Trend Presentation 2008: SUN CARE Ver. 1.1 Since 1978 Sun Care with elegant feel and transparency like skin care For more information, please visit our home page: www.sunjinchem.com or email: sales@sunjinchem.co.kr or call office tel: 82-31-494-6322(300) or call mobile: 82-11-9920-1454 2008.7.1 CHEMICAL CO LTD Micro Beads, Nano Materials Surfactants For Cosmetics, Films, Paints, Plastics
EU regulation about UVA protection EU Commission Recommendation of 22 September 2006 on the efficacy of sunscreen products and the claims made relating thereto UVB Protection UVA Protection Critical Wavelength Sun Protection Factor minimum 6. Only 8 defined SPF values allowed Level of UVA protection (measured by in vivo or in vitro methods) at least 1/3 of labelled SPF. (UVA label can be used to highlight achievement of protection level) Additional criteria, minimum of 370nm to ensure broad band protection All products need to comply by 2009, at which point it is expected to be treated as a law. Products that do not comply with these requirements will not be regarded as Sunscreen Products Page 1
Page 2 Relative UVA parameters
Page 3 Relative UVA parameters
Page 4 Remarkable Sun Care Products in the market Water in Oil Oil in Water SPF50 PA+++ SPF50 PA+++ SPF40 PA+++ SPF50 PA+++ SPF50 PA+++
Page 5 Evaluation: SPF/PA by in vitro All data hereafter measured at the same date in February, 2008 by the same operator at the same sample preparation condition to have the correct comparison SPF/PA of the samples
Page 6 Evaluation: Transparency 12.5 μm draw down With applicator Measure transparency With color meter NIPPON DENSHOKU COLOR METER ZE 2000 W: White Index Higher White index means less transparency
SHISEIDO Anessa SPF50 PA+++ SPF 33.4, Boots Star Rating 3 Critical Wavelength 370.3 White Index=24.1 :Very Transparent Active Ingredients 1. Ethylhexyl methoxycinnamate 2. Octocrylene 3. Zinc oxide 4. BMDBM 5. Ethylhexyl TRIAZONE W/O SPF 50 PA+++ SHISEIDO Anessa W*=24.1 W*: White Index Page 7
Biotherm Homme SPF50, PA+++ SPF 38.7 Boots Star Rating 3 Critical Wavelength 376.8 White Index=25.7 Very Transparent O/W SPF 50 PA+++ Active Ingredients Biotherm Homme 1. Terephthalylidene dicamphorsulfonic Acid 2. Ethylhexyl methoxycinnamate 3. Drometrizole trisiloxane 4. Titanium dioxide 5. Benzophenone-3 W=25.7 6. Phenylbenzimidazole sulfonic Acid Page 8
THE FACE SHOP(KOREAN) Active White SPF50, PA+++ SPF 39.8 Boots Star Rating 2 Critical Wavelength 374.5 White Index=32.4 A bit White O/W SPF 50 PA+++ 더페이스샵 Active White Active Ingredients 1. Ethylhexyl methoxycinnamate 2. Ethylhexyl Salicylate 3. Methylbenzylidene camphor 4. Isoamyl p-methoxycinnamate W=32.4 5. BMDBM 6. Titanium dioxide Page 9
L`OREAL Solar Expertise SPF40, PA+++ SPF 36.1 Boots Star Rating 5 Critical Wavelength 383.4 White Index=34.6 White O/W SPF 40 PA+++ L`OREAL Solar Expertise Active Ingredients 1. Octocrylene 2. BMDBM 3. Titanium dioxide 4. Drometrizole trisiloxane W=34.6 5. Terephthalylidene dicamphorsulfonic Acid Page 10
Biotherm Sun50, SPF50, PA+++ SPF 39.8 Boots Star Rating 5 Critical Wavelength 385.1 White Index=40.0 Very White O/W SPF 50 PA+++ Biotherm SUN50 Active Ingredients 1. Octocrylene 2. Titanium dioxide 3. Drometrizole trisiloxane 4. BMDBM W=40.0 5. Terephthalylidene dicamphorsulfonic Acid Page 11
Page 12 Trend Presentation High SPF, PA but should be transparent HOW?
Page 13 KEY UV FILTERS 1. Hybrid ABOMC: Chemical UV filters inside PMMA bead Grade Function UV FILTER Composition MATRIX Hybrid ABOMC UVA + UVB BMDBM (Avo Benzone) 31% PMMA 62% 2-Ethylhexyl 4-methoxycinnamate 7% 2. SUNSIL T in 40: TiO2 inside Silica bead Grade Descriptions Crystal size of TiO2 Size of silica bead ( μm ) SUNSIL-T in 40 TiO2 30~40% & Silica 60~70% 12 nm 2~7 3. SUNZNO-NAS: Alkyl silane treated ZnO Grade Descriptions Surface treatment Crystal size(nm) SUNZNO-NAS Zinc Oxide Alkyl Silane 40 4. Z50AQX: Alkyl silane treated ZnO inside water Grade SUNCLEAR Z50AQX ZNO crystal size /content/surface treatment 40nm / 45~50% / alkyl silane Media water Dispersant Disodium Sulfosuccinamate
W/O SPF 50 PA+++ SUN Cream Formulation Transparent Sun Cream, W/O type - 080111 Hybrid ABOMC provides excellent transparency and High protection of UVA No Ingredients % INCI Name A B C Water 34.1 Aqua Glycerin 98% 4.0 Glycerin 1,3 BG 2.0 Butylene glycol NaCl 0.5 Sodium chloride Mehtyl paraben 0.2 Methyl paraben Phenoxy ethanol 0.3 Phenoxy ethanol KF-995 15.5 Cyclomethicone Tegosoft DEC 5.0 Diethylhexyl carbonate Finsolv-TN 4.0 C12-15 Alkyl benzoate Abil EM-90 2.0 Cetyl PEG/PPG-10/1 dimethicone Normcort HK-G 1.0 Clyceryl behenate/eicosadioate Bentone 38 1.0 Quaternium-18 hectorite SUNGEL D20 4.0 Arlacel 83 0.5 Sorbitan sesquioleate Dimethicone vinyldimethicone crosspolymer and dimethicone Parsol MCX 7.0 Ethylhexyl methoxycinnamate Parsol EHS 3.0 Ethylhexyl Salicylate Parsol 5000 2.0 4-methylbenzylidene camphor Hybrid ABOMC50_31_7 6.0 PMMA/Avobenzone/Ethylhexyl methoxycinnamate SUNSIL-Tin40 5.0 Silica & Titanium dioxide SUNZNO-NAS 3.5 Zinc oxide & alkyl silane Tocopheryl acetate 0.1 Tocopheryl acetate 21 Fragrance 0.3 Fragrance Page 14
W/O SPF 50 PA+++ SUN Cream SPF 39.3 Boots Star Rating 3 Critical Wavelength 378.7 White Index=19.7 Truly Transparent W/O SPF 50 PA+++ Active Ingredients 1. Ethylhexyl methoxycinnamate 2. Hybrid ABOMC50_31_7 (BMDBM + Ethylhexyl methoxycinnamate) 3. Ethylhexyl Salicylate 4. Methylbenzylidene camphor W=19.7 5. SUNSIL-Tin40 (Silica & Titanium dioxide) 6. SUNZNO-NAS (Zinc oxide & alkyl silane) Page 15
Summary: Water in Oil W/O SPF 50 PA+++ SPF 39.3 Boots Star Rating 3 C.W. 378.7 White Index=19.7 Truly Transparent W=19.7 W/O SPF 50 PA+++ SHISEIDO Anessa SPF 33.4, Boots Star Rating 3 C.W. 370.3 White Index=24.1 :Very Transparent W=24.1 Page 16
O/W SPF 50 PA+++ SUN Cream Formulation Transparent Sun Cream, O/W type - 080213 Hybrid ABOMC provides excellent transparency and High protection of UVA Procedure 1. Mix all materials in Phase A at 75 2. Mix all materials in Phase B at 75 3. Slowly add Phase A into Phase B with homogenizer(2500 RPM) 4. Cool down 5. Add phase C into 4 with homogenizer(2500 rpm) 6. Add phase D into 5 4 with homogenizer(2500 rpm) 7. Cool down No Ingredients Contents INCI Name Cetiol LC 1.5 Coco-Caprylate/Caprate TSF 405 3 Cyclomethicone Salacos 99 1 Isononyl Isononanoate KALCOHL 6870 2 Cetyl alcohol In vivo proven formula Aracel 165 2 Glyceryl monostearate/peg-100 Stearate A Tween 60 1.7 Polysorbate 60 Emersol 7036NF 1 Stearic acid Parsol MCX 6.5 Ethylhexyl methoxycinnamate Parsol EHS 4 Ethylhexyl Salicylate Parsol 5000 3 4-methylbenzylidene camphor Vegewax 70 1 dhydrogenated Vegetable oil PP 0.1 Propyl Paraben 1,3-BG 6 Butylene glycol 5% Veegum 25 Magnesium aluminum silicate B Water 20 WATER DC2501 WAX 1 Dimethicone copoyol MP 0.1 Methyl paraben Hybrid ABOMC50_31_7 9 PMMA/Avobenzone/Ethylhexyl methoxycinnamate C SUNSIL Tin 40 5 Silica & Titanium dioxide Sunclear Z50AQS 7 zinc oxide Sunclear T40AQS 0 Titanium dioxide D perfume 0.1 Perfume extract 0 Page 17
O/W SPF 50 PA+++ SUN Cream SPF 37.9 Boots Star Rating 3 Critical Wavelength 380.1 White Index=29.8 Transparent O/W SPF 50 PA+++ Active Ingredients 1. Ethylhexyl methoxycinnamate 2. Hybrid ABOMC50_31_7 (BMDBM + Ethylhexyl methoxycinnamate) 3. Ethylhexyl Salicylate 4. Methylbenzylidene camphor W=29.8 5. SUNSIL-Tin40 (Silica & Titanium dioxide) 6. SUNCLEAR-Z50AQS (Zinc oxide) Page 18
Summary: Oil in Water SPF 38.7 Boots Star Rating 3 C.W. 376.8 O/W SPF50 PA+++ Biotherm Homme SPF 37.9 Boots Star Rating 3 C.W. 380.1 O/W SPF 50 PA+++ SPF 39.8 Boots Star Rating 2 C.W. 374.5 O/W SPF 50 PA+++ THE FACE SHOP Active White W=25.7 O/W SPF 40 PA+++ L`oreal Solar Expertise W=29.8 O/W SPF 50 PA+++ Biotherm SUN50 W=32.4 W=34.6 W=40.0 SPF 36.1 SPF 39.8 Boots Star Rating 5 Boots Star Rating 5 C.W.383.4 C.W.385.1 Page 19
W/O SUN LOTION: SPF 50, PA+++ Formulation Transparent Sun Lotion, W/O type - 080707 Hybrid ABOMC provides excellent transparency and High protection of UVA ABOMC L/N : 08074001(6%) No Ingredients % INCI Name Water 34.1 Aqua Glycerin 98% 4.0 Glycerin A 1,3 BG 2.0 Butylene glycol NaCl 0.5 Sodium chloride Phenoxy ethanol 0.5 Phenoxy ethanol KF-995 18.7 Cyclomethicone Tegosoft DEC 5.0 Diethylhexyl carbonate Finsolv-TN 4.0 C12-15 Alkyl benzoate Abil EM-90 2.0 Cetyl PEG/PPG-10/1 dimethicone B Bentone 38 0.8 Quaternium-18 hectorite SUNGEL D20 3.0 Dimethicone vinyldimethicone crosspolymer and dimethicone Arlacel 83 0.5 Sorbitan sesquioleate Procedure 1) Mix all materials in Phase A at 75 2) Mix all materials in Phase B at 75 3) Slowly add Phase A into Phase B with homogenizer(2500 RPM) 4) Cool down 5) Add phase C into 4 with homogenizer(2500rpm) 6) Add phase D into 5 4 with homogenizer (2500rpm) C Parsol MCX 7.0 Ethylhexyl methoxycinnamate Parsol EHS 5.0 Ethylhexyl Salicylate Hybrid ABOMC50_31_7 6.0 PMMA/Avobenzone/Ethylhexyl methoxycinnamate SUNSIL-Tin40 3.0 Silica & Titanium dioxide SUNZNO-NAS 3.5 Zinc oxide & alkyl silane Tocopheryl acetate 0.1 Tocopheryl acetate D Fragrance 0.3 Fragrance Page 20
W/O SPF50, PA+++ : SPF/PA Value Test Result Active Ingredients 1. Ethylhexyl methoxycinnamate : 7% 2. Ethylhexyl Salicylate : 5% 3. Hybrid ABOMC : 6% 4.Tin 40 : 3% 5. ZnO-NAS : 3.5% SPF 31.88 UVA:UVB=0.956:1 = 1: 1.05 Boots Star Rating 5 Critical Wavelength 383.4 Page 21
W/O SUN LOTION: SPF 35 PA++ Formulation Transparent Sun Lotion, W/O type 080707-2 Hybrid ABOMC provides excellent transparency and High protection of UVA ABOMC L/N : 08074001 (3%) No Ingredients % INCI Name Water 36.1 Aqua Glycerin 98% 4.0 Glycerin A 1,3 BG 2.0 Butylene glycol NaCl 0.5 Sodium chloride Phenoxy ethanol 0.5 Phenoxy ethanol KF-995 19.7 Cyclomethicone Tegosoft DEC 5.0 Diethylhexyl carbonate Finsolv-TN 4.0 C12-15 Alkyl benzoate Abil EM-90 2.0 Cetyl PEG/PPG-10/1 dimethicone B Bentone 38 0.8 Quaternium-18 hectorite SUNGEL D20 3.0 Dimethicone vinyldimethicone crosspolymer and dimethicone Arlacel 83 0.5 Sorbitan sesquioleate Procedure 1) Mix all materials in Phase A at 75 2) Mix all materials in Phase B at 75 3) Slowly add Phase A into Phase B with homogenizer(2500 RPM) 4) Cool down 5) Add phase C into 4 with homogenizer(2500rpm) 6) Add phase D into 5 4 with homogenizer (2500rpm) C Parsol MCX 7.0 Ethylhexyl methoxycinnamate Parsol EHS 5.0 Ethylhexyl Salicylate Hybrid ABOMC50_31_7 3.0 PMMA/Avobenzone/Ethylhexyl methoxycinnamate SUNSIL-Tin40 3.0 Silica & Titanium dioxide SUNZNO-NAS 3.5 Zinc oxide & alkyl silane Tocopheryl acetate 0.1 Tocopheryl acetate D Fragrance 0.3 Fragrance Page 22
W/O SPF 35 PA++ : SPF/PA Value Test Result Active Ingredients 1. Ethylhexyl methoxycinnamate : 7% 2. Ethylhexyl Salicylate : 5% 3. Hybrid ABOMC : 3% 4.Tin 40 : 3% 5. ZnO-NAS : 3.5% SPF 23.2 UVA:UVB=0.834:1 = 1: 19 Boots Star Rating 4 Critical Wavelength 380.1 Page 23
O/W SUN LOTION: SPF 50 PA+++ Formulation Transparent Sun Lotion, O/W type 080707-3 Hybrid ABOMC provides excellent transparency and High protection of UVA ABOMC L/N : 08074001 (6%) Procedure 1) Mix all materials in Phase A at 75 2) Mix all materials in Phase B at 75 3) Slowly add Phase A into Phase B with homogenizer(2500 RPM) 4) Cool down 5) Add phase C into 4 with homogenizer(2500rpm) No Ingredients Contents INCI Name Cetiol LC 1.5 Coco-Caprylate/Caprate TSF 405 4 Cyclomethicone Salacos 99 2 Isononyl Isononanoate KALCOHL 6870 1 Cetyl alcohol Aracel 165 2 Glyceryl monostearate/peg-100 Stearate A Tween 60 1 Polysorbate 60 Emersol 7036NF 1 Stearic acid Parsol MCX 7 Ethylhexyl methoxycinnamate Parsol EHS 5 Ethylhexyl Salicylate Vegewax 70 0.5 dhydrogenated Vegetable oil PP 0.1 Propyl Paraben 1,3-BG 6 Butylene glycol 5% Veegum 18 Magnesium aluminum silicate B Water 33.7 WATER DC2501 WAX 1 Dimethicone copoyol Phenoxy Ethanol 0.1 Methyl paraben Hybrid ABOMC 6 PMMA/Avobenzone/Ethylhexyl methoxycinnamate C SUNCLEAR-Z50AQX 7 zinc oxide Sunsil-Tin40 3 Titanium Dioxide perfume 0.1 Perfume Page 24
O/W SUN LOTION: SPF 50 PA+++ Active Ingredients 1. Ethylhexyl methoxycinnamate : 7% 2. Ethylhexyl Salicylate : 5% 3. Hybrid ABOMC : 6% 4.Tin 40 : 3% 5. SUNClear-Z50AQX : 7% SPF 32.26 UVA:UVB=0.91:1 = 1: 1.09 Boots Star Rating 5 Critical Wavelength 382.7 Page 25
O/W SUN LOTION: SPF 35 PA++ Formulation Transparent Sun Lotion, O/W type 080707-4 Hybrid ABOMC provides excellent transparency and High protection of UVA ABOMC L/N : 08074001 (3%) Procedure 1) Mix all materials in Phase A at 75 2) Mix all materials in Phase B at 75 3) Slowly add Phase A into Phase B with homogenizer(2500 RPM) 4) Cool down 5) Add phase C into 4 with homogenizer(2500rpm) No Ingredients Contents INCI Name Cetiol LC 1.5 Coco-Caprylate/Caprate TSF 405 6 Cyclomethicone Salacos 99 2 Isononyl Isononanoate KALCOHL 6870 1 Cetyl alcohol Aracel 165 2 Glyceryl monostearate/peg-100 Stearate A Tween 60 1 Polysorbate 60 Emersol 7036NF 1 Stearic acid Parsol MCX 7 Ethylhexyl methoxycinnamate Parsol EHS 5 Ethylhexyl Salicylate Vegewax 70 0.5 dhydrogenated Vegetable oil PP 0.1 Propyl Paraben 1,3-BG 6 Butylene glycol 5% Veegum 18 Magnesium aluminum silicate B Water 34.7 WATER DC2501 WAX 1 Dimethicone copoyol Phenoxy Ethanol 0.1 Methyl paraben Hybrid ABOMC 3 PMMA/Avobenzone/Ethylhexyl methoxycinnamate C SUNCLEAR-Z50AQX 7 zinc oxide Sunsil-Tin40 3 Titanium Dioxide perfume 0.1 Perfume Page 26
O/W SPF 35 PA++ : SPF/PA Value Test Result Active Ingredients 1. Ethylhexyl methoxycinnamate : 7% 2. Ethylhexyl Salicylate : 5% 3. Hybrid ABOMC : 3% 4.Tin 40 : 3% 5. SUNClear-Z50AQX : 7% SPF 25.8 UVA:UVB=0.8:1 = 1: 1.25 Boots Star Rating 3 Critical Wavelength 380 Page 27