Section 6: ACCIDENTAL RELEASE MEASURES Personal Precautions: Use personal protection recommended in Section 8. Isolate area. Remove sources of ignition. Keep unnecessary personnel away. Ruptured cylinders may rocket. Environmental Precautions: Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Prevent entry into waterways, sewers, basements or confined areas. Methods for Containment: Prevent further leakage or spillage if safe to do so. Use sand, perlite or vermiculite as an absorbent for large spills of this material. Methods for Clean-Up: Sweep up or gather material and place in appropriate container for disposal. Allow gas to dissipate into the atmosphere. Other Information: Page 2 of 6
MATERIAL SAFETY DATA SHEET Section 7: HANDLING AND STORAGE Handling: Keep away from sources of ignition. No smoking. Avoid contact with skin and eyes. Do not swallow. Do not breathe gas/fumes/vapor/spray. Use only in well-ventilated areas. Handle and open container with care. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. Storage: Keep out of the reach of children. Do not store at temperatures above 49 C. Keep away from food, drink and animal feedingstuffs. Exposure Guidelines Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Limits Ingredient OSHA-PEL ACGIH-TLV Perchloroethylene 25 ppm 25 ppm Carbon dioxide 5000 ppm 5000 ppm Engineering Controls: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Personal Protective Equipment: Eye/Face Protection: Wear safety glasses with side shields. Hand Protection: Wear suitable gloves. Skin and Body Protection: Wear suitable protective clothing. Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations: Handle in accordance with good industrial hygiene and safety practice. Section 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Color: Odour: Odour Threshold: Physical State: ph: Clear. Colorless. Sweet. Gas/Pressurized Liquid. Viscosity: Water thin. Freezing Point: Boiling Point: 121 C Flash Point: Evaporation Rate: Lower Flammability Limit: Upper Flammability Limit: Page 3 of 6
MATERIAL SAFETY DATA SHEET Vapor Pressure: 13 mm/hg @ 20 C Vapor Density: ~ 4.1 Specific Gravity: 1.62 @ 25 C (H2O = 1) Solubility in Water: Coefficient of Water/Oil Distribution: Auto-ignition Temperature: Percent Volatile, wt. %: VOC content, wt. %: Partial. Section 10: STABILITY AND REACTIVITY Stability: Stable under recommended storage conditions. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. Store away from heat. Conditions of Reactivity: Heat. Incompatible materials. Incompatible Materials: Acids. Bases. Oxidizers. Sulphuric acid. Nitric acid. Chlorine. Chloroform. Hazardous Decomposition Products: Oxides of carbon. Oxides of chlorine. Oxides of phosgene. Possibility of Hazardous Reactions: No dangerous reaction known under conditions of normal use. EFFECTS OF ACUTE EXPOSURE Component Analysis Section 11: TOXICOLOGY INFORMATION Ingredient LD50 (oral) LC50 Perchloroethylene 2629 mg/kg, rat 34.2 g/m 3 8hrs, rat Carbon dioxide Eye: Skin: Ingestion: May irritate eyes. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May irritate skin. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Not a normal route of exposure. Harmful: may cause lung damage if swallowed. May cause stomach distress, nausea or vomiting. Inhalation: May cause respiratory tract irritation. Aspiration of material into lungs can cause chemical pneumonitis. EFFECTS OF CHRONIC EXPOSURE Target Organs: Chronic Effects: Hazardous by WHMIS criteria. Carcinogenicity: Hazardous by WHMIS criteria. Ingredient Perchloroethylene Carbon dioxide * See Section 15 for more information. Chemical Listed as Carcinogen or Potential Carcinogen * G-A3, I-2A, N-2, CP65 Not listed. Page 4 of 6
MATERIAL SAFETY DATA SHEET Mutagenicity: Not hazardous by WHMIS criteria. Reproductive Effects: Not hazardous by WHMIS criteria. Developmental Effects: Teratogenicity: Not hazardous by WHMIS criteria. Embryotoxicity: Not hazardous by WHMIS criteria. Respiratory Sensitization: Not hazardous by WHMIS criteria. Skin Sensitization: Not hazardous by WHMIS criteria. Toxicologically Synergistic Materials: Section 12: ECOLOGICAL INFORMATION Ecotoxicity: This product is not expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. Persistence / Degradability: Bioaccumulation / Accumulation: Mobility in Environment: Section 13: DISPOSAL CONSIDERATIONS Disposal Instructions: This material and its container must be disposed of in a safe way. Dispose in accordance with all applicable regulations. Section 14: TRANSPORTATION INFORMATION TDG Classification Limited Quantity Section 15: REGULATORY INFORMATION Federal Regulations Canadian: This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Global Inventories Ingredient Perchloroethylene Carbon dioxide HMIS - Hazardous Materials Identification System Health - 2 Flammability - 0 Physical Hazard - 2 NFPA - National Fire Protection Association: Health - 2 Fire - 0 Reactivity - 0 Hazard Rating: 0 = minimal, 1 = slight, 2 = moderate, 3 = severe, 4 = extreme Canada DSL/NDSL DSL DSL Page 5 of 6
WHMIS Classification(s): Class A - Compressed Gas Class D1 B - Toxic Material Class D2A - Carcinogenicity Class D2B - Chronic Toxic Effects Class D2B - Skin/Eye Irritant WHMIS Hazard Symbols: MATERIAL SAFETY DATA SHEET SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: OSHA (O) Occupational Safety and Health Administration. ACGIH (G) American Conference of Governmental Industrial Hygienists. A1 - Confirmed human carcinogen. A2 - Suspected human carcinogen. A3 - Animal carcinogen. A4 - Not classifiable as a human carcinogen. A5 - Not suspected as a human carcinogen. IARC (I) NTP (N) International Agency for Research on Cancer. 1 - The agent (mixture) is carcinogenic to humans. 2A - The agent (mixture) is probably carcinogenic to humans; there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. 2B - The agent (mixture) is possibly carcinogenic to humans; there is limited evidence of carcinogenicity in humans in the absence of sufficient evidence of carcinogenicity in experimental animals. 3 - The agent (mixture, exposure circumstance) is not classifiable as to its carcinogenicity to humans. 4 - The agent (mixture, exposure circumstance) is probably not carcinogenic to humans. National Toxicology Program. 1 - Known to be carcinogens. 2 - Reasonably anticipated to be carcinogens. Section 16: OTHER INFORMATION Disclaimer: The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user s responsibility to satisfy oneself as to the suitability and completeness of this information for the user s own particular use. Expiry Date: April 30, 2015 Prepared by: Kleeen-Flo Tumbler Ind. Ltd. Phone: 905 793-4311 Page 6 of 6