Date of issue: 03/12/2014 Revision date: 10/02/2015 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Pro-V Fill 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : For professional use only 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Manufacturer: Bisco, Inc. 1100 W Irving Park Road, Schaumburg, IL 60193 USA 1-847-534-6000, during normal business hours www.bisco.com EC Representative: Bisico France, 120, allée de la Coudoulette, 13680 Lançon de Provence, France Telephone: 33-4-90-42-92-92 1.4. Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Skin Irrit. 2 Eye Irrit. 2 H315 H319 Resp. Sens. 1 H334 Skin Sens. 1 STOT SE 3 H317 H335 Full text of H-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : : CHEMTREC - 24-Hour Hazmat Emergency Communications Center Domestic: 1-800-424-9300 Outside the U.S.: 1-703-527-3887, collect calls accepted Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) GHS07 : Irritant ; Sensitizer 10/02/2015 EN (English) 1/8 GHS08 : Glass filler, URETHANE ACRYLATE BLEND, Triethylene glycol dimethacrylate : H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 - May cause respiratory irritation : P264 - Wash hands thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P333+P313 - If skin irritation or rash occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention
P403+P233 - Store in a well-ventilated place. Keep container tightly closed P501 - Dispose in a safe manner in accordance with local/national regulations P270 - Do not eat, drink or smoke when using this product 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC Glass filler (CAS No) 65987-18-4 50-75 Xi; R36/37/38 URETHANE ACRYLATE BLEND (CAS No) Proprietary 10-30 Xi; R36/37/38 Triethylene glycol dimethacrylate (CAS No) 109-16-0 5-10 Xi; R36/37/38 R43 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Glass filler (CAS No) 65987-18-4 50-75 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 STOT SE 3, H335 URETHANE ACRYLATE BLEND (CAS No) Proprietary 10-30 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 STOT SE 3, H335 Triethylene glycol dimethacrylate (CAS No) 109-16-0 5-10 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 STOT SE 3, H335 Full text of R- and H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a poison center or a doctor. If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see First aid measures on this label). If skin irritation or rash occurs: : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. : Call a poison center or a doctor if you feel unwell. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation Symptoms/injuries after skin contact Symptoms/injuries after eye contact : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. : Irritation. Causes skin irritation. : Mild eye irritation. Causes eye irritation. Causes serious eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. 10/02/2015 EN (English) 2/8
SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Hazardous decomposition products in case of fire : : : 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Other information 6.4. Reference to other sections : Recover mechanically the product. On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Dispose of materials or solid residues at an authorized site. For further information refer to section 13. See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Ensure good ventilation of the work station. Avoid breathing mist, vapours. Avoid contact with skin and eyes. Wear personal protective equipment. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Use only outdoors or in a wellventilated area. : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Wash hands thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. : Store in a well-ventilated place. Keep cool. Keep container tightly closed. : Strong bases. Strong acids. : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Ensure good ventilation of the work station. : Avoid all unnecessary exposure. 10/02/2015 EN (English) 3/8
Hand protection Eye protection Skin and body protection Respiratory protection Environmental exposure controls Other information : Wear protective gloves : Safety glasses. Chemical goggles or safety glasses : Wear suitable protective clothing : Wear respiratory protection. In case of inadequate ventilation wear respiratory protection : Avoid release to the environment. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : Viscous Paste. Colour : tooth. Odour : acrylic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point : > 55 C Auto-ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density : > 1 Solubility Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity ---------- TO BE COMPLETED ---------- 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Glass filler (65987-18-4) LD50 oral rat 10/02/2015 EN (English) 4/8
Glass filler (65987-18-4) LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LC50 inhalation rat (Vapours - mg/l/4h) URETHANE ACRYLATE BLEND (Proprietary) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LC50 inhalation rat (Vapours - mg/l/4h) Triethylene glycol dimethacrylate (109-16-0) LD50 oral rat LD50 dermal rat LD50 dermal rabbit LC50 inhalation rat (ppm) LC50 inhalation rat (Dust/Mist - mg/l/4h) LC50 inhalation rat (Vapours - mg/l/4h) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 10837 mg/kg : Causes skin irritation. Causes skin irritation : Causes serious eye irritation. : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. : May cause respiratory irritation. Glass filler (65987-18-4) LOAEL (oral, rat) LOAEL (dermal, rat/rabbit) LOAEL (inhalation, rat, gas) LOAEL (inhalation, rat, vapour) LOAEL (inhalation, rat, dust/mist/fume) URETHANE ACRYLATE BLEND (Proprietary) LOAEL (oral, rat) LOAEL (dermal, rat/rabbit) LOAEL (inhalation, rat, gas) LOAEL (inhalation, rat, vapour) LOAEL (inhalation, rat, dust/mist/fume) Triethylene glycol dimethacrylate (109-16-0) LOAEL (oral, rat) LOAEL (dermal, rat/rabbit) LOAEL (inhalation, rat, gas) LOAEL (inhalation, rat, vapour) LOAEL (inhalation, rat, dust/mist/fume) Specific target organ toxicity (repeated exposure) Glass filler (65987-18-4) LOAEL (oral, rat, 90 days) LOAEL (dermal, rat/rabbit, 90 days) LOAEL (inhalation, rat, gas, 90 days) LOAEL (inhalation, rat, vapour, 90 days) LOAEL (inhalation, rat,dust/mist/fume, 90 days) mg/kg bodyweight mg/kg bodyweight ppmv/4h mg/kg bodyweight mg/kg bodyweight ppmv/4h mg/kg bodyweight mg/kg bodyweight ppmv/4h mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day 10/02/2015 EN (English) 5/8
URETHANE ACRYLATE BLEND (Proprietary) LOAEL (oral, rat, 90 days) LOAEL (dermal, rat/rabbit, 90 days) LOAEL (inhalation, rat, gas, 90 days) LOAEL (inhalation, rat, vapour, 90 days) LOAEL (inhalation, rat,dust/mist/fume, 90 days) Triethylene glycol dimethacrylate (109-16-0) LOAEL (oral, rat, 90 days) LOAEL (dermal, rat/rabbit, 90 days) LOAEL (inhalation, rat, gas, 90 days) LOAEL (inhalation, rat, vapour, 90 days) LOAEL (inhalation, rat,dust/mist/fume, 90 days) Aspiration hazard Potential adverse human health effects and symptoms mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day mg/kg bodyweight/day mg/kg bodyweight/day ppmv/6h/day mg/l/6h/day mg/l/6h/day :. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 12.2. Persistence and degradability Pro-V Fill Persistence and degradability 12.3. Bioaccumulative potential Pro-V Fill Bioaccumulative potential Not established. Not established. 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects Additional information : Avoid release to the environment SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not regulated for transport 14.2. UN proper shipping name Proper Shipping Name (ADR) Proper Shipping Name (IMDG) Proper Shipping Name (IATA) Proper Shipping Name (ADN) Proper Shipping Name (RID) 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) IMDG Transport hazard class(es) (IMDG) 10/02/2015 EN (English) 6/8
IATA Transport hazard class(es) (IATA) ADN Transport hazard class(es) (ADN) RID Transport hazard class(es) (RID) 14.4. Packing group Packing group (ADR) Packing group (IMDG) Packing group (IATA) Packing group (ADN) Packing group (RID) 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : No supplementary information available 14.6. Special precautions for user 14.6.1. Overland transport 14.6.2. Transport by sea 14.6.3. Air transport 14.6.4. Inland waterway transport Not subject to ADN 14.6.5. Rail transport Carriage prohibited (RID) : No : No 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations Contains no substances with Annex XVII restrictions Pro-V Fill is not on the REACH Candidate List Contains no substance on the REACH candidate list Contains no REACH Annex XIV substances. 15.1.2. National regulations Germany Water hazard class (WGK) : 3 - strongly hazardous to water 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Other information Data sources Other information : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of R-, H- and EUH-phrases: Eye Irrit. 2 Serious eye damage/eye irritation, Category 2 Resp. Sens. 1 Sensitisation Respiratory, category 1 10/02/2015 EN (English) 7/8
Skin Irrit. 2 Skin corrosion/irritation, Category 2 Skin Sens. 1 Sensitisation Skin, category 1 STOT SE 3 Specific target organ toxicity Single exposure, Category 3, Respiratory tract irritation H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H334 H335 R36/37/38 R43 Xi May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Irritating to eyes, respiratory system and skin May cause sensitisation by skin contact Irritant SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 10/02/2015 EN (English) 8/8