Table 1 Fuel Oil UST Closure Analytical s St. Ann Center for Intergenerational Care Sigma Project No. 14643 DRAFT Sample Location: S-1 (north base) S-2 (south base) S-3 (east wall) S-4 (south wall) Sample Depth (feet bgs): 10 10 8 8 8 8 Groundwater Non-Industrial Industrial Sample Collection Date: 1/28/15 1/28/15 1/28/15 1/28/15 1/28/15 1/28/15 Pathway Direct Contact Direct Contact Depth to Groundwater (feet bgs): 9+/- 9+/- 9+/- 9+/- 9+/- 9+/- RCL 4 RCL 5 RCL 6 Unsaturated/Smear Zone (U) or Saturated (S): S S U U U S Vapor Monitor ppm 0.0 0.0 0.0 0.0 0.0 0.0 NS NS NS PVOCs & Detected VOCs Benzene µg/kg <25 <25 <25 <9.2 <9.2 <9.2 5.1 1,490 7,410 Ethylbenzene µg/kg <25 <25 <25 <10 <10 <10 1,570 7,470 37,000 Methyl-tert-butyl-ether µg/kg <25 <25 <25 <30 <30 <30 27 59,400 293,000 Naphthalene µg/kg 4,500 540 <25 <110 <110 <110 658.2 5,150 26,000 Toluene µg/kg <25 <25 <25 <20 <20 <20 1,107.2 818,000 818,000 1,2,4-Trimethylbenzene µg/kg 182 <25 <25 <26 <26 <26 89,800 219,000 1,382.1 1,3,5-Trimethylbenzene µg/kg 60 29.6 J <25 <26 <26 <26 182,000 182,000 Xylenes (total) µg/kg 294 J <75 <75 <99 <99 <99 3,940 258,000 258,000 Cumulative DC RCL Exceeded (Y/N)? N N N N N N --- --- --- Notes: 1. Unsaturated/smear zone versus satured soil conditions based on: (1) measured water levels in adjacent/nearby monitoring wells, (2) soil moisture conditions recorded on soil boring logs, and/or (3) soil moisture contents reported on laboratory analytical reports. 2. Analytical units: µg/kg = micrograms per kilogram (equivalent to parts per billion, ppb) mg/kg = milligrams per kilogram (equivalent to parts per million, ppm) 3. NA = not analyzed 4. Groundwater Pathway RCL = Residual Contaminant Level for protection of groundwater as presented on the WDNR's RCL Spreadsheet (dated June 2014) referenced in WDNR guidance 5. Non-Industrial Direct Contact RCL = Residual Contaminant Level for protection of direct contact at a non-industrial property as presented on the WDNR's RCL Spreadsheet (dated June 2014) 6. Industrial Direct Contact RCL = Residual Contaminant Level for protection of direct contact at an industrial property as presented on the WDNR's RCL Spreadsheet (dated June 2014) with 7. NS = no standard established 8. Laboratory flags: "J" = Analyte detected between Limit of Detection and Limit of Quantitation 9. Exceedances: BOLD = Concentration exceeds Groundwater Pathway RCL (unsaturated soil samples only) [ ] = Concentration exceeds Non-Industrial OR Industrial Direct Contact RCL (unsaturated soil samples only) S-5 (north wall) S-6 (west wall)
DRAFT SITE BOUNDARY PROPOSED BUILDING 05/23/14 Project : 14643 Directory: Figures Filename: 14643_SPM.pdf Created By: JVW Date: 0 100 ft. FORMER 550 gal. FUEL OIL UST REMEDIAL EXCAVATION AREA FORMER 1,000 gal. WASTE OIL UST SGP-5 SGP-1 SITE PLAN MAP SGP-2 SGP-3 SGP-4 PARK WEST D REDEVELOPMENT NORTH 24th STREET/WEST NORTH AVENUE MILWAUKEE, WISCONSIN FIGURE 1
Synergy Environmental Lab, INC. 1990 Prospect Ct., Appleton, WI 54914 *P 920-830-2455 * F 920-733-0631 MARY TROTTA THE SIGMA GROUP, INC. 1300 W. CANAL STREET MILWAUKEE, WI 53233 Report Date 30-Apr-15 Project Name ST. ANN CENTER 14643-002 5028829A SAE-1 4/23/2015 E28829 Solids Percent 83.4 % 1 5021 4/27/2015 LPA 1 Acenaphthene 0.032 ''J'' mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Acenaphthylene 0.0285 ''J'' mg/kg 0.0198 0.062 1 M8270C 4/28/2015 4/30/2015 MDK 1 Anthracene 0.136 mg/kg 0.0171 0.054 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)anthracene 0.52 mg/kg 0.0191 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)pyrene 0.55 mg/kg 0.0143 0.045 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(b)fluoranthene 0.86 mg/kg 0.019 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(g,h,i)perylene 0.53 mg/kg 0.02 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(k)fluoranthene 0.264 mg/kg 0.0174 0.055 1 M8270C 4/28/2015 4/30/2015 MDK 1 Chrysene 0.54 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Dibenzo(a,h)anthracene 0.096 mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluoranthene 1.23 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluorene 0.036 ''J'' mg/kg 0.0184 0.058 1 M8270C 4/28/2015 4/30/2015 MDK 1 Indeno(1,2,3-cd)pyrene 0.43 mg/kg 0.0165 0.052 1 M8270C 4/28/2015 4/30/2015 MDK 1 1-Methyl naphthalene < 0.0205 mg/kg 0.0205 0.065 1 M8270C 4/28/2015 4/30/2015 MDK 1 2-Methyl naphthalene < 0.0199 mg/kg 0.0199 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Naphthalene < 0.0203 mg/kg 0.0203 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Phenanthrene 0.46 mg/kg 0.0198 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Pyrene 1.08 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 VOC's Benzene < 0.016 mg/kg 0.016 0.049 1 8260B Bromobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Bromodichloromethane < 0.015 mg/kg 0.015 0.048 1 8260B Bromoform < 0.023 mg/kg 0.023 0.073 1 8260B tert-butylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B sec-butylbenzene < 0.036 mg/kg 0.036 0.11 1 8260B n-butylbenzene < 0.086 mg/kg 0.086 0.27 1 8260B Carbon Tetrachloride < 0.021 mg/kg 0.021 0.067 1 8260B Chlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B WI DNR Lab Certification # 445037560 Page 1 of 6
ST. ANN CENTER 14643-002 E28829 5028829A SAE-1 4/23/2015 Chloroethane < 0.045 mg/kg 0.045 0.14 1 8260B Chloroform < 0.026 mg/kg 0.026 0.081 1 8260B Chloromethane < 0.25 mg/kg 0.25 0.78 1 8260B 2-Chlorotoluene < 0.029 mg/kg 0.029 0.093 1 8260B 4-Chlorotoluene < 0.032 mg/kg 0.032 0.1 1 8260B 1,2-Dibromo-3-chloropropane < 0.078 mg/kg 0.078 0.25 1 8260B Dibromochloromethane < 0.031 mg/kg 0.031 0.098 1 8260B 1,4-Dichlorobenzene < 0.03 mg/kg 0.03 0.096 1 8260B 1,3-Dichlorobenzene < 0.03 mg/kg 0.03 0.097 1 8260B 1,2-Dichlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Dichlorodifluoromethane < 0.043 mg/kg 0.043 0.14 1 8260B 1,2-Dichloroethane < 0.03 mg/kg 0.03 0.096 1 8260B 1,1-Dichloroethane < 0.025 mg/kg 0.025 0.079 1 8260B 1,1-Dichloroethene < 0.029 mg/kg 0.029 0.093 1 8260B 4/27/2015 CJR 2 7 cis-1,2-dichloroethene < 0.021 mg/kg 0.021 0.068 1 8260B trans-1,2-dichloroethene < 0.024 mg/kg 0.024 0.076 1 8260B 1,2-Dichloropropane < 0.025 mg/kg 0.025 0.078 1 8260B 2,2-Dichloropropane < 0.1 mg/kg 0.1 0.33 1 8260B 4/27/2015 CJR 8 1,3-Dichloropropane < 0.031 mg/kg 0.031 0.097 1 8260B Di-isopropyl ether < 0.012 mg/kg 0.012 0.04 1 8260B EDB (1,2-Dibromoethane) < 0.035 mg/kg 0.035 0.11 1 8260B Ethylbenzene < 0.027 mg/kg 0.027 0.086 1 8260B Hexachlorobutadiene < 0.11 mg/kg 0.11 0.36 1 8260B Isopropylbenzene < 0.037 mg/kg 0.037 0.12 1 8260B p-isopropyltoluene < 0.056 mg/kg 0.056 0.18 1 8260B Methylene chloride < 0.22 mg/kg 0.22 0.7 1 8260B Methyl tert-butyl ether (MTBE) < 0.025 mg/kg 0.025 0.078 1 8260B Naphthalene < 0.087 mg/kg 0.087 0.28 1 8260B n-propylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B 1,1,2,2-Tetrachloroethane < 0.013 mg/kg 0.013 0.04 1 8260B 1,1,1,2-Tetrachloroethane < 0.029 mg/kg 0.029 0.093 1 8260B Tetrachloroethene < 0.054 mg/kg 0.054 0.17 1 8260B Toluene < 0.031 mg/kg 0.031 0.099 1 8260B 1,2,4-Trichlorobenzene < 0.085 mg/kg 0.085 0.27 1 8260B 1,2,3-Trichlorobenzene < 0.12 mg/kg 0.12 0.38 1 8260B 1,1,1-Trichloroethane < 0.04 mg/kg 0.04 0.13 1 8260B 1,1,2-Trichloroethane < 0.033 mg/kg 0.033 0.11 1 8260B Trichloroethene (TCE) < 0.042 mg/kg 0.042 0.13 1 8260B Trichlorofluoromethane < 0.06 mg/kg 0.06 0.19 1 8260B 1,2,4-Trimethylbenzene < 0.078 mg/kg 0.078 0.25 1 8260B 1,3,5-Trimethylbenzene < 0.089 mg/kg 0.089 0.28 1 8260B Vinyl Chloride < 0.01 mg/kg 0.01 0.031 1 8260B m&p-xylene < 0.07 mg/kg 0.07 0.22 1 8260B o-xylene < 0.029 mg/kg 0.029 0.092 1 8260B SUR - 1,2-Dichloroethane-d4 88 Rec % 1 8260B SUR - 4-Bromofluorobenzene 98 Rec % 1 8260B SUR - Dibromofluoromethane 82 Rec % 1 8260B SUR - Toluene-d8 106 Rec % 1 8260B WI DNR Lab Certification # 445037560 Page 2 of 6
ST. ANN CENTER 14643-002 5028829B SAE-4 4/23/2015 E28829 Solids Percent 87.3 % 1 5021 4/27/2015 LPA 1 Acenaphthene 0.26 mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Acenaphthylene 0.034 ''J'' mg/kg 0.0198 0.062 1 M8270C 4/28/2015 4/30/2015 MDK 1 Anthracene 0.82 mg/kg 0.0171 0.054 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)anthracene 1.62 mg/kg 0.0191 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)pyrene 1.59 mg/kg 0.0143 0.045 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(b)fluoranthene 2.09 mg/kg 0.019 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(g,h,i)perylene 1.1 mg/kg 0.02 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(k)fluoranthene 0.70 mg/kg 0.0174 0.055 1 M8270C 4/28/2015 4/30/2015 MDK 1 Chrysene 1.4 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Dibenzo(a,h)anthracene 0.249 mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluoranthene 3.7 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluorene 0.37 mg/kg 0.0184 0.058 1 M8270C 4/28/2015 4/30/2015 MDK 1 Indeno(1,2,3-cd)pyrene 0.98 mg/kg 0.0165 0.052 1 M8270C 4/28/2015 4/30/2015 MDK 1 1-Methyl naphthalene 0.056 ''J'' mg/kg 0.0205 0.065 1 M8270C 4/28/2015 4/30/2015 MDK 1 2-Methyl naphthalene 0.073 mg/kg 0.0199 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Naphthalene 0.132 mg/kg 0.0203 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Phenanthrene 2.26 mg/kg 0.0198 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Pyrene 3.15 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 VOC's Benzene < 0.016 mg/kg 0.016 0.049 1 8260B Bromobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Bromodichloromethane < 0.015 mg/kg 0.015 0.048 1 8260B Bromoform < 0.023 mg/kg 0.023 0.073 1 8260B tert-butylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B sec-butylbenzene < 0.036 mg/kg 0.036 0.11 1 8260B n-butylbenzene < 0.086 mg/kg 0.086 0.27 1 8260B Carbon Tetrachloride < 0.021 mg/kg 0.021 0.067 1 8260B Chlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Chloroethane < 0.045 mg/kg 0.045 0.14 1 8260B Chloroform < 0.026 mg/kg 0.026 0.081 1 8260B Chloromethane < 0.25 mg/kg 0.25 0.78 1 8260B 2-Chlorotoluene < 0.029 mg/kg 0.029 0.093 1 8260B 4-Chlorotoluene < 0.032 mg/kg 0.032 0.1 1 8260B 1,2-Dibromo-3-chloropropane < 0.078 mg/kg 0.078 0.25 1 8260B Dibromochloromethane < 0.031 mg/kg 0.031 0.098 1 8260B 1,4-Dichlorobenzene < 0.03 mg/kg 0.03 0.096 1 8260B 1,3-Dichlorobenzene < 0.03 mg/kg 0.03 0.097 1 8260B 1,2-Dichlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Dichlorodifluoromethane < 0.043 mg/kg 0.043 0.14 1 8260B 1,2-Dichloroethane < 0.03 mg/kg 0.03 0.096 1 8260B 1,1-Dichloroethane < 0.025 mg/kg 0.025 0.079 1 8260B 1,1-Dichloroethene < 0.029 mg/kg 0.029 0.093 1 8260B 4/27/2015 CJR 2 7 cis-1,2-dichloroethene < 0.021 mg/kg 0.021 0.068 1 8260B trans-1,2-dichloroethene < 0.024 mg/kg 0.024 0.076 1 8260B 1,2-Dichloropropane < 0.025 mg/kg 0.025 0.078 1 8260B 2,2-Dichloropropane < 0.1 mg/kg 0.1 0.33 1 8260B 4/27/2015 CJR 8 1,3-Dichloropropane < 0.031 mg/kg 0.031 0.097 1 8260B Di-isopropyl ether < 0.012 mg/kg 0.012 0.04 1 8260B EDB (1,2-Dibromoethane) < 0.035 mg/kg 0.035 0.11 1 8260B Ethylbenzene < 0.027 mg/kg 0.027 0.086 1 8260B Hexachlorobutadiene < 0.11 mg/kg 0.11 0.36 1 8260B Isopropylbenzene < 0.037 mg/kg 0.037 0.12 1 8260B p-isopropyltoluene < 0.056 mg/kg 0.056 0.18 1 8260B WI DNR Lab Certification # 445037560 Page 3 of 6
ST. ANN CENTER 14643-002 E28829 5028829B SAE-4 4/23/2015 Methylene chloride < 0.22 mg/kg 0.22 0.7 1 8260B Methyl tert-butyl ether (MTBE) < 0.025 mg/kg 0.025 0.078 1 8260B Naphthalene < 0.087 mg/kg 0.087 0.28 1 8260B n-propylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B 1,1,2,2-Tetrachloroethane < 0.013 mg/kg 0.013 0.04 1 8260B 1,1,1,2-Tetrachloroethane < 0.029 mg/kg 0.029 0.093 1 8260B Tetrachloroethene < 0.054 mg/kg 0.054 0.17 1 8260B Toluene < 0.031 mg/kg 0.031 0.099 1 8260B 1,2,4-Trichlorobenzene < 0.085 mg/kg 0.085 0.27 1 8260B 1,2,3-Trichlorobenzene < 0.12 mg/kg 0.12 0.38 1 8260B 1,1,1-Trichloroethane < 0.04 mg/kg 0.04 0.13 1 8260B 1,1,2-Trichloroethane < 0.033 mg/kg 0.033 0.11 1 8260B Trichloroethene (TCE) < 0.042 mg/kg 0.042 0.13 1 8260B Trichlorofluoromethane < 0.06 mg/kg 0.06 0.19 1 8260B 1,2,4-Trimethylbenzene < 0.078 mg/kg 0.078 0.25 1 8260B 1,3,5-Trimethylbenzene < 0.089 mg/kg 0.089 0.28 1 8260B Vinyl Chloride < 0.01 mg/kg 0.01 0.031 1 8260B m&p-xylene < 0.07 mg/kg 0.07 0.22 1 8260B o-xylene < 0.029 mg/kg 0.029 0.092 1 8260B SUR - Toluene-d8 107 Rec % 1 8260B SUR - 1,2-Dichloroethane-d4 89 Rec % 1 8260B SUR - 4-Bromofluorobenzene 96 Rec % 1 8260B SUR - Dibromofluoromethane 82 Rec % 1 8260B WI DNR Lab Certification # 445037560 Page 4 of 6
ST. ANN CENTER 14643-002 5028829C SAE-10 4/23/2015 E28829 Solids Percent 94.0 % 1 5021 4/27/2015 LPA 1 Acenaphthene 0.33 mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Acenaphthylene 0.045 ''J'' mg/kg 0.0198 0.062 1 M8270C 4/28/2015 4/30/2015 MDK 1 Anthracene 1.09 mg/kg 0.0171 0.054 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)anthracene 2.02 mg/kg 0.0191 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(a)pyrene 1.81 mg/kg 0.0143 0.045 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(b)fluoranthene 2.4 mg/kg 0.019 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(g,h,i)perylene 1.14 mg/kg 0.02 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Benzo(k)fluoranthene 0.77 mg/kg 0.0174 0.055 1 M8270C 4/28/2015 4/30/2015 MDK 1 Chrysene 1.79 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Dibenzo(a,h)anthracene 0.299 mg/kg 0.0201 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluoranthene 4.7 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 Fluorene 0.45 mg/kg 0.0184 0.058 1 M8270C 4/28/2015 4/30/2015 MDK 1 Indeno(1,2,3-cd)pyrene 1.07 mg/kg 0.0165 0.052 1 M8270C 4/28/2015 4/30/2015 MDK 1 1-Methyl naphthalene 0.047 ''J'' mg/kg 0.0205 0.065 1 M8270C 4/28/2015 4/30/2015 MDK 1 2-Methyl naphthalene 0.055 ''J'' mg/kg 0.0199 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Naphthalene 0.069 mg/kg 0.0203 0.064 1 M8270C 4/28/2015 4/30/2015 MDK 1 Phenanthrene 2.78 mg/kg 0.0198 0.063 1 M8270C 4/28/2015 4/30/2015 MDK 1 Pyrene 3.8 mg/kg 0.0192 0.061 1 M8270C 4/28/2015 4/30/2015 MDK 1 VOC's Benzene < 0.016 mg/kg 0.016 0.049 1 8260B Bromobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Bromodichloromethane < 0.015 mg/kg 0.015 0.048 1 8260B Bromoform < 0.023 mg/kg 0.023 0.073 1 8260B tert-butylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B sec-butylbenzene < 0.036 mg/kg 0.036 0.11 1 8260B n-butylbenzene < 0.086 mg/kg 0.086 0.27 1 8260B Carbon Tetrachloride < 0.021 mg/kg 0.021 0.067 1 8260B Chlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Chloroethane < 0.045 mg/kg 0.045 0.14 1 8260B Chloroform < 0.026 mg/kg 0.026 0.081 1 8260B Chloromethane < 0.25 mg/kg 0.25 0.78 1 8260B 2-Chlorotoluene < 0.029 mg/kg 0.029 0.093 1 8260B 4-Chlorotoluene < 0.032 mg/kg 0.032 0.1 1 8260B 1,2-Dibromo-3-chloropropane < 0.078 mg/kg 0.078 0.25 1 8260B Dibromochloromethane < 0.031 mg/kg 0.031 0.098 1 8260B 1,4-Dichlorobenzene < 0.03 mg/kg 0.03 0.096 1 8260B 1,3-Dichlorobenzene < 0.03 mg/kg 0.03 0.097 1 8260B 1,2-Dichlorobenzene < 0.039 mg/kg 0.039 0.12 1 8260B Dichlorodifluoromethane < 0.043 mg/kg 0.043 0.14 1 8260B 1,2-Dichloroethane < 0.03 mg/kg 0.03 0.096 1 8260B 1,1-Dichloroethane < 0.025 mg/kg 0.025 0.079 1 8260B 1,1-Dichloroethene < 0.029 mg/kg 0.029 0.093 1 8260B 4/28/2015 CJR 2 7 cis-1,2-dichloroethene < 0.021 mg/kg 0.021 0.068 1 8260B trans-1,2-dichloroethene < 0.024 mg/kg 0.024 0.076 1 8260B 1,2-Dichloropropane < 0.025 mg/kg 0.025 0.078 1 8260B 2,2-Dichloropropane < 0.1 mg/kg 0.1 0.33 1 8260B 4/28/2015 CJR 8 1,3-Dichloropropane < 0.031 mg/kg 0.031 0.097 1 8260B Di-isopropyl ether < 0.012 mg/kg 0.012 0.04 1 8260B EDB (1,2-Dibromoethane) < 0.035 mg/kg 0.035 0.11 1 8260B Ethylbenzene < 0.027 mg/kg 0.027 0.086 1 8260B Hexachlorobutadiene < 0.11 mg/kg 0.11 0.36 1 8260B Isopropylbenzene < 0.037 mg/kg 0.037 0.12 1 8260B p-isopropyltoluene < 0.056 mg/kg 0.056 0.18 1 8260B WI DNR Lab Certification # 445037560 Page 5 of 6
ST. ANN CENTER 14643-002 E28829 5028829C SAE-10 4/23/2015 Methylene chloride < 0.22 mg/kg 0.22 0.7 1 8260B Methyl tert-butyl ether (MTBE) < 0.025 mg/kg 0.025 0.078 1 8260B Naphthalene < 0.087 mg/kg 0.087 0.28 1 8260B n-propylbenzene < 0.035 mg/kg 0.035 0.11 1 8260B 1,1,2,2-Tetrachloroethane < 0.013 mg/kg 0.013 0.04 1 8260B 1,1,1,2-Tetrachloroethane < 0.029 mg/kg 0.029 0.093 1 8260B Tetrachloroethene < 0.054 mg/kg 0.054 0.17 1 8260B Toluene < 0.031 mg/kg 0.031 0.099 1 8260B 1,2,4-Trichlorobenzene < 0.085 mg/kg 0.085 0.27 1 8260B 1,2,3-Trichlorobenzene < 0.12 mg/kg 0.12 0.38 1 8260B 1,1,1-Trichloroethane < 0.04 mg/kg 0.04 0.13 1 8260B 1,1,2-Trichloroethane < 0.033 mg/kg 0.033 0.11 1 8260B Trichloroethene (TCE) < 0.042 mg/kg 0.042 0.13 1 8260B Trichlorofluoromethane < 0.06 mg/kg 0.06 0.19 1 8260B 1,2,4-Trimethylbenzene < 0.078 mg/kg 0.078 0.25 1 8260B 1,3,5-Trimethylbenzene < 0.089 mg/kg 0.089 0.28 1 8260B Vinyl Chloride < 0.01 mg/kg 0.01 0.031 1 8260B m&p-xylene < 0.07 mg/kg 0.07 0.22 1 8260B o-xylene < 0.029 mg/kg 0.029 0.092 1 8260B SUR - Toluene-d8 106 Rec % 1 8260B SUR - 1,2-Dichloroethane-d4 90 Rec % 1 8260B SUR - 4-Bromofluorobenzene 98 Rec % 1 8260B SUR - Dibromofluoromethane 80 Rec % 1 8260B "J" Flag: Analyte detected between LOD and LOQ LOD Limit of Detection LOQ Limit of Quantitation Code 1 Comment Laboratory QC within limits. 2 Relative percent difference failed for laboratory spiked samples. 7 The LCS not within established limits. 8 Closing calibration standard not within established limits. All solid sample results reported on a dry weight basis unless otherwise indicated. All LOD's and LOQ's are adjusted for dilutions but not dry weight. Subcontracted results are denoted by SUB in the analyst field. Authorized Signature Michael Ricker WI DNR Lab Certification # 445037560 Page 6 of 6
Synergy Environmental Lab, INC. 1990 Prospect Ct., Appleton, WI 54914 *P 920-830-2455 * F 920-733-0631 DANIEL SCHWARTZ THE SIGMA GROUP, INC. 1300 W. CANAL STREET MILWAUKEE, WI 53233 Report Date 03-Aug-15 Project Name PARK WEST "D" REDEVELOPMENT 14643 5029366A GRAB 1 (1') 7/30/2015 E29366 Solids Percent 89.8 % 1 5021 7/31/2015 MDK 1 Acenaphthene < 0.0201 mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Acenaphthylene < 0.0198 mg/kg 0.0198 0.062 1 M8270C 7/31/2015 8/3/2015 MDK 1 Anthracene 0.11 mg/kg 0.0171 0.054 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)anthracene 0.41 mg/kg 0.0191 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)pyrene 0.41 mg/kg 0.0143 0.045 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(b)fluoranthene 0.61 mg/kg 0.019 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(g,h,i)perylene 0.32 mg/kg 0.02 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(k)fluoranthene 0.273 mg/kg 0.0174 0.055 1 M8270C 7/31/2015 8/3/2015 MDK 1 Chrysene 0.46 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Dibenzo(a,h)anthracene 0.051 ''J'' mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluoranthene 0.89 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluorene < 0.0184 mg/kg 0.0184 0.058 1 M8270C 7/31/2015 8/3/2015 MDK 1 Indeno(1,2,3-cd)pyrene 0.282 mg/kg 0.0165 0.052 1 M8270C 7/31/2015 8/3/2015 MDK 1 1-Methyl naphthalene < 0.0205 mg/kg 0.0205 0.065 1 M8270C 7/31/2015 8/3/2015 MDK 1 2-Methyl naphthalene < 0.0199 mg/kg 0.0199 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Naphthalene < 0.0203 mg/kg 0.0203 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Phenanthrene 0.31 mg/kg 0.0198 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Pyrene 0.75 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 WI DNR Lab Certification # 445037560 Page 1 of 3
PARK WEST "D" REDEVELOPMENT 14643 5029366B GRAB 2 (1') 7/30/2015 E29366 Solids Percent 91.0 % 1 5021 7/31/2015 MDK 1 Acenaphthene < 0.0201 mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Acenaphthylene < 0.0198 mg/kg 0.0198 0.062 1 M8270C 7/31/2015 8/3/2015 MDK 1 Anthracene 0.052 ''J'' mg/kg 0.0171 0.054 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)anthracene 0.176 mg/kg 0.0191 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)pyrene 0.187 mg/kg 0.0143 0.045 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(b)fluoranthene 0.284 mg/kg 0.019 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(g,h,i)perylene 0.147 mg/kg 0.02 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(k)fluoranthene 0.112 mg/kg 0.0174 0.055 1 M8270C 7/31/2015 8/3/2015 MDK 1 Chrysene 0.207 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Dibenzo(a,h)anthracene 0.0245 ''J'' mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluoranthene 0.37 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluorene < 0.0184 mg/kg 0.0184 0.058 1 M8270C 7/31/2015 8/3/2015 MDK 1 Indeno(1,2,3-cd)pyrene 0.123 mg/kg 0.0165 0.052 1 M8270C 7/31/2015 8/3/2015 MDK 1 1-Methyl naphthalene < 0.0205 mg/kg 0.0205 0.065 1 M8270C 7/31/2015 8/3/2015 MDK 1 2-Methyl naphthalene < 0.0199 mg/kg 0.0199 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Naphthalene < 0.0203 mg/kg 0.0203 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Phenanthrene 0.132 mg/kg 0.0198 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Pyrene 0.33 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 5029366C GRAB 3 (1') 7/30/2015 Solids Percent 90.8 % 1 5021 7/31/2015 MDK 1 Acenaphthene 0.50 mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Acenaphthylene 0.065 mg/kg 0.0198 0.062 1 M8270C 7/31/2015 8/3/2015 MDK 1 Anthracene 1.81 mg/kg 0.0171 0.054 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)anthracene 2.86 mg/kg 0.0191 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)pyrene 2.62 mg/kg 0.0143 0.045 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(b)fluoranthene 3.4 mg/kg 0.019 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(g,h,i)perylene 1.63 mg/kg 0.02 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(k)fluoranthene 1.81 mg/kg 0.0174 0.055 1 M8270C 7/31/2015 8/3/2015 MDK 1 Chrysene 2.55 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Dibenzo(a,h)anthracene 0.36 mg/kg 0.0201 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluoranthene 5.7 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 Fluorene 0.72 mg/kg 0.0184 0.058 1 M8270C 7/31/2015 8/3/2015 MDK 1 Indeno(1,2,3-cd)pyrene 1.48 mg/kg 0.0165 0.052 1 M8270C 7/31/2015 8/3/2015 MDK 1 1-Methyl naphthalene 0.054 ''J'' mg/kg 0.0205 0.065 1 M8270C 7/31/2015 8/3/2015 MDK 1 2-Methyl naphthalene 0.038 ''J'' mg/kg 0.0199 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Naphthalene 0.042 ''J'' mg/kg 0.0203 0.064 1 M8270C 7/31/2015 8/3/2015 MDK 1 Phenanthrene 3.2 mg/kg 0.0198 0.063 1 M8270C 7/31/2015 8/3/2015 MDK 1 Pyrene 4.5 mg/kg 0.0192 0.061 1 M8270C 7/31/2015 8/3/2015 MDK 1 WI DNR Lab Certification # 445037560 Page 2 of 3
PARK WEST "D" REDEVELOPMENT 14643 5029366D GRAB 4 (1') 7/30/2015 E29366 Solids Percent 84.9 % 1 5021 7/31/2015 MDK 1 Acenaphthene 2.48 mg/kg 0.201 0.64 10 M8270C 7/31/2015 8/3/2015 MDK 1 Acenaphthylene 0.32 ''J'' mg/kg 0.198 0.62 10 M8270C 7/31/2015 8/3/2015 MDK 1 Anthracene 8.5 mg/kg 0.171 0.54 10 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)anthracene 10.7 mg/kg 0.191 0.61 10 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(a)pyrene 9.4 mg/kg 0.143 0.45 10 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(b)fluoranthene 12.5 mg/kg 0.19 0.61 10 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(g,h,i)perylene 5.7 mg/kg 0.2 0.64 10 M8270C 7/31/2015 8/3/2015 MDK 1 Benzo(k)fluoranthene 5.9 mg/kg 0.174 0.55 10 M8270C 7/31/2015 8/3/2015 MDK 1 Chrysene 9.5 mg/kg 0.192 0.61 10 M8270C 7/31/2015 8/3/2015 MDK 1 Dibenzo(a,h)anthracene 1.15 mg/kg 0.201 0.64 10 M8270C 7/31/2015 8/3/2015 MDK 1 Fluoranthene 23.4 mg/kg 0.192 0.61 10 M8270C 7/31/2015 8/3/2015 MDK 1 Fluorene 3.8 mg/kg 0.184 0.58 10 M8270C 7/31/2015 8/3/2015 MDK 1 Indeno(1,2,3-cd)pyrene 5.1 mg/kg 0.165 0.52 10 M8270C 7/31/2015 8/3/2015 MDK 1 1-Methyl naphthalene 0.58 ''J'' mg/kg 0.205 0.65 10 M8270C 7/31/2015 8/3/2015 MDK 1 2-Methyl naphthalene 0.52 ''J'' mg/kg 0.199 0.63 10 M8270C 7/31/2015 8/3/2015 MDK 1 Naphthalene 0.95 mg/kg 0.203 0.64 10 M8270C 7/31/2015 8/3/2015 MDK 1 Phenanthrene 17.2 mg/kg 0.198 0.63 10 M8270C 7/31/2015 8/3/2015 MDK 1 Pyrene 18.3 mg/kg 0.192 0.61 10 M8270C 7/31/2015 8/3/2015 MDK 1 "J" Flag: Analyte detected between LOD and LOQ LOD Limit of Detection LOQ Limit of Quantitation Code Comment 1 Laboratory QC within limits. All solid sample results reported on a dry weight basis unless otherwise indicated. All LOD's and LOQ's are adjusted for dilutions but not dry weight. Subcontracted results are denoted by SUB in the analyst field. Authorized Signature Michael Ricker WI DNR Lab Certification # 445037560 Page 3 of 3
Site Investigation, Management, and Capping Plan PAH Impacted Areas, St. Ann Center for Intergenerational Care, 2450 West North Avenue, Milwaukee, Wisconsin, DNR BRRTS Activity #02-41-56425, DNR FID #341265210 APPENDIX B LABORATORY ANALYTICAL REPORT AND CHAIN OF CUSTODY DOCUMENTATION (STANTEC, 2015)